scholarly journals Effect of Carbon Nanotubes (CNT) Functionalization and Maleic Anhydride-Grafted Poly(trimethylene terephthalate) (PTT-g-MA) on the Preparation of Antistatic Packages of PTT/CNT Nanocomposites

2020 ◽  
Vol 4 (2) ◽  
pp. 44 ◽  
Author(s):  
Natália Ferreira Braga ◽  
Henrique Morales Zaggo ◽  
Larissa Stieven Montagna ◽  
Fabio Roberto Passador
Keyword(s):  
Carbon Nanotubes ◽  
Maleic Anhydride ◽  
Interfacial Adhesion ◽  
Morphological Analysis ◽  
Electrostatic Discharge ◽  
Electronic Devices ◽  
Tensile Tests ◽  
Extrusion Process ◽  
Agent Based ◽  
Trimethylene Terephthalate

Electronic devices require the use of antistatic packing to prevent electrostatic discharge during their storage or transport. Poly (trimethylene terephthalate) (PTT) is a polyester with excellent properties and can be a good candidate for this application. To make this insulating polymer an extrinsic conductor, carbon nanotubes (CNT) can be added to reduce the electrical resistivity of the nanocomposites. In order to facilitate the CNT distribution on polymeric matrix, it was proposed a chemical functionalization using nitric acid for the creation of functional groups on its surface. Moreover, the PTT matrix was modified with a compatibilizer agent based on maleic anhydride grafted PTT (PTT-g-MA), to improve interfacial adhesion between the nanofiller and matrix. In this work, nanocomposites based on PTT/PTT-g-MA/CNT were prepared by extrusion process, with 0.5 wt% and 1.0 wt% of CNT and functionalized CNT. CNT was characterized by stability dispersion in water, Raman spectroscopy, FTIR and XPS analysis, which prove the success of functionalization. The nanocomposites were evaluated by thermal analysis, tensile tests, electrical conductivity, and morphological analysis. The CNT functionalization and the addition of PTT-g-MA increased the dispersion and distribution of CNT in the PTT matrix. The electrical properties show that this material can be used as an antistatic packaging.

Mechanical and Morphology Properties of Polypropylene/ Nano-CaCO3 Composites

2013 ◽  
Vol 774-776 ◽  
pp. 625-628
Author(s):  
Teng Fei Shen ◽  
Fa Chao Wu
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Electron Microscope ◽  
Maleic Anhydride ◽  
Interfacial Adhesion ◽  
Tensile Tests ◽  
Melt Blending ◽  
Elongation At Break ◽  
High Fraction ◽  
Scanning Electron

To provide polypropylene (PP) with better excellent mechanical properties, nanoCaCO3 particles are incorporated into PP matrix by melt blending in this work. To improve the mophology between PP and nanoCaCO3, maleic-anhydride grafted PP (PP-g-MAH) was added as a compatibiliser. The results showed that PP-g-MAH indeed enhanced the interfacial adhesion of PP /nanoCaCO3 composites, which is demonstrated by the measurement of scanning electron microscope (SEM). The results of tensile tests revealed that the inclusion of nanoCaCO3 slightly increased modulus and decreased tensile strength and significantly increased the elongation at break. At high fraction of nanoCaCO3, the elongation at break was declined. The nanosized feature, shape and dispersion conditions of nanoCaCO3, played important roles in determining the performances of PP/nanoCaCO3 composites.

scholarly journals Electronic Textiles Fabricated with Graphene Oxide-Coated Commercial Textiles

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 489
Author(s):  
Hyun-Seok Jang ◽  
Min-Soo Moon ◽  
Byung-Hoon Kim
Keyword(s):  
Heat Treatment ◽  
Carbon Nanotubes ◽  
Graphene Oxide ◽  
Electronic Devices ◽  
Electronic Textiles ◽  
Axial Tension ◽  
Coated Cotton

Demand for wearable and portable electronic devices has increased, raising interest in electronic textiles (e-textiles). E-textiles have been produced using various materials including carbon nanotubes, graphene, and graphene oxide. Among the materials in this minireview, we introduce e-textiles fabricated with graphene oxide (GO) coating, using commercial textiles. GO-coated cotton, nylon, polyester, and silk are reported. The GO-coated commercial textiles were reduced chemically and thermally. The maximum e-textile conductivity of about 10 S/cm was achieved in GO-coated silk. We also introduce an e-textile made of uncoated silk. The silk-based e-textiles were obtained using a simple heat treatment with axial tension. The conductivity of the e-textiles was over 100 S/cm.

scholarly journals Functionalized Carbon Materials for Electronic Devices: A Review

Micromachines ◽  
2019 ◽  
Vol 10 (4) ◽  
pp. 234 ◽  
Author(s):  
Urooj Kamran ◽  
Young-Jung Heo ◽  
Ji Won Lee ◽  
Soo-Jin Park
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Materials ◽  
Electronic Devices ◽  
Pressure Sensors ◽  
Future Generation ◽  
High Specific Surface Area ◽  
Synthetic Methods ◽  
Energy Storage Devices ◽  
Self Powered ◽  
Walled Carbon Nanotubes

Carbon-based materials, including graphene, single walled carbon nanotubes (SWCNTs), and multi walled carbon nanotubes (MWCNTs), are very promising materials for developing future-generation electronic devices. Their efficient physical, chemical, and electrical properties, such as high conductivity, efficient thermal and electrochemical stability, and high specific surface area, enable them to fulfill the requirements of modern electronic industries. In this review article, we discuss the synthetic methods of different functionalized carbon materials based on graphene oxide (GO), SWCNTs, MWCNTs, carbon fibers (CFs), and activated carbon (AC). Furthermore, we highlight the recent developments and applications of functionalized carbon materials in energy storage devices (supercapacitors), inkjet printing appliances, self-powered automatic sensing devices (biosensors, gas sensors, pressure sensors), and stretchable/flexible wearable electronic devices.

Synthesis and Characterization of Poly(2,5-benzimidazole) (ABPBI) Grafted Carbon Nanotubes

2009 ◽  
Vol 1240 ◽  
Author(s):  
Ji-Ye Kang ◽  
Su-Mi Eo ◽  
Loon-Seng Tan ◽  
Jong-Beom Baek
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Interfacial Adhesion ◽  
Synthesis And Characterization ◽  
Acylation Reaction ◽  
Single Walled Carbon Nanotube ◽  
Mechanical And Electrical Properties ◽  
Multi Walled Carbon Nanotube

AbstractSingle-walled carbon nanotube (SWCNT) and multi-walled carbon nanotube (MWCNT) were functionalized with 3,4-diaminobenzoic acid via “direct” Friedel-Crafts acylation reaction in PPA/P2O5 to afford ortho-diamino-functionalized SWCNT (DIF-SWCNT) and MWCNT (DIF-MWCNT). The resultant DIF-SWCNT and DIF-MWCNT showed improved solubility and dispersibility. To improve interfacial adhesion between CNT and polymer matrix, the grafting of ABPBI onto the surface of DIF-SWCNT (10 wt%) or DIF-MWCNT (10 wt%) was conducted by simple in-situ polymerization of AB monomer, 3,4-diaminobenzoic acid dihydrochloride, in PPA. The resultant ABPBI-g-MWCNT and ABPBI-g-SWCNT showed improved the mechanical and electrical properties.

scholarly journals Optical Characterizations and Electronic Devices of Nearly Pure (10,5) Single-Walled Carbon Nanotubes

2009 ◽  
Vol 131 (7) ◽  
pp. 2454-2455 ◽  
Author(s):  
Li Zhang ◽  
Xiaomin Tu ◽  
Kevin Welsher ◽  
Xinran Wang ◽  
Ming Zheng ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electronic Devices ◽  
Single Walled Carbon Nanotubes ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

An Innovative Method to Reduce Percolation Threshold of Carbon Nanotubes Filled Nylon6/Polystyrene Blends

2012 ◽  
Vol 557-559 ◽  
pp. 654-658
Author(s):  
Chang Lu ◽  
Xin Hui Huang ◽  
Jia Xi Wang ◽  
Xiao Ning Hu
Keyword(s):  
Carbon Nanotubes ◽  
Maleic Anhydride ◽  
Percolation Threshold ◽  
Polymer Blend ◽  
Immiscible Polymer Blend ◽  
Innovative Method ◽  
Immiscible Polymer ◽  
Selective Localization

Selective localization of carbon nanotubes (CNTs) at the interface of immiscible polymer blend was achieved by the method that poly(styrene-co-maleic anhydride) (SMA) was first reacted with CNTs, and then blended with nylon6/polystyrene (PA6/PS). In the PA6/PS blends, CNTs was localized in PA6 phase and the percolation threshold was 2wt%. However, for the PA6/PS/(SMA- CNTs) composites, TEM results showed that most of CNTs were selectively localized in matrix, but some of tubes were induced by SMA to disperse at the interface. The localization of CNTs at the interface caused the percolation threshold of PA6/PS/(SMA- CNTs) was only 0.33 wt%, which is much lower than that of PA6/PS/ CNTs.

Effect of the addition of aliphatic diamine-functionalized carbon nanotubes on the interfacial adhesion of glass fiber/epoxy composites

2021 ◽  
pp. 004051752110519
Author(s):  
Yecheng Fan ◽  
Shen Ziyue ◽  
Shaohua Zeng ◽  
Pengpeng Chen ◽  
Ying Xu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Glass Fiber ◽  
Interfacial Adhesion ◽  
Control Sample ◽  
Epoxy Composites ◽  
Aliphatic Diamine ◽  
Uniform Dispersion ◽  
Fiber Matrix ◽  
Interlaminar Shear ◽  
Chain Lengths

To improve the interfacial adhesion of glass fiber (GF)/epoxy composites, the GF surface was treated by dispersing aliphatic diamine-functionalized multi-walled carbon nanotubes (MWCNTs). Carboxyl MWCNTs were first modified by aliphatic diamine with different alkyl chain lengths and then deposited on the surface of GF. The effect of aliphatic diamine chain lengths on the MWCNTs’ dispersion and interfacial properties of resultant composites was investigated in detail. The results showed that uniform dispersion of MWCNTs and strong fiber/matrix interfacial adhesion could be achieved, based on the grafting of 1,8-octanediamine onto MWCNTs. Compared with the control sample, the interlaminar shear, flexural, and tensile strengths of the treated composites increased by 41%, 29%, and 30%, respectively; the interlaminar fracture toughness and storage modulus in the glass region were significantly enhanced; and the glass transition temperature increased by more than 8°C. This work demonstrates that the carbon nanotubes functionalized by appropriate chain lengths of amine modifier can improve the fiber/matrix interfacial interactions and thus enhance the strength, toughness, and stiffness of fiber-reinforced composites.

THE STRENGTH OF NANOCOMPOSITES POLYMER / 2D-NANOFILLER WITH ULTRASMALL FILLER CONTENTS

2020 ◽  
pp. 3-6
Author(s):  
Gasan M. Magomedov ◽  
Guseyn M. Magomedov ◽  
I. V. Dolbin
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Fibers ◽  
Interfacial Adhesion ◽  
Fracture Process ◽  
Interfacial Strength ◽  
Geometrical Parameters ◽  
Correct Description ◽  
Two Phase ◽  
Small Aggregation ◽  
Appreciable Reduction

The theoretical model, using the notions of fractal analysis is proposed for description of strength of nanocomposites polymer/2D-nanofiller on the example of nanocomposites polyvinylalcohol/boron nitride. For correct description of strength of these two-phase nanomaterial the knowledge of initial characteristics of matrix polymer (stress of fracture), geometrical parameters of nanofiller and level of interfacial adhesion polymer matrix-nanofiller is necessary. The indicated level, characterizing by shear interfacial strength, was determined theoretically within the framework of fractal conception of adhesion. Its absolute values found high enough – they are comparable with this characteristic in systems polymer-carbon nanotubes and are higher essentially than in systems polymer-microfiber (glassy and carbon fibers). This factor defines high enough strength of the considered nanocomposites. The important factor for fracture process of nanomaterials is aggregation of initial platelets of nanofiller, which forms “packets” (tactoids) of such platelets. The relatively small aggregation degree of nanofiller gives appreciable reduction of strength of nanocomposites polymer/2D-nanofiller. The indicated reduction is connected with transition of 2D-nanofiller structure from exfoliated to intercalated one, i.e. from separate platelets to their tactoids.

scholarly journals The Adhesion and Diffusion of Saturate, Asphaltene, Resin and Aromatic (SARA) Molecules on Oxygenated and Hydrogenated Carbon Nanotubes (CNTs)

2021 ◽  
Vol 6 (9) ◽  
pp. 123
Author(s):  
Mehdi Shishehbor ◽  
Hadi S. Esmaeeli ◽  
M. Reza Pouranian
Keyword(s):  
Carbon Nanotubes ◽  
Interfacial Adhesion ◽  
Asphalt Binder ◽  
Adhesion Energy ◽  
Dynamics Simulation ◽  
Hydroxyl Groups ◽  
Reactive Molecular Dynamics ◽  
Cnts Surface ◽  
And Diffusion ◽  
Diffusion Properties

The interfacial adhesion between asphalt binder and carbon nanotubes (CNTs) depends on many nanoscopic properties such as diffusion of SARA molecules on CNTs surface. Functionalization of CNTs with Oxygens (O=CNTs), hydroxyl groups (HO–CNTs), and hydrogens (H–CNTs) has been an effective way to modify the surface properties of CNTs and ultimately the macroscopic properties of the CNT-composites. This paper presents the effect of different dosages of oxygenated and hydrogenated CNTs on the adhesion and diffusion of SARA molecules on CNTs’ surfaces. First, reactive molecular dynamics simulation is used to oxygenate and hydrogenate CNTs up to a certain dosage. Next, it is employed to model the interaction and diffusion of SARA molecules with the functionalized CNTs. We employ the steer molecular dynamic (SMD) and Einstein formula to calculate the adhesion and diffusion properties. The results demonstrate that hydrogenation has little effect on the adhesion energy, while oxygenation can increase adhesion energy up to 100% for 25% dosage. The diffusion coefficient dramatically drops for both oxygenated and hydrogenated CNTs, with lower values for the latter. We observe that for hydrogenated and oxygenated CNTs at different dosages, asphaltene, resin, aromatic, and saturate molecules have the highest to lowest values, respectively.

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