scholarly journals The Effect of Class C Fly Ash on the Plasticity and Ageing of Ceramic Mixtures Based on Kaolin

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2761
Author(s):  
Radomir Sokolar ◽  
Martin Nguyen

The main aim of the presented article is to describe the behavior of class C fly ash—kaolin plastic doughs during the ageing process. Class C fly ash (CCFA) from the fluidized technology of fuel combustion in a thermal power plant was used as a non-plastic admixture to modify the plasticity in a kaolin–quartz sand mixture (for example, the base of a porcelain mixture). The ageing of plastic ceramic dough determined the effect of the CCFA admixture (0–10–20 wt. %) on the initial water content, plasticity (according to the Pfefferkorn test) and bulk density of a dried green body. The main feature of the CCFA admixture in the kaolin–quartz sand mixture is a solidifying effect. Fly ash increases the initial (mixing) water for the preparation of ceramic dough with constant plasticity (30 mm height of deformed cone Hf, according to the Pfefferkorn test), and Hf increases as the dough ages (the dough solidifies faster and loses its plasticity) with the addition of class C fly ash. The effect of CCFA addition on the plasticity and ageing of kaolin–quartz sand dough is documented on Bigot curves: higher content of fly ash decreases the drying shrinkage of the plastic dough, especially when drying samples that have been aged for 24 h in a plastic wrap (without the possibility of drying). The plastic dough’s ageing increases the porosity of the dried green body with increased content of CCFA in the raw materials mixture and increased ageing time.

2021 ◽  
Vol 321 ◽  
pp. 141-147
Author(s):  
Radomír Sokolař ◽  
Martin Nguyen ◽  
Oldřich Pavelka

The effect of fluidized fly ash (Tisová, ČEZ Group Czech Republic, class C according to ASTM C618) on the porosity (water absorption, bulk density, capillarity) and water impermeability of brick body used for the production of clay roofing tiles (Wienerberger, Czech Republic). The properties of plastic body (mixing water, drying shrinkage) are discussed too. The addition (10 %wt) of fluidized fly ash in the raw materials mixture for the production of clay roofing tiles generally reduces the sensitivity to the formation of reducing cores during firing thanks to higher porosity of dried green body (higher mixing water) - this is also related to the higher water absorption and capillarity of the fired body and hence to the impaired water impermeability when the fly ash is used.


2018 ◽  
Vol 276 ◽  
pp. 110-115
Author(s):  
Martin Ťažký ◽  
Martin Labaj ◽  
Rudolf Hela

The by-products of energy industry are nowadays often affected by new limits governing the production of harmful gases discharged into the air. These stricter and stricter criteria are often met by electricity producers by changing the combustion process in thermal power plants itself. Nowadays, the SNCR (selective non-catalytic reduction) application is quite common in the combustion process in order to help reduce the nitrogen oxide emission. This article deals with the primary measures of thermal power plants, which in particular consist of a modified treatment of raw materials (coal) entering the combustion process. These primary measures then often cause the formation of fly ash with unsuitable fineness for the use in concrete according to EN 450. The paper presents the comparison of the physico-mechanical parameters of several fly ashes with a different fineness values. The primary task is to assess the impact of non-suitable granulometry in terms of EN 450 on the other physico-mechanical parameters of fly ashes sampled within the same thermal power plant. Several fly ashes produced in the Czech Republic and surrounding countries were evaluated in this way.


China's industries are rapidly growing, and with that generation of waste is also increasing. Associated environmental concerns over construction and demolition waste, industrial waste such as fly ash generated by thermal power plants need to be utilized in some form. Autoclave aerated concrete is a lightweight material that can be used as an alternative building material; it is widely composed of raw materials such as cement, quicklime, sand, gypsum, and an aerating agent like aluminum powder. In this study, 40% waste will be utilized, Construction waste (5%,10%,15%....40%) and Fly ash (35%,30%,25….0%)respectively, keeping the aerating agent constant at 0.06% that is aluminum powder. The compressive strength of the material will be checked after autoclaving at 2000 temperature and 1Mpa Pressure for 6 hours. The study aims to design an autoclave aerated concrete material and to recycle the waste generated by various industries mainly from the construction sector.


2018 ◽  
Vol 60 ◽  
pp. 00026
Author(s):  
Olena Svietkina ◽  
Hanna Tarasova ◽  
Olha Netiaha ◽  
Svitlana Lysytska

The objective of the work is to study the aluminosilicate fractionation from fly ash, physical and mechanical properties of fly ash derived from the Thermal Power Plants (TPP) wastes. Ash, carbon concentrate (unburned carbon), ash concentrate and products of their treatment with reagents were tested by optical methods. The particle morphology of the objects of research was studied with the scanning electron microscope REM-100. The composition of the ash phases was investigated using the X-ray diffractometer DRON-2. A dispersed analysis of the TPP fly ash suggests a conclusion that it is advisable to separate particles of a narrow grain-size class within the range from 40 to 150 μm with an ash content of about 33%. The first product may be enriched by flotation method. Such a coal product may be used as a reducing medium in metallurgical processes, agglomeration, etc. The calorific capacitance of the concentrate is about 6000 kcal/kg (25000 kJ/kg).


2016 ◽  
Vol 2016 ◽  
pp. 1-11 ◽  
Author(s):  
A. Binal

Contemporarily, there are 16 coal-burning thermal power plants currently operating in Turkey. This number is expected to rise to 46 in the future. Annually, about 15 million tons of fly ash are removed from the existing thermal power plants in Turkey, but a small proportion of it, 2%, is recyclable. Turkey’s plants are fired by lignite, producing Class C fly ash containing a high percentage of lime. Sulfate and alkali levels are also higher in Class C fly ashes. Therefore, fly ash is, commonly, unsuitable as an additive in cement or concrete in Turkey. In this study, highly alkaline fly ash obtained from the Yeniköy thermal power plants is combined with soil samples in different proportions (5%, 10%, 15%, 20%, and 25%) and changes in the geomechanical properties of Ankara clay were investigated. The effect of curing time on the physicomechanical properties of the fly ash mixed soil samples was also analyzed. The soil classification of Ankara clay changed from CH to MH due to fly ash additives. Free swelling index values showed a decrease of 92.6%. Direct shear tests on the cohesion value of Ankara clay have shown increases by multiples of 15.85 and 3.01 in internal friction angle values. The California bearing ratio has seen a more drastic increase in value (68.7 times for 25% fly ash mix).


2016 ◽  
Vol 865 ◽  
pp. 42-46 ◽  
Author(s):  
Ján Fleischhacker ◽  
Ester Helanová ◽  
Rostislav Drochytka

Tobermorite is the main mineral which provides to aerated concrete mechanical properties. It is produces during hydrothermal conditions by reacting silicon and calcium oxides. Within this research was evaluated tobermorite formation using high temperature combustion fly ash and quartz sand, as the siliceous raw materials. As a binder was used lime. Emphasis was also placed on the molar ratio of C/S, which is crucial for the formation of tobermorite and was given 0.73 and 1.00. Hydrothermal synthesis was carried out in a laboratory autoclave at temperatures of 170 and 190 °C.


2020 ◽  
Vol 195 ◽  
pp. 06001
Author(s):  
Canan Turan ◽  
Akbar Javadi ◽  
Raffaele Vinai ◽  
Nader Shariatmadari ◽  
Raziyeh Farmani

Fine-grained soils may have undesired characteristics such as high swelling potential and low strength, thus requiring improvements. One of the stabilization methods involves the use of fly ash. Fly ash is a waste material obtained from burning coal in thermal power plants. The use of fly ash is encouraged as an alternative material for soil stabilization, due to its features such as pozzolanic properties and economic availability. This paper describes the results of an experimental study on stabilization of a clayey soil with fly ash. Unconfined compressive strength (UCS), triaxial and consolidation tests were carried out on samples of kaolinite mixed with class C fly ash at different percentages and cured for 1, 7, and 28 days, in order to study the effects of class C fly ash on the mechanical behaviour of the stabilized soil. The results showed that the inclusion of fly ash significantly improves the strength characteristics of the soil. Curing time was also found to have a significant effect on improving the properties of the soil.


Author(s):  
Karolina Knapik ◽  
Joanna Bzówka

Abstract Based on known correlations permeability was calculated for the mixtures containing various proportions of selected FBC fly ash, Speswhite kaolin and lime. The influence of initial water content of the mixtures was also considered. The study was limited to the first four weeks of curing time. Results of calculations were discussed on the background of previously obtained observations for mixtures of tested materials.


2020 ◽  
Vol 7 ◽  
pp. 22
Author(s):  
Silviya Boycheva ◽  
Denitza Zgureva ◽  
Hristina Lazarova ◽  
Katerina Lazarova ◽  
Cyril Popov ◽  
...  

High-grade zeolite nanocomposites are synthesized utilizing solid by-products from combustion of coal for energy production in Thermal Power Plants applying alkaline aging, hydrothermal and fusion-hydrothermal activation procedures. The obtained coal ash zeolites were studied with respect to their chemical and phase composition, morphology, surface parameters and thermal properties. It was found that they are distinguished in nanocrystalline morphology and significant content of iron oxide nanoparticles (γ-Fe2O3, α-Fe2O3, γ-Fe3O4) and doping elements (Cu, Co, Mn, V, W, etc.) transferred from the raw coal ash, and therefore they are assumed as nanocomposites. Coal fly ash zeolite nanocomposites are characterized by a mixed micro-mesoporous texture, significant concentration of acidic Brønsted centers due to their high surface insaturation, high chemical and thermal stabilty. This unique combination of compositional and textural properties predetermines the application of these materials as catalysts for thermal oxidation processes, anticorrosion barrier coatings, carbon capture adsorbents, matrices for hosting functional groups, detergents etc. Examples for coal fly ash zeolite applications for substitution of critical raw materials in practice are provided.


Materials ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3406
Author(s):  
Saidu Kamara ◽  
Wei Wang ◽  
Chaoqian Ai

Coal fly ash and kaolin are ceramic compounds utilized as raw materials in the production of refractories. Fly ash is an environmental pollutant that emanates abundantly from coal thermal power plants. The management of the large amounts of fly ash produced has been very challenging, with serious economic and environmental consequences. Kaolin, on the other hand, is a natural and synthetic clay material used in medicines, paper, plastics, and cosmetic preparations. In this research, refractory materials (cordierite (Mg2Al4Si5O18), mullite (3Al2O3·2SiO3), and kyanite (Al2SiO5)) were fabricated in four different experiments, and an assessment was made of the strength of each of the materials. Coal fly ash and kaolin were each blended with alumina as starting materials. MgO and AlF3·3H2O were each applied as additives to the reacting materials. The mixtures were molded and sintered at temperatures between 1000 °C and 1200 °C for three hours in a muffle furnace, and characterized by SEM and XRD. The analysis revealed the evolution of cordierite, mullite, and kyanite alongside other crystalline compounds. The formation of kyanite in experiment C, due to the addition of AlF3·3H2O, is unprecedented and phenomenal. The XRD figures show the corundum phases crystallize at 1100 °C in experiments A and B, and disappear at 1200 °C.


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