scholarly journals Anti-Gnawing, Thermo-Mechanical and Rheological Properties of Polyvinyl Chloride: Effect of Capsicum Oleoresin and Denatonium Benzoate

2021 ◽  
Vol 6 (1) ◽  
pp. 8
Author(s):  
Laongdaw Techawinyutham ◽  
Arnuparb Prasarnsri ◽  
Suchart Siengchin ◽  
Rapeephun Dangtungee ◽  
Sanjay Mavinkere Rangappa
Keyword(s):  
Weight Loss ◽  
Rheological Properties ◽  
Polyvinyl Chloride ◽  
Loss Modulus ◽  
Zinc Stearate ◽  
Toxic Substances ◽  
Elongation At Break ◽  
Denatonium Benzoate ◽  
Chloride Effect ◽  
Level Of Significance

Anti-rodent polymer composites were prepared using non-toxic substances denatonium benzoate (DB) and capsicum oleroresin (CO) mixed with polyvinyl chloride (PVC) matrix. DB is mixed in zinc stearate (ZnSt) called DB/ZnSt, and CO, providing burning sensation, is impregnated in mesoporous silica named SiCO. There are three sets of sample: Blank, composites Set I and Set II. Set I consists of DB/ZnSt at concentration of 1.96 wt% and SiCO at concentration of 12.16 wt%, 14.47 wt%, 18.75 wt% and 23.53 wt%. Set II comprises SiCO at the same amount of Set I. The anti-rodent composites studied are anti-gnawing, surface morphology, thermo-mechanical and rheological properties. Anti-rodent testing is analyzed by one-way blocked analysis of variance (ANOVA) and compared with Tukey test with a 95% level of significance, presenting good anti-gnawing efficiency. The best rat-proof sample is II.4, consisting of SiCO 23.53 wt%, which presents percentage of weight loss from gnawing at 1.68% compared to weight loss of neat PVC at 59.74%. The addition of SiCO at concentration ranging from 12.16 to 23.53 wt% reduces tensile strength around 25–50%, elongation at break strength around 2–23%, shear storage modulus (G′) around 30%, shear loss modulus (G″) shear viscosity (η) and glass transition (Tg) around 43% compared to Blank. The increase in SiCO concentration slightly improves the thermal stability of PVC composites around 3%, but the addition of DB/ZnSt at 1.96 wt% slightly reduces those properties.

Anti-Rodent Polymer Composites

2019 ◽  
Vol 818 ◽  
pp. 1-6 ◽  
Author(s):  
Laongdaw Techawinyutham ◽  
Rapeephun Dangtungee
Keyword(s):  
Weight Loss ◽  
Essential Oil ◽  
Polymer Composites ◽  
Polyvinyl Chloride ◽  
Polymer Matrix ◽  
Bitter Taste ◽  
Burning Sensation ◽  
Denatonium Benzoate ◽  
Internal Mixer

This study is to examine substances which can protect the polymer composites against gnawing from rodent. Polyvinyl chloride (PVC) compound acted as polymer matrix was mixed with anti-rodent substances in internal mixer. Several substances were added in PVC namely: denatonium benzoate (DB), capsaicum oleroresin (CO), deltamethrin (DM), caffeine, pepper, salt, wasabi and essential oil. There were 6 sets of anti-rodent samples. The percentage of weight loss of each sample was recorded and compared. The result showed the best repellent substances were DB and CO giving bitter taste and burning sensation to the rodent, respectively. The best anti-rodent composites are samples in set 6 consisting of DB at concentration of 1.961 wt% and SiCO at concentration of 12.162 to 23.529 wt%.

Electrical conductivity and rheological properties of carbon black based conductive polymer composites prior to and after annealing

2021 ◽  
pp. 096739112110012
Author(s):  
Qingsen Gao ◽  
Jingguang Liu ◽  
Xianhu Liu
Keyword(s):  
Electrical Conductivity ◽  
Carbon Black ◽  
Percolation Threshold ◽  
Rheological Properties ◽  
Network Formation ◽  
Loss Modulus ◽  
Conductive Polymer ◽  
Complex Viscosity ◽  
Electrical Percolation ◽  
Electrical Percolation Threshold

The effect of annealing on the electrical and rheological properties of polymer (poly (methyl methacrylate) (PMMA) and polystyrene (PS)) composites filled with carbon black (CB) was investigated. For a composite with CB content near the electrical percolation threshold, the formation of conductive pathways during annealing has a significant impact on electrical conductivity, complex viscosity, storage modulus and loss modulus. For the annealed samples, a reduction in the electrical and rheological percolation threshold was observed. Moreover, a simple model is proposed to explain these behaviors. This finding emphasizes the differences in network formation with respect to electrical or rheological properties as both properties belong to different physical origins.

Impact of high-pressure homogenization on the microstructure and rheological properties of citrus fiber

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Dianbin Su ◽  
Xin-Di Zhu ◽  
Yong Wang ◽  
Dong Li ◽  
Li-Jun Wang
Keyword(s):  
Particle Size ◽  
High Pressure ◽  
Rheological Properties ◽  
Binding Capacity ◽  
Loss Modulus ◽  
High Pressure Homogenization ◽  
Carreau Model ◽  
Hydration Properties ◽  
Water Binding ◽  
Water Holding

Abstract Citrus fiber dispersion with different concentrations (5–25 g/kg) was treated by high-pressure homogenization (90 and 160 MPa) for two cycles. The particle size distribution, hydration properties of powders, morphology and rheological measurements were carried out to study the microstructure and rheological properties changes by high-pressure homogenization (HPH). In conclusion, the HPH can reduce the particle size of fiber, improve the water holding capacity and water binding capacity. Furthermore, fiber shape can be modified from globular cluster to flake-like slices, and tiny pores can be formed on the surface of citrus fiber. The apparent viscosity, storage modulus and loss modulus were increased by HPH whereas the activation energy was reduced. The Hershcel–Bulkley model, Carreau model and Power Law mode were selected to evaluate the rheological properties.

Properties of Random PSF/PES Copolymers as High-Performance Polymers

2011 ◽  
Vol 217-218 ◽  
pp. 1606-1610
Author(s):  
Dong Jiang ◽  
Xiao Ran Zhang ◽  
Yan Mei Ma ◽  
Cheng You Ma
Keyword(s):  
Weight Loss ◽  
Tensile Strength ◽  
Glass Transition ◽  
High Performance ◽  
Molar Ratio ◽  
Transition Temperatures ◽  
Elongation At Break ◽  
Glass Transition Temperatures ◽  
High Performance Polymers ◽  
Diphenyl Sulfone

A series of random polysulfone/polyethersulfone (PSF/PES) copolymers were synthesized by the polycondensation of 4, 4'-isopropylidendiphenol, 4, 4΄-dihyolroxy diphenyl sulfone and 4, 4'-dichlorodiphenyl sulfone in the presence of K2CO3. We obtained a series of copolymers by changing the molar ratio of 4, 4΄-dihyolroxy diphenyl sulfone and 4, 4'-isopropylidendiphenol (it was marked as the ratio of S:A). The copolymers have the similar solubility with polyethersulfone. They also have high glass transition temperatures (Tg: 199°C~229°C) and 5% weight loss temperatures (4, 4'-isopropylidendiphenol: 4, 4΄-dihyolroxy diphenyl sulfone=1:1, Td5=497°C). At the same time the elongation at break is much higher than that of PES, while the tensile strength is a little lower than that of PES.

Enhanced the Thermal Stability of Polyvinyl Chloride via Synergistic Effects of Basic Lanthanum Tartrate with Zinc Stearate and Pentaerythritol

2021 ◽  
Vol 63 (2) ◽  
pp. 182-190
Author(s):  
Zhaogang Liu ◽  
Jingang Zhao ◽  
Mei Li ◽  
Yanhong Hu ◽  
Jinxiu Wu ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Polyvinyl Chloride ◽  
Synergistic Effects ◽  
Zinc Stearate ◽  
Thermal Stability Of

Preparation and characterizations of ternary biodegradable blends composed of polylactide, poly(ε-caprolactone), and wood flour

2012 ◽  
Vol 32 (6-7) ◽  
pp. 435-444 ◽  
Author(s):  
Hsin-Tzu Liao ◽  
Chin-San Wu
Keyword(s):  
Mechanical Properties ◽  
Weight Loss ◽  
Tensile Strength ◽  
Fourier Transform ◽  
Wood Flour ◽  
High Price ◽  
Infrared Analysis ◽  
Melt Blending ◽  
Ternary Blends ◽  
Elongation At Break

Abstract Melt blending of polylactide (PLA), poly(ε-caprolactone) (PCL), and wood flour (WF) was performed in an effort to overcome the major drawbacks (brittleness and high price) of PLA. In addition, the acrylic acid (AA)-grafted PLA70PCL30 (PLA70PCL30-g-AA) was used as the alternative for the preparation of ternary blends to improve the compatibility and the dispersability of WF within the PLA70PCL30 matrix. As expected, PCL improved the elongation at break and the toughness of PLA but decreased the tensile strength and modulus. Because the hydrophilic WF is dispersed physically in the hydrophobic PLA70PCL30 matrix, as the result of Fourier transform infrared analysis, the mechanical properties of PLA70PCL30 became noticeably worse when it was blended with WF. This problem was successfully conquered by using PLA70PCL30-g-AA to replace PLA70PCL30 due to the formation of an ester carbonyl group between PLA70PCL30-g-AA and WF. Furthermore, the PLA70PCL30-g-AA/WF blend provided a plateau tensile strength at break when the WF content was up to 50 wt%. PLA70PCL30/WF exhibited a tensile strength at break of approximately 3–25 MPa more than PLA70PCL30-g-AA/WF. By using p-cresol and tyrosinase, the enzymatic biodegradable test showed that PLA70PCL30-g-AA is somewhat more biodegradable than PLA70PCL30 because the former has better water absorption. After 16 weeks, the weight loss of the PLA70PCL30/WF (50 wt%) composite was >80%. PLA70PCL30-g-AA/WF exhibited a weight loss of approximately 1–12 wt% more than PLA70PCL30-g-AA/WF. It was also found that the addition of WF to PLA70PCL30 or PLA70PCL30-g-AA decreased the crystallinity of PLA and PCL in PLA70PCL30 or PLA70PCL30-g-AA and then increased their biodegradable property.

Effect of hard segments content on the properties, structure and biodegradation of nonisocyanate polyurethane

2018 ◽  
Vol 26 (8-9) ◽  
pp. 423-430 ◽  
Author(s):  
A Białkowska ◽  
K Mucha ◽  
M Przybyłek ◽  
M Bakar
Keyword(s):  
Weight Loss ◽  
Relative Elongation ◽  
Garden Soil ◽  
Crystalline Region ◽  
Electron Microscopic ◽  
Elongation At Break ◽  
Scanning Electron Microscopic ◽  
Maximum Decrease ◽  
Hard Segments ◽  
Nonisocyanate Polyurethane

The present study investigates the biodegradation of synthesized condensation nonisocyanate polyurethanes (NIPUs). It was prepared by reacting phenol sulphonic acid and oligooxypropylene diol and formaldehyde and contained different amounts of hard segments (HSs). Polyurethane samples were submitted to biodegradation with microorganisms R-14 and in garden soil. The tensile strength (TS), relative elongation at break and weight loss of the prepared samples were evaluated and their structure and morphology analysed. It was found that maximum decrease of the TS of all tested NIPU samples occurred only after 7 days of biodegradation. Maximum TS decrease attained was approximately 70% and 75%, respectively, for NIPU based on 0.8-mol and 1-mol HS. Moreover, significant decrease of relative elongation at break and weight loss values after biodegradation in culture R-14 for NIPU samples based on 0.9-mol HS and 1-mol HS was observed. Fourier transform infrared and scanning electron microscopic results confirmed that biodegradation occurred in urea or urethane groups. The glass transition of HSs decreased by at least 20°C due to biodegradation, suggesting that this later took place almost only in the crystalline region of NIPU samples.

scholarly journals Preparation, properties and applications of wheat gluten edible films

2000 ◽  
Vol 9 (1) ◽  
pp. 23-35 ◽  
Author(s):  
P. TANADA-PALMU ◽  
H. HELÉN ◽  
L. HYVÖNEN
Keyword(s):  
Weight Loss ◽  
Tensile Strength ◽  
Water Vapor ◽  
Wheat Gluten ◽  
Single Layer ◽  
Water Vapor Permeability ◽  
Edible Films ◽  
Bilayer Film ◽  
Vapor Permeability ◽  
Elongation At Break

Edible films from wheat gluten were prepared with various amounts of glycerol as a plasticizer. Water vapor permeability, oxygen permeability, tensile strength and percentage elongation at break at different water activities ( aw ) were measured. Films with low amounts of glycerol had lower water vapor and oxygen permeabilities, higher tensile strength and lower elongation at break. Wheat gluten coatings reduced weight loss during two weeks of storage for cherry tomatoes and sharon fruits compared to uncoated controls. A bilayer film of wheat gluten and beeswax significantly lowered weight loss from coated cheese cubes compared to single layer coating of wheat gluten.;

Effect of Vulcanization Temperature and Different Fillers on the Properties of Efficiently Vulcanized Natural Rubber

1979 ◽  
Vol 52 (2) ◽  
pp. 263-277 ◽  
Author(s):  
R. Mukhopadyay ◽  
S. K. De
Keyword(s):  
Particle Size ◽  
Natural Rubber ◽  
Crosslinking Density ◽  
Filler Loading ◽  
Zinc Stearate ◽  
Curing Temperature ◽  
Abnormal Behavior ◽  
Elongation At Break ◽  
Polymer Filler ◽  
Reinforcing Fillers

Abstract The present work deals with effect of vulcanization temperature on the polymer-filler interaction parameter, vulcanizate structure, and the technical properties of efficiently vulcanized natural rubber stocks in the presence of different fillers. We have used carbon blacks of four different particle sizes (ISAF, HAF, SRF, FT), reinforcing silica, and whiting. In the case of black fillers, as the particle size increases, reversion resistance increases. For all fillers, an increase of curing temperature from 150 to 180°C caused a reduction in strength, modulus, hardness, resilience; and an increase in elongation at break, compression set, and heat build-up. However, the flexing properties and abrasion loss showed improvement at higher curing temperature. Kraus' plots indicate that increase of curing temperature caused reduction in polymer-filler attachment. At both curing temperatures, the activity of fillers follow the order, ISAF > HAF > SRF > FT. Silica showed erratic behavior in that Kraus plots indicate nonreinforcement by the filler. Whiting also behaved abnormally with respect to Kraus plots; at lower filler loading, the system is nonadherent, becoming weakly adherent at higher concentrations. The abnormal behavior of silica-filled compounds has been explained on the basis of a reaction on the silica surface between silanol groups and zinc stearate. Westlinning and Wolff's αF values were found to be independent of curing temperature and characteristic of fillers only (the larger the particle size, the lower is the αF value). The increase in apparent crosslinking density in the case of reinforcing fillers is due to increased υr arising out of increased polymer-filler interaction. Therefore, the sulfur inefficiency parameters (E values) and zinc sulfide efficiency parameters (F values) become less significant in filled vulcanizates.

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