scholarly journals Experimental Study of Mechanical Properties of Epoxy Compounds Modified with Calcium Carbonate and Carbon after Hygrothermal Exposure

Materials ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 5439
Author(s):  
Anna Rudawska
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Activated Carbon ◽  
Calcium Carbonate ◽  
Epoxy Resin ◽  
Thermal Shock ◽  
Climate Chamber ◽  
Shock Chamber ◽  
Modified Epoxy ◽  
Thermal Shocks

The objective of this paper is to analyze the effects of hygrothermal exposure on the mechanical properties of epoxy compounds modified with calcium carbonate or carbon fillers. In addition, comparative tests were carried out with the same parameters as hygrothermal exposure, but the epoxy compounds were additionally exposed to thermal shocks. The analysis used cylindrical specimens produced from two different epoxy compounds. The specimens were fabricated from compounds of epoxy resins, based on Bisphenol A (one mixture modified, one unmodified) and a polyamide curing agent. Some of the epoxy compounds were modified with calcium carbonate (CaCO3). The remainder were modified with activated carbon (C). Each modifying agent, or filler, was added at a rate of 1 g, 2 g, or 3 g per 100 g of epoxy resin. The effect of the hygrothermal exposure (82 °C temperature and 95% RH humidity) was examined. The effects of thermal shocks, achieved by cycling between 82 °C and −40 °C, on selected mechanical properties of the filler-modified epoxy compounds were investigated. Strength tests were carried out on the cured epoxy compound specimens to determine the shear strength, compression modulus, and compressive strain. The analysis of the results led to the conclusion that the type of tested epoxy compounds and the quantity and type of filler determine the effects of climate chamber aging and thermal shock chamber processing on the compressive strength for the tested epoxy compounds. The different filler quantities, 1–3 g of calcium carbonate (CaCO3) or activated carbon (C), determined the strength parameters, with results varying from the reference compounds and the compounds exposure in the climate chamber and thermal shock chamber. The epoxy compounds which contained unmodified epoxy resin achieved a higher strength performance than the epoxy compounds made with modified epoxy resin. In most instances, the epoxy compounds modified with CaCO3 had a higher compressive strength than the epoxy compounds modified with C (activated carbon).

scholarly journals Investigation of the Effect of Operational Factors on Conveyor Belt Mechanical Properties

2020 ◽  
Vol 10 (12) ◽  
pp. 4201
Author(s):  
Anna Rudawska ◽  
Radovan Madleňák ◽  
Lucia Madleňáková ◽  
Paweł Droździel
Keyword(s):  
Mechanical Properties ◽  
Thermal Shock ◽  
Tensile Modulus ◽  
Conveyor Belt ◽  
Specific Humidity ◽  
Climatic Chamber ◽  
Strength Parameters ◽  
Shock Chamber ◽  
Operational Factors ◽  
Thermal Shocks

This paper aims to present the effect of specific operational factors (temperature and humidity) on the selected mechanical properties of a conveyor belt. The tests were conducted in a climatic chamber, simulating the effect of both minus and plus temperatures −30 °C to 80 °C (243 K to 353 K) at specific humidity, and in a thermal shock chamber where a varying number of ageing cycles was applied for a specific range of thermal shocks. Six different tests in the climatic chamber and four different tests in a thermal shock chamber were conducted. The results of the climatic chamber tests demonstrate that many strength parameters have undesired values at a temperature of 10 °C (283 K) and 80 °C (353 K) at a relative humidity of 80%. Interestingly, the results revealed that tensile strength, tensile modulus and yield strength are higher at below 0 °C temperature than at above 0 °C temperature. For example, comparing the temperature −30 °C (243 K) and +30 °C (303 K) obtained a difference of tensile modulus of nearly 10%, and comparing the temperature −30 °C (243 K) and +10 °C (283 K) the differences were 22%.

scholarly journals Aging Effects of Aqueous Environment on Mechanical Properties of Calcium Carbonate-Modified Epoxy Resin

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2541 ◽  
Author(s):  
Anna Rudawska ◽  
Mariaenrica Frigione
Keyword(s):  
Mechanical Properties ◽  
Calcium Carbonate ◽  
Ambient Temperature ◽  
Epoxy Resin ◽  
Compressive Modulus ◽  
Maximum Strength ◽  
Aqueous Environment ◽  
Structural Adhesives ◽  
Modified Epoxy ◽  
Epoxy Systems

The purpose of this study was to assess the effects of different aqueous environments (i.e., demineralised, distilled and spring water) on the mechanical properties of a cold-cured bisphenolic epoxy resin modified with the addition of calcium carbonate filler, typically employed as structural adhesive. The parameters selected for the analysis have been; the kind of curing agent employed to cure the epoxy resin at ambient temperature (i.e., Mannich base and triethylenetetramine); the load of calcium carbonate added to liquid epoxy (i.e., from 1 to 3 g per 100 g of resin) and; the duration of the exposure to the different aging conditions (i.e., from 1 to 10 months). Cylindrical specimens of calcium carbonate-modified epoxy systems were tested in compression mode, before and after each of the aging regimes. The effect of the selected curing agents is very small, and they are both suitable for a cure at ambient temperature, on the unfilled epoxy on compressive maximum strength and strain at break; the choice of the hardener affects instead the compressive modulus. The CaCO3 amount was demonstrated to have a significant effect on the mechanical characteristics of un-aged epoxy systems, leading to growth in compressive modulus and maximum strength with reductions in strain at break. Generally speaking, the aging time noticeably affects the compressive properties of calcium carbonate-modified epoxies while almost negligible is the kind of water employed in each exposure regime. Notwithstanding the adverse effects of an aqueous environment on compressive mechanical properties of CaCO3-filled epoxies, these systems keep compressive modulus and maximum strength greater than, and close to, respectively, the same characteristics measured on unaged unfilled control epoxies, demonstrating the positive effect of the addition of this kind of filler to epoxy-based structural adhesives, especially with the addition of 2 and 3 g of CaCO3 per 100 g resin. The results obtained in this study demonstrated that it is possible to contrast the detrimental effects observed in cold-cured epoxy-based structural adhesives due to their aging in water upon the addition of limited amounts (particularly at 2 and 3 g per 100 g resin) of a cheap CaCO3 filler.

scholarly journals Study on the Physical and Mechanical Properties of Granite After Multiple Thermal Shock Treatments

2020 ◽  
Author(s):  
Li Yu ◽  
Hai-wang PENG ◽  
Yu Zhang ◽  
GuoWei Li
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Compressive Strength ◽  
High Temperature ◽  
Thermal Shock ◽  
Tensile Modulus ◽  
Physical And Mechanical Properties ◽  
P Wave ◽  
Water Cooling ◽  
Thermal Shocks

Abstract To study the influence of thermal shock caused by water cooling on the physical and mechanical properties of high-temperature granite, granite was subjected to an increasing number of high-temperature (300℃) water-cooling and thermal shock treatment cycles, and static mechanical experiments were carried out on the treated granite. The results support the following conclusions: (1) Thermal shock causes an increase in the number and size of the pores and cracks within the granite; thus, its volume expands, density decreases, water absorption rate increases, and P-wave velocity decreases. (2) With an increase in the number of thermal shocks, both the compressive strength and tensile strength of the granite decrease, and there is a linear relationship between the compressive strength and tensile strength. With the corresponding fitting formula, the change in the strength of the granite can be accurately predicted. (3) With an increase in the number of thermal shocks, the plasticity of the granite increases and its resistance to deformation weakens, which is manifested as a decrease in both the compressive modulus and tensile modulus of the granite. After 15 cycles of thermal shock, the compressive elastic modulus and tensile modulus of the granite decreased by 25.18% and 46.76%, respectively. (4) The m and s values of the damaged granite were calculated based on the Hoek-Brown empirical criterion, and it was found that both of these parameters decrease with the increase in the number of thermal shocks. The calculation results can provide a reference for engineering rock mass failure.Clinical trial registration

scholarly journals Mechanical properties of unmodified and montmorillonite-modified epoxy compounds. Part I: compression test

2021 ◽  
Vol 9 (1) ◽  
Author(s):  
Anna Rudawska
Keyword(s):  
Compressive Strength ◽  
Thermal Shock ◽  
Aging Time ◽  
Compressive Strain ◽  
Effect Of Temperature ◽  
Shock Chamber ◽  
Thermal Chamber ◽  
Modified Epoxy ◽  
Reference Samples ◽  
Made In

AbstractThe aim of the article was to determine the compressive strength and compressive strain of an unmodified and a modified epoxy compounds containing a montmorillonite filler, as well as to determine the effect of temperature and an aging time on the mechanical parameters of the considered epoxy compounds. The subject of the research was both the unmodified and the modified adhesive compounds. The unmodified epoxy compounds were made in four variants, which included the epoxy resins based on a bisphenol A as well as the curing agents: a triethylenetetramine and a polyamide curing agent. The modified compounds containing the montmorillonite filler, were also made in four variants. The samples were subjected in a thermal chamber at 80 °C for 1 and 2 months and in a thermal shock chamber in the temperature range from − 40 °C to 80 °C for 1 and 2 months. The reference samples were seasoned at room temperature 20–25 °C. The epoxy compounds samples were subjected to the compression strength tests in accordance with ISO 604 standard. The compressive strength is influenced by the environment and temperature, the aging time and the presence of the modifying agent. The epoxy compounds subjected at elevated or variable temperatures have higher compressive strength than the reference epoxy compounds. The operation of the climatic chamber or the thermal shock chamber makes the samples more deformable than the reference samples.

The Mechanical Properties of Organic Modified Epoxy Resin

2020 ◽  
Vol 43 (3) ◽  
pp. 10-14
Author(s):  
Georgel MIHU ◽  
Claudia Veronica UNGUREANU ◽  
Vasile BRIA ◽  
Marina BUNEA ◽  
Rodica CHIHAI PEȚU ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Composite Materials ◽  
Epoxy Resin ◽  
Epoxy Matrix ◽  
Epoxy Resins ◽  
Mechanical Tests ◽  
Organic Modification ◽  
Three Point Bending ◽  
Modified Epoxy

Epoxy resins have been presenting a lot of scientific and technical interests and organic modified epoxy resins have recently receiving a great deal of attention. For obtaining the composite materials with good mechanical proprieties, a large variety of organic modification agents were used. For this study gluten and gelatin had been used as modifying agents thinking that their dispersion inside the polymer could increase the polymer biocompatibility. Equal amounts of the proteins were milled together and the obtained compound was used to form 1 to 5% weight ratios organic agents modified epoxy materials. To highlight the effect of these proteins in epoxy matrix mechanical tests as three-point bending and compression were performed.

Mechanichal Properties of DGEBA/TEPA Modified Epoxy Resin

2014 ◽  
Vol 775-776 ◽  
pp. 588-592
Author(s):  
Camila Rodrigues Amaral ◽  
Ruben Jesus Sanchez Rodriguez ◽  
Magno Luiz Tavares Bessa ◽  
Verônica Scarpini Cândido ◽  
Sergio Neves Monteiro
Keyword(s):  
Mechanical Properties ◽  
Plastic Deformation ◽  
Epoxy Resin ◽  
Yield Stress ◽  
Diglycidyl Ether ◽  
Notch Toughness ◽  
Epoxy Network ◽  
Structural Network ◽  
Flexural Tests ◽  
Modified Epoxy

The correlation between the structural network of a diglycidyl ether of the bisphenol-A (DGEBA) epoxy resin, modified by two distinct aliphatic amines (tetraethylenepentamine TEPA and jeffamine D230), and its mechanical properties, was investigated as possible matrix for abrasive composites applications. Both flexural tests, to determine the yield stress and the elastic modulus, as well as impact tests to determine the notch toughness, were performed. The DGEBA/D230 presented the highest stiffness and toughness but lowest yield stress. This epoxy network also displayed a greater plastic deformation during fracture.

scholarly journals Effects of Bacillus subtilis biocementation on the mechanical properties of mortars

2019 ◽  
Vol 12 (1) ◽  
pp. 31-38 ◽  
Author(s):  
N. SCHWANTES-CEZARIO ◽  
M. F. PORTO ◽  
G. F. B. SANDOVAL ◽  
G. F. N. NOGUEIRA ◽  
A. F. COUTO ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Calcium Carbonate ◽  
Cementitious Materials ◽  
Mechanical Analysis ◽  
Sem Analysis ◽  
Subtilis Strain ◽  
Cement Mortars ◽  
Water To Cement Ratio ◽  
Mixing Water

Abstract This study aims to evaluate the influence of B. subtilis AP91 spores addition on the mechanical properties of mortars. B. subtilis strain AP91, isolated from rice leaves of the needle variety, which has an early cycle of production, was used at the concentration of 105 spores/mL in mortars with cement-to-sand ratio of 1:3 (by weight) and water-to-cement ratio (w/c) of 0.63. These spores were added in two different ways: in the mixing water and by immersion in a solution containing bacterial spores. Scanning Electron Microscope (SEM) analysis showed crystals with calcium peaks on the EDS, which possibly indicates the presence of bioprecipitated calcium carbonate. The results obtained in the mechanical analysis showed that the bioprecipitation of CaCO3 by B. subtilis strain AP91 was satisfactory, particularly when the spores were added in the mixing water, increasing the compressive strength up to 31%. Thus, it was concluded that the addition of B. subtilis AP91 spores in the mixing water of cement mortars induced biocementation, which increased the compressive strength. This bioprecipitation of calcium carbonate may very well have other advantageous consequences, such as the closure of pores and cracks in cementitious materials that could improve durability properties, although more research is still needed on this matter.

Sign in / Sign up

Export Citation Format

Share Document