scholarly journals Origin of Critical Metals in Fe–Ni Laterites from the Balkan Peninsula: Opportunities and Environmental Risk

Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1009
Author(s):  
Maria Economou-Eliopoulos ◽  
Magdalena Laskou ◽  
Demetrios Eliopoulos ◽  
Ifigeneia Megremi ◽  
Sofia Kalatha ◽  
...  
Keyword(s):  
Renewable Energy Sources ◽  
Human Health Risk ◽  
Balkan Peninsula ◽  
Critical Metals ◽  
Mining Areas ◽  
Icp Ms ◽  
Lowermost Part ◽  
The Eu ◽  
Laterite Ore ◽  
Epigenetic Processes

As the global energy sector is expected to experience a gradual shift towards renewable energy sources, access to special metals in known resources is of growing concern within the EU and at a worldwide scale. This is a review on the Fe–Ni ± Co-laterite deposits in the Balkan Peninsula, which are characterized by multistage weathering/redeposition and intense tectonic activities. The ICP-MS analyses of those laterites indicated that they are major natural sources of Ni and Co, with ore grading from 0.21 to 3.5 wt.% Ni and 0.03 to 0.31 wt.% Co, as well as a significant Sc content (average 55 mg/kg). The SEM-EDS analyses revealed that fine Fe-, Ni-, Co-, and Mn-(hydr)oxides are dominant host minerals and that the enrichment in these elements is probably controlled by the post-formation evolution of initial ore redeposition. The paucity of rare earth element (REE) within the typical Fe–Ni laterite ore and the preferential occurrence of Co (up to 0.31 wt.%), REE content (up to 6000 mg/kg ΣREE), and REE-minerals along with Ni, Co, and Mn (asbolane and silicates) towards the lowermost part of the Lokris (C. Greece) laterite ore suggest that their deposition is controlled by epigenetic processes. The platinum-group element (PGE) content in those Fe–Ni laterites, reaching up to 88 μg/kg Pt and 26 μg/kg Pd (up to 186 μg/kg Pd in one sample), which is higher than those in the majority of chromite deposits associated with ophiolites, may indicate important weathering and PGE supergene accumulation. Therefore, the mineralogical and geochemical features of Fe–Ni laterites from the Balkan Peninsula provide evidence for potential sources of certain critical metals and insights to suitable processing and metallurgical methods. In addition, the contamination of soil by heavy metals and irrigation groundwater by toxic Cr(VI), coupled with relatively high Cr(VI) concentrations in water leachates for laterite samples, altered ultramafic rocks and soils neighboring the mining areas and point to a potential human health risk and call for integrated water–soil–plant investigations in the basins surrounding laterite mines.

scholarly journals Evaluation of Sustainable Energy Development Progress in EU Member States in the Context of Building Renovation

Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4209
Author(s):  
Rita Remeikienė ◽  
Ligita Gasparėnienė ◽  
Aleksandra Fedajev ◽  
Marek Szarucki ◽  
Marija Đekić ◽  
...  
Keyword(s):  
Energy Efficiency ◽  
Energy Consumption ◽  
Co2 Emissions ◽  
Renewable Energy Sources ◽  
Investment Efficiency ◽  
The European Union ◽  
Energy Usage ◽  
Member States ◽  
Eu Member States ◽  
The Eu

The main goal of setting energy efficiency priorities is to find ways to reduce energy consumption without harming consumers and the environment. The renovation of buildings can be considered one of the main aspects of energy efficiency in the European Union (EU). In the EU, only 5% of the renovation projects have been able to yield energy-saving at the deep renovation level. No other study has thus far ranked the EU member states according to achieved results in terms of increased usage in renewable sources, a decrease in energy usage and import, and reduction in harmful gas emissions due to energy usage. The main purpose of this article is to perform a comparative analysis of EU economies according to selected indicators related to the usage of renewable resources, energy efficiency, and emissions of harmful gasses as a result of energy usage. The methodological contribution of our study is related to developing a complex and robust research method for investment efficiency assessment allowing the study of three groups of indicators related to the usage of renewable energy sources, energy efficiency, and ecological aspects of energy. It was based on the PROMETHEE II method and allows testing it in other time periods, as well as modifying it for research purposes. The EU member states were categorized by such criteria as energy from renewables and biofuels, final energy consumption from renewables and biofuels, gross electricity generation from renewables and biofuels and import dependency, and usage of renewables and biofuels for heating and cooling. The results of energy per unit of Gross Domestic Product (GDP), Greenhouse gasses (GHG) emissions per million inhabitants (ECO2), energy per capita, the share of CO2 emissions from public electricity, and heat production from total CO2 emissions revealed that Latvia, Sweden, Portugal, Croatia, Austria, Lithuania, Romania, Denmark, and Finland are the nine most advanced countries in the area under consideration. In the group of the most advanced countries, energy consumption from renewables and biofuels is higher than the EU average.

scholarly journals Changes in Energy Consumption in Agriculture in the EU Countries

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1570
Author(s):  
Tomasz Rokicki ◽  
Aleksandra Perkowska ◽  
Bogdan Klepacki ◽  
Piotr Bórawski ◽  
Aneta Bełdycka-Bórawska ◽  
...  
Keyword(s):  
European Union ◽  
Renewable Energy ◽  
Energy Consumption ◽  
Correlation Coefficient ◽  
Renewable Energy Sources ◽  
Energy Sources ◽  
The European Union ◽  
Eu Countries ◽  
Research Hypothesis ◽  
The Eu

The paper’s main purpose was to identify and present the current situation and changes in energy consumption in agriculture in the European Union (EU) countries. The specific objectives were the determination of the degree of concentration of energy consumption in agriculture in the EU countries, showing the directions of their changes, types of energy used, and changes in this respect, establishing the correlation between energy consumption and changes in the economic and agricultural situation in the EU countries. All member states of the European Union were deliberately selected for research on 31 December 2018 (28 countries). The research period covered the years 2005–2018. The sources of materials were the literature on the subject, and data from Eurostat. Descriptive, tabular, and graphical methods were used to analyze and present materials, dynamics indicators with a stable base, Gini concentration coefficient, concentration analysis using the Lorenz curve, coefficient of variation, Kendall’s tau correlation coefficient, and Spearman’s rank correlation coefficient. A high concentration of energy consumption in agriculture was found in several EU countries, the largest in countries with the largest agricultural sector, i.e., France and Poland. There were practically no changes in the concentration level. Only in the case of renewable energy, a gradual decrease in concentration was visible. More and more countries developed technologies that allow the use of this type of energy. However, the EU countries differed in terms of the structure of the energy sources used. The majority of the basis was liquid fuels, while stable and gaseous fuels were abandoned in favor of electricity and renewable sources—according to which, in the EU countries, the research hypothesis was confirmed: a gradual diversification of energy sources used in agriculture, with a systematic increase in the importance of renewable energy sources. The second research hypothesis was also confirmed, according to which the increase in the consumption of renewable energy in agriculture is closely related to the economy’s parameters. The use of renewable energy is necessary and results from concern for the natural environment. Therefore, economic factors may have a smaller impact.

scholarly journals Mineralogy and Geochemistry of Ultramafic Rocks from Rachoni Magnesite Mine, Gerakini (Chalkidiki, Northern Greece)

Minerals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 934
Author(s):  
Evangelos Tzamos ◽  
Micol Bussolesi ◽  
Giovanni Grieco ◽  
Pietro Marescotti ◽  
Laura Crispini ◽  
...  
Keyword(s):  
Raw Materials ◽  
Mining Area ◽  
Ultramafic Rocks ◽  
Northern Greece ◽  
Icp Ms ◽  
Time In Literature ◽  
History Of ◽  
First Time ◽  
The Eu

The importance of magnesite for the EU economy and industry is very high, making the understanding of their genesis for the exploration for new deposits a priority for the raw materials scientific community. In this direction, the study of the magnesite-hosting ultramafic rocks can be proved very useful. For the present study, ultramafic rock samples were collected from the magnesite ore-hosting ophiolite of the Gerakini mining area (Chalkidiki, Greece) to investigate the consecutive alteration events of the rocks which led to the metallogenesis of the significant magnesite ores of the area. All samples were subjected to a series of analytical methods for the determination of their mineralogical and geochemical characteristics: optical microscopy, XRD, SEM, EMPA, ICP–MS/OES and CIPW normalization. The results of these analyses revealed that the ultramafic rocks of the area have not only all been subjected to serpentinization, but these rocks have also undergone carbonation, silification and clay alteration. The latter events are attributed to the circulation of CO2-rich fluids responsible for the formation of the magnesite ores and locally, the further alteration of the serpentinites into listvenites. The current mineralogy of these rocks was found to be linked to one or more alteration event that took place, thus a significant contribution to the metallo- and petrogenetic history of the Gerakini ophiolite has been made. Furthermore, for the first time in literature, Fe inclusions in olivines from Greece were reported.

scholarly journals Influence of the Climate Policy of the European Union on the Competitiveness of Pollution-generating Sectors of the Polish Economy in the Context of Sustainable Development

2012 ◽  
Vol 14 (4) ◽  
pp. 81-96
Author(s):  
Małgorzata Burchard-Dziubińska
Keyword(s):  
Climate Policy ◽  
Renewable Energy Sources ◽  
Production Costs ◽  
The European Union ◽  
Greenhouse Gasses ◽  
Common System ◽  
Eu Climate Policy ◽  
Polish Economy ◽  
Emission Limits ◽  
The Eu

The text analyses the influence of the EU climate policy on the competitiveness pollution-generating of sectors of the Polish economy. Study of literature and the results of the questionnaire survey, carried out in 2008 in enterprises located in Poland and representing the steel, glass, aluminium and cement industries became a basis for formulating conclusions concerning the consequences of the climate policy already implemented and planned after 2012. The EU climate policy, particularly the common system of emission allowances trade, makes the enterprises face new developmental barriers. The expected increase in production costs will not only slow down the production dynamics, but may also entail lowering the competitiveness of Polish companies compared to companies from outside the EU, to which the greenhouse gasses emission limits do not apply. Adverse consequences for employment and for regional development should also be considered indisputable. If that was accompanied by an emission leakage outside the EU, achieving the global purposes of the climate policy would also become questionable. The businesses surveyed represent industries which are pollution generators by their nature and even ecologically-oriented technological progress is incapable of ensuring considerable emission reductions without general switching of the economy to renewable energy sources.

Mercury contamination in fish from gold mining areas in Indonesia and human health risk assessment

2006 ◽  
Vol 368 (1) ◽  
pp. 320-325 ◽  
Author(s):  
Zuleica C. Castilhos ◽  
Saulo Rodrigues-Filho ◽  
Ana Paula C. Rodrigues ◽  
Roberto C. Villas-Bôas ◽  
Shefa Siegel ◽  
...  
Keyword(s):  
Risk Assessment ◽  
Health Risk ◽  
Human Health ◽  
Health Risk Assessment ◽  
Gold Mining ◽  
Human Health Risk ◽  
Human Health Risk Assessment ◽  
Mercury Contamination ◽  
Mining Areas

scholarly journals Rare and Critical Metals in Pyrite, Chalcopyrite, Magnetite, and Titanite from the Vathi Porphyry Cu-Au±Mo Deposit, Northern Greece

Minerals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 630
Author(s):  
Christos L. Stergiou ◽  
Vasilios Melfos ◽  
Panagiotis Voudouris ◽  
Lambrini Papadopoulou ◽  
Paul G. Spry ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
Mineral Chemistry ◽  
Critical Metals ◽  
Northern Greece ◽  
Inductively Coupled ◽  
Porphyry Cu ◽  
Icp Ms ◽  
Quartz Monzonite ◽  
Ore Minerals ◽  
Plasma Mass Spectrometry

The Vathi porphyry Cu-Au±Mo deposit is located in the Kilkis ore district, northern Greece. Hydrothermally altered and mineralized samples of latite and quartz monzonite are enriched with numerous rare and critical metals. The present study focuses on the bulk geochemistry and the mineral chemistry of pyrite, chalcopyrite, magnetite, and titanite. Pyrite and chalcopyrite are the most abundant ore minerals at Vathi and are related to potassic, propylitic, and sericitic hydrothermal alterations (A- and D-veins), as well as to the late-stage epithermal overprint (E-veins). Magnetite and titanite are found mainly in M-type veins and as disseminations in the potassic-calcic alteration of quartz monzonite. Disseminated magnetite is also present in the potassic alteration in latite, which is overprinted by sericitic alteration. Scanning electron microscopy and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of pyrite and chalcopyrite reveal the presence of pyrrhotite, galena, and Bi-telluride inclusions in pyrite and enrichments of Ag, Co, Sb, Se, and Ti. Chalcopyrite hosts bornite, sphalerite, galena, and Bi-sulfosalt inclusions and is enriched with Ag, In, and Ti. Inclusions of wittichenite, tetradymite, and cuprobismutite reflect enrichments of Te and Bi in the mineralizing fluids. Native gold is related to A- and D-type veins and is found as nano-inclusions in pyrite. Titanite inclusions characterize magnetite, whereas titanite is a major host of Ce, Gd, La, Nd, Sm, Th, and W.

Arsenic Speciation in Rice, Mechanisms and Associated Health Risk Through Rice Consumption in Various Districts of Khyber Pakhtunkhwa, Pakistan

2021 ◽  
Author(s):  
Tasneem Sarwar ◽  
Sardar Khan ◽  
Said Muhammad ◽  
Javed Nawab ◽  
Shehla Amin ◽  
...  
Keyword(s):  
Health Risk ◽  
Human Health ◽  
Human Health Risk ◽  
Daily Intake ◽  
Mining Activities ◽  
Khyber Pakhtunkhwa ◽  
Icp Ms ◽  
Rice Samples ◽  
Potential Human Health Risk ◽  
Potential Human Health

Abstract Arsenic (As) is one of the toxic metalloids therefore can cause health risk in the consumers through consumption of contaminated food and rice. The current study focused on As speciation in rice, bioavailability, mechanisms and its potential human health risk. For this purpose, rice and soil samples were collected from 16 different districts (non-mining and mining) of Khyber Pakhtunkhwa (Pakistan). Soil physicochemical characteristic such as texture, electrical conductivity (EC), organic matter (OM), pH, iron (Fe) and phosphorus (P) were determined. Total arsenic (AsT) concentrations were analyzed using ICP-MS, while the arsenite (As3+), arsenate (As5+), arsenobetine (BAs), dimethylarsenic (DMA) and monomethyl arsenic (MMA) were determined by HPLC–ICP-MS method. Results showed the highest AsT (0.28 mg/kg) was observed in the rice samples of DI Khan District and lowest (0.06 mg/kg) in Shangla District. However, these findings were found within the permissible limits set by various authorities. Furthermore, results showed higher concentrations of inorganic As (Asi) than organic As (Aso) species in rice. The estimated daily intake (EDI) and incremental lifetime cancer risk (ILTCR) were used to evaluate the potential human health risk for As consumption in rice. Results revealed that the rice samples collected from the district having mining activities had higher value of As (0.28 mg/kg of AsT) as compared to non-mining (0.072 mg/kg of AsT). The highest ILTCR value (0.00196) was observed for rice collected from mining districts. This study revealed that mining activities have great influence on the As contamination of soil and grown rice. This study recommends the soil amendment in districts having mining activities to lower As availability in soil and its bioaccumulation in growing rice that will help to keep lower the potential risk.

scholarly journals Modern Trends in the Development of Renewable Energy: the Experience of the EU and Leading Countries of the World

2020 ◽  
pp. 117-133
Author(s):  
L.Hr. Melnyk ◽  
O.N. Derykolenko ◽  
Yu.O. Mazin ◽  
O.I. Matsenko ◽  
V.S. Piven
Keyword(s):  
Sustainable Development ◽  
Renewable Energy ◽  
Global Economy ◽  
Alternative Energy ◽  
Power Plants ◽  
Renewable Energy Sources ◽  
Energy Sources ◽  
Alternative Energy Sources ◽  
The World ◽  
The Eu

Energy security and independence is one of the key points in sustainable development. In modern conditions of rapid growth and development of technologies, more and more attention is paid to finding practical solutions for environmentally friendly and inexpensive energy production. For a long time, scientists from various fields of scientific activity around the world have been engaged in the development and use of alternative energy sources. The share of renewable energy sources in the generation of electricity around the world is growing steadily, which indicates an increase in the use of energy obtained from alternative sources, such as, for example, wind and sun. These trends testify to the desire of consumers to abandon the use of fossil energy sources and nuclear power plants as much as possible in order to ensure further sister development. Under the current conditions of the COVID-19 pandemic, the demand for electricity worldwide has decreased, however, as the study shows, this pandemic has not affected the development of renewable energy. The article analyzes modern trends in the development of renewable energy, taking into account the experience of the EU countries and leading countries of the world in this area. As a result, it was concluded that in modern conditions, to achieve sustainable development, transformation processes are needed in such an important area as energy. Various processes in the global economy, which contributed to the intensive development of alternative energy sources, served as a powerful impetus for such changes. Many countries have made significant progress in the development of renewable energy.

scholarly journals Sb- Bi-Bearing Metallogeny of the SerboMacedonian-Rhodope Metallogenic Belt (SRMB)

2019 ◽  
Vol 55 (1) ◽  
pp. 34 ◽  
Author(s):  
Ananias Tsirambides ◽  
Anestis Filippidis
Keyword(s):  
European Union ◽  
Mineral Assemblage ◽  
Balkan Peninsula ◽  
The European Union ◽  
Rare Metals ◽  
Ore Deposit ◽  
Porphyry Cu ◽  
Metallogenic Belt ◽  
Critical Metal ◽  
The Eu

Various types of deposits such as carbonate-replacement Pb-Zn-Ag-Au, porphyry Cu-Mo-Au, stratiform volcano-sedimentary, isolated magmatic-hydrothermal and skarns compose the Serbomacedonian-Rhodope Metallogenic Belt (SRMB), which intersects with a NNW-SSE trend the Balkan Peninsula. This arcuate belt is about 500 km long and 130-180 km wide. Sb-Bi alloys and Ag-Cu-Pb-Sb-Bi sulfosalts have been discovered in some metal assemblages in the SRMB. The European Union (EU) is highly dependent on critical and rare metals, such as Sb and Bi, which are very important for a sustainable development. Greece is one of the EU countries with the most potential for supplying the strategic metal Sb in the future, since it hosts a significant ore deposit at Rizana/Lachanas (central Macedonia). Here, the stibnite reserves are 5,000 t (proven) and 50,000-100,000 t (indicated). Both have average Sb=0.3 wt%. In addition, at the same district, there are 1000 t (proven) of wolframite. Another promising Sb-bearing mineral assemblage exists at Alshar (North Macedonia). Here, the stibnite reserves are >20,000 t (indicated) with average Sb=0.5 wt%. At both mineralization districts further investigations are needed to determine the grade and the proven reserves of the critical metal Sb. Until today none encouraging site has been located in the SRMB for remarkable Bi-bearing ore.

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