scholarly journals A New, Carbon-Negative Precipitated Calcium Carbonate Admixture (PCC-A) for Low Carbon Portland Cements

Materials ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 554 ◽  
Author(s):  
Lewis McDonald ◽  
Fredrik Glasser ◽  
Mohammed Imbabi
Keyword(s):  
Calcium Carbonate ◽  
Portland Cement ◽  
Co2 Emissions ◽  
Carbon Footprint ◽  
Carbon Capture ◽  
Chemical Properties ◽  
Cement Clinker ◽  
Low Carbon ◽  
Precipitated Calcium Carbonate ◽  
Portland Cements

The production of Portland cement accounts for approximately 7% of global anthropogenic CO2 emissions. Carbon CAPture and CONversion (CAPCON) technology under development by the authors allows for new methods to be developed to offset these emissions. Carbon-negative Precipitated Calcium Carbonate (PCC), produced from CO2 emissions, can be used as a means of offsetting the carbon footprint of cement production while potentially providing benefits to cement hydration, workability, durability and strength. In this paper, we present preliminary test results obtained for the mechanical and chemical properties of a new class of PCC blended Portland cements. These initial findings have shown that these cements behave differently from commonly used Portland cement and Portland limestone cement, which have been well documented to improve workability and the rate of hydration. The strength of blended Portland cements incorporating carbon-negative PCC Admixture (PCC-A) has been found to exceed that of the reference baseline—Ordinary Portland Cement (OPC). The reduction of the cement clinker factor, when using carbon-negative PCC-A, and the observed increase in compressive strength and the associated reduction in member size can reduce the carbon footprint of blended Portland cements by more than 25%.

scholarly journals A Step by Step Methodology for Building Sustainable Cementitious Matrices

2020 ◽  
Vol 10 (8) ◽  
pp. 2955 ◽  
Author(s):  
Styliani Papatzani ◽  
Kevin Paine
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Silica Fume ◽  
Carbon Footprint ◽  
State Of The Art ◽  
Cost Effective ◽  
Strength Development ◽  
Low Carbon ◽  
Current State ◽  
First Time

In an effort to produce cost-effective and environmentally friendly cementitious binders. mainly ternary (Portland cement + limestone + pozzolanas) formulations have been investigated so far. Various proportions of constituents have been suggested, all, however, employing typical Portland cement (PC) substitution rates, as prescribed by the current codes. With the current paper a step by step methodology on developing low carbon footprint binary, ternary and quaternary cementitious binders is presented (PC replacement up to 57%). Best performing binary (60% PC and 40% LS (limestone)) and ternary formulations (60% PC, 20% LS, 20% FA (fly ash) or 43% PC, 20% LS 37% FA) were selected on the grounds of sustainability and strength development and were further optimized with the addition of silica fume. For the first time a protocol for successfully selecting and testing binders was discussed and the combined effect of highly pozzolanic constituents in low PC content formulations was assessed and a number of successful matrices were recommended. The present paper enriched the current state of the art in composite low carbon footprint cementitious binders and can serve as a basis for further enhancements by other researchers in the field.

scholarly journals Pathways for Low-Carbon Transition of the Steel Industry—A Swedish Case Study

Energies ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3840
Author(s):  
Alla Toktarova ◽  
Ida Karlsson ◽  
Johan Rootzén ◽  
Lisa Göransson ◽  
Mikael Odenberger ◽  
...  
Keyword(s):  
Blast Furnace ◽  
Co2 Emissions ◽  
Steel Industry ◽  
Carbon Capture ◽  
Direct Reduction ◽  
Carbon Capture And Storage ◽  
Steel Production ◽  
Mitigation Measures ◽  
Production Plant ◽  
Low Carbon

The concept of techno-economic pathways is used to investigate the potential implementation of CO2 abatement measures over time towards zero-emission steelmaking in Sweden. The following mitigation measures are investigated and combined in three pathways: top gas recycling blast furnace (TGRBF); carbon capture and storage (CCS); substitution of pulverized coal injection (PCI) with biomass; hydrogen direct reduction of iron ore (H-DR); and electric arc furnace (EAF), where fossil fuels are replaced with biomass. The results show that CCS in combination with biomass substitution in the blast furnace and a replacement primary steel production plant with EAF with biomass (Pathway 1) yield CO2 emission reductions of 83% in 2045 compared to CO2 emissions with current steel process configurations. Electrification of the primary steel production in terms of H-DR/EAF process (Pathway 2), could result in almost fossil-free steel production, and Sweden could achieve a 10% reduction in total CO2 emissions. Finally, (Pathway 3) we show that increased production of hot briquetted iron pellets (HBI), could lead to decarbonization of the steel industry outside Sweden, assuming that the exported HBI will be converted via EAF and the receiving country has a decarbonized power sector.

Is magnesia cement low carbon? Life cycle carbon footprint comparing with Portland cement

2016 ◽  
Vol 131 ◽  
pp. 20-27 ◽  
Author(s):  
Weiguo Shen ◽  
Liu Cao ◽  
Qiu Li ◽  
Zhaijun Wen ◽  
Jing Wang ◽  
...  
Keyword(s):  
Life Cycle ◽  
Portland Cement ◽  
Carbon Footprint ◽  
Low Carbon

scholarly journals Granulated Blast-Furnace Slag and Coal Fly Ash Ternary Portland Cements Optimization

2020 ◽  
Vol 12 (14) ◽  
pp. 5783 ◽  
Author(s):  
Rosa Abnelia Rivera ◽  
Miguel Ángel Sanjuán ◽  
Domingo Alfonso Martín
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Portland Cement ◽  
Blast Furnace Slag ◽  
Coal Fly Ash ◽  
Cement Clinker ◽  
Portland Cements ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

Granulated blast-furnace slag (GBFS) and coal fly ash (CFA) are two well-known constituents in Portland cements. Ternary Portland cements (GBFS-CFA-K) provide environmental advantages by reducing Portland cement clinker (K) production and, therefore, promote lower CO2 emissions. Nevertheless, both of them cause a delay in the compressive strength gain. Given that, the early compressive strength for both constituents is low, but they improve the compressive strength at medium and later ages as consequence of the pozzolanic reaction. In this paper, a full factorial design with two levels was developed for the mortar compressive strength estimation at 2, 7 and 28 days. Mortar prisms made with 25% and 40% of granulated blast-furnace slag (GBFS) and/or coal fly ash (CFA) were tested. The effects of the interaction between GBFS and CFA on the compressive strength development of ternary Portland cement mortars were reported. Results show that the contribution of both cement constituents to the ternary mortar mix reduces the compressive strength for all the tested ages. Nevertheless, the finer the GBFS, the better ternary cement performance was achieved, showing that the synergistic effect is more effective when the finer GBFS is used, probably due to a more adequate particle size distribution. Finally, a relationship between compressive strength, fineness, GBFS content and CFA content was found for each age.

scholarly journals Retrofit Decarbonization of Coal Power Plants—A Case Study for Poland

Energies ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 120
Author(s):  
Staffan Qvist ◽  
Paweł Gładysz ◽  
Łukasz Bartela ◽  
Anna Sowiżdżał
Keyword(s):  
Co2 Emissions ◽  
Carbon Capture ◽  
Power Plants ◽  
Low Carbon ◽  
Levelized Cost Of Electricity ◽  
Term Operation ◽  
Capital Costs ◽  
Coal Power ◽  
Low Carbon Energy

Out of 2 TWe of coal power plant capacity in operation globally today, more than half is less than 14 years old. Climate policy related to limiting CO2-emissions makes the longer-term operation of these plants untenable. In this study, we assess the spectrum of available options for the future of both equipment and jobs in the coal power sector by assessing the full scope of “retrofit decarbonization” options. Retrofit decarbonization is an umbrella term that includes adding carbon capture, fuel conversion, and the replacement of coal boilers with new low-carbon energy sources, in each case re-using as much of the existing equipment as economically practicable while reducing or eliminating emissions. This article explores this idea using the Polish coal power fleet as a case study. Retrofit decarbonization in Poland was shown to be most attractive using high-temperature small modular nuclear reactors (SMRs) to replace coal boilers, which can lower upfront capital costs by ~28–35% and levelized cost of electricity by 9–28% compared to a greenfield installation. If retrofit decarbonization is implemented globally by the late 2020s, up to 200 billion tons of otherwise-committed CO2-emissions could be avoided.

A method for measuring the in-plane compressive strength and the compression behavior of coating layers

TAPPI Journal ◽  
2011 ◽  
Vol 10 (7) ◽  
pp. 29-34
Author(s):  
TEEMU PUHAKKA ◽  
ISKO KAJANTO ◽  
NINA PYKÄLÄINEN
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Calcium Carbonate ◽  
Coating Layer ◽  
Test Methods ◽  
Coating Films ◽  
Precipitated Calcium Carbonate ◽  
Coating Color ◽  
Mineral Coatings ◽  
Styrene Butadiene

Cracking at the fold is a quality defect sometimes observed in coated paper and board. Although tensile and compressive stresses occur during folding, test methods to measure the compressive strength of a coating have not been available. Our objective was to develop a method to measure the compressive strength of a coating layer and to investigate how different mineral coatings behave under compression. We used the short-span compressive strength test (SCT) to measure the in-plane compressive strength of a free coating layer. Unsupported free coating films were prepared for the measurements. Results indicate that the SCT method was suitable for measuring the in-plane compressive strength of a coating layer. Coating color formulations containing different kaolin and calcium carbonate minerals were used to study the effect of pigment particles’ shape on the compressive and tensile strengths of coatings. Latices having two different glass transition temperatures were used. Results showed that pigment particle shape influenced the strength of a coating layer. Platy clay gave better strength than spherical or needle-shaped carbonate pigments. Compressive and tensile strength decreased as a function of the amount of calcium carbonate in the coating color, particularly with precipitated calcium carbonate. We also assessed the influence of styrene-butadiene binder on the compressive strength of the coating layer, which increased with the binder level. The compressive strength of the coating layer was about three times the tensile strength.

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