scholarly journals An Archaeometric Investigation of Gems and Glass Beads Decorating the Double-Arm Reliquary Cross from Liège, Belgium

Heritage ◽  
2021 ◽  
Vol 4 (4) ◽  
pp. 4542-4557
Author(s):  
Yannick Bruni ◽  
Frédéric Hatert ◽  
Merry Demaude ◽  
Nicolas Delmelle ◽  
Philippe George ◽  
...  

In 1914, a magnificent reliquary cross dating from the early XIIIth century was discovered in a safe from the Liège Cathedral. This double-arm cross shows a wooden structure, covered by gold-coated copper on the front, and by carved silver plates on the back. Its total length is 34 cm, and it is covered by filigrees, gems, glass beads, and pearls on its front. The reliquary cross was analysed by Raman spectrometry and X-ray fluorescence spectrometry (pXRF) to determine the mineralogical and chemical compositions of gems, glass beads, and metals that have been used to decorate it. The results confirm the identification of twenty-five turquoises from Egypt, one garnet from Sri Lanka, as well as six quartz and one opal whose origin is difficult to certify. Twelve glass beads, showing green, blue, or amber tints, were also identified. Their compositions either correspond to soda lime glasses with natron or to potash–lead glasses similar to those of Central Europe. Moreover, a small polished red cross and a green stone appear to be constituted by nice doublets, composed of coloured glass covered by quartz. The filigrees contain Au and Cu, while carved plates covering the edges and the back of the cross are made of silver.

2020 ◽  
Vol 8 (1) ◽  
Author(s):  
Dong Wang ◽  
Rui Wen ◽  
Julian Henderson ◽  
Xingjun Hu ◽  
Wenying Li

AbstractThe Hetian Bizili site in Lop County, located on the southern route of the Silk Road in Xinjiang, China, was a trade and cultural hub between the East and the West in ancient times. In 2016, a large number of glass beads were unearthed from the 40 tombs excavated on this site. In this study we determined the chemical compositions and manufacturing technology of bodies and decorations of twelve glass beads from the M5 tomb of Bizili by using LA-ICP-AES, EDXRF, Raman Spectrometry, and SR-μCT. The chemical compositions of the beads were all Na2O–CaO–SiO2, with plant ash mainly used as a flux. Lead antimonate and lead stannate were used as the opacifying agents. We detected elevated levels of boron and high levels of phosphorus in some beads: this is discussed in the context of the type of flux used and the possible use of a P-rich opacifier. Some of the beads with high contents of aluminum may potentially come from Pakistan. In terms of manufacturing technology, the craftsmen made ‘eye’ beads in different ways and also trail decorated beads.


2020 ◽  
Author(s):  
Dong Wang ◽  
Rui Wen ◽  
Xingjun Hu ◽  
Wenying Li

Abstract The Hetian Bizili site of the Lop County, located in the southern route of the Silk Road in the Xinjiang, China, was a trade and cultural hub between the East and the West in ancient times. In 2016, a large number of glass beads were unearthed from the 40 tombs excavated in this site. This study analyzed the chemical composition and manufacturing technology of twelve glass beads from the M5 tomb of the Bizili site by using various analytical techniques such as LA-ICP-AES, EDXRF, Raman Spectrometry, and SR-μCT. The chemical compositions of the beads were all Na 2 O-CaO-SiO 2 , with plant ash and natron as fluxes. The lead antimonite and lead stannate were applied as the opacifying agents. Some of the beads with high contents of aluminum may potentially come from Ancient India. In terms of manufacturing technology, the craftsmen made eyeballs of glass beads in different ways, and even applied the same process as Etched Carnelian beads in some beads. This study confirmed that Bizili was an essential place for the interactions between the East and the West and provided the foundation for the spreading of glass beads.


2020 ◽  
Author(s):  
Dong Wang ◽  
Rui Wen ◽  
Xingjun Hu ◽  
Wenying Li

Abstract The Hetian Bizili site of the Lop County, located in the southern route of the Silk Road in Xinjiang, China, was a trade and cultural hub between the East and the West in ancient times. In 2016, a large number of glass beads were unearthed from the 40 tombs excavated on this site. This study analyzed the chemical composition and manufacturing technology of twelve glass beads from the M5 tomb of the Bizili site by using various analytical techniques such as LA-ICP-AES, EDXRF, Raman Spectrometry, and SR-μCT. The chemical compositions of the beads were all Na 2 O-CaO-SiO 2 , with plant ash and natron as fluxes. The lead antimonite and lead stannate were applied as the opacifying agents. Some of the beads with high contents of aluminum may potentially come from Ancient India. In terms of manufacturing technology, the craftsmen made eyeballs of glass beads in different ways and even applied the same process as Etched Carnelian beads in some beads. This study confirmed that Bizili was an essential place for the interactions between the East and the West and provided the foundation for the spreading of glass beads.


2000 ◽  
Vol 49 (5) ◽  
pp. 297-306 ◽  
Author(s):  
Hideo ASAKURA ◽  
Katsushige IKEGAMI ◽  
Yasujiro YAMADA ◽  
Hisanobu WAKITA

2018 ◽  
Vol 766 ◽  
pp. 139-144
Author(s):  
Patiphan Nakkam ◽  
Napat Chantaramee

Feasibility of producing glass-ceramics from cullet, eggshell and perlite was investigated. In this study, a nucleating agent was synthesized from calcined eggshell and expanded perlite prior to blend with soda-lime waste glass, and then sintered at temperatures ranging from 850 to 1050°C at a heating rate of 10°C/min for 30 - 180 minutes. The crystallization behavior of glass-ceramics was investigated by means of X-ray diffraction analysis and surface morphology, and the chemical compositions were evaluated by scanning electron microscopy and energy dispersive X-ray spectroscopy. Results showed that crystalline phase embedded in the glass phase were needle-like crystal of wollastonite, cristobalite and quartz. According to the chemical resistance test, the obtained glass-ceramics showed acceptable corrosion resistance particularly in acidic environment. The weight loss for glass-ceramics immersed in 1wt% of sodium hydroxide solution was 0.28 - 0.50 wt%, while weight loss due to 1vol% of sulfuric acid solution was 0.04 - 0.16 wt%.


2000 ◽  
Vol 49 (10) ◽  
pp. 735-744
Author(s):  
Hideo ASAKURA ◽  
Katsushige IKEGAMI ◽  
Yukari NAKAI ◽  
Hisanobu WAKITA

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Piotr Łuczkiewicz ◽  
Małgorzata Daszkiewicz ◽  
Aneta Kuzioła ◽  
Jörg Kleemann ◽  
Oliver Mecking ◽  
...  

Abstract The cemetery at Malbork-Wielbark, Pomeranian voivodship, northern Poland, was in use from phase A1 of the Late Pre-Roman Iron Age (end of the 3rd/beginning of the 2nd century AD) to the early Migration Period (phase D1 – beginning of the 5th century AD). To date over 2,000 cremation and inhumation burials have been excavated at this site, yielding at least 3,500 glass beads. They appear mainly in inhumation graves from the early and late Roman Period and the early phase of the Migration Period (phases C1b–C3–D1), and at that time they were deposited in about 40 % of the graves in this cemetery. They are rarely found in cremation graves, and when they do appear it is usually in assemblages of later date. The number of beads in cremation graves throughout the lifespan of the necropolis was usually limited to just one or no more than a few. There is no clear correlation between the presence of glass beads in graves (cremation and inhumation) and the ‘quality’ of the grave goods, and therefore the status of the deceased. Beads (in varying numbers) appear sometimes in poor burials of various date, where they constitute the only (or almost only) grave goods. In theory, graves with more burial goods should contain a correspondingly greater number of beads, but there are many exceptions to this rule. Extensive, multi-element necklaces were one of the characteristic features of dress during the so-called “Wielbark Baroque” (phase B2/C1–C1a). In Malbork-Wielbark, such prestigious necklaces, with numerous glass beads, appear mainly in richly furnished burials from phase C of the Roman Period. In some really rich graves, however, the presence of beads seems to be reduced to a symbolic minimum. Anthropological analyses could be performed for 25 bead-bearing burials of the 41 excavated during 2008–2018. The results seem to suggest no relationship between the age of the individual, the type of burial rite and the variation in the number of beads in the grave. However, it is interesting that a relatively large proportion of the graves with a greater range of glass ornaments and items of dress were burials representing the infans I and infans II age groups. The selected beads were subjected to various laboratory analyses, examining both the morphology of the materials, based on surface observation with a scanning electron microscope (SEM), and their chemical composition. The chemical composition of all beads submitted for analysis was determined using the Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) technique. This analysis was performed for each colour in the case of multicoloured beads. A total of 43 glasses were analysed, including 18 single-colour beads and 25 analyses of variously coloured glasses taken from eight multicoloured beads. Additionally, some samples were analysed using an energy-dispersive X-ray spectroscopy (EDS) microanalysis system fitted with SEM, and for some the chemical composition was determined by wavelength-dispersive X-ray fluorescence (WD-XRF). The obtained results showed that all analysed samples represent soda-lime-silica glass (SLS glass), the majority of these samples having been made using a natural soda (natron). Due to the low content of Mg and K, they are referred to as LMLK glass. This means that, taking into account the results of the analysis, the majority of the analysed beads are consistent with glass beads produced in the Roman tradition. Only five of the 43 glass samples represent types of soda-lime-silica glass using plant ash as the flux. Due to the high content of Mg and K they are referred to as HMHK glasses. The individual glasses used in each bead came not from one but from various glass-melting factories. There is virtually no correlation between the type/ variety of glass and the dating of the graves in which the beads were deposited.


1971 ◽  
Vol 28 (3) ◽  
pp. 369-377 ◽  
Author(s):  
J. R. Calaprice

The chemical composition of samples of fry and adult sockeye salmon (Oncorhynchus nerka) collected in different areas was characterized by X-ray fluorescence spectrometry. Multivariate analysis of the spectra indicate that fish taken from an area possess recognizably distinct chemical compositions. Discriminant functions computed using spectral data were used to classify unknowns successfully. The relative similarity of groups characterized by fluorescence spectrometry is shown by canonical analysis and the nature of the chemical differences is discussed. The results indicate that these aquatic organisms possess a chemoprint, a form of natural tag.


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