scholarly journals Electrochemical Performance of Titania 3D Nanonetwork Electrodes Induced by Pulse Ionization at Varied Pulse Repetitions

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1062
Author(s):  
Amirhossein Gholami ◽  
Chae-Ho Yim ◽  
Amirkianoosh Kiani
Keyword(s):  
Electrochemical Performance ◽  
Electrochemical Impedance ◽  
Pulse Frequency ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Electrochemical Tests ◽  
Binder Free ◽  
Higher Temperature ◽  
The One ◽  
Fabrication Parameters

Pulse ionized titania 3D-nanonetworks (T3DN) are emerging materials for fabricating binder-free and carbon-free electrodes for electrochemical energy storage devices. In this article, we investigate the effect of the one of the most important fabrication parameters, pulse frequency, for optimizing supercapacitor efficiency. A series of coin cell batteries with laser-induced electrodes was fabricated; the effect of pulse frequency on oxidation levels and material properties was studied using both experimental and theoretical analysis. Also, detailed electrochemical tests including cyclic voltammetry (CV), charge/discharge, and electrochemical impedance spectroscopy (EIS) were conducted to better understand the effect of pulse frequency on the electrochemical performance of the fabricated devices. The results show that at a frequency of 600 kHz, more T3DN were observed due to the higher temperature and stabler formation of the plasma plume, which resulted in better performance of the fabricated supercapacitors; specific capacitances of samples fabricated at 600 kHz and 1200 kHz were calculated to be 59.85 and 54.39 mF/g at 500 mV/s, respectively.

Orderly Arranged Bead-Chain Cu2O-Mn3O4-NiO Ternary Nanocomposites with High Specific Capacitance for Supercapacitors

NANO ◽  
2020 ◽  
Vol 15 (06) ◽  
pp. 2050082
Author(s):  
Lei Su ◽  
Chunyong Zhang ◽  
Li Shu ◽  
Linna Huang ◽  
Jianning Li ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Electrode Materials ◽  
High Specific Capacitance ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Electrochemical Tests ◽  
Excellent Electrochemical Performance ◽  
Oxide Particles

A series of metal oxide nanocomposites have been successfully synthesized by electrospinning technology. The obtained nanocomposites (Cu2O-Mn3O4-NiO) are an ordered arrangement of metal oxide particles (10[Formula: see text]nm), with the shape like bead chain. The acquired Cu2O-Mn3O4-NiO ternary nanocomposites were used as electrode materials to manufacture a supercapacitor. Electrochemical tests showed that the synthesis of nanocomposites made of electrode materials had good electrochemical performance in 6[Formula: see text]mol/L KOH electrolyte. The results showed that at a scan rate of 5[Formula: see text]mV/s, the specific capacitance of Cu2O-Mn3O4-NiO had a larger specific capacitance of 1306[Formula: see text]F/g than NiO, Cu2O-NiO and Mn3O4-NiO. The excellent electrochemical performance showed that the electrostatic spinning method is an effective technology for developing nanocomposites for energy storage devices.

Flexible all-solid-state fiber-shaped Ni–Fe batteries with high electrochemical performance

2019 ◽  
Vol 7 (2) ◽  
pp. 520-530 ◽  
Author(s):  
Qiulong Li ◽  
Qichong Zhang ◽  
Chenglong Liu ◽  
Juan Sun ◽  
Jiabin Guo ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Electrochemical Performance ◽  
High Capacity ◽  
Core Shell ◽  
Next Generation ◽  
Energy Storage Devices ◽  
Storage Devices

The fiber-shaped Ni–Fe battery takes advantage of high capacity of hierarchical CoP@Ni(OH)2 NWAs/CNTF core–shell heterostructure and spindle-like α-Fe2O3/CNTF electrodes to yield outstanding electrochemical performance, demonstrating great potential for next-generation portable wearable energy storage devices.

MXene binder stabilizes pseudocapacitance of conducting polymers

2021 ◽  
Vol 9 (36) ◽  
pp. 20356-20361
Author(s):  
Muhammad Boota ◽  
Euiyeon Jung ◽  
Rajeev Ahuja ◽  
Tanveer Hussain
Keyword(s):  
Energy Storage ◽  
Conducting Polymers ◽  
Electrochemical Performance ◽  
Organic Materials ◽  
Sustainable Energy ◽  
Large Family ◽  
Energy Storage Devices ◽  
Storage Devices

Unlike conventional additives, the use of MXene as a binder improves the electrochemical performance of conducting polymers. The approach is extendable to a large family of poorly conducting organic materials for sustainable energy storage devices.

Gel Electrolyte Based Supercapacitors with Higher Capacitances and Lower Resistances than Devices with a Liquid Electrolyte

MRS Advances ◽  
2018 ◽  
Vol 3 (22) ◽  
pp. 1261-1267 ◽  
Author(s):  
Belqasem Aljafari ◽  
Arash Takshi
Keyword(s):  
Polymer Electrolytes ◽  
Room Temperature ◽  
Electrochemical Impedance ◽  
Liquid Electrolyte ◽  
Gel Electrolyte ◽  
Superior Performance ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Gel Electrolytes ◽  
Further Development

ABSTRACTRecently, gel polymer electrolytes (GPEs) have been drawn noteworthy attention for different applications, specifically, for supercapacitors. GPEs could become an excellent substitute to liquid electrolytes (LEs) for making flexible and more durable devices. The performance of two different electrolytes (GPEs and LEs) in multi-wall carbon nanotube based supercapacitors were investigated. In spite of significantly lower conductivity of GPEs than LEs, devices with the gel electrolyte presented a superior performance. More focused has been given in this work on demonstrating the performance of supercapacitors based on GPEs and LEs at different concentrations of the acids ranging from 1M to 3M. Both electrolytes have been characterized at room temperature by making supercapacitors and using cyclic voltammetry, charging-discharging, electrochemical impedance spectroscopy, and leakage tests. The experimental results showed that GPE devices had much better capacitances and resistances compare to the LE based devices. Moreover, the capacitances of all devices were increased proportionally with the increase in the concentration from 1M to 3M, and the resistances were increased inversely with the decreased of concentration. The promising results from the gel electrolytes is encouraging for further development of flexible and high capacitance energy storage devices.

scholarly journals Online diagnosis of supercapacitors using extended Kalman filter combined with PID corrector

2021 ◽  
Vol 12 (3) ◽  
pp. 1521
Author(s):  
Zoubida Bououchma ◽  
Jalal Sabor
Keyword(s):  
Electrochemical Impedance ◽  
New Method ◽  
Specific Power ◽  
Attractive Alternative ◽  
State Of Health ◽  
Energy Storage Devices ◽  
Good Efficiency ◽  
Storage Devices ◽  
Online Identification ◽  
Identification Method

<span>Supercapacitors are electrical energy storage devices with a high specific power density, a long cycle life and a good efficiency, which make them attractive alternative storage devices for various applications. However, supercapacitors are subject to a progressive degradation of their perfor-mance because of aging phenomenon. Therefore, it is very important to be able to estimate their State-of-Health during operation. Electrochemical Impedance Spectroscopy (EIS) is a very recog-nized technique to determine supercapacitors’ state-of-health. However, it requires the interrup-tion of system operation and thus cannot be performed in real time (online). In this paper, a new online identification method is proposed based on extended Kalman observer combined with a complementary PID corrector. The proposed method allows to accurately estimating supercapacitor resistance and capacitance, which are the main indicators of supercapacitor state-of-health. The new online identification method was applied for two voltage/current profiles using two different supercapacitors. The resistance/capacitance estimated by the new method and the conventional EKF were compared with those obtained by an experimental offline method. In comparison with conventional EKF, the capacitance obtained by the new method is significantly more accurate.</span>

scholarly journals Tailoring the supercapacitive performances of noble metal oxides, porous carbons and their composites

2013 ◽  
Vol 78 (12) ◽  
pp. 2141-2164 ◽  
Author(s):  
Vladimir Panic ◽  
Aleksandar Dekanski ◽  
Branislav Nikolic
Keyword(s):  
Energy Storage ◽  
Metal Oxides ◽  
Noble Metal ◽  
Electrochemical Impedance ◽  
Depth Profiling ◽  
Thin Layers ◽  
Energy Storage Devices ◽  
Capacitive Energy Storage ◽  
Storage Devices ◽  
Noble Metal Oxides

Porous electrochemical supercapacitive materials, as an important type of new-generation energy storage devices, require a detailed analysis and knowledge of their capacitive performances upon different charging/discharging regimes. The investigation of the responses to dynamic perturbations of typical representatives, noble metal oxides, carbonaceous materials and RuO2-impregnated carbon blacks, by electrochemical impedance spectroscopy (EIS) is presented. This presentation follows a brief description of supercapacitive behavior and origin of pseudocapacitive response of noble metal oxides. For all investigated materials, the electrical charging/discharging equivalent of the EIS response was found to obey the transmission line model envisaged as so-called ?resistor/capacitor (RC) ladder?. The ladder features are correlated to material physicochemical properties, its composition and the composition of the electrolyte. Fitting of the EIS data of different supercapacitive materials to appropriate RC ladders enables the in-depth profiling of the capacitance and pore resistance of their porous thin-layers and finally the complete revelation of capacitive energy storage issues.

Controllable synthesis of 3D hierarchical bismuth compounds with good electrochemical performance for advanced energy storage devices

RSC Advances ◽  
2015 ◽  
Vol 5 (64) ◽  
pp. 51773-51778 ◽  
Author(s):  
Jinfeng Sun ◽  
Jinqing Wang ◽  
Zhangpeng Li ◽  
Zhigang Yang ◽  
Shengrong Yang
Keyword(s):  
Energy Storage ◽  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Rate Capability ◽  
High Specific Capacitance ◽  
Controllable Synthesis ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Bismuth Compounds

3D hierarchical bismuth (Bi)-based compounds with controllable sizes and morphologies exhibit high specific capacitance and superior rate capability.

Electrochemical Performance of PbO2 and PbO2–CNT Composite Electrodes for Energy Storage Devices

2015 ◽  
Vol 15 (1) ◽  
pp. 703-708 ◽  
Author(s):  
M. S. Soumya ◽  
G. Binitha ◽  
P. Praveen ◽  
K. R. V. Subramanian ◽  
Y. S. Lee ◽  
...  
Keyword(s):  
Energy Storage ◽  
Electrochemical Performance ◽  
Composite Electrodes ◽  
Energy Storage Devices ◽  
Storage Devices

Nitrogen-enriched carbon spheres coupled with graphitic carbon nitride nanosheets for high performance supercapacitors

2018 ◽  
Vol 47 (29) ◽  
pp. 9724-9732 ◽  
Author(s):  
Jun Zhu ◽  
Lirong Kong ◽  
Xiaoping Shen ◽  
Hu Zhou ◽  
Guoxing Zhu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Carbon Nitride ◽  
Clean Energy ◽  
Carbon Spheres ◽  
Energy Storage Devices ◽  
Step Method ◽  
Storage Devices ◽  
Excellent Electrochemical Performance ◽  
Carbon Nitride Nanosheets

A facile two-step method is proposed to synthesize g-CN/NCS composites, which exhibit an excellent electrochemical performance in clean energy storage devices.

Rich sulfur doped porous carbon materials derived from ginkgo leaves for multiple electrochemical energy storage devices

2017 ◽  
Vol 5 (5) ◽  
pp. 2204-2214 ◽  
Author(s):  
Enchao Hao ◽  
Wei Liu ◽  
Shuang Liu ◽  
Yuan Zhang ◽  
Huanlei Wang ◽  
...  
Keyword(s):  
Energy Storage ◽  
Electrochemical Performance ◽  
Porous Carbon ◽  
Carbon Materials ◽  
Multilayered Structure ◽  
Electrochemical Energy Storage ◽  
Energy Storage Devices ◽  
Carbon Nanosheets ◽  
Storage Devices ◽  
Excellent Electrochemical Performance

Based on the unique multilayered structure of ginkgo leaves, interconnected carbon nanosheets with rich micro/meso pores have been fabricated, showing excellent electrochemical performance in multiple energy storage devices.

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