scholarly journals Iron Silicides in Fulgurites

Minerals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1394
Author(s):  
Tian Feng ◽  
Joshua Abbatiello ◽  
Arthur Omran ◽  
Christopher Mehta ◽  
Matthew A. Pasek

Iron silicide minerals (Fe-Si group) are found in terrestrial and solar system samples. These minerals tend to be more common in extraterrestrial rocks such as meteorites, and their existence in terrestrial rocks is limited due to a requirement of extremely reducing conditions to promote their formation. Such extremely reducing conditions can be found in fulgurites, which are glasses formed as cloud-to-ground lightning heats and fuses sand, soil, or rock. The objective of this paper is to review reports of iron silicides in fulgurites, note any similarities between separate fulgurite observations, and to explain the core connection between geological environments wherein these minerals are found. In addition, we also compare iron silicides in fulgurites to those in extraterrestrial samples.

1994 ◽  
Vol 353 ◽  
Author(s):  
R. Bros ◽  
F. Gauthier-Lafaye ◽  
P. Larque ◽  
J. Samuel ◽  
P. Stille

AbstractNew mineralogical and isotopic studies were carried out on samples from the Bangombé natural nuclear reactor. This reactor is located at shallow depth in the weathering profile and has been subjected to severe supergene alteration. Textural evidence indicates partial dissolution of uraninite in the Bangombé ore related to precipitation of Fe-Ti oxi-hydroxides and clay minerals (kaolinite and metahalloysite). As a consequence of the alteration of the uraninite, uranium and f issiogenic rare earth elements were released in the clayey border of the reactor, whereas radiogenic 232Th remained confined in the close vicinity of the core. A retention effect is also evidenced, under reducing conditions, in the black shales located above the reactor.


Science ◽  
2012 ◽  
Vol 336 (6077) ◽  
pp. 72-75 ◽  
Author(s):  
Christopher W. Dale ◽  
Kevin W. Burton ◽  
Richard C. Greenwood ◽  
Abdelmouhcine Gannoun ◽  
Jonathan Wade ◽  
...  

Late accretion of primitive chondritic material to Earth, the Moon, and Mars, after core formation had ceased, can account for the absolute and relative abundances of highly siderophile elements (HSEs) in their silicate mantles. Here we show that smaller planetesimals also possess elevated HSE abundances in chondritic proportions. This demonstrates that late addition of chondritic material was a common feature of all differentiated planets and planetesimals, irrespective of when they accreted; occurring ≤5 to ≥150 million years after the formation of the solar system. Parent-body size played a role in producing variations in absolute HSE abundances among these bodies; however, the oxidation state of the body exerted the major control by influencing the extent to which late-accreted material was mixed into the silicate mantle rather than removed to the core.


2020 ◽  
Vol 117 (45) ◽  
pp. 27893-27898
Author(s):  
Dongyang Huang ◽  
James Badro ◽  
Julien Siebert

The bulk silicate Earth (BSE), and all its sampleable reservoirs, have a subchondritic niobium-to-tantalum ratio (Nb/Ta). Because both elements are refractory, and Nb/Ta is fairly constant across chondrite groups, this can only be explained by a preferential sequestration of Nb relative to Ta in a hidden (unsampled) reservoir. Experiments have shown that Nb becomes more siderophile than Ta under very reducing conditions, leading the way for the accepted hypothesis that Earth’s core could have stripped sufficient amounts of Nb during its formation to account for the subchondritic signature of the BSE. Consequently, this suggestion has been used as an argument that Earth accreted and differentiated, for most of its history, under very reducing conditions. Here, we present a series of metal–silicate partitioning experiments of Nb and Ta in a laser-heated diamond anvil cell, at pressure and temperature conditions directly comparable to those of core formation; we find that Nb is more siderophile than Ta under any conditions relevant to a deep magma ocean, confirming that BSE’s missing Nb is in the core. However, multistage core formation modeling only allows for moderately reducing or oxidizing accretionary conditions, ruling out the need for very reducing conditions, which lead to an overdepletion of Nb from the mantle (and a low Nb/Ta ratio) that is incompatible with geochemical observations. Earth’s primordial magma ocean cannot have contained less than 2% or more than 18% FeO since the onset of core formation.


Author(s):  
George A. F. Hendry ◽  
R. M. M. Crawford

The Galileo satellite during its recent passes close to the Earth recorded a planet with an unusual red-absorbing pigment, a poisonous atmosphere, simultaneously rich in oxygen and in methane, with strong, modulated, narrow-band, radio emissions in the MHz frequencies (Sagan et al. 1993). To an observer visiting the solar system, these features; the photo-oxidisable pigment chlorophyll, abundant atmospheric oxygen, the existence of reducing conditions and intelligent life might well appear self-contradictory. While intelligent life is a recent event, the presence of other forms of life based on photosynthesis and survival under both oxygen-rich atmospheres and reducing conditions go back to the earliest times (Table 1). Life on Earth has evolved over nearly 4 G years under atmospheric environments ranging from anoxia, to hypoxia, to hyperoxia (relative to the present day), and not always in that sequence.


Author(s):  
David Ehrenfeld

At the end of the Cretaceous period, the last dinosaurs disappeared from the earth, setting off an evolutionary jubilee among the Milquetoast-like mammals that survived them, and preparing the ground for what was to become, 65 million years later, a permanent source of gainful occupation for scientists whose job it is to wonder why the dinosaurs died out. Scores of reasons have been given for this remarkable concatenation of extinctions. Global climate and sea level were changed by a city-sized asteroid striking the earth near what is now the Yucatan, or by a massive set of volcanic eruptions, or by the solar system passing through the core of a giant molecular cloud, perhaps colliding with a supercomet loosened from the Oort cluster, which orbits the Sun beyond Pluto. Theories of catastrophic extinction abound. Some of the most daring even conjure up the specter of an unseen companion star to our Sun, named Nemesis, whose eccentric orbit brings a wave of potentially deadly comet showers—and extinctions—every 26 million years. But there are also paleontologists who argue that the dinosaurs went away gradually, not suddenly, over a period of millions of years, and that toward the end they coexisted with the earliest hooved mammals, including ancestors of horses, cows, and sheep. If extinction was gradual, a different line of thought opens up: perhaps the dinosaurs died out because they couldn’t adapt and compete in a changing world. The big lummoxes were obsolete. I heard about the dinosaurs’ obsolescence back in my student days. It was as satisfying a notion then as it is today, especially if you didn’t think about it too hard. Here were these lumbering, pea-brained reptiles, barely able to walk and chew gum at the same time, while all around and underneath them, cleverly hiding behind clumps of primitive vegetation and cleverly burrowing in tunnels in the ground, were the nerdy but smart little mammals about to emerge from the shadows and begin their ascent to glory—somewhat, it occurs to me now, like Bill Gates in the waning days of heavy manufacturing.


2008 ◽  
Vol 272 ◽  
pp. 99-106
Author(s):  
Dao Ren Gong ◽  
Dong Sheng Li ◽  
Zhi Zhong Yuan ◽  
De Ren Yang

Iron silicide films with two different structures were fabricated by electron beam evaporation (EBE) technique. X-ray diffraction (XRD), Fourier transform infrared (FTIR) and scanning electron microscope (SEM) were carried out to describe the characteristics and structures of the films. It was found that after annealing at 800oC for 5 h, the β-FeSi2 film formed in the sample with the structure of Si/Fe film on silicon substrate, while only FeSi film generated in the sample with the structure of Si/Fe/Si films on silicon substrate. It is considered that the different iron silicides may be due to the different reaction of iron with crystal silicon or amorphous silicon, which is related to diffusion of iron or silicon atoms.


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