scholarly journals Synthesis of Ti-Al-xNb Ternary Alloys via Laser-Engineered Net Shaping for Biomedical Application: Densification, Electrochemical and Mechanical Properties Studies

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 544
Author(s):  
Lehlogonolo Rudolf Kanyane ◽  
Abimbola Patricia Idowu Popoola ◽  
Sisa Pityana ◽  
Monnamme Tlotleng
Keyword(s):  
Biomedical Application ◽  
Corrosion Behaviour ◽  
Alloy System ◽  
Processing Parameters ◽  
Ternary Alloys ◽  
Al Alloy ◽  
Heart Transplants ◽  
Medical Interventions ◽  
Net Shaping ◽  
The Cost

The lives of many people around the world are impaired and shortened mostly by cardiovascular diseases (CVD). Despite the fact that medical interventions and surgical heart transplants may improve the lives of patients suffering from cardiovascular disease, the cost of treatments and securing a perfect donor are aspects that compel patients to consider cheaper and less invasive therapies. The use of synthetic biomaterials such as titanium-based implants are an alternative for cardiac repair and regeneration. In this work, an in situ development of Ti-Al-xNb alloys were synthesized via laser additive manufacturing for biomedical application. The effect of Nb composition on Ti-Al was investigated. The microstructural evolution was characterized using a scanning electron microscope (SEM) equipped with energy dispersive spectroscopy (EDS). A potentiodynamic polarization technique was utilized to investigate the corrosion behavior of TiAl-Nb in 3.5% NaCl. The microhardness and corrosion behaviour of the synthesized Ti-Al-Nb alloys were found to be dependent on laser-processing parameters. The microhardness performance of the samples increased with an increase in the Nb feed rate to the Ti-Al alloy system. Maximum microhardness of 699.8 HVN was evident at 0.061 g/min while at 0.041 g/min the microhardness was 515.8 HVN at Nb gas carrier of 1L/min, respectively.

Microstructures of LENS™ Deposited Nb-Si Alloys

2004 ◽  
Vol 842 ◽  
Author(s):  
Ryan R. Dehoff ◽  
Peter M. Sarosi ◽  
Peter C. Collins ◽  
Hamish L. Fraser ◽  
Michael J. Mills
Keyword(s):  
Elevated Temperatures ◽  
Alloy System ◽  
Enthalpy Of Mixing ◽  
Processing Parameters ◽  
Metal Loss ◽  
Matrix Composites ◽  
Heat Treated ◽  
Shaping Process ◽  
Structural Applications ◽  
Net Shaping

ABSTRACTNb-Si “in-situ” metal matrix composites consist of Nb3Si and Nb5Si3 intermetallic phases in a body centered cubic Nb solid solution, and show promising potential for elevated temperature structural applications. Cr and Ti have been shown to increase the oxidation resistance and metal loss rate at elevated temperatures compared to the binary Nb-Si system. In this study, the LENS™ (Laser Engineered Net Shaping) process is being implemented to construct the Nb-Ti-Cr-Si alloy system from elemental powder blends. Fast cooling rates associated with LENS™ processing yield a reduction in microstructural scale over conventional alloy processes such as directional solidification. Other advantages of LENS™ processing include the ability to produce near net shaped components with graded compositions as well as a more uniform microstructure resulting from the negative enthalpy of mixing associated with the silicide phases. Processing parameters can also be varied, resulting in distinct microstructural differences. Deposits were made with varying compositions of Nb, Ti, Cr and Si. The as-deposited as well as heat treated microstructures were examined using SEM and TEM techniques. The influence of composition and subsequent heat treatment on microstructure will be discussed.

Effect of processing parameters on corrosion behaviour of Al reinforced with Ni-40Fe-10Ti alloy fabricated by FSP

2020 ◽  
Vol 110 (9-10) ◽  
pp. 2703-2711
Author(s):  
T. H. Sibisi ◽  
M. B. Shongwe ◽  
O. T. Johnson ◽  
R. M. Mahamood ◽  
S. A. Akinlabi ◽  
...  
Keyword(s):  
Corrosion Behaviour ◽  
Processing Parameters

Process Modeling in Laser Deposition of Multilayer SS410 Steel

2007 ◽  
Vol 129 (6) ◽  
pp. 1028-1034 ◽  
Author(s):  
Liang Wang ◽  
Sergio Felicelli
Keyword(s):  
Phase Transformation ◽  
Temperature Distribution ◽  
Three Dimensional ◽  
Element Model ◽  
Traverse Speed ◽  
Processing Parameters ◽  
Dimensional Finite Element ◽  
Net Shaping ◽  
Three Dimensional Finite Element ◽  
Continuous Cooling Transformation Diagram

A three-dimensional finite element model was developed to predict the temperature distribution and phase transformation in deposited stainless steel 410 (SS410) during the Laser Engineered Net Shaping (LENS™) rapid fabrication process. The development of the model was carried out using the SYSWELD software package. The model calculates the evolution of temperature in the part during the fabrication of a SS410 plate. The metallurgical transformations are taken into account using the temperature-dependent material properties and the continuous cooling transformation diagram. The ferritic and martensitic transformation as well as austenitization and tempering of martensite are considered. The influence of processing parameters such as laser power and traverse speed on the phase transformation and the consequent hardness are analyzed. The potential presence of porosity due to lack of fusion is also discussed. The results show that the temperature distribution, the microstructure, and hardness in the final part depend significantly on the processing parameters.

scholarly journals Effect of Structural Modification on Corrosion Behavior of Hypo Eutectic Al-Si Alloy

2018 ◽  
Vol 778 ◽  
pp. 16-21
Author(s):  
Muhammad Mansoor ◽  
Muhammad Kamran Yaseen ◽  
Shaheed Khan
Keyword(s):  
Corrosion Rate ◽  
Corrosion Behavior ◽  
Earth Metal ◽  
Alloy System ◽  
Eutectic Phase ◽  
Al Alloy ◽  
General Corrosion ◽  
Corrosion Properties ◽  
Unmodified Alloy ◽  
Cast Alloys

Al-Si eutectic cast alloys are widely used in aeronautical and automobile industries where significantly high strength, toughness and wear resistance are required. This class of cast alloys exhibit relatively low corrosion resistance in brine environments. The mechanical properties of the alloy system mainly depend upon the shape of Si rich eutectic phase, which mainly has acicular geometry. In present research, the effect of modified microstructure of 12 wt. % Si-Al alloy on corrosion behavior was studied. The needle like Si rich eutectic phase was modified to disperse spherical structure using rare earth metal halides. The corrosion rate and pitting behavior of modified and unmodified alloy were evaluated in 3.5% NaCl solution by general corrosion for calculated time. It was observed that the corrosion rate and pitting tendency of modified alloy had been appreciably reduced as compare to unmodified alloy. The improvement of corrosion properties were the attributes of changed morphology and distribution of Si rich eutectic phase.

scholarly journals Corrosion of the Welded Aluminium Alloy in 0.5 M NaCl Solution. Part 2: Coating Protection

Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2177 ◽  
Author(s):  
Andrey Gnedenkov ◽  
Sergey Sinebryukhov ◽  
Dmitry Mashtalyar ◽  
Igor Vyaliy ◽  
Vladimir Egorkin ◽  
...  
Keyword(s):  
Aluminium Alloy ◽  
Welded Joint ◽  
Electrochemical Impedance ◽  
Corrosion Behaviour ◽  
Weld Interface ◽  
Open Circuit ◽  
Al Alloy ◽  
Protective Properties ◽  
Coating Formation ◽  
Electrode Technique

The high electrochemical activity of the aircraft 1579 aluminium alloy with a welded joint and the necessity of the coating formation to protect this material against corrosion as well as to increase the stability of the weld interface in the corrosive medium has been previously established. In this work, two suggested methods of protective coating formation based on plasma electrolytic oxidation (PEO) in tartrate-fluoride electrolyte significantly increased the protective properties of the welded joint area of the 1579 Al alloy. The electrochemical properties of the formed surface layers have been investigated using SVET (scanning vibrating electrode technique) and SIET (scanning ion-selective electrode technique), EIS (electrochemical impedance spectroscopy), OCP (open circuit potential), and PDP (potentiodynamic polarization) in 0.5 M NaCl. The less expressed character of the local electrochemical processes on the welded 1579 Al alloy with the composite coating in comparison with the base PEO-layer has been established. Polymer-containing coatings obtained using superdispersed polytetrafluoroethylene (SPTFE) treatment are characterized by the best possible protective properties and prevent the material from corrosion destruction. Single SPTFE treatment enables one to increase PEO-layer protection by 5.5 times. The results of this study indicate that SVET and SIET are promising to characterize and to compare corrosion behaviour of coated and uncoated samples with a welded joint in chloride-containing media.

scholarly journals Effect of laser processing parameters on the efficiency of material: a review in industrial application field

2019 ◽  
Vol 8 (4) ◽  
pp. 509
Author(s):  
Muhammed Sabri Sabri Salim ◽  
Naseer Sabri ◽  
T. K. Ibrahim ◽  
Noaman M. Noaman ◽  
Israa N. Akram ◽  
...  
Keyword(s):  
Surface Treatment ◽  
Surface Composition ◽  
Laser Energy ◽  
Low Cost ◽  
Processing Parameters ◽  
Laser Materials ◽  
Initial State ◽  
Higher Power ◽  
The Cost ◽  
Laser Devices

There is considerable interest in reducing the cost of alloy components that are highly resistant to corrosion. Therefore, low-cost laser energy was used compared to other treatments, where this energy was used to enhance surface resistance of the alloy. In this paper, the advantages of surface treatment using laser energy have demonstrated, in addition, analysis of the effect of the treatment parameters on the material properties. Surface treatment methods for laser materials were classified in thermal processes and thermal chemical processes. The chemical thermal process shows a change in the surface composition of the treated material. The initial state of hydration for cement paste can be identified by analyzing the changes resulting from the intensity of the laser processor. Alumina samples in Ceram proved more soluble areas and became more homogenous and smooth with fewer openings and cracks, especially with energy higher than 10 W CO2 and higher power density than Excimer 6.2 J / cm laser devices. The optimum power of the laser used to remove the material is 40-200 W / cm2. 

Corrosion behavior of heat-treated and cryorolled Al 5052 alloys in different chloride ion concentrations

2020 ◽  
Vol 67 (1) ◽  
pp. 7-15 ◽  
Author(s):  
Anasyida Abu Seman ◽  
Ji Kit Chan ◽  
Muhammad Anas Norazman ◽  
Zuhailawati Hussain ◽  
Dhindaw Brij ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Corrosion Behaviour ◽  
Solution Treatment ◽  
Chloride Ion ◽  
Optical Microscope ◽  
Al Alloy ◽  
Content Type ◽  
Ion Concentrations ◽  
Heat Treated ◽  
Chloride Environment

Purpose This paper aims to investigate the corrosion behaviour of heat-treated and cryorolled Al 5052 alloys in different Cl− ion concentrations. Design/methodology/approach NaCl solutions with concentrations of 0, 0.5, 3.5 and 5.5 per cent were selected. Samples were subjected to pre-heat treatment (annealing at 300 °C and solution treatment at 540 °C) and cryorolling up to 30 per cent reduction before undergoing corrosion tests. The corrosion behaviour of the samples was then investigated by potentiodynamic polarization. The microstructure of the corroded samples was evaluated under an optical microscope, and the percentages of pits on their surfaces were calculated. Findings The cryorolled samples had a lower corrosion rate than the samples that were not cryorolled. The cryorolled sample that underwent solution treatment showed the highest corrosion resistance among all the samples tested. Practical implications The commercial impact of the study is the possibility of using the cryorolled Al alloy in various ion chloride environment. Originality/value The obtained results help in understanding the corrosion behaviour of cryorolled samples under different heat treatment conditions.

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