scholarly journals Exploring the Potential for Utilization of Medium and Highly Sulfidic Mine Tailings in Construction Materials: A Review

2021 ◽  
Vol 13 (21) ◽  
pp. 12150
Author(s):  
Natalia Pires Martins ◽  
Sumit Srivastava ◽  
Francisco Veiga Simão ◽  
He Niu ◽  
Priyadharshini Perumal ◽  
...  

Medium and highly sulfidic tailings are high-volume wastes that can lead to severe environmental damage if not properly managed. Due to the high content of sulfide minerals, these tailings can undergo weathering if put in contact with oxygen and water, generating acid mine drainage (AMD). The moderate-to-high sulfide content is also an important technical limitation for their implementation in the production of construction materials. This paper reviews the use of sulfidic tailings as raw material in construction products, with a focus on cement, concrete, and ceramics. When used as aggregates in concrete, this can lead to concrete degradation by internal sulfate attack. In building ceramics, their implementation without prior treatment is undesirable due to the formation of black reduction core, efflorescence, SOx emissions, and their associated costs. Moreover, their intrinsic low reactivity represents a barrier for their use as supplementary cementitious materials (SCMs) and as precursors for alkali-activated materials (AAMs). Nevertheless, the production of calcium sulfoaluminate (CSA) cement can be a suitable path for the valorization of medium and highly sulfidic tailings. Otherwise difficult to upcycle, sulfidic tailings could be used in the clinker raw meal as an alternative raw material. Not only the SO3 and SiO2-rich bulk material is incorporated into reactive clinker phases, but also some minor constituents in the tailings may contribute to the production of such low-CO2 cements at lower temperatures. Nevertheless, this valorization route remains poorly explored and demands further research.

Materials ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 1929 ◽  
Author(s):  
Yu-You Wu ◽  
Jing Zhang ◽  
Changjiang Liu ◽  
Zhoulian Zheng ◽  
Paul Lambert

Nanomaterials have been increasingly employed for improving the mechanical properties and durability of ultra-high-performance concrete (UHPC) with high volume supplementary cementitious materials (SCMs). Recently, graphene oxide (GO) nanosheets have appeared as one of the most promising nanomaterials for enhancing the properties of cementitious composites. To date, a majority of studies have concentrated on cement pastes and mortars with fewer investigations on normal concrete, ultra-high strength concrete, and ultra-high-performance cement-based composites with a high volume of cement content. The studies of UHPC with high volume SCMs have not yet been widely investigated. This paper presents an experimental investigation into the mini slump flow and physical properties of such a UHPC containing GO nanosheets at additions from 0.00 to 0.05% by weight of cement and a water–cement ratio of 0.16. The study demonstrates that the mini slump flow gradually decreases with increasing GO nanosheet content. The results also confirm that the optimal content of GO nanosheets under standard curing and under steam curing is 0.02% and 0.04%, respectively, and the corresponding compressive and flexural strengths are significantly improved, establishing a fundamental step toward developing a cost-effective and environmentally friendly UHPC for more sustainable infrastructure.


2020 ◽  
Vol 166 ◽  
pp. 06007
Author(s):  
Myroslav Sanytsky ◽  
Tetiana Kropyvnytska ◽  
Stanislav Fic ◽  
Hanna Ivashchyshyn

Sustainable development depends on a consistency of interests, social, ecological and economic, and that the interests are evaluated in a balanced manner. In order to reduce CO2 emissions, the conception of decreasing clinker factor and increasing the role of supplementary cementitious materials (SCMs) in the cementitious materials has high economical and environmental efficiency. The performance of clinkerefficient blended cements with supplementary cementitious materials were examined. The influence of superfine zeolite with increased surface energy on the physical and chemical properties of low-carbon blended cements is shown. Increasing the dispersion of cementitious materials contributes to the growth of their strength activity index due to compaction of cement matrix and pozzolanic reactions in unclincker part. In consequence of the early structure formation and the directed formation of the microstructure of the cement matrix is solving the problem of obtaining clinker-efficient concretes. Shown that low-carbon blended cements with high volume of SCMs are suitable, in principle, for producing structural concretes.


2014 ◽  
Vol 660 ◽  
pp. 162-167
Author(s):  
Elbachir Elbahi ◽  
Sidi Mohammed El Amine Boukli Hacene

The resonance frequency method is one of many non-destructive tests which allow us to evaluate construction materials. It was used to determine the dynamic properties of concrete, required in structures design and control, also considered as the key elements for materials dynamic. In this study, we chose a non-destructive approach to quantify-in laboratory-, the influence of adding “crushed limestone” and “natural pozzolan” on local concrete’s dynamic characteristics. However, several concrete mixtures have been prepared with limestone aggregates. The experimental used plan, allowed us to determine the dynamic modulus of elasticity, the dynamic modulus of rigidity of different formulated concretes.


2021 ◽  
Vol 920 (1) ◽  
pp. 012014
Author(s):  
R M K Tahara ◽  
M H Hasnan ◽  
N Z N Azizan

Abstract Conventional construction materials are considered as exploitation to natural resources. Thus, numerous alternative materials using natural or waste materials are proposed for concrete production as a response for greener, renewable and biodegradable environments with regard to sustainability. Natural fibre such as bamboo has been rapidly proposed for many applications especially for concrete production in construction. In order to tackle the environmental issues and focusing on sustainability, natural fibre of Beting bamboo is proposed for partial replacement used as supplementary cementitious materials. Current study investigates the partial replacement of coarse aggregate with Beting bamboo in concrete mixtures. The outcome of the study discovers that through the mix design, replacing 5% by weight of Beting bamboo is an ideal % to achieve concrete mixture for structural and nonstructural application. However, with the increase % of Beting bamboo for partial replacement, the strength of the concrete gradually decreased.


2018 ◽  
Vol 69 (4) ◽  
pp. 860-863 ◽  
Author(s):  
Carmen Oproiu ◽  
Georgeta Voicu ◽  
Adrian Ionut Nicoara ◽  
Alina Ioana Badanoiu

The use of wastes in cement industry have impact both from economic and environmental point of views. Wastes can be used in clinker manufacture (to substitute raw materials or as alternative fuel) as well as supplementary cementitious materials in cement. This paper presents results regarding the use of heavy ash (bottom ash) as component of raw mix used for the clinker manufacture. Two types of cements were obtained by the milling of clinker produced with/without heavy ash (HA) as component of raw mix and gypsum (2%). The compressive strengths of these cements was assessed on plastic mortars (water:binder = 1:2 ratio and binder:aggregate = 1:3 ratio), cast in prismatic moulds (14x14x160 mm3), hardened different periods of time comprised between 1 to 28 days. The hydration and hardening processes which occur in the cementitious systems with/without waste content were assessed on pastes with water to binder ratio of 0.5, hardened for 1 up to 90 days. X-ray diffraction (XRD) and complex thermal analysis (DTA-TG) were used for pastes� characterization. The composition of clinker was assessed by XRD and microstructure by scanning electron microscopy (SEM). The results obtained in the framework of this research do not show any important difference between the clinkers� characteristics produced with alternative raw material (heavy ash) as compared with the ones produced with natural raw materials. Also, the properties of cements produced of these clinkers are similar.


Author(s):  
Hayder H. Alghazali ◽  
John J. Myers

Sustainability of precast/prestressed concrete plant can be promoted by using supplementary cementitious material and that significantly reduces the embodied energy of precast/ prestressed concrete products. Usually, up to 25% of the cement can be replaced with supplementary cementitious materials (SCM). Increasing the level of replacement to exceed 25% is considered to be High-Volume SCM. Appropriate testing should be conducted to ensure desired performance of the concrete. This context reports the results of an experimental investigation of effect of accelerated curing on abrasion resistance of High Volume Supplementary Cementitious Material – Self Consolidating Concrete (HVSCM-SCC). Different mixes proportion with supplementary cementitious materials such as Fly Ash, Micro Silica, and lime (Up to 75% of cement replacement) were tested. Rheological properties of the HVSCM-SCC were measured. Mechanical properties at different ages 1, 3, 7, 28, 56, and 90 days were monitored. To investigate the abrasion resistance, 12 x 12 x 3.5 in specimens at age of 28, 56, and 90 days were conducted. The results of abrasion resistance of HVSCM-SCC were compared to the same mixes cured in the moist room. The result showed that the accelerated curing has a significant influence on abrasion resistance of concrete at early ages.


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