scholarly journals Ultramafic Alkaline Rocks of Kepino Cluster, Arkhangelsk, Russia: Different Evolution of Kimberlite Melts in Sills and Pipes

Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 540
Author(s):  
Alexey Vladimirovich Kargin ◽  
Anna Andreevna Nosova ◽  
Ludmila Vyacheslavovna Sazonova ◽  
Vladimir Vasilievich Tretyachenko ◽  
Yulia Olegovna Larionova ◽  
...  

To provide new insights into the evolution of kimberlitic magmas, we have undertaken a detailed petrographic and mineralogical investigation of highly evolved carbonate–phlogopite-bearing kimberlites of the Kepino cluster, Arkhangelsk kimberlite province, Russia. The Kepino kimberlites are represented by volcanoclastic breccias and massive macrocrystic units within pipes as well as coherent porphyritic kimberlites within sills. The volcanoclastic units from pipes are similar in petrography and mineral composition to archetypal (Group 1) kimberlite, whereas the sills represent evolved kimberlites that exhibit a wide variation in amounts of carbonate and phlogopite. The late-stage evolution of kimberlitic melts involves increasing oxygen fugacity and fluid-phase evolution (forming carbonate segregations by exsolution, etc.). These processes are accompanied by the transformation of primary Al- and Ti-bearing phlogopite toward tetraferriphlogopite and the transition of spinel compositions from magmatic chromite to magnesian ulvöspinel and titanomagnetite. Similar primary kimberlitic melts emplaced as sills and pipes may be transitional to carbonatite melts in the shallow crust. The kimberlitic pipes are characterised by low carbonate amounts that may reflect the fluid degassing process during an explosive emplacement of the pipes. The Kepino kimberlite age, determined as 397.3 ± 1.2 Ma, indicates two episodes of ultramafic alkaline magmatism in the Arkhangelsk province, the first producing non-economic evolved kimberlites of the Kepino cluster and the second producing economic-grade diamondiferous kimberlites.

Minerals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 418 ◽  
Author(s):  
Shangsong Yang ◽  
Heng Wang ◽  
Xinyou Zhu ◽  
Tao Zou ◽  
Chaolei Yang ◽  
...  

Skarn Sn-polymetallic deposits, located in the southern Great Khingan Range, can be divided into Sn–Fe and Sn–Pb–Zn deposits. By systematically studying the geochemical characteristics of source granitoid and deposits, the ore-forming mechanisms were established, and the differences in ore-forming processes between Sn–Fe and Sn–Pb–Zn deposits are discussed. The main findings are as follows: (1) these two deposits were formed in the Late-Yanshanian period; (2) the source granitoid evolved at an early stage in a reducing environment, while the oxygen fugacity increased at a late stage through the influence of a deep-seated fault; (3) fine-grained syenogranite from Dashishan showed a higher degree of evolution than the syenogranite from Damogutu; (4) the Damogutu Sn–Fe and Dashishan Sn–Pb–Zn deposits shared a source of ore-forming fluid, and Fe, Sn, Pb, and Zn all derived from Late-Yanshanian granitoids; and (5) the ore-forming fluid experienced a continuous evolution process from the magmatic to hydrothermal stage, and the magmatic–hydrothermal transitional fluid played a very important role in skarnization and mineralization.


1995 ◽  
Vol 109 (4) ◽  
pp. 300-303 ◽  
Author(s):  
Bharath Singh

AbstractThe place of conservative treatment in sinogenic orbital complications has not been fully explained in the literature. The question that remains unresolved is – at which stage of the disease is surgery indicated?A study was undertaken in 240 patients with sinogenic orbital complications, to determine this. The patients were divided into three groups according to the stage of the disease as determined clinically: Group 1 (52 patients) with early stage disease, as detected by cellulitis only; Group 2 (76 patients) with intermediate stage, as detected by periorbital cellulitis and proptosis, but with full range of eye movement and unaltered vision: Group 3 (122 patients) with late stage disease, as detected by periorbital cellulitis and gross proptosis. with limitation of eye movement and altered vision.Group I and Group 2 patients were treated conservatively, with intravenous antibiotics and antral lavage. Group 3 patients were treated with intravenous antibiotics and surgery. External frontoethmoidectomy was performed in 31 (bilateral in two), ethmoidectomy in 91 (bilateral in five), sphenoidectomy in 15 and bilateral antral washout in all (122 patients). There was 100 per cent success with conservative treatment in Group 1 patients, whilst in Group 2 there was 98.6 per cent failure. The 75 patients in whom conservative treatment failed were successfully treated with surgery: frontoethmoidectomy was performed in 66 and ethmoidectomy in nine. In Group 3 patients, 100 per cent success was achieved with intravenous antibiotics and surgery.Sinogenic orbital complications can be treated conservatively and surgically, depending on the stage of the disease on presentation. Conservative treatment is only suitable for early complications, i.e. patients with periorbital cellulitis only. For disease beyond this stage i.e. intermediate and late stage disease, surgery is the treatment of choice.


1993 ◽  
Vol 30 (12) ◽  
pp. 2423-2435 ◽  
Author(s):  
D. Pillet ◽  
M. Chenevoy ◽  
M. Bélanger

Mineral zonation in the Québec–Labrador Brisson Lake peralkaline granite displays quartzose and feldspathic lithofacies arranged concentrically, the latter occupying the centre of the intrusion. The zonation is the result of successive magmatic pulses. In the feldspathic facies, agpaitic crystallization began under hypersolvus conditions around 720 °C with PF = 0.1 GPa. Subsolvus crystallization involving enrichment of the residual liquid in F continued to below 500 °C. The quartzose facies is more differentiated and its composition was controlled by feldspar fractionation. Early quartz crystallization is partly explained by the high content of F in the magma. The mafic mineral succession is, in both facies: Li- and Zn-rich arfvedsonite with an important ferrorichtérite component, which crystallized along with alkali feldspar under low [Formula: see text]; aenigmatite contemporary of amphibole or anterior, destabilized to form neptunite, astrophyllite, aegirine, or arfvedsonite; primary titaniferous aegyrine, contemporary with the amphibole and replaced by secondary aegyrine; neptunite and astrophyllite replacing aenigmatite. This succession is in accordance with the increase of Na and F in the fluid phase, and the increase of [Formula: see text] near the end of crystallization. Among the accessory minerals, euhedral zircon is indicative of the initial richness of the magma in Zr. Magmatic vlasovite, and elpidite formed from late fluid, are evidence that residual system entered the zirconium silicate stability field. Zircon with a fibrous, radiating texture, and gittinsite are indicative of the postmagmatic evolution of the pluton and the presence of a late stage residual fluid which was enriched in Ca and Sr.


2016 ◽  
Vol 466 (2) ◽  
pp. 135-137 ◽  
Author(s):  
A. I. Buikin ◽  
A. B. Verchovsky ◽  
L. N. Kogarko ◽  
V. A. Grinenko ◽  
O. V. Kuznetsova

1988 ◽  
Vol 125 (6) ◽  
pp. 573-582 ◽  
Author(s):  
R. P. Hall ◽  
D. J. Hughes ◽  
L. Joyner

AbstractThe pyroxene assemblages of four samples of ferrodolerite from the Mesozoic Mount Wellington sill of southern Tasmania are described. The pyroxenes of each sample define an Fe-enrichment trend equivalent to almost half of a Skaergaard-type pyroxene evolution trend. The calcic pyroxenes range from augite to ferroaugite (Ca30–40Mg40–17Fe15–45) and late-stage hedenbergite (Ca45 Mg5Fe50), and the pigeonites from intermediate to ferriferous types (Ca13Mg55–15Fe32–70). XMg numbers (Mg/(Mg + Fe)) of the calcic pyroxenes vary from 0.8 to 0.1, and of the calcium-poor pyroxenes (pigeonites) from 0.62 to 0.17. The chemical variation in the pyroxenes within individual samples is far greater than between the different samples. One sample contains an extremely wide range of pyroxenes which include some of the most ferriferous pigeonites ever recorded (Ca14Mg15 Fe71). Ti and Al contents are also highly varied, Ti:Al ionic ratios ranging from 1:15 to 1:2 with decreasing XMg. The augites have higher Ti and Al contents than pigeonites with corresponding XMg. The hedenbergites have erratic but generally low Ti contents, due to their late precipitation together with ulvospinel. The presence of such highly variable pyroxenes within individual samples and in some cases as single, complex grains makes the recognition of coexisting pyroxene pairs in such dolerites very difficult, but graphical pyroxene thermometers suggest a crystallization temperature range of 1100 to 850 °C.The range of pyroxene compositions in such dolerites is strongly influenced by the oxygen fugacity (fO2) of the liquid from which they derive. The primary Fe-Ti oxide phase in these Tasmanian dolerites is ulvospinel (now oxidized to ilmenite ‘oxidation-exsolution’ lamellae in titanomagnetite hosts) clearly demonstrating the originally low fO2 of the parental tholeiitic magma of the Mount Wellington sill.


Author(s):  
Henning Sørensen ◽  
Lotte Melchior Larsen

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Sørensen , H., & Melchior Larsen, L. (2001). The hyper-agpaitic stage in the evolution of the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin, 190, 83-94. https://doi.org/10.34194/ggub.v190.5177 _______________ The term hyper-agpaitic covers mineral associations characterised by a wealth of Na-rich minerals such as natrosilite, zirsinalite, ussingite, vuonnemite, vitusite and lomonosovite. This mineral association clearly indicates a higher degree of alkalinity than for agpaitic rocks in general. In the Ilímaussaq complex hyper-agpaitic mineral associations occur not only in pegmatites and hydrothermal veins as in the Kola complexes, Khibina and Lovozero, but also in highly evolved lujavrites and in the fenitised volcanic rocks in the roof of the complex. This paper reviews the occurrences of hyper-agpaitic mineral associations in the Ilímaussaq complex. The mineral assemblages are determined by an interplay of temperature, pressure, oxygen fugacity, alkalinity, especially the concentration of Na, and contents of elements such as Zr, Ti, Nb, REE, Fe, Mn, U, Th, P, F, Cl and H2O. Increasing and decreasing stages of alkalinity may be distinguished. At increasing alkalinity nepheline is for instance substituted by naujakasite, while at decreasing alkalinity and temperature naujakasite is substituted by analcime.


1986 ◽  
Vol 50 (358) ◽  
pp. 611-620 ◽  
Author(s):  
Kevin W. Burton

AbstractGarnets with an unusual inclusion pattern of cylindrical quartz intergrowths have been found to develop exclusively in the presence of graphite. The intergrowths consist of quartz rods, 1–5 µm in diameter, originating at the sector-zone interfaces in the garnet with the long axes normal to the crystal faces. The lattice orientation and continuity of the quartz suggests that the interphase boundaries between the quartz and garnet are epitaxially related and that new material was added to the tube as the crystal face of the garnet grew. In the presence of a C-O-H fluid, at the temperatures and pressures recorded, (P = 6.5 kbar, T = 500°C), the amount of CO2 present restricts the solubility of SiO2 in the intergranular fluid phase, where the oxygen fugacity (fo2) is below the Quartz-fayalite-magnetite (QFM) buffer, and within the stability field of graphite. The reduced solubility will lower the concentration of SiO2 in solution, and hence restrict its ease of transport via the fluid, resulting in an excess of SiO2at the site of garnet growth. Under such conditions the SiO2 is incorporated in the growing garnet in the form of the cylindrical quartz intergrowths.


2001 ◽  
Vol 172 (3) ◽  
pp. 309-317 ◽  
Author(s):  
El Hassan El Aouli ◽  
Dominique Gasquet ◽  
Moha Ikenne

Abstract In the Igherm inlier (western Anti-Atlas, Morocco) doleritic dyke swarms with various directions and gabbroic intrusive bodies were emplaced during Neoproterozoic times, cutting across either Eburnean micaschists and granites or Panafrican limestones and quartzites. All these rocks were deformed by the main Panafrican schistosity and covered by molassic and volcanic Upper Neoproterozoic series. The primary mineralogical assemblages (plagioclase, augite, olivine...) of the mafic rocks are nearly completely replaced by secondary assemblages (albite, actinolite, chlorite, epidote, calcite, quartz, leucoxene, magnetite, hematite...). However, three main groups have been recognized by the means of relative chronology and petrography. The group 1 is earlier, as shown by the intrusive character of the dykes of the other two groups into its gabbroic bodies. Using incompatible trace elements and rare earth elements it appears that this magmatism is truly heterogeneous and that the three groups have different magmatic affinities. The group 1 corresponds to tholeiitic dolerites and gabbros characterized by intersertal and ophitic textures and by high contents in Fe 2 O 3 (12.16 to 16.64%), TiO 2 (1.46 to 2.5%), Zr (90 to 174 ppm), Nb (7 to 13 ppm), Y (21.68 to 38.74 ppm) and V (264 to 419 ppm). The REE contents are low (Sigma REE = 49 to 137 ppm) and the REE patterns are flat [1.99<(La/Yb) N <4.56] showing a relative slight enrichment in LREE and no anomaly in Eu (0.89>Eu/Eu (super *) <1.11). These features as the TiO 2 vs FeO (super *) /MgO and V vs Ti/1000 diagrams are characteristic of anorogenic intraplate magmas. The group 2 corresponds to calc-alkaline dolerites and gabbros showing fine-grained intersertal textures and high contents of Al 2 O 3 (14.10 to 20.64%) and low contents of Fe 2 O 3 (8.35 to 12.91%), TiO 2 (0.68 to 1.41%), Zr (66 to 106 ppm), Nb (5 to 7 ppm), Y (16.41 to 20.75 ppm) and V (144 to 264 ppm). The REE contents vary from 67 to 155 ppm and the REE patterns are fractionated (2.78<(La/Yb) N <6.62) with a strong enrichment in LREE. The slight positive Eu anomaly (0.91<Eu/Eu (super *) <1.37) is related to the wealth of plagioclases frequently observed in these rocks. The TiO 2 contents of these rocks and their low FeO (super *) /MgO ratios give them a calc-alkaline affinity similar to that of calc-alkaline orogenic basalts related to an oceanic subduction. The group 3 corresponds to alkaline dolerites characterized by fine-grained intersertal textures with high contents of TiO 2 (3.85 to 3.97%), P 2 O 5 (0.66 to 0.77%), Nb (33 to 39 ppm), Zr (262 to 287 ppm), Y (39.6 to 47.7 ppm) and REE (Sigma REE = 205 to 218 ppm). The REE patterns are fractionated (7.77<La/Yb) N <6.65) without no Eu anomaly (0.99<Eu/Eu (super *) <1.02). The Ti/V and Y/Nb ratios (65.26 to 74.95 and 1.19 to 1.22, respectively) are those of alkaline rocks found in intraplate environments. The detailed petrographical, geochemical and field studies of the Igherm inlier show that the mafic magmatism is more complex than previously described. The mafic tholeiitic and alkaline magmatism occurring in the Igherm inlier is also present in the other inliers of the Moroccan Anti-Atlas during Neoproterozoic times. On the other hand the calc-alkaline Neoproterozoic mafic magmatism is very rare elsewhere in the Anti-Atlas except in the Siroua Massif and locally in the Bas Draa and Tagragra d'Akka inliers (western Anti-Atlas). The geodynamical environment of this mafic magmatism is linked to a strong extensional tectonic regime occurring at the northern border of the West African craton during Neoproterozoic times. This regime is related to the oceanic opening described in Central Anti-Atlas and to the emplacement of the ophiolites of Bou Azzer and Siroua or occurs immediately after the oceanic opening. The chemical heterogeneities observed in the three defined groups can be related to heterogeneities of mantellic sources and/or various partial melting ratios of the sub-continental mantle. We can assume that this major fissural magmatic event, not precisely dated, is equivalent to that observed in the other Neoproterozoic provinces in Hoggar, Cameroon, north America and Brazil.


1978 ◽  
Vol 42 (323) ◽  
pp. 391-399 ◽  
Author(s):  
Michael E. Cherry ◽  
Lowell T. Trembath

SummaryThe variation in the structural state of potassium feldspars from the St. George pluton, New Brunswick, Canada, is discussed. Monoclinic potassium feldspars occur near the eastern end of the pluton whereas the granites at the western end contain triclinic potassium feldspars. Although the bulk compositions of the host rocks are all very near the granite minimum melt composition there is a systematic increase in the degree of ordering for both the triclinic and monoclinic suites of feldspars with the more ordered variants tending to occur within rocks nearest the minimum melt composition. There is more abundant textural evidence for the presence of a late-stage fluid phase in the granites containing the monoclinic potassium feldspars. It is proposed that a slower post-crystallization cooling rate was also a factor in the nucleation of triclinic domains in the potassium feldspars at the western end of the pluton.


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