scholarly journals Manufacturing and Characterisation of Polymeric Membranes for Water Treatment and Numerical Investigation of Mechanics of Nanocomposite Membranes

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1661
Author(s):  
Seren Acarer ◽  
İnci Pir ◽  
Mertol Tüfekci ◽  
Güler Türkoğlu Demirkol ◽  
Neşe Tüfekci
Keyword(s):  
Water Treatment ◽  
Polyvinylidene Fluoride ◽  
Equivalent Stress ◽  
Tensile Tests ◽  
Mechanical Tests ◽  
Size Analysis ◽  
Inversion Method ◽  
Nanocomposite Membranes ◽  
Pore Size Analysis ◽  
Von Mises

In this study, polyethersulfone (PES) and polyvinylidene fluoride (PVDF) microfiltration membranes containing polyvinylpyrrolidone (PVP) with and without support layers of 130 and 150 μm thickness are manufactured using the phase inversion method and then experimentally characterised. For the characterisation of membranes, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and pore size analysis are performed, the contact angle and water content of membranes are measured and the tensile test is applied to membranes without support layers. Using the results obtained from the tensile tests, the mechanical properties of the halloysite nanotube (HNT) and nano-silicon dioxide (nano SiO2) reinforced nanocomposite membranes are approximately determined by the Mori–Tanaka homogenisation method without applying any further mechanical tests. Then, plain polymeric and PES and PVDF based nanocomposite membranes are modelled using the finite element method to determine the effect of the geometry of the membrane on the mechanical behaviour for fifteen different geometries. The modelled membranes compared in terms of three different criteria: equivalent stress (von Mises), displacement, and in-plane principal strain. Based on the data obtained from the characterisation part of the study and the numerical analysis, the membrane with the best performance is determined. The most appropriate shape and material for a membrane for water treatment is specified as a 1% HNT doped PVDF based elliptical membrane.

scholarly journals The Synthesis and Electrochemical Performance of Si Composite with Hollow Carbon Microtubes by the Carbonization of Milkweed from Nature as Anode Template for Lithium Ion Batteries

Energies ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 5124
Author(s):  
Eun Hyuk Chung ◽  
Jong Pil Kim ◽  
Hyun Gyu Kim ◽  
Jae-Min Chung ◽  
Sei-Jin Lee ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Electrical Conductivity ◽  
Electrochemical Performance ◽  
Pore Size ◽  
Lithium Ion Batteries ◽  
Polyvinylidene Fluoride ◽  
Lithium Ion ◽  
Size Analysis ◽  
Pore Size Analysis ◽  
Hollow Carbon

It has been reported that improving electrical conductivity and maintaining stable structure during discharge/charge process are challenge for Si to be used as an anode for lithium ion batteries (LIB). To address this problem, milkweed (MW) was carbonized to prepare hollow carbon microtubes (HCMT) derived from biomass as an anode template for LIB. In order to improve electrical conductivity, various materials such as chitosan (CTS), agarose, and polyvinylidene fluoride (PVDF) are used as carbon source (C1, C2, and C3) by carbonization. Carbon coated HCMT@Si composits, HCMT@Si@C1, HCMT@Si@C1@C2, and HCMT@Si@C1@C3, have been successfully synthesized. Changes in structure and crystallinity of HCMT@Si composites were characterized by using X-ray diffraction (XRD). Specific surface area for samples was calculated by using BET (Brunauer–Emmett–Teller). Also, pore size and particle size were obtained by particle and pore size analysis system. The surface morphology was evaluated using high resolution scanning electron microscopy (HR-SEM), Field Emission transmission electron microscopy (TEM). The thermal properties of HCMT@Si composites were analyzed by thermogravimetric analysis (TGA). Our research was performed to study the synthesis and electrochemical performance of Si composite with HCMT by the carbonization of natural micro hollow milkweed to form an inner space. After carbonization at 900 °C for 2 h in N2 flow, inner diameter of HCMT obtained was about 10 μm. The electrochemical tests indicate that HCMT@Si@C1@C3 exhibits discharge capacity of 932.18 mAh/g at 0.5 A/g after 100 cycles.

scholarly journals Improved salt rejection, hydrophilicity and mechanical properties of novel thermoplastic polymer/chitosan nanofibre membranes

2020 ◽  
Vol 15 ◽  
pp. 155892502092317
Author(s):  
Fahad S Al-Mubaddel ◽  
Hamad S AlRomaih ◽  
Mohammad Rezaul Karim ◽  
Monis Luqman ◽  
Maher M Al-Rashed ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Contact Angle ◽  
Polyvinylidene Fluoride ◽  
Phase Inversion ◽  
Water Flux ◽  
Tensile Tests ◽  
Membrane Properties ◽  
Inversion Method ◽  
Thermoplastic Polymer ◽  
Salt Rejection

The present study reports on the preparation of novel nanofibre membranes from the thermoplastic polymer polyvinylidene fluoride coated with chitosan to enhance membrane properties such as hydrophilicity, mechanical properties, water flux and salt rejection. Initially, a supporting layer was produced from polyvinylidene fluoride using phase inversion methods, followed by being coated with chitosan using either electrospinning or immersion methods. Two types of fabricated membranes with different coating methods were characterized and tested for physical and chemical performance using field-emission scanning electron microscopy, tensile tests, permeation tests (water flux and salt rejection) and contact angle measurements. It was found that the support membrane (polyvinylidene fluoride) produced by the phase inversion method that was coated with chitosan using electrospinning showed better performance, with a salt rejection up to 70% for MgSO4, a decreased the contact angle (52°) and improved the elongation at the breaking point (~82%).

scholarly journals Incorporation of PVDF Nanofibre Multilayers into Functional Structure for Filtration Applications

Nanomaterials ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 771 ◽  
Author(s):  
Remi Roche ◽  
Fatma Yalcinkaya
Keyword(s):  
Polyvinylidene Fluoride ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Water Filtration ◽  
Size Analysis ◽  
Air Filtration ◽  
Water Contact ◽  
Pore Size Analysis ◽  
Lamination Process ◽  
Temperature Force

Membranes are considered as a promising technology for separation and filtration processes. Here, novel polyvinylidene fluoride (PVDF) nanofibrous multilayer membranes were fabricated by wire-based industrial electrospinning equipment following by a lamination process. The lamination process was optimised under various applied temperature, force of lamination, and lamination time. Air permeability and burst-pressure tests were run to determine the optimum membranes for filtration application. The structures of the prepared membranes were characterised by scanning electron microscopy and pore-size analysis. The hydrophilic properties of the membranes were evaluated using water contact angle measurement, and the mechanical strength of the membranes was analysed. Air and water filtration tests were run to find the possible application of prepared membranes. The air filtration results showed that membranes had high filtration efficiencies: Over 99.00% for PM2.5, and PM0.1. The water filtration results indicated that permeability of the membranes changed from 288 to 3275 L/m2hbar. The successful preparation of such an interesting material may provide a new approach for the design and development of electrospun filter membranes.

An Analysis of Filament Overwound Toroidal Pressure Vessels and Optimum Design of Such Structures

2002 ◽  
Vol 124 (2) ◽  
pp. 215-222 ◽  
Author(s):  
Shuguang Li ◽  
John Cook
Keyword(s):  
Optimum Design ◽  
Equivalent Stress ◽  
Mechanical Damage ◽  
Stress Rupture ◽  
Optimization Procedure ◽  
Pressure Vessels ◽  
Thickness Variation ◽  
Von Mises Equivalent Stress ◽  
Metal Liner ◽  
Von Mises

This paper is concerned with the membrane shell analysis of filament overwound toroidal pressure vessels and optimum design of such pressure vessels using the results of the analysis by means of mathematical nonlinear programming. The nature of the coupling between overwind and linear has been considered based on two extreme idealizations. In the first, the overwind is rigidly coupled with the liner, so that the two deform together in the meridional direction as the vessel dilates. In the second, the overwind is free to slide relative to the linear, but the overall elongations of the two around a meridian are identical. Optimized designs with the two idealizations show only minor differences, and it is concluded that either approximation is satisfactory for the purposes of vessel design. Aspects taken into account are the intrinsic overwind thickness variation arising from the winding process and the effects of fiber pre-tension. Pre-tension can be used not only to defer the onset of yielding, but also to achieve a favorable in-plane stress ratio which minimizes the von Mises equivalent stress in the metal liner. Aramid fibers are the most appropriate fibers to be used for the overwind in this type of application. The quantity of fiber required is determined by both its short-term strength and its long-term stress rupture characteristics. An optimization procedure for the design of such vessels, taking all these factors into account, has been established. The stress distributions in the vessels designed in this way have been examined and discussed through the examples. A design which gives due consideration of possible mechanical damage to the surface of the overwind has also been addressed.

Mechanical properties of PVDF-coated fabric under tensile tests

2015 ◽  
Vol 35 (4) ◽  
pp. 377-390 ◽  
Author(s):  
Andrzej Ambroziak
Keyword(s):  
Mechanical Properties ◽  
Polyvinylidene Fluoride ◽  
Cyclic Load ◽  
Tensile Tests ◽  
Woven Fabrics ◽  
Uniaxial Tensile ◽  
Cyclic Tests ◽  
Comprehensive Investigation ◽  
Coated Fabric ◽  
Coated Fabrics

Abstract This article describes the laboratory tests necessary to identify the mechanical properties of the polyvinylidene fluoride (PVDF)-coated fabrics named Precontraint 1202S and Precontraint 1302S. First, a short survey of the literature concerning the description of coated woven fabrics is presented. Second, the material parameters for PVDF-coated fabrics are specified on the basis of biaxial tensile tests. A comparison of the 1:1 biaxial and the uniaxial tensile tests results is also given. Additionally, biaxial cyclic tests were performed to observe the change of immediate mechanical properties under cyclic load. The article is aimed as an introduction to a comprehensive investigation of the mechanical properties of coated fabrics.

Investigation of the Staging of Damage Accumulation in Polymer Composite Materials during Bending and Tensile Tests

2021 ◽  
Vol 887 ◽  
pp. 116-122
Author(s):  
A.A. Bryansky ◽  
O.V. Bashkov ◽  
Daria P. Malysheva ◽  
Denis B. Solovev
Keyword(s):  
Acoustic Emission ◽  
Composite Materials ◽  
Polymer Composite ◽  
Loading Rate ◽  
Tensile Tests ◽  
Mechanical Tests ◽  
Rate Effect ◽  
Polymer Composite Materials ◽  
Static Tension ◽  
Point Bend

The paper presents the results of the study of registered acoustic emission (AE) parameters during static deformation and damaging of polymer composite materials (PCM). Mechanical tests were done by a static tension and a static three-point bend, accompanied by an acoustic emission method. The assessment of the loading rate effect on defects formation processes was done by additional static tension test at rate equal half of recommended by the standard and static three-point bend test at rate ten times lower than that calculated by the standard. Clustering by frequency components of the recorded AE signals with a self-organizing Kohonen map was performed. The characteristics of the types of PCM structure damage by the centroids of the obtained clusters are given. Based on the clusters accumulation during mechanical tests, the stages of damage formation for static tension and static three-point bend, the loading rate effect on the process of damage formation are described.

Biomechanical Behavior of All-Ceramic Crowns with Variable Thicknesses of Zirconia Frameworks

2016 ◽  
Vol 835 ◽  
pp. 97-102
Author(s):  
Liliana Porojan ◽  
Florin Topală ◽  
Sorin Porojan
Keyword(s):  
Mechanical Behavior ◽  
Equivalent Stress ◽  
The Finite Element Method ◽  
Static Loads ◽  
Biomechanical Behavior ◽  
All Ceramic ◽  
Ceramic Crowns ◽  
Von Mises Equivalent Stress ◽  
Von Mises ◽  
Posterior Restorations

Zirconia is an extremely successful material for prosthetic restorations, offering attractive mechanical and optical properties. It offers several advantages for posterior restorations because it can withstand physiological posterior forces. The aim of the study was to achieve the influence of zirconia framework thickness on the mechanical behavior of all-ceramic crowns using numerical simulation. For the study a premolar was chosen in order to simulate the mechanical behavior in the components of all-ceramic crowns and teeth structures regarding to the zirconia framework thickness. Maximal Von Mises equivalent stress values were recorded in teeth and restorations. Due to the registered maximal stress values it can be concluded that it is indicated to achieve frameworks of at least 0.5 mm thickness in the premolar area. Regarding stress distribution concentration were observed in the veneer around the contact areas with the antagonists, in the framework under the functional cusp and in the oral part overall and in dentin around and under the marginal line, also oral. The biomechanical behavior of all ceramic crowns under static loads can be investigated by the finite element method.

Investigation on Mechanism of Ductile Fracture of AA5754 Sheet

2006 ◽  
Vol 519-521 ◽  
pp. 985-990 ◽  
Author(s):  
Ji Dong Kang ◽  
David S. Wilkinson ◽  
J. David Embury ◽  
Khalid Hussain
Keyword(s):  
Ductile Fracture ◽  
Sample Surface ◽  
Tensile Tests ◽  
Direct Chill ◽  
Mechanical Tests ◽  
Strain Mapping ◽  
Sequence Of Events ◽  
Fe Content ◽  
Cone Type ◽  
Shear Process

A number of mechanical tests and metallographic techniques have been used to investigate the mechanism of ductile fracture of AA5754 sheet. The sequence of events in the development of shear localization is clarified using in situ strain mapping on both the sample surface and through thickness direction during tensile tests. It is observed that the failure mode changes from cup-cone type to shearing with increasing Fe content in both continuous cast (CC) and direct-chill cast (DC) AA5754 sheets. However, this transition happens in CC with much lower Fe content than DC. As very little damage is found near the fracture surface, this suggests that damage may be a consequence of the shear process rather than a trigger that determines material ductility. For both CC and DC with same Fe content of 0.21%, fracture strain of CC is much lower than DC. It is postulated that this is due to the differences of particle distribution in these two materials, especially the increased fraction of stringer type structures which exist in CC material.

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