scholarly journals Technical Study of the Paint Layers from Buddhist Sculptures Unearthed from the Longxing Temple Site in Qingzhou, China

Heritage ◽  
2021 ◽  
Vol 4 (4) ◽  
pp. 2599-2622
Author(s):  
Yan Song ◽  
Linlin Zhou ◽  
Yunpeng Wang ◽  
Fangzhi Liu ◽  
Juwen Guo ◽  
...  

In 1996, more than four hundred Buddhist statues were excavated from the Hoard of Longxing Temple site in Qingzhou, Shandong Province, China. They are of great significance in the study of Buddhism history during the Northern and Southern Dynasties of China, and have attracted widespread attention since they were unearthed. In this paper, the paint layers from 14 of the Buddhist statues unearthed from the Longxing Temple site were analyzed using portable 3D microscopy, Raman spectroscopy and X-ray fluorescence spectroscopy was used to determine the materials used in their production. Several microscopic samples were analyzed in the laboratory using scanning electron microscopy/energy dispersive spectrometer, X-ray diffraction and micro-Raman spectroscopy. The combined results from the field and laboratory analyses materials used in painting layers of these statues were identified, and the technique for the production of the sculptures was studied. After the stone sculpture of Buddha was finished, a priming layer of lead white was applied over the stone body as a ground, over which pigments were applied. These include mineral pigments (cinnabar, malachite, lapis lazuli and cerussite), Chinese ink (carbon black) and gold leaf. Cinnabar was used for the outer garments, the halos and ornaments of Buddha and Bodhisattva statues; malachite, was found primarily on the Monk’s clothing; the blue pigment, lapis lazuli, was mainly used for the Buddha’s bun, halo and outer garment edges; carbon black ink was employed for drafting and sketching clothing and decorative patterns.

TANSO ◽  
2016 ◽  
Vol 2016 (274) ◽  
pp. 132-138 ◽  
Author(s):  
Kazuki Dewa ◽  
Kiminori Ono ◽  
Yoshiya Matsukawa ◽  
Kaname Takahashi ◽  
Yasuhiro Saito ◽  
...  

2021 ◽  
Author(s):  
Luciano Honorato Chagas ◽  
Sandra Shirley Ximeno Chiaro ◽  
Alexandre Amaral Leitão ◽  
Renata Diniz

This chapter covers a brief review of the definition, structural characteristics and main applications of hydrotalcite, an interesting multifunctional material which finds applicability in different areas. Particularly, some catalytic reactions using hydrotalcite or mixed oxides derived from these materials are addressed (Ethanol Steam Reforming, Photochemical conversions, Hydrodesulfurization). The use of Raman Spectroscopy associated with other techniques, such as powder X-ray diffraction (XRD), Extended X-ray Absorption Fine-Structure (EXAFS), Temperature Programmed Reduction of hydrogen (H2-TPR), Fourier-Transform Infrared (FTIR) and Density Functional Theory (DFT) simulations, to characterize this type of material is addressed through examples described in the current literature. In this sense, multidisciplinary efforts must be made in order to increase the understanding of the properties of these materials and the catalytic behavior in the most varied reactions.


2014 ◽  
Vol 70 (a1) ◽  
pp. C863-C863
Author(s):  
Sophie Cersoy ◽  
Pauline Martinetto ◽  
Pierre Bordet ◽  
Jean-Louis Hodeau ◽  
Philippe Walter ◽  
...  

Carbon black materials have been frequently used from prehistory as pigments for drawings and paintings and also as dyes, inks and cosmetics. If these material are easy to make by burning organic matter from animal or vegetal origin (e.g. peach black), they form carbonaceous phases, often ill-ordered, that can hardly be characterized [1]. This project is part of studies on archaeological cosmetics, shedding light on ancient manufacturing in physical-chemistry. Six black Roman micro samples found in vessels in Pompeii Houses were studied. To understand the composition of these complex, heterogeneous (mixture of organic/mineral, crystallized/amorphous phases) and precious black powders, a new methodology had to be developed. X-ray powder diffraction tomography enabled to locate the various phases (either crystallized or not) in virtual slices among which ill-ordered materials were analyzed using the Pair Distribution Function (PDF) [2]. X-ray diffraction data were recorded on D2AM beamline at ESRF on the samples and on reference modern carbon black powders purchased from pigments suppliers to help the interpretation of the diffuse signal. High Q data were acquired by scanning the 2D detector and using 25 keV X-rays. This enabled us to obtain well-resolved PDFs to study the amorphous carbonaceous phases contained in our samples (see figure). A comparison between archaeological samples and pure carbon black references was carried out after identification and quantitative analysis of the crystallized phases using Rietveld refinement. The proportion of crystallized phases versus ill-ordered carbonaceous ones was estimated on the PDFs using the maximization of Pearson product-moment correlation coefficients [3]. Results were confronted with those from Raman spectroscopy, known to account for the degree of disorder of non-graphitic carbons. The combination of both methods also provided specific information about the origin (plant, animal or mineral) of carbon black pigments.


Carbon ◽  
2017 ◽  
Vol 114 ◽  
pp. 749 ◽  
Author(s):  
Kazuki Dewa ◽  
Kiminori Ono ◽  
Yoshiya Matsukawa ◽  
Kaname Takahashi ◽  
Yasuhiro Saito ◽  
...  

2005 ◽  
Vol 126 ◽  
pp. 101-105 ◽  
Author(s):  
B. Moulin ◽  
L. Hennet ◽  
D. Thiaudière ◽  
P. Melin ◽  
P. Simon

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1085
Author(s):  
Patricia Castaño-Rivera ◽  
Isabel Calle-Holguín ◽  
Johanna Castaño ◽  
Gustavo Cabrera-Barjas ◽  
Karen Galvez-Garrido ◽  
...  

Organoclay nanoparticles (Cloisite® C10A, Cloisite® C15) and their combination with carbon black (N330) were studied as fillers in chloroprene/natural/butadiene rubber blends to prepare nanocomposites. The effect of filler type and load on the physical mechanical properties of nanocomposites was determined and correlated with its structure, compatibility and cure properties using Fourier Transformed Infrared (FT-IR), X-ray Diffraction (XRD), Thermogravimetric Analysis (TGA) and rheometric analysis. Physical mechanical properties were improved by organoclays at 5–7 phr. Nanocomposites with organoclays exhibited a remarkable increase up to 46% in abrasion resistance. The improvement in properties was attributed to good organoclay dispersion in the rubber matrix and to the compatibility between them and the chloroprene rubber. Carbon black at a 40 phr load was not the optimal concentration to interact with organoclays. The present study confirmed that organoclays can be a reinforcing filler for high performance applications in rubber nanocomposites.


Minerals ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 533 ◽  
Author(s):  
Xin Zhang ◽  
Guanghui Li ◽  
Jinxiang You ◽  
Jian Wang ◽  
Jun Luo ◽  
...  

Ludwigite ore is a typical low-grade boron ore accounting for 58.5% boron resource of China, which is mainly composed of magnetite, lizardite and szaibelyite. During soda-ash roasting of ludwigite ore, the presence of lizardite hinders the selective activation of boron. In this work, lizardite and szaibelyite were prepared and their soda-ash roasting behaviors were investigated using thermogravimetric-differential scanning calorimetry (TG-DSC), X-ray diffraction (XRD), and scanning electron microscope and energy dispersive spectrometer (SEM-EDS) analyses, in order to shed light on the soda-ash activation of boron within ludwigite ore. Thermodynamics of Na2CO3-MgSiO3-Mg2SiO4-Mg2B2O5 via FactSage show that the formation of Na2MgSiO4 was preferential for the reaction between Na2CO3 and MgSiO3/Mg2SiO4. While, regarding the reaction between Na2CO3 and Mg2B2O5, the formation of NaBO2 was foremost. Raising temperature was beneficial for the soda-ash roasting of lizardite and szaibelyite. At a temperature lower than the melting of sodium carbonate (851 °C), the soda-ash roasting of szaibelyite was faster than that of lizardite. Moreover, the melting of sodium carbonate accelerated the reaction between lizardite with sodium carbonate.


2009 ◽  
Vol 2009 ◽  
pp. 1-4 ◽  
Author(s):  
L. Bourja ◽  
B. Bakiz ◽  
A. Benlhachemi ◽  
M. Ezahri ◽  
J. C. Valmalette ◽  
...  

A series of ceramics samples belonging to theCeO2-Bi2O3phase system have been prepared via a coprecipitation route. The crystallized phases were obtained by heating the solid precursors at600∘Cfor 6 hours, then quenching the samples. X-ray diffraction analyses show that forx<0.20a solid solutionCe1−xBixO2−x/2with fluorine structure is formed. For x ranging between 0.25 and 0.7, a tetragonalβ′phase coexisting with the FCC solid solution is observed. For x ranging between 0.8 and 0.9, a new tetragonalβphase appears. Theβ′phase is postulated to be a superstructure of theβphase. Finally, close tox=1, the classical monoclinicα Bi2O3structure is observed. Raman spectroscopy confirms the existence of the phase changes as x varies between 0 and 1.


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