scholarly journals Microstructure and Mechanical Properties of Rapidly Solidified β-Type Ti–Fe–Sn–Mo Alloys with High Specific Strength and Low Elastic Modulus

Metals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 1135 ◽  
Author(s):  
Li ◽  
Ma ◽  
Jia ◽  
Meng ◽  
Tang ◽  
...  

The microstructure and mechanical properties of rapidly solidified β-type Ti–Fe–Sn–Mo alloys with high specific strength and low elastic modulus were investigated. The results show that the phases of Ti–Fe–Sn–Mo alloys are composed of the β-Ti, α-Ti, and TiFe phases; the volume fraction of TiFe phase decreases with the increase of Mo content. The high Fe content results in the deposition of TiFe phase along the grain boundary of the Ti phase. The Ti75Fe19Sn5Mo1 alloy exhibits the high yield strength, maximum compressive strength, large plastic deformation, high specific strength, high Vickers hardness, and large toughness value, which is a superior new engineering material. The elastic modulus (42.1 GPa) of Ti75Fe15Sn5Mo5 alloy is very close to the elastic modulus of human bone (10–30 GPa), which indicating that the alloy can be used as a good biomedical alloy. In addition, the large H/Er and H3/Er2 values of Ti75Fe19Sn5Mo1 alloy indicate the good wear resistance and long service life as biomedical materials.

Metals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 2052
Author(s):  
Juraj Lapin ◽  
Kateryna Kamyshnykova

The effect of Ta and W additions on microstructure and mechanical properties of tilt-cast Ti-45Al-5Nb-2C (at.%) alloy was investigated. Three alloys with nominal composition Ti-45Al-5Nb-2C-2X (in at.%), where X is Ta or W, were prepared by vacuum induction melting in graphite crucibles followed by tilt casting into graphite moulds. The microstructure of the tilt-cast alloys consists of the α2(Ti3Al) + γ(TiAl) lamellar grains, single γ phase, (Ti,Nb,X)2AlC particles with a small amount of (Ti,Nb,X)C, and β/B2 phase identified only in W containing alloy. The EDS analysis shows that Ta segregates into the carbide particles and reduces dissolution of Nb in both (Ti,Nb,Ta)C and (Ti,Nb,Ta)2AlC phases. The alloying with W reduces Nb content in both carbide phases and leads to stabilisation of β/B2 phase in the lamellar α2 + γ regions. The alloying with Ta and W does not affect the volume fraction of the carbide particles but influences their size and morphology. While the alloying with Ta and W has no significant effect on Vickers hardness and the indentation elastic modulus of the studied alloys, the addition of Ta affects the nanohardness and elastic modulus of the (Ti,Nb,Ta)2AlC phase. The addition of W significantly increases the Vickers microhardness of the lamellar α2 + γ regions.


Author(s):  
S. Fujishiro

In an effort to increase the elastic modulus of commercial Beta-III Titanium alloy (Ti-12Mo4.5Sn5.5Zr) without impairing other mechanical properties, the alloy has been solutionized in the beta and beta/alpha fields and subsequently aged at the alpha and alpha/omega forming temperature range, following water quench; the volume fraction and morphology of the precipitation phases govern the elastic modulus and other mechanical characteristics. Dilatometric technique was employed to determine the omega forming range which is indicated by a notable contraction; contraction is due to depletion of the Mo content in the beta phase. TEM was utilized in order to identify the phases and define morphology whereas the volume fraction of phases was determined by X-ray.


Materials ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3114 ◽  
Author(s):  
Li ◽  
Jia ◽  
Wang ◽  
Li ◽  
Meng ◽  
...  

Effect of Fe addition on microstructure and mechanical properties of as-cast Ti49Ni51 alloy were investigated. The experimental results shows the microstructures of Ti48.5Ni51Fe0.5 and Ti48Ni51Fe1 alloys are mainly composed of TiNi matrix phase (body-centered cubic, BCC), Ti3Ni4 and Ni2.67Ti1.33 phases; the microstructure of Ti47Ni51Fe2 alloy is mainly composed of BCC TiNi, Ti3Ni4, Ni2.67Ti1.33, and Ni3Ti phases; the microstructure of the Ti45Ni51Fe4 alloy is mainly composed of TiNi, Ti3Ni4 and Ni3Ti phases. The Ni3Ti nanocrystalline precipitates at the adjacent position of Ni2.67Ti1.33 phase. The Ti48.5Ni51Fe0.5 and Ti48Ni51Fe1 alloys have high yield strength and fracture strength, and can be as the engineering materials with excellent mechanical properties. In addition, the Ti48.5Ni51Fe0.5 alloy with the low elastic modulus and large elastic energy is also a good biomedical alloy of hard tissue implants. The fracture mechanism of the four alloys is mainly cleavage fracture or quasi-cleavage fracture, supplemented by ductile fracture. The experimental data obtained provide the valuable references in application of as-cast alloys and heat-treated samples in the future.


Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1556
Author(s):  
Zhao Li ◽  
Run Wu ◽  
Mingwei Li ◽  
Song-Sheng Zeng ◽  
Yu Wang ◽  
...  

High boron steel is prone to brittle failure due to the boride distributed in it with net-like or fishbone morphology, which limit its applications. The Quenching and Partitioning (Q&P) heat treatment is a promising process to produce martensitic steel with excellent mechanical properties, especially high toughness by increasing the volume fraction of retained austensite (RA) in the martensitic matrix. In this work, the Q&P heat treatment is used to improve the inherent defect of insufficient toughness of high boron steel, and the effect mechanism of this process on microstructure transformation and the change of mechanical properties of the steel has also been investigated. The high boron steel as-casted is composed of martensite, retained austensite (RA) and eutectic borides. A proper quenching and partitioning heat treatment leads to a significant change of the microstructure and mechanical properties of the steel. The net-like and fishbone-like boride is partially broken and spheroidized. The volume fraction of RA increases from 10% in the as-cast condition to 19%, and its morphology also changes from blocky to film-like. Although the macro-hardness has slightly reduced, the toughness is significantly increased up to 7.5 J·cm−2, and the wear resistance is also improved.


Nanomaterials ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 1024 ◽  
Author(s):  
Milad Haghighi ◽  
Mohammad Shaeri ◽  
Arman Sedghi ◽  
Faramarz Djavanroodi

The effect of graphene nanosheet (GNS) reinforcement on the microstructure and mechanical properties of the titanium matrix composite has been discussed. For this purpose, composites with various GNS contents were prepared by cold pressing and sintering at various time periods. Density calculation by Archimedes’ principle revealed that Ti/GNSs composites with reasonable high density (more than 99.5% of theoretical density) were produced after sintering for 5 h. Microstructural analysis by X-ray diffraction (XRD) and a field emission scanning electron microscope (FESEM) showed that TiC particles were formed in the matrix during the sintering process as a result of a titanium reaction with carbon. Higher GNS content as well as sintering time resulted in an increase in TiC particle size and volume fraction. Microhardness and shear punch tests demonstrated considerable improvement of the specimens’ mechanical properties with the increment of sintering time and GNS content up to 1 wt. %. The microhardness and shear strength of 1 wt. % GNS composites were enhanced from 316 HV and 610 MPa to 613 HV and 754 MPa, respectively, when composites sintered for 5 h. It is worth mentioning that the formation of the agglomerates of unreacted GNSs in 1.5 wt. % GNS composites resulted in a dramatic decrease in mechanical properties.


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