scholarly journals A Multi-Analytical Approach for Studying the Effect of New LED Lighting Systems on Modern Paints: Chemical Stability Investigations

Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4441
Author(s):  
Valentina Pintus ◽  
Ferenc Szabó ◽  
Dávid Noel Tóth ◽  
Karin Wieland ◽  
Péter Csuti ◽  
...  

This study aims to investigate the chemical stability of some modern paint samples exposed to a new Light Emitting Diode (LED)-lighting system and a halogen lamp by using micro-attenuated total reflectance of Fourier transform infrared spectroscopy (µ-ATR-FTIR), µ-Raman, pyrolysis—gas chromatography/mass spectrometry (Py-GC/MS), and thermally assisted hydrolysis and methylation of GC/MS (THM-GC/MS). Those investigations were performed before and after the exposure of the samples to lightings for 1250, 2400, 3300, and 5000 h. The results obtained with µ-Raman spectroscopy show the high stability of the selected inorganic pigments after the exposure to the lighting systems; while similar to the UV/Vis/NIR results reported in a previous study, µ-ATR-FTIR and THM-GC/MS results evidence greater chemical changes occurring principally on the linseed oil binder-based mock-ups among the acrylic and alkyd-based samples. Moreover, principal component analyses (PCA) and hierarchical cluster analyses (HCA) of THM-GC/MS results highlight that those changes were mostly dependent on the exposure time and on the type of pigment, while being independent of the lighting system used. Finally, semi-quantitative µ-ATR-FTIR results show slight pigment enrichment at the paint surface due to the auto and photo-oxidative degradation of the linseed oil binder.

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Valentina Pintus ◽  
Ferenc Szabó ◽  
Renáta Gazdag-Kéri ◽  
Dávid Noel Tóth ◽  
Róbert Nagy ◽  
...  

AbstractThis research focuses on the investigation of the effect of a new light emitting diode (LED)-lighting system which reproduces indoor museum conditions, on some self-made art paint colours (acrylic-, alkyd-, and linseed oil-based paints) often used in modern-contemporary art. A halogen lamp representing a traditional light source for museum lighting was also considered. Lighting-set-up and lighting optimization parameters were considered while Ultraviolet/Visible/Near Infrared (UV/Vis/NIR) spectrophotometry was used for investigating the colour change of the paint samples. Univariate analyses allowed determining the highest effect of the lighting systems on the linseed oil binder and ultramarine blue PB29 mixture upon ageing, according to the highest total colour change ΔE*ab. In a more specific and detailed way, variance analyses not only demonstrated the strong correlation between the type of binder and pigment used for the paint samples with the colour variation, but also showed that the short-wavelength blue LEDs influenced the change along the yellow–blue b* axis of the yellow and blue samples, whereas the halogen lamp mostly had an impact towards the red–green a* axis of mostly the green specimens.


Author(s):  
Baoshi Sun ◽  
Qiaoli Zhang ◽  
Shi Cao

Illumination is one of the most important environmental factors in the classroom. Researchers have discovered that lighting settings have significant impact on students’ performance. Although light-emitting diode (LED) lighting systems can precisely control brightness level and correlated color temperature (CCT), existing designs of LED lighting control systems for classrooms are focused on energy-saving but lack context-based illumination control ability. In this study, a smart lighting system with continuous evolution capability was developed. It can adjust brightness, CCT, and illuminance distribution dynamically according to specific learning context. This system allows not only manual control, but also automatic switching of scenes by integrating with school schedules. Based on existing knowledge about lighting preference, 10 lighting modes confined in the comfortable zone of Kruithof curve were proposed for various classroom scenarios. Moreover, a classroom environmental data-processing framework for collecting and analyzing learning context, illumination settings, environmental data, and students’ performance data was introduced. This framework can help researchers explore the correlation between student performance and environmental parameters.


2012 ◽  
Vol 490-495 ◽  
pp. 2254-2258
Author(s):  
Li Lin Zang ◽  
Shuo Li ◽  
Da Jun Tian

The light emitting diode (LED) street lighting systems based on solar photovoltaic technology have been used for some time. In this paper, we present an analysis aiming at assessing the feasibility and economic performance of a solar-powered street lighting system for a 1km road. The present study introduces the architecture of a classical solar-powered LED street lighting system and estimates the total investment cost for a 1 km highway with 2 lanes. The cost comparison of solar-powered LED lighting and sodium lamps using grid was carried out. The calculations show that the energy saving effect of solar-powered LED lighting systems is obvious but the initial investment of solar-powered LED systems is more than sodium lighting systems using grid. The investment cycle is about 2.2 years under the current conditions.


Energies ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 202
Author(s):  
Gianluca Serale ◽  
Luca Gnoli ◽  
Emanuele Giraudo ◽  
Enrico Fabrizio

Artificial lighting systems are used in commercial greenhouses to ensure year-round yields. Current Light Emitting Diode (LED) technologies improved the system efficiency. Nevertheless, having artificial lighting systems extended for hectares with power densities over 50W/m2 causes energy and power demand of greenhouses to be really significant. The present paper introduces an innovative supervisory and predictive control strategy to optimize the energy performance of the artificial lights of greenhouses. The controller has been implemented in a multi-span plastic greenhouse located in North Italy. The proposed control strategy has been tested on a greenhouse of 1 hectare with a lighting system with a nominal power density of 50 Wm−2 requiring an overall power supply of 1 MW for a period of 80 days. The results have been compared with the data coming from another greenhouse of 1 hectare in the same conditions implementing a state-of-the-art strategy for artificial lighting control. Results outlines that potential 19.4% cost savings are achievable. Moreover, the algorithm can be used to transform the greenhouse in a viable source of energy flexibility for grid reliability.


2021 ◽  
Vol 15 (1) ◽  
pp. 43
Author(s):  
Raja Zubaidah Raja Sabaradin ◽  
Rozita Osman

The car paint system consisted of four different layers; namely cathodic electrodeposition (CED), primer, the basecoat, and clear coat. Each of these layers may offer valuable information in an analysis of car paint. However, the recovery of a small amount of car paint from a crime scene may not consist of all four layers. Thus, this study is conducted to evaluate the evidence value of car primer in the presence of basecoat and absence of clear coat. In this study, 80 car paint samples, consisting of eight different red basecoats and ten types of primers were analyzed using Py-GC-MS to evaluate the contribution of the primer layer in the analysis of car paint sample. The chromatographic dataset obtained was subjected to chemometric techniques namely principal component analysis (PCA) and cluster analysis (CA). 22 principal components were rendered from PCA with a total variance of 81.23%. CA’s three clusters are cluster 1 and 3 which was based on the shades of red basecoat while cluster 2 was based on the type of primer. This observation showed that the car primer might have a significant contribution to the analysis of car paint using Py-GC-MS. Keywords: Car primer, car paint analysis, Py-GC-MS, chemometric


2020 ◽  
Vol 10 (4) ◽  
pp. 1330
Author(s):  
Vincent K. S. Hsiao ◽  
Teng-Yun Cheng ◽  
Chih-Feng Chen ◽  
Hao Shiu ◽  
Yong-Jin Yu ◽  
...  

We investigated a light emitting diode (LED) lighting system applied to a water bamboo field during winter season at night, and the results indicated that this lighting system can prevent the stunting of water bamboo leaves and further assist its growth. Compared with previous LED systems, in which the LED bulbs were placed directly above water bamboo leaves, our LED lighting system presents the benefit of easy handling during harvest. To prevent the inhomogeneous coverage of LED light patterns, a new design of LED lenses was also incorporated.


2020 ◽  
Vol 15 (6) ◽  
pp. 734-742
Author(s):  
Hailiang Liu ◽  
Jiade Cheng ◽  
Asnidar Hanim Yusuf

Light Emitting Diode (LED) is widely used in garden landscape decoration because of its small size, low power, concentrated light, and the capability of showing more vivid colors. While designing the LED lighting system, considering that a single Advanced RISC Machine (ARM)-based control system cannot achieve large-scale LED display, and a single Field Programmable Gate Array (FPGA)-based control system cannot control the lighting system well, an LED system with the combination of ARM processor-FPGA is proposed. In this system, the ARM processor is used as the major control component. The Linux system realizes remote monitoring and intelligent management of image data. In addition, FPGA is used for LED data output. The lighting system consists of a major control node and a lighting node. The nodes are connected in parallel through a chain network. The major control node uses an ARM Cortex processor and is equipped with a Linux operating system. The lighting node uses ARM + FPGA hardware architecture. During the experiments, the LED lighting system is tested first. The results show that the reading and writing speed is fast. The LED display screen meets the lighting requirements. This LED lighting system is used for night lighting of garden landscapes. During the brightness test, the brightness of lighting objects and the background is used as research objects. Experiments have proved that the ratio of the lighting object brightness to the background brightness between (Yu, M. and Li, X., 2012. A little current k-factor method for measuring junction temperature of aviation lighting power led. Guangxue Jishu/Optical Technique, 38(3), pp.371–375; Monas, A., Verma, A., Gawari, A. and Paswan, R. S., 2016. Portable network monitor using arm processor. Procedia Computer Science, 92, pp.493–497.) is suitable for night lighting of garden landscape decoration, which will not bring discomfort to people who enjoy night scenery.


2016 ◽  
Vol 10 (5) ◽  
pp. 2485-2500 ◽  
Author(s):  
Robert B. Sparkes ◽  
Ayça Doğrul Selver ◽  
Örjan Gustafsson ◽  
Igor P. Semiletov ◽  
Negar Haghipour ◽  
...  

Abstract. Mobilisation of terrestrial organic carbon (terrOC) from permafrost environments in eastern Siberia has the potential to deliver significant amounts of carbon to the Arctic Ocean, via both fluvial and coastal erosion. Eroded terrOC can be degraded during offshore transport or deposited across the wide East Siberian Arctic Shelf (ESAS). Most studies of terrOC on the ESAS have concentrated on solvent-extractable organic matter, but this represents only a small proportion of the total terrOC load. In this study we have used pyrolysis–gas chromatography–mass spectrometry (py-GCMS) to study all major groups of macromolecular components of the terrOC; this is the first time that this technique has been applied to the ESAS. This has shown that there is a strong offshore trend from terrestrial phenols, aromatics and cyclopentenones to marine pyridines. There is good agreement between proportion phenols measured using py-GCMS and independent quantification of lignin phenol concentrations (r2 = 0.67, p < 0.01, n = 24). Furfurals, thought to represent carbohydrates, show no offshore trend and are likely found in both marine and terrestrial organic matter. We have also collected new radiocarbon data for bulk OC (14COC) which, when coupled with previous measurements, allows us to produce the most comprehensive 14COC map of the ESAS to date. Combining the 14COC and py-GCMS data suggests that the aromatics group of compounds is likely sourced from old, aged terrOC, in contrast to the phenols group, which is likely sourced from modern woody material. We propose that an index of the relative proportions of phenols and pyridines can be used as a novel terrestrial vs. marine proxy measurement for macromolecular organic matter. Principal component analysis found that various terrestrial vs. marine proxies show different patterns across the ESAS, and it shows that multiple river–ocean transects of surface sediments transition from river-dominated to coastal-erosion-dominated to marine-dominated signatures.


Author(s):  
I. I. Maronchuk ◽  
I. V. Shirokov ◽  
A. A. Velchenko ◽  
V. I. Mironchuk

The article presents the development of an intelligent control system for LED lighting, applicable to autonomous electric lighting installations, outdoor lighting fixtures on posts to illuminate highways, roads, streets and surrounding areas. The system combines all local lighting systems in which the motion sensor and the LED luminaire are integrated into one network. Turning on the LED luminaire at reduced power is carried out automatically when the level of external natural light is less than a certain threshold value. In the case of appearance of an object moving along the motion sensors of neighboring local lighting systems, the speed and direction of movement of the object are determined. In accordance to the speed and direction of the object movement the number of local lighting systems is determined whose LED lamps should be switched on at a higher power and the appearance of the object at the next design point is predicted. The increase in the power of LED lamps is carried out smoothly when the object is approaching the corresponding local lighting system. Due to the dynamic control of the power of the LED luminaires, as moving objects appear in the coverage area of the intelligent lighting system, significant energy savings are achieved. Traffic safety conditions are increased, as the number of LED lamps operating with increased power is determined by the speed of the object, and its possible braking distance will be significantly less than the illuminated section of the roadway. Smooth changes in the power of LED lamps reduce the pressure on the driver of the vehicle. The choice of the motion sensor based on the autodyne radio blocking, which detects moving objects in a given sector of the controlled space, regardless of the time of day and weather conditions, is grounded.


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