scholarly journals Fertility Deterioration in a Remediated Petroleum-Contaminated Soil

Author(s):  
Verónica Isidra Domínguez-Rodríguez ◽  
Randy H. Adams ◽  
Mariloli Vargas-Almeida ◽  
Joel Zavala-Cruz ◽  
Enrique Romero-Frasca

A soil that had been remediated by soil washing and chemical oxidation was evaluated, comparing it to an uncontaminated control soil ~30 m away. Profile descriptions were made of both soils over a 0–1 m depth, and samples were analyzed from each soil horizon. Samples were also analyzed from surface soil (0–30 cm). The control soil (a Fluvisol), had several unaltered A and C horizons, but the remediated soil presented only two poorly differentiated horizons, without structure and much lower in organic matter (<0.5%). In surface samples (0–30 cm), the bulk density, sand-silt-clay contents, field capacity, organic matter, and porosity were different with respect to the control (p > 0.05), and there was much greater compaction (3.04 vs. 1.10 MPa). However, the hydrocarbon concentration in the remediated soil was low (969.12 mg kg−1, average), and was not correlated to soil fertility parameters, such as porosity, organic matter, pH, moisture, field capacity or texture (R2 < 0.69), indicating that the impacts (such as compaction, lower field capacity and moisture content) were not due to residual hydrocarbons. Likewise, acute toxicity (Microtox) was not found, nor water repellency (penetration time < 5 s). It was concluded that the fertility deterioration in this soil was caused principally from the mixture of upper (loam) and lower (silty clay to silty clay loam) horizons during remediation treatment. Another important factor was the reduction in organic material, probably caused by the chemical oxidation treatment.

2018 ◽  
Vol 66 (3) ◽  
pp. 271-278 ◽  
Author(s):  
Nasrollah Sepehrnia ◽  
Olga Fishkis ◽  
Bernd Huwe ◽  
Jörg Bachmann

AbstractThe coupled transport of pollutants that are adsorbed to colloidal particles has always been a major topic for environmental sciences due to many unfavorable effects on soils and groundwater. This laboratory column study was conducted under saturated moisture conditions to compare the hydrophobic character of the suspended and mobilized colloids in the percolates released from a wettable subsoil and a water repellent topsoil. Both soils with different organic matter content were analyzed for wettability changes before and after leaching using sessile drop contact angles as well as water and ethanol sorptivity curves, summarized as repellency index. Hydrophobicity of the effluent suspensions was assessed using the C18 adsorption method. Water repellency level of the repellent soil decreased after leaching but remained on a lower level of water repellency, while, the wettable soil remained wettable. The leached colloids from the repellent soil were predominantly hydrophilic and the percentage of the hydrophobic colloid fraction in the effluent did not systematically changed with time. Total colloid release depended on soil carbon stock but not on soil wettability. Our results suggest that due to the respective character of transported colloids a similar co-transport mechanism for pollutants may occur which does not depend explicitly on soil wettability of the releasing horizon, but could be more affected by total SOM content. Further studies with a wider range of soils are necessary to determine if the dominant hydrophilic character of leached colloids is typical. Due to the mostly hydrophilic colloid character we conclude also that changes in wettability status, i.e. of wettable subsoil horizons due to the leachate, may not necessarily occur very fast, even when the overlaying topsoil is a repellent soil horizon with a high organic matter content.


Forests ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 24 ◽  
Author(s):  
Wojciech Piaszczyk ◽  
Jarosław Lasota ◽  
Ewa Błońska

The wood of dead trees is an essential element of the forest ecosystem, as it affects the characteristics of forest soil properties. The present study aimed to determine the influence of dead alder and aspen wood in various stages of decomposition on the physical properties of forest soil. The study was carried out in the area of the Czarna Rózga reserve in central Poland. Alder and aspen logs in third, fourth, and fifth decay classes were selected for the study. Wood and soil samples under the direct influence of wood and soil samples without the influence of deadwood were collected for laboratory analyses. Physical properties of the soil samples, such as bulk density, moisture, porosity, field capacity, and air capacity were analyzed. Water repellency (WR) was also determined. Our study confirmed that decomposing wood influenced the physical properties of forest soil. Organic matter released from decomposing wood penetrates the soil and alters its physical properties. By releasing organic matter from deadwood, it is possible to stimulate the formation of soil aggregates, improve soil porosity, and significantly increase the number of micropores, which results in the retention of more water in the soil.


Weed Science ◽  
1973 ◽  
Vol 21 (5) ◽  
pp. 451-454 ◽  
Author(s):  
B. A. Kratky ◽  
G. F. Warren

The phytotoxicity of terbacil (3-tert-butyl-5-chloro-6-methyluracil) is not closely correlated with the amount applied, the amount in available soil solution, or the concentration in available soil solution since soil type has a pronounced effect on the levels necessary for phytotoxicity. About 19 times more terbacil was needed in a Chalmers silty clay loam (24% organic matter) than in a Bloomfield fine sand (0.3% organic matter) to cause a 30% control of sorghum (Sorghum biclor(L.) Moench ‘R.S. 610’). However, the Bloomfield fine sand required twice as great a concentration of terbacil in the soil solution as the Chalmers silty clay loam (0.314 μg/ml versus 0.157 μg/ml). The total adsorption of terbacil in the latter soil decreased 4.5 fold when the water: soil ratio was increased from 0.6:1 (approximately field capacity) to 32:1, but the ratio of the concentration adsorbed: concentration in the soil solution did not vary appreciably.


2005 ◽  
Vol 35 (9) ◽  
pp. 2178-2187 ◽  
Author(s):  
J C Neff ◽  
J W Harden ◽  
G Gleixner

Boreal ecosystems contain a substantial fraction of the earth's soil carbon stores and are prone to frequent and severe wildfires. In this study, we examine changes in element and organic matter stocks due to a 1999 wildfire in Alaska. One year after the wildfire, burned soils contained between 1071 and 1420 g/m2 less carbon than unburned soils. Burned soils had lower nitrogen than unburned soils, higher calcium, and nearly unchanged potassium, magnesium, and phosphorus stocks. Burned surface soils tended to have higher concentrations of noncombustible elements such as calcium, potassium, magnesium, and phosphorus compared with unburned soils. Combustion losses of carbon were mostly limited to surface dead moss and fibric horizons, with no change in the underlying mineral horizons. Burning caused significant changes in soil organic matter structure, with a 12% higher ratio of carbon to combustible organic matter in surface burned horizons compared with unburned horizons. Pyrolysis gas chromatography – mass spectroscopy also shows preferential volatilization of polysaccharide-derived organic matter and enrichment of lignin- and lipid-derived compounds in surface soils. The chemistry of deeper soil layers in burned and unburned sites was similar, suggesting that immediate fire impacts were restricted to the surface soil horizon.


2013 ◽  
Vol 22 (4) ◽  
pp. 515 ◽  
Author(s):  
Naama Tessler ◽  
Lea Wittenberg ◽  
Noam Greenbaum

Variations in forest fires regime affect: (1) the natural patterns of community structure and vegetation; (2) the physico-chemical properties of soils and consequently (3) runoff, erosion and sediment yield. In recent decades the Mediterranean ecosystem of Mount Carmel, north-western Israel, is subjected to an increasing number of forest fires, thus, the objectives of the study were to evaluate the long-term effects of single and recurrent fires on soil water repellency (WR) and organic matter (OM) content. Water repellency was studied by applying water drop penetration time (WDPT) tests at sites burnt by single-fire, two fires, three fires and unburnt control sites. Water repellency in the burnt sites was significantly lower than in the unburnt control sites, and the soil maintained its wettability for more than 2 decades, whereas after recurrent fires, the rehabilitation was more complicated and protracted. The OM content was significantly lower after recurrent than after a single fire, causing a clear proportional decrease in WR. The rehabilitation of WR to natural values is highly dependent on restoration of organic matter and revegetation. Recurrent fires may cause a delay in recovery and reduced productivity of the soil for a long period.


2014 ◽  
Vol 27 (5) ◽  
pp. 1413-1423 ◽  
Author(s):  
Nicasio T. Jiménez‐Morillo ◽  
José A. González‐Pérez ◽  
Antonio Jordán ◽  
Lorena M. Zavala ◽  
José María Rosa ◽  
...  

2021 ◽  
Vol 9 (9) ◽  
pp. 1943
Author(s):  
Milan Varsadiya ◽  
Tim Urich ◽  
Gustaf Hugelius ◽  
Jiří Bárta

Permafrost-affected soil stores a significant amount of organic carbon. Identifying the biological constraints of soil organic matter transformation, e.g., the interaction of major soil microbial soil organic matter decomposers, is crucial for predicting carbon vulnerability in permafrost-affected soil. Fungi are important players in the decomposition of soil organic matter and often interact in various mutualistic relationships during this process. We investigated four different soil horizon types (including specific horizons of cryoturbated soil organic matter (cryoOM)) across different types of permafrost-affected soil in the Western Canadian Arctic, determined the composition of fungal communities by sequencing (Illumina MPS) the fungal internal transcribed spacer region, assigned fungal lifestyles, and by determining the co-occurrence of fungal network properties, identified the topological role of keystone fungal taxa. Compositional analysis revealed a significantly higher relative proportion of the litter saprotroph Lachnum and root-associated saprotroph Phialocephala in the topsoil and the ectomycorrhizal close-contact exploring Russula in cryoOM, whereas Sites 1 and 2 had a significantly higher mean proportion of plant pathogens and lichenized trophic modes. Co-occurrence network analysis revealed the lowest modularity and average path length, and highest clustering coefficient in cryoOM, which suggested a lower network resistance to environmental perturbation. Zi-Pi plot analysis suggested that some keystone taxa changed their role from generalist to specialist, depending on the specific horizon concerned, Cladophialophora in topsoil, saprotrophic Mortierella in cryoOM, and Penicillium in subsoil were classified as generalists for the respective horizons but specialists elsewhere. The litter saprotrophic taxon Cadophora finlandica played a role as a generalist in Site 1 and specialist in the rest of the sites. Overall, these results suggested that fungal communities within cryoOM were more susceptible to environmental change and some taxa may shift their role, which may lead to changes in carbon storage in permafrost-affected soil.


2021 ◽  
Author(s):  
Shane Stoner ◽  
Carlos Sierra ◽  
Marion Schrumpf ◽  
Sebastian Dötterl ◽  
Susan Trumbore

&lt;p&gt;Soil organic matter (SOM) is a complex collection of organic molecules of varying origin, structure, chemical activity, and mineral association. A wide array of laboratory methods exists to separate SOM based on qualitative, biological, chemical, and physical characteristics. However, all present conceptual and logistical limitations, including the requirement of a substantial amount soil material.&lt;/p&gt;&lt;p&gt;An newly applied alternative method of fractionation relies on a conceptual analogue between biochemical stability in soil and thermal stability, e.g. more persistent SOM will require higher temperatures (greater energy inputs) to decompose than less persistent SOM. This accounts for both chemical complexity and mineral association as main factors in determining SOM persistence.&lt;/p&gt;&lt;p&gt;In this method, carbon is released by heating SOM to 900&amp;#176;C at a constant rate. The peaks of carbon release are grouped into activation energy pools, CO&lt;sub&gt;2 &lt;/sub&gt;is collected, and analyzed for &lt;sup&gt;13&lt;/sup&gt;C and &lt;sup&gt;14&lt;/sup&gt;C. We seek to describe in finer detail the distribution of soil radiocarbon by adding another fractionation step following a different paradigm of SOM stability, and explore mineralogical effects on SOM quality and stability using thermal analysis, radiocarbon, and gas chromatography.&lt;/p&gt;&lt;p&gt;Here, we analyzed bulk soil and soil fractions derived from density separation and chemical oxidation, as well as mineral horizons dominated by diverse mineralogies. Density fractions contained a wide range of radiocarbon activities and that young SOM is stabilized across multiple fractions, likely due to organomineral complexation. Initial results showed that soil minerals with limited stabilization potential released C at lower temperatures than those with diverse stabilization mechanisms. High-temperature sub-fractions contained the oldest carbon across fractions and minerals, thus supporting the assumption that thermal stability can be used as a limited analogue for stability in soil. We present a fine-scale distribution of radiocarbon in SOM and discuss the potential of this method for comparison with other fractionation techniques.&lt;/p&gt;


Author(s):  
Muhammad Abbas AZIZ ◽  
Hamaad Raza AHMAD ◽  
Dennis L. CORWIN ◽  
Muhammad SABIR ◽  
Khalid Rehman HAKEEM ◽  
...  

Continuous irrigation of soils with untreated effluents can result in the accumulation and translocation of some metals in the soils and plants. Application of farmyard manure (FYM) to such soils may increase or decrease their availability and retention time. Calcareous soils contaminated with 100, 200, and 400mg kg–1 Ni, Zn, and Pb as chloride salts were used, and farmyard manure added (40g kg–1 for 90 days) with moisture contents at field capacity. Soil samples were drawn at 30 day intervals, and metals extracted with (AB-DTPA) C14H23NO3O10. With FYM application of 400 mg kg–1, Ni availability increased from 179 (day 30) to 240 mg kg–1(day 90); Zn from 163 (day 30) to 230 mg kg–1 (day 90), but, Pb decreased from 214 to 161 mg kg–1. FYM forms multi-dentate complex which greatly enhances the Ni and Zn solubility, and organic matter immobilizes Pb in the soil.


2008 ◽  
Vol 88 (1) ◽  
pp. 85-97 ◽  
Author(s):  
Hafida Zaher ◽  
Jean Caron

The slaking process after rapid wetting is a key factor controlling soil structural stability in dry soil, and an understanding of the relative importance of the different mechanisms involved in slaking may help in the design of management strategies aimed at maintaining a stable surface soil structure. Slaking has been linked to, among other factors, rapid pressure build-up in aggregate, and previous work has emphasized the role of organic matter to hamper that pressure build-up, possibly due to hydrophobicity, reducing rapid water entry within aggregates and hence the build-up. This study emphasizes this latter aspect linked to slaking. The evolution of the intra-aggregate pressure, the matter lost by slaking and the expelled air after rapid wetting of two soils of different textures (clay loam soil and silty-clay loam soil) amended with different types of paper sludge were studied. Hydrophobicity effects were also studied using a tensio-active solution. The results of these experiments showed that when aggregates were submitted to sudden wetting, those treated with paper sludge had an improved resistance to the destructive action of rapid wetting. The lower pressures measured in the aggregates from the amended soils and having less slaking resulted most likely from slow water entry and reduced swelling. Detailed investigation on the link between hydrophobicity and water entry revealed that the true hydrophobic effect (modification of contact angle) was non-existent for the silty-clay loam and minor for the clay loam. This study, rather, suggests that changes in the water potential at the wetting front following organic matter addition and aggregate immersion most likely depend on pore occlusion and on changes in pore surface roughness. Key words: Aggregate stability, organic matter, slaking, pressure, swelling, wettability


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