Imaging the Polymorphic Transformation in a Single Cu6Sn5 Grain in a Solder Joint
Keyword(s):
In-situ observations of the polymorphic transformation in a single targeted Cu6Sn5 grain constrained between Sn-0.7 wt % Cu solder and Cu-Cu3Sn phases and the associated structural evolution during a solid-state thermal cycle were achieved via a high-voltage transmission electron microscope (HV-TEM) technique. Here, we show that the monoclinic η′-Cu6Sn5 superlattice reflections appear in the hexagonal η-Cu6Sn5 diffraction pattern upon cooling to isothermal 140 °C from 210 °C. The in-situ real space imaging shows that the η′-Cu6Sn5 contrast pattern is initiated at the grain boundary. This method demonstrates a new approach for further understanding the polymorphic transformation behavior on a real solder joint.
1995 ◽
Vol 53
◽
pp. 244-245
1998 ◽
Vol 16
(5)
◽
pp. 2956-2960
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2020 ◽
2020 ◽
Vol 378
(2186)
◽
pp. 20190602