Composite Zn(II) Ferrocyanide/Polyethylenimine Cryogels for Point-of-Use Selective Removal of Cs-137 Radionuclides

The feasibility of several approaches to the fabrication of monolith composite cryogels containing transition-metal ferrocyanides for Cs+ ion uptake has been evaluated. Although in the series of investigated metal ion precursors (Cu(II), Zn(II), Ni(II), and Co(II)), in situ formation of the sorption active phase in polyethyleneimine (PEI) cryogel was feasible only in the case of Zn(II) ferrocyanide, this approach has shown significant advantages over the immobilization of ex situ synthesized ferrocyanide nanoparticles. Nanoparticles of the mixed ferrocyanide Zn1.85K0.33[Fe(CN)6] formed in situ had an average size of 516 ± 146 nm and were homogeneously distributed in the monolith located at the polymer surface rather than embedded in the matrix. The Young modulus of the PEI cryogel increased after modification from 25 to 57 kPa, but composites maintained high permeability to the flow. Sorption of Cs+ ions has been investigated at superficial velocity up to 8 m/h. Steep breakthrough profiles and uptake efficiency of >99.5% until breakthrough point confirmed that a supermacroporous structure of the monolith composite assured good mass transfer, so that intraparticle diffusion was not the limiting stage of sorption kinetics. Application of the rate-constant distribution model (RCD model) to analyze the breakthrough curves of Cs+ sorption allowed the identification of two types of sorption sites with a difference in sorption rate constants of ~1 log unit. Most likely, sorption on “fast” sorption sites was governed by ion exchange between Cs+ ions in solution and K+ ions in the ferrocyanide lattice. Cs-137 radionuclide removal was investigated using the monolith composite columns of various geometries at superficial velocity up to the 6.6 m/h; specific gamma activity was reduced from 265 kBq/L to the background level, showing high potential of these materials for POU application.

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Properties of Metal / Polyphenylquinoxaline Interfaces

MRS Proceedings ◽

10.1557/proc-337-715 ◽

1994 ◽

Vol 337 ◽

Cited By ~ 2

Author(s):

L. Bellard ◽

J.M. Themlin ◽

F. Palmino ◽

A. Cros

Keyword(s):

Metal Layer ◽

High Vacuum ◽

Polymer Surface ◽

Pure Metal ◽

Ultra High Vacuum ◽

Ex Situ ◽

Layer By Layer ◽

Force Microscopy ◽

Atomic Force

ABSTRACTWe have investigated the microscopic properties of copper and chromium layers deposited on polyphenylquinoxaline (PPQ). PPQ is a thermostable polymer used for multichip module applications. The metal is deposited under ultra-high vacuum conditions and analysed in-situ by X-ray photoemission (XPS) and atomic force microscopy (ex situ). Copper does not react significantly with the PPQ and tends to diffuse into the polymer matrix upon annealing. On the contrary, chromium strongly reacts with the polymer surface at room temperature. With increasing metal coverage, chromium grows in a layer-by-layer mode and the reacted interface is progressively burried under the pure metal layer.

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Assess the Extinction Risk of Mountain Endemic Plants in Egypt Under the Current Climatic Condition: A Case Study of Endemic Silene Species

European Journal of Biology and Biotechnology ◽

10.24018/ejbio.2021.2.5.261 ◽

2021 ◽

Vol 2 (5) ◽

pp. 34-47

Author(s):

Karim Omar ◽

Ibrahim Elgamal

Keyword(s):

Species Distribution Model ◽

Extinction Risk ◽

Field Research ◽

Iucn Red List ◽

Red List ◽

Ex Situ ◽

Distribution Model ◽

High Mountain ◽

Endemic Plant

The process of developing a conservation programme for endemic plant species, in particular those with a small geographical size in mountain ecosystems, whether in situ of ex situ, is a very complex matter, especially if data on the state of the environment and conservation are unavailable. Silene leucophylla and Silene oreosinaica are perennial plants endemic to St. Catherine Protected Area (SCPA), which locate at South Sinai, Egypt. For long time, the second species has not been observed in the field. As a result, the purpose of this study was to increase understanding of the two species' ecological and conservation statuses by: The first step is to confirm their existence on the ground; the second step is to determine the present ecological and conservation conditions through an extinction risk assessment by using IUCN Red List methodology; and the third step is the use of Species Distribution Model (SDM) to locate and extract current appropriate habitat suitability. The field research, which was conducted between March to December 2017, resulted in building knowledge of the current distribution, characteristics of current species populations, and status of ecology and habitat, in addition to identifying the main threats. Both species have been recorded in 20 major sites, in a very restricted area, particularly in a high mountain region (19 sites of Silene leucophylla and 3 sites of S. oreosinaica), with Extent of Occurrence about 468.2 km2 for Silene leucophylla and 24.5 km2 for S. oreosinaica. The population size was very small and fragmented and the extreme drought and overgrazing clearly affected both species. Based on the collected data, the extinction risk was calculated as Critically Endangered for S. oreosinaica and as Endangered for S. leucophylla according to IUCN Red List. For both species, appropriate habitat is concentrated in the high mountain ranges in the central north section of the SCPA, according to SDM. For Silene leucophylla, a presence probability of 20.5 km2 was anticipated, whereas for S. oreosinaica, a presence probability of 62.1 km2 had been predicted. Conservation methods are advocated both in situ (via recovery) and ex situ (by seed collecting and storage, awareness building, and grazing control).

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Rational Design of Polyamine-Based Cryogels for Metal Ion Sorption

Molecules ◽

10.3390/molecules25204801 ◽

2020 ◽

Vol 25 (20) ◽

pp. 4801

Author(s):

Irina Malakhova ◽

Yuliya Privar ◽

Yuliya Parotkina ◽

Aleksandr Mironenko ◽

Marina Eliseikina ◽

...

Keyword(s):

Metal Ion ◽

Rational Design ◽

Fixed Bed ◽

Diglycidyl Ether ◽

Ex Situ ◽

Advantages And Disadvantages ◽

Ion Sorption ◽

In Situ Formation ◽

The Difference

Here we report the method of fabrication of supermacroporous monolith sorbents (cryogels) via covalent cross-linking of polyallylamine (PAA) with diglycidyl ether of 1,4-butandiol. Using comparative analysis of the permeability and sorption performance of the obtained PAA cryogels and earlier developed polyethyleneimine (PEI) cryogels, we have demonstrated the advantages and disadvantages of these polymers as sorbents of heavy metal ions (Cu(II), Zn(II), Cd(II), and Ni(II)) in fixed-bed applications and as supermacroporous matrices for the fabrication of composite cryogels containing copper ferrocyanide (CuFCN) for cesium ion sorption. Applying the rate constant distribution (RCD) model to the kinetic curves of Cu(II) ion sorption on PAA and PEI cryogels, we have elucidated the difference in sorption/desorption rates and affinity constants of these materials and showed that physical sorption contributed to the Cu(II) uptake by PAA, but not to that by PEI cryogels. It was shown that PAA cryogels had significantly higher selectivity for Cu(II) sorption in the presence of Zn(II) and Cd(II) ions in comparison with that of PEI cryogels, while irreversible sorption of Co(II) ions by PEI can be used for the separation of Ni(II) and Co(II) ions. Using IR and Mössbauer spectroscopy, we have demonstrated that strong complexation of Cu(II) ions with PEI significantly affects the in situ formation of Cu(II) ferrocyanide nanosorbents leading to their inefficiency for Cs+ ions selective uptake, whereas PAA cryogel was applicable for the fabrication of efficient monolith composites via the in situ formation of CuFCN or loading of ex situ formed CuFCN colloids.

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An in situ and ex situ TEM study of the formation of thin cobalt silicide films by molecular beam epitaxy on the silicon (100) surface

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010010648x ◽

1988 ◽

Vol 46 ◽

pp. 884-885

Author(s):

D. Loretto ◽

J. M. Gibson ◽

S. M. Yalisove ◽

R. T. Tung

Keyword(s):

Molecular Beam Epitaxy ◽

Molecular Beam ◽

Defect Density ◽

High Vacuum ◽

Ultra High Vacuum ◽

Ex Situ ◽

Metal Base ◽

In Situ Experiments ◽

Potential Applications

The cobalt disilicide/silicon system has potential applications as a metal-base and as a permeable-base transistor. Although thin, low defect density, films of CoSi2 on Si(111) have been successfully grown, there are reasons to believe that Si(100)/CoSi2 may be better suited to the transmission of electrons at the silicon/silicide interface than Si(111)/CoSi2. A TEM study of the formation of CoSi2 on Si(100) is therefore being conducted. We have previously reported TEM observations on Si(111)/CoSi2 grown both in situ, in an ultra high vacuum (UHV) TEM and ex situ, in a conventional Molecular Beam Epitaxy system.The procedures used for the MBE growth have been described elsewhere. In situ experiments were performed in a JEOL 200CX electron microscope, extensively modified to give a vacuum of better than 10-9 T in the specimen region and the capacity to do in situ sample heating and deposition. Cobalt was deposited onto clean Si(100) samples by thermal evaporation from cobalt-coated Ta filaments.

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The use of transmission and analytical electron microscopy in studying reactions and phase transformations in thin film

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100150046 ◽

1993 ◽

Vol 51 ◽

pp. 842-843

Author(s):

K. Barmak

Keyword(s):

Thin Film ◽

Thin Films ◽

Phase Transformations ◽

Analytical Electron Microscopy ◽

Ex Situ ◽

Multilayer Thin Films ◽

Absolute Concentration ◽

Analytical Electron ◽

Deposition Step

Generally, processing of thin films involves several annealing steps in addition to the deposition step. During the annealing steps, diffusion, transformations and reactions take place. In this paper, examples of the use of TEM and AEM for ex situ and in situ studies of reactions and phase transformations in thin films will be presented.The ex situ studies were carried out on Nb/Al multilayer thin films annealed to different stages of reaction. Figure 1 shows a multilayer with dNb = 383 and dAl = 117 nm annealed at 750°C for 4 hours. As can be seen in the micrograph, there are four phases, Nb/Nb3-xAl/Nb2-xAl/NbAl3, present in the film at this stage of the reaction. The composition of each of the four regions marked 1-4 was obtained by EDX analysis. The absolute concentration in each region could not be determined due to the lack of thickness and geometry parameters that were required to make the necessary absorption and fluorescence corrections.

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Transmission Electron Microscopy of Epitaxial silicides grown by ultra high vacuum deposition

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100154287 ◽

1989 ◽

Vol 47 ◽

pp. 462-463

Author(s):

D. Loretto ◽

J. M. Gibson ◽

S. M. Yalisove

Keyword(s):

Electron Microscopy ◽

Transmission Electron Microscopy ◽

Electron Diffraction ◽

High Vacuum ◽

High Energy ◽

Energy Electron ◽

Ultra High Vacuum ◽

Ex Situ ◽

Transmission Electron

The silicides CoSi2 and NiSi2 are both metallic with the fee flourite structure and lattice constants which are close to silicon (1.2% and 0.6% smaller at room temperature respectively) Consequently epitaxial cobalt and nickel disilicide can be grown on silicon. If these layers are formed by ultra high vacuum (UHV) deposition (also known as molecular beam epitaxy or MBE) their thickness can be controlled to within a few monolayers. Such ultrathin metal/silicon systems have many potential applications: for example electronic devices based on ballistic transport. They also provide a model system to study the properties of heterointerfaces. In this work we will discuss results obtained using in situ and ex situ transmission electron microscopy (TEM).In situ TEM is suited to the study of MBE growth for several reasons. It offers high spatial resolution and the ability to penetrate many monolayers of material. This is in contrast to the techniques which are usually employed for in situ measurements in MBE, for example low energy electron diffraction (LEED) and reflection high energy electron diffraction (RHEED), which are both sensitive to only a few monolayers at the surface.

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Atomic Layer Deposition of LiF and Lithium Ion Conducting (AlF3)(LiF)x Alloys Using Trimethylaluminum, Lithium Hexamethyldisilazide and Hydrogen Fluoride

10.26434/chemrxiv.5459653 ◽

2017 ◽

Author(s):

Younghee Lee ◽

Daniela M. Piper ◽

Andrew S. Cavanagh ◽

Matthias J. Young ◽

Se-Hee Lee ◽

...

Keyword(s):

Lithium Ion ◽

Atomic Layer ◽

Mass Gain ◽

Alloy Film ◽

Ex Situ ◽

X Ray ◽

Layer Deposition ◽

Ion Conducting ◽

Good Agreement

<div>Atomic layer deposition (ALD) of LiF and lithium ion conducting (AlF3)(LiF)x alloys was developed using trimethylaluminum, lithium hexamethyldisilazide (LiHMDS) and hydrogen fluoride derived from HF-pyridine solution. ALD of LiF was studied using in situ quartz crystal microbalance (QCM) and in situ quadrupole mass spectrometer (QMS) at reaction temperatures between 125°C and 250°C. A mass gain per cycle of 12 ng/(cm2 cycle) was obtained from QCM measurements at 150°C and decreased at higher temperatures. QMS detected FSi(CH3)3 as a reaction byproduct instead of HMDS at 150°C. LiF ALD showed self-limiting behavior. Ex situ measurements using X-ray reflectivity (XRR) and spectroscopic ellipsometry (SE) showed a growth rate of 0.5-0.6 Å/cycle, in good agreement with the in situ QCM measurements.</div><div>ALD of lithium ion conducting (AlF3)(LiF)x alloys was also demonstrated using in situ QCM and in situ QMS at reaction temperatures at 150°C A mass gain per sequence of 22 ng/(cm2 cycle) was obtained from QCM measurements at 150°C. Ex situ measurements using XRR and SE showed a linear growth rate of 0.9 Å/sequence, in good agreement with the in situ QCM measurements. Stoichiometry between AlF3 and LiF by QCM experiment was calculated to 1:2.8. XPS showed LiF film consist of lithium and fluorine. XPS also showed (AlF3)(LiF)x alloy consists of aluminum, lithium and fluorine. Carbon, oxygen, and nitrogen impurities were both below the detection limit of XPS. Grazing incidence X-ray diffraction (GIXRD) observed that LiF and (AlF3)(LiF)x alloy film have crystalline structures. Inductively coupled plasma mass spectrometry (ICP-MS) and ionic chromatography revealed atomic ratio of Li:F=1:1.1 and Al:Li:F=1:2.7: 5.4 for (AlF3)(LiF)x alloy film. These atomic ratios were consistent with the calculation from QCM experiments. Finally, lithium ion conductivity (AlF3)(LiF)x alloy film was measured as σ = 7.5 × 10-6 S/cm.</div>

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A New Method of Wafer Level Plan View TEM Sample Preparation by DualBeam

ISTFA 2008: Conference Proceedings from the 34th International Symposium for Testing and Failure Analysis ◽

10.31399/asm.cp.istfa2008p0168 ◽

2008 ◽

Author(s):

Hyoung H. Kang ◽

Michael A. Gribelyuk ◽

Oliver D. Patterson ◽

Steven B. Herschbein ◽

Corey Senowitz

Keyword(s):

Sample Preparation ◽

Ex Situ ◽

Wafer Level ◽

Cross Sectional ◽

Plan View ◽

Manufacturing Line ◽

Transmission Electron ◽

Thin Lamella ◽

Preparation Techniques

Abstract Cross-sectional style transmission electron microscopy (TEM) sample preparation techniques by DualBeam (SEM/FIB) systems are widely used in both laboratory and manufacturing lines with either in-situ or ex-situ lift out methods. By contrast, however, the plan view TEM sample has only been prepared in the laboratory environment, and only after breaking the wafer. This paper introduces a novel methodology for in-line, plan view TEM sample preparation at the 300mm wafer level that does not require breaking the wafer. It also presents the benefit of the technique on electrically short defects. The methodology of thin lamella TEM sample preparation for plan view work in two different tool configurations is also presented. The detailed procedure of thin lamella sample preparation is also described. In-line, full wafer plan view (S)TEM provides a quick turn around solution for defect analysis in the manufacturing line.

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PROPUESTA DE CONSERVACIÓN DE TRES ESPECIES MEXICANAS DE PICEA EN PELIGRO DE EXTINCIÓN

Revista Fitotecnia Mexicana ◽

10.35196/rfm.2015.3.235 ◽

2015 ◽

Vol 38 (3) ◽

pp. 235 ◽

Cited By ~ 1

Author(s):

Eduardo Mendoza-Maya ◽

Judith Espino-Espino ◽

Carmen Z. Quiñones-Pérez ◽

Celestino Flores-López ◽

Christian Wehenkel ◽

...

Keyword(s):

Ex Situ

Picea mexicana Martínez, P. chihuahuana Martínez y P. martinezii Patterson son especies endémicas de México en peligro de extinción. Se presenta una síntesis de su situación actual y una propuesta de manejo para su conservación in situ y ex situ, con base en la diversidad y estructura genética de las poblaciones y la ubicación de las áreas en donde se predice existirá el hábitat climático que les es propicio en el futuro (años 2030, 2060 y 2090; al promediar los modelos Canadiense, Hadley y Geofísica de Fluidos con escenarios de emisiones A y B). Para la conservación in situ se plantea la protección, el incremento de la diversidad genética y la expansión de las tres únicas poblaciones de P. mexicana, las cuatro únicas de P. martinezii y ocho poblaciones designadas prioritarias de las 40 poblaciones de P. chihuahuana, mediante la plantación de individuos originados de otras poblaciones hasta alcanzar un tamaño mínimo de población genéticamente viable (entre 1035 a 3836 individuos). Para la conservación ex situ se propone el establecimiento de poblaciones en sitios fuera del rango de distribución natural de las especies, en donde se ha proyectado que ocurrirá el clima que les es propicio, con al menos 3606 individuos de P. mexicana en el volcán Cofre de Perote, Veracruz; 2431 individuos de P. chihuahuana en el municipio de Guanaceví, Durango; y 3092 individuos de P. martinezii en la región de Tlatlauquitepec, Puebla, con plantas originadas de una mezcla de semillas colectadas de árboles al azar de poblaciones específicas.

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Hot Workability of 300M Steel Investigated by In Situ and Ex Situ Compression Tests

Metals ◽

10.3390/met9080880 ◽

2019 ◽

Vol 9 (8) ◽

pp. 880 ◽

Cited By ~ 2

Author(s):

Rongchuang Chen ◽

Haifeng Xiao ◽

Min Wang ◽

Jianjun Li

Keyword(s):

Flow Stress ◽

Strain Rate ◽

Hot Working ◽

Ex Situ ◽

Lower Strain Rate ◽

Hot Workability ◽

Compression Tests ◽

300M Steel ◽

Lower Strain

In this work, hot compression experiments of 300M steel were performed at 900–1150 °C and 0.01–10 s−1. The relation of flow stress and microstructure evolution was analyzed. The intriguing finding was that at a lower strain rate (0.01 s−1), the flow stress curves were single-peaked, while at a higher strain rate (10 s−1), no peak occurred. Metallographic observation results revealed the phenomenon was because dynamic recrystallization was more complete at a lower strain rate. In situ compression tests were carried out to compare with the results by ex situ compression tests. Hot working maps representing the influences of strains, strain rates, and temperatures were established. It was found that the power dissipation coefficient was not only related to the recrystallized grain size but was also related to the volume fraction of recrystallized grains. The optimal hot working parameters were suggested. This work provides comprehensive understanding of the hot workability of 300M steel in thermal compression.

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