scholarly journals Comparison of the Thermal Properties of Geopolymer and Modified Gypsum

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1220
Author(s):  
Karol Prałat ◽  
Justyna Ciemnicka ◽  
Artur Koper ◽  
Katarzyna Ewa Buczkowska ◽  
Piotr Łoś

The paper presents the results of research concerning the influence of micromaterials on the heat conductivity coefficient λ, specifically heat Cp and thermal diffusivity a of modified gypsum and geopolymer. Microspheres, hydroxyethyl methylcellulose (HEMC) polymer, and aerogel were used as the gypsum’s modifying materials. The study also investigated an alkali potassium-activated methakaolin-based geopolymer with the addition of aluminium dust. During the measurements of thermal parameters, the nonstationary method was chosen, and an Isomet device—which recorded the required physical quantities—was used. When compared to the reference sample, a decrease in the thermal conductivity and diffusivity of the hardened gypsum— and a simultaneous increase in specific heat—was observed with the addition of micromaterials. The geopolymer sample was characterized by the lowest value of thermal conductivity, equal to 0.1141 W/(m·K). It was over 62% lower than the reference sample containing only gypsum. The experimental values of the thermal conductivity of the gypsum samples with the addition of HEMC, aerogel and microspheres were, respectively, over 23%, 6%, and 8% lower than those of the unmodified gypsum samples. The lowest values of thermal conductivity were observed in the case of the gypsum samples modified with polymer; this resulted from the fact that the polymer caused the greatest change in the structure of the gypsum’s composite, which were expressed by the lowest density and highest porosity.

Author(s):  
Messiha Saad ◽  
Darryl Baker ◽  
Rhys Reaves

Thermal properties of materials such as specific heat, thermal diffusivity, and thermal conductivity are very important in the engineering design process and analysis of aerospace vehicles as well as space systems. These properties are also important in power generation, transportation, and energy storage devices including fuel cells and solar cells. Thermal conductivity plays a critical role in the performance of materials in high temperature applications. Thermal conductivity is the property that determines the working temperature levels of the material, and it is an important parameter in problems involving heat transfer and thermal structures. The objective of this research is to develop thermal properties data base for carbon-carbon and graphitized carbon-carbon composite materials. The carbon-carbon composites tested were produced by the Resin Transfer Molding (RTM) process using T300 2-D carbon fabric and Primaset PT-30 cyanate ester. The graphitized carbon-carbon composite was heat treated to 2500°C. The flash method was used to measure the thermal diffusivity of the materials; this method is based on America Society for Testing and Materials, ASTM E1461 standard. In addition, the differential scanning calorimeter was used in accordance with the ASTM E1269 standard to determine the specific heat. The thermal conductivity was determined using the measured values of their thermal diffusivity, specific heat, and the density of the materials.


2021 ◽  
Vol 407 ◽  
pp. 185-191
Author(s):  
Josef Tomas ◽  
Andreas Öchsner ◽  
Markus Merkel

Experimental analyses are performed to determine thermal conductivity, thermal diffusivity and volumetric specific heat with transient plane source method on hollow sphere structures. Single-sided testing is used on different samples and different surfaces. Results dependency on the surface is observed.


2019 ◽  
Vol 2 (22) ◽  
pp. 151-167 ◽  
Author(s):  
Izabela Staniszewska ◽  
Szymon Staszyński ◽  
Magdalena Zielińska

The aim of study was to determine the influence of sonication and freezing on the kinetic of the microwave-vacuum drying, energy consumption and physical properties of whole cranberries as well as evaluate the applicability of sonication instead of freezing in order to change their physical properties and the drying kinetic of whole cranberries. Microwave-vacuum drying of whole cranberries with/without initial treatments took from 12 ± 1 to 14.5 ± 0.5 minutes. All of treatments did not significantly shorten the drying time of cranberries. However, they increased SMER values even by 31%. Despite of cryogenic freezing, all of treatments significantly increased the values of Dew. Sonication combined with drying allowed to obtain dried berries characterized by the lowest cohesiveness (0.19±0.02), springiness (0.62±0.02) and chewiness (3.4±0.8 N), while cryogenic freezing combined with drying allowed to obtain dried fruits characterized by highest springiness (0.75±0.03) and low chewiness (3.3±0.5 N). The highest lightness (32.2±0.7), redness (32.6±0.8), and yellowness (11.1±0.7) were found for fruits subjected to initial convective freezing before drying. The efficiency of sonication in color change was comparable to cryogenic freezing and much lower than convective freezing. All of initial treatments increased such thermal properties of dried cranberries as thermal conductivity and thermal diffusivity.


Author(s):  
Siti Shahirah Suhaili ◽  
Md Azree Othuman Mydin ◽  
Hanizam Awang

The addition of mesocarp fibre as a bio-composite material in foamed concrete can be well used in building components to provide energy efficiency in the buildings if the fibre could also offer excellent thermal properties to the foamed concrete. It has practical significance as making it a suitable material for building that can reduce heat gain through the envelope into the building thus improved the internal thermal comfort. Hence, the aim of the present study is to investigate the influence of different volume fractions of mesocarp fibre on thermal properties of foamed concrete. The mesocarp fibre was prepared with 10, 20, 30, 40, 50 and 60% by volume fraction and then incorporated into the 600, 1200 and 1800 kg/m3 density of foamed concrete with constant cement-sand ratio of 1:1.5 and water-cement ratio of 0.45. Hot disk thermal constant analyser was used to attain the thermal conductivity, thermal diffusivity and specific heat capacity of foamed concrete of various volume fractions and densities. From the experimental results, it had shown that addition of mesocarp fibre of 10-40% by volume fraction resulting in low thermal conductivity and specific heat capacity and high the thermal diffusivity of foamed concrete with 600 and 1800 kg/m3 density compared to the control mix while the optimum amount of mesocarp fibre only limit up to 30% by volume fraction for 1200 kg/m3 density compared to control mix. The results demonstrated a very high correlation between thermal conductivity, thermal diffusivity and specific heat capacity which R2 value more than 90%.


Author(s):  
Danie`le Fournier ◽  
Jean Paul Roger ◽  
Christian Fretigny

Lateral heat diffusion thermoreflectance is a very powerful tool for determining directly the thermal diffusivity of layered structures. To do that, experimental data are fitted with the help of a heat diffusion model in which the ratio between the thermal conductivity k and the thermal diffusivity D of each layer is fixed, and the thermal properties of the substrate are known. We have shown in a previous work that it is possible to determine independently the thermal diffusivity and the thermal conductivity of a metallic layer deposited on an insulator, by taking into consideration all the data obtained at different modulation frequencies. Moreover, it is well known that to prevent a lack of adhesion of a gold film deposited on substrates like silica, an intermediate very thin (Cr or Ti) layer is deposited to assure a good thermal contact. We extend our previous work: the asymptotic behaviour determination of the surface temperature wave at large distances from the modulated point heat source for one layer deposited on the substrate to the two layers model. In this case (very thin adhesion coating whose thermal properties and thickness are known), it can be establish that the thermal diffusivity and the thermal conductivity of the top layer can still be determined independently. It is interesting to underline that the calculus can also be extended to the case of a thermal contact resistance which has often to be taken into account between two solids. We call thermal resistance a very thin layer exhibiting a very low thermal conductivity. In this case, the three parameters we have to determine are the thermal conductivity and the thermal diffusivity of the layer and the thermal resistance. We will show that, in this case, the thermal conductivity of the layer is always obtained independently of a bound of the couple thermal resistance – thermal diffusivity, the thermal diffusivity being under bounded and the thermal resistance lower bounded. Experimental results on thin gold layers deposited on silica with and without adhesion layers are presented to illustrate the method. Discussions on the accuracy will also be presented.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Cletus Matthew Magoda ◽  
Jasson Gryzagoridis ◽  
Kant Kanyarusoke

Purpose The purpose of this paper is to validate an assumption of what to use as an effective (steady state) heat transfer coefficient of thermal conductivity for the honeycomb core sandwiched by Fiberglass face sheets composite. A one-dimensional model based on Fourier law is developed. The results are validated experimentally. Design/methodology/approach The results were obtained from the one-dimensional mathematical model of an overall or effective heat conductivity of the Honeycomb composite panel. These results were validated experimentally by applying heat flux on the specimen under controlled environment. The surface temperatures at different voltages were recorded and analysed. The skin of the sandwich composite material used in the investigation was Fiberglass sheet with a thickness of 0.5 mm at the bottom and 1.0 mm at the top surface. Both skins have a stacking sequence of zero degrees. Due to the presence of air cells in the core (Honeycomb), the model considers the conduction, convection and radiation heat transfer, across the thickness of the panel, combined as an effective conduction mode, whose value may be predicted by using the coefficient of thermal conductivity of the air based on the average temperature difference between the two skins. The experimental results for the heat transfer through the thickness of the panel provide validation of this assumption/prediction. Both infrared thermography and conventional temperature measurement techniques (thermocouples) were used to collect the data. Findings The heat transfer experiment and mathematical modeling were conducted. The data obtained were analyzed, and it was found that the effective thermal conductivity was temperature-dependent as expected. The effective thermal conductivity of the honeycomb panel was close to that of air, and its value could be predicted if the panel surface temperatures were known. It was also found that as temperature raised the variation between experimental and predicted effective air conduction raised up. This is because there was an increase in molecular diffusion and vibration. Therefore, the convection heat transfer increased at high temperatures and the air became an insulator. Originality/value Honeycomb composite panels have excellent physical and thermal properties that influence their performance. This study provides an appropriate method in determining thermal conductivity, which is one of the critical thermal properties of porous composite material. This paper also gives useful and practical data to industries that use or manufacture honeycomb composite panels.


1978 ◽  
Vol 100 (2) ◽  
pp. 330-333 ◽  
Author(s):  
R. E. Taylor

Samples of sintered and arc-cast tungsten are available from NBS as thermal conductivity (SRM 730) and electrical resistivity (SRM 799) standards for the temperature range from 4 to 3000K. NBS recommended values for these properties above room temperature are based on results of various researchers during a previous international program which included arc-cast and sintered tungsten. The sintered tungsten used in this program was found to be unsuited for use as a standard material due to inhomogeneity and high temperature instability. The present paper gives results at high temperatures for thermal conductivity, electrical resistivity, specific heat, thermal diffusivity and Wiedemann-Franz-Lorenz ratio for a sample of the NBS sintered tungsten using the Properties Research Laboratory’s multiproperty apparatus. These results are compared to values recommended by the Thermophysical Properties Research Center, NBS, and an international program.


2010 ◽  
Vol 658 ◽  
pp. 372-375 ◽  
Author(s):  
Sang Yeop Lee ◽  
Jae Young Kwon ◽  
Tae Woong Kang ◽  
Yeon Gil Jung ◽  
Ung Yu Paik

Thermal barrier coating systems (TBCs) prepared by an air-plasma spray (APS) have been used to protect metallic components of gas turbines because of its economic advantage. To enhance the energy efficiency of gas turbine systems, the operating temperature is increased to over 1300 °C, which requires a new material with low thermal conductivity and an increase of TBC thickness. In this study we have focused the microstructure related to the thickness of TBC and their thermal properties, with specific attention to defect species as well as to its morphology with the thermal exposure time. Resintering of TBC happens during thermal exposure in a high temperature, resulting in the less strain tolerance and the higher thermal conductivity. In order to investigate the thermal properties of TBC related to the microstructural evolution, TBCs with different thicknesses of 200 µm, 400 µm, 600 µm, and 2000 µm were deposited on a flat graphite by the APS. The thermal exposure tests were conducted in different dwell time till 800h at 1100 °C. The thermal diffusivity is significantly increased after thermal exposures, depending on the thermal exposure time. Microstructural analysis clearly shows that the variation of thermal diffusivity is ascribed to the coalescence of small cracks and the resintering effect. The hardness values of TBCs are also increased as well. The relationship between mechanical properties and TBC thickness is discussed, including the effect of thickness on thermal properties.


2020 ◽  
Vol 45 (4) ◽  
pp. 71-80
Author(s):  
Ide Ejike ◽  
Ike Oluka ◽  
Eze Chukwuka

The specific heat, thermal conductivity and thermal diffusivity of the Horse-Eye bean (Mucuna sloanei) were determined as a function of moisture content using the method reported by A.O.A.C (2000). The sample varieties used were the Big Sized and the Small Sized Horse-Eye bean. The specific heat and the thermal conductivity were measured using a Bomb Calorimeter. The thermal diffusivity was calculated from the measured specific heat, thermal conductivity and bulk density of the samples. Within the moisture range of 10.5% to 16.87% (b.b), the specific heat, thermal conductivity and thermal diffusivity varied with the moisture content. Results showed that the specific heat, thermal conductivity and thermal diffusivity of the Horse-Eye bean seeds ranged from 116.76 to 203.29 kJ/kgK; 21.07 to 32.23 W/moC; and 3.12 x 10-7 to 9.19 x 10-7 m 2 /s, for the Big Sized varieties, and 112.06 to 194.61 kJ/kgK; 19.85 to 24.08 W/moC; and 3.05 x 10-7 to 6.71 x 10-7 m 2 /s, for the Small Sized varieties as the moisture content increases from 10.5% to 16.87%. Regression analysis were also carried out on the thermal properties of the Horse-Eye bean varieties and moisture content, and there was positive relationship between the parameters. There were significant effects of moisture content (p < 0.05) on all the parameters conducted. The findings and the data generated will create an impact in the food processing industries for Horse-Eye bean.


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