scholarly journals Deterministic Assessment of the Risk of Phthalate Esters in Sediments of U-Tapao Canal, Southern Thailand

Toxics ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 93
Author(s):  
Okpara Kingsley ◽  
Banchong Witthayawirasak
Keyword(s):  
Ecological Risk ◽  
Total Concentration ◽  
Phthalate Esters ◽  
Sediment Quality ◽  
Potential Ecological Risk ◽  
Concentration Addition ◽  
Sediment Samples ◽  
Mixture Effects ◽  
Quality Guidelines ◽  
Southern Thailand

This baseline study evaluated the ecological risk associated with the concentration of six common Phthalate esters (PAEs) in sediment samples collected from the U-Tapao canal in Southern Thailand. Deterministic approaches consisting of standard sediment quality guidelines (SQGs) and Risk quotient (RQ) were used to evaluate the potential ecological risk of individuals and a mixture of Phthalate esters (PAEs) detected in sediment samples. Of the 6 PAEs measured, only three, including di-n-butyl phthalate (DBP), di-2-ethyl hexyl phthalate (DEHP) and di-isononyl phthalate (DiNP), were identified and quantified. The total concentration of the 3 PAEs congeners found in the sediment samples ranged from 190 to 2010 ng/g dw. The results from the SQGs and RQ were not consistent with each other. The SQGs results for individual PAEs showed that DEHP and DBP found in sediment was estimated to cause moderate risk on benthic organisms, DiNP was not estimated due to lack of SQGs data. However, the RQ method indicated a low risk of DEHP and DBP on algae, crustacean and fish, whereas DiNP poses no risk on crustacean. Furthermore, based on the result obtained in this study, the consensus SQGs for mixture effects prove to be a more protective tool than the RQ concentration addition approach in predicting mixture effects. Despite inevitable uncertainties, the integration of several screening approaches of ecological risk assessment (ERA) can help get a more inclusive and credible result of the first tier of individuals and a mixture of these pollutants.

scholarly journals Ecological risk by potentially toxic elements in surface sediments of the Lake Maracaibo (Venezuela)

2021 ◽  
Vol 27 (4) ◽  
pp. 210232-0
Author(s):  
Julio Marín ◽  
Marinela Colina ◽  
Hilda Ledo ◽  
P.H.E. Gardiner
Keyword(s):  
Ecological Risk ◽  
Toxic Elements ◽  
Sediment Quality ◽  
Potential Ecological Risk ◽  
Potentially Toxic Elements ◽  
Lake Area ◽  
Risk Assessment Code ◽  
Quality Guidelines ◽  
Lake Maracaibo ◽  
Superficial Sediments

The evaluation of potential ecological risk of aquatic sediments associated with the presence of potentially toxic elements (PTE) determines its degree of danger on native biota. In this work, the potential ecological risk of V, Ti, Cr, Ni, Cu, Zn, As, Se, Cd, Sn, Hg and Pb in superficial sediments is explained in three different areas of Lake Maracaibo: El Tablazo Bay, Strait of Maracaibo and the lake itself, through a multi-guideline approach (elemental enrichment (enrichment factor, contamination degree, pollutant load index and geo-accumulation index), sediment quality guidelines and risk assessment code). The PTE levels ranged from < 0.025 to 176.722 mg·kg−1 DW, with an overall proportion of V > Ti > Pb > Zn > Cr > Cu > Ni > As > Cd > Se > Hg > Sn. The PTE concurrent effect on biota was El Tablazo Bay > lake > Strait of Maracaibo. The superficial sediments of Lake Maracaibo constitute a medium with a high potential ecological risk on estuarine biota. This is mainly due to the levels of As in El Tablazo Bay, Cd in the Strait of Maracaibo and Pb in the lake area. This represents a latent toxicity hazard for native biological communities and other associated organisms.

scholarly journals Hydrocarbon Pollution and Potential Ecological Risk of Heavy Metals in the Sediments of the Oturuba Creek, Niger Delta, Nigeria

2017 ◽  
Vol 10 (1-2) ◽  
pp. 1-10
Author(s):  
Clinton Ifeanyichukwu Ezekwe ◽  
Israel Clinton Utong
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
Oil Pollution ◽  
Sediment Quality ◽  
Potential Ecological Risk ◽  
Oil Refineries ◽  
Quality Guidelines ◽  
Risk Indices ◽  
Guideline Values ◽  
The Impact

Abstract This study aimed at examining the impact of oil pollution from artisanal oil refineries on the Oturuba river ecosystem using active river bottom sediment. Specific objectives included to determine the level of hydrocarbons and trace metals (Pb, Cd, Zn, Cu, Ni, V and Mg) in the sediments and to relate this with general ecosystem health. The study found elevated concentrations of both hydrocarbons and heavy metals in the range above most sediment quality guidelines exceeding the respective Threshold Effects Level and Probable Effects. Level guideline values and occurring at levels where impairment to biological communities is certain an d where toxicity levels can lead to negative impacts on benthic animals or infaunal communities. Heavy metal geochemical accumulation index and potential ecological risk analysis also returned anomalously high concentrations in the range of very highly polluted sediment environments with very high ecological risk indices, thereby ranking the Oturuba Creek as one of the most polluted coastal river systems in the world.

scholarly journals Ecological Risk and Economic Loss Estimation of Heavy Metals Pollution in The Beijiang River

2014 ◽  
Vol 21 (2) ◽  
pp. 189-199 ◽  
Author(s):  
Jiajun He ◽  
Huimin Zhang ◽  
Hui Zhang ◽  
Xuan Guo ◽  
Mingwei Song ◽  
...  
Keyword(s):  
Ecological Risk ◽  
Risk Index ◽  
Sediment Quality ◽  
Economic Loss ◽  
Potential Ecological Risk ◽  
Heavy Metal Accumulation ◽  
Ecological Risk Index ◽  
Beijiang River ◽  
Quality Guidelines ◽  
The Pearl River

Abstract The distribution and extent of heavy metal accumulation in the fluvial sediment of the Beijiang River are described. The potential toxicity of this pollution was quantified using a consensus based sediment quality guidelines (SQGs) method and the Hakanson potential ecological risk index. The concentrations of Hg, As, Cu, Zn, Pb, Ni and Cr were high enough to damage the sediment biota on a frequent basis. The potential ecological risk was much higher in the downstream, urbanized reaches of the river than in the upstream reaches which are still rural, but all sections of the river posed at least a moderate level of ecological risk. Estimates of the economic loss associated with these pollutions were appreciable, and were mainly due to Hg and Cu. The Beijiang River basin is heavily polluted, posing environmental risks for the downstream reaches of the Pearl River, and economic loss to the whole watershed.

scholarly journals Year over year comparison of sediment quality in the rivers of Eastern Slovakia

2020 ◽  
Vol 29 (3) ◽  
pp. 289-297
Author(s):  
Eva Singovszka ◽  
Magdalena Balintova
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
Risk Index ◽  
Sediment Quality ◽  
Potential Ecological Risk ◽  
Ecological Risk Index ◽  
Potential Ecological Risk Index ◽  
Sediment Samples ◽  
Better Than

Quality is one of the most important risk indicators in river basins. Therefore, monitoring and evaluating water and sediment quality has a very important role in process of risk management. The aim of the monitoring is provide for the sustainability of water bodies and these results are the basis for the risk management in the river catchment area. Hornad, Laborec and Poprad are the rivers in Eastern Slovakia. Hornad and Laborec belongs to basin of Danube and Poprad belongs to basin of Vistula. Sediment sampling was carried out according to ISO 5667-6. Monitoring was carried out in the spring on 2017–2018. The chemical composition of sediments was determined by means of X-ray fluorescence (XRF) using SPECTRO iQ II (Ametek, Germany, 2000). The results of sediment quality evaluated by method PERI revealed that the quality of sediment in 2018 was better than 2017. Results of XRF analysis of sediments were compared with the limited values according to the Slovak Act 188/2003 Coll. of Laws on the application of treated sludge and bottom sediments to fields. It can be state that limit values comparing with Slovak legislation were not exceeding in all sediment samples in rivers in Eastern Slovakia. Based on the monitoring data of sediment quality in the study area, a quantitative analysis of heavy-metal pollution in sediment was conducted using the method of potential ecological risk index (PERI) which is method for evaluate the potential ecological risk of heavy metals. It is based exclusively on chemical parameters of sediments because sediment data show mean integrated values in time, with higher stability than water column parameters; sediments are easily sampled at field work; sediment samples are more representative for time and space scales and analytical data are easily obtained, especially because sediments present high concentrations of contaminants, decreasing the possible errors due to detection limits of the applied analytical method. This method comprehensively considers the synergy, toxic level, concentration of the heavy metals and ecological sensitivity of heavy metals. Potential ecological risk index can be obtained using three basic modules: degree of contamination (CD), toxic-response factor (TR) and potential ecological risk factor (ER). The results show on the basis on potential ecological risk index that the quality of sediment in 2018 is better than 2017. The worst result shows Hornad in 2017. Significant improvement occurred at the sampling point S2 in Hornad in 2018. The best results show Laborec in 2018. The results show on the basis on potential ecological risk index that quality of sediment in 2018 is better than 2017.

scholarly journals Occurrence, Ecological and Health Risk Assessment of Phthalate Esters in Surface Water of U-Tapao Canal, Southern, Thailand

Toxics ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 58
Author(s):  
Okpara Kingsley ◽  
Banchong Witthayawirasak
Keyword(s):  
Risk Assessment ◽  
Water Samples ◽  
Environmental Protection Agency ◽  
Total Concentration ◽  
Phthalate Esters ◽  
Aquatic Organisms ◽  
The United States ◽  
Potential Ecological Risk ◽  
Average Concentration ◽  
Southern Thailand

Phthalate esters (PAEs) are well known for their environmental contamination and endocrine-disrupting effects on wildlife and humans. In this study, the occurrence of PAEs and ecotoxicological risk assessments were performed in one of the significant canals in southern Thailand, named U-Tapao. Water samples were collected and analyzed for the six most common PAEs by using a gas chromatograph-mass spectrometer (GC-MS). Of the 6 PAEs analyzed, only three PAEs, including di-n-butyl phthalate (DBP), di (2-Ethylhexyl) phthalate (DEHP), and diisononyl phthalate (DiNP) were detected in water samples. The total concentration of PAEs ranged from 1.44 to 12.08 µg/L, with a mean level of 4.76 µg/L. The total average concentration of PAEs found in the canal was higher than the criteria of 3 µg/L for PAEs recommended for the protection of fish and other aquatic organisms by the United States Environmental Protection Agency (USEPA). The results of the potential ecological risk assessment of the risk quotient (RQ) method revealed that DEHP and DiNP posed a high risk to algae and crustacean and crustacean and fish, respectively, whereas DBP posed a medium risk to the different aquatic species. However, current levels of noncarcinogenic and carcinogenic risks via ingestion and dermal exposure in children and adults are within acceptable limits. The baseline data of PAEs in this canal will be beneficial to the strategic and future pollutant control along the canal network.

scholarly journals ENVIRONMENTAL AND ECOLOGICAL RISK ASSESSMENT OF HEAVY METAL IN DREDGED SEDIMENTS IN LAGOS, NIGERIA: AN INDEX APPROACH ANALYSES

2017 ◽  
Vol 4 (1) ◽  
Author(s):  
Abdulrafiu Majolagbe ◽  
Abosed Yususf ◽  
Adebola Adeyi
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
Potential Risk ◽  
Risk Index ◽  
Sediment Quality ◽  
Pollution Index ◽  
Potential Ecological Risk ◽  
Entire Study ◽  
Dredged Sediments ◽  
Quality Guidelines

The present study investigate the distribution of Heavy metals (Cadmium, Copper, Zinc, lead and Nickel) and potential ecological risk associated in surface sediments samples from six coastal communities (Ajah, Imore, Ilado, Ajindo, Ojo and Gbelejo) in Lagos, Nigeria. Composite samples were collected from ten (10) different locations in each of the communities and analysed of heavy metals using employing Atomic Absorption Spectrophotometer (AAS). The interim Sediment Quality Guidelines (ISQG) was applied to characterize the dredged sediments and assess the potential ecological risk on the environment through multivariate quality indices such as pollution index (Pi), pollution classification (Pc), geo accumulation index(I geo) and potential ecological risk index (RI). The concentration of zinc was observed higher in the sediments from commercially dredge areas (Ajah and Imore). The result obtained classified entire study area as polluted with respect of Pb and Ni, and as contaminated with (Cd, Cu, and Zn) respect of other metals investigated. The overall ecological risk for the six study areas revealed moderate potential risk (110 ? RI < 200), except Imore and Gbelejo which showed low potential risk (RI < 110). The need for regular monitoring by the relevant agencies cannot be overemphasized to ensure sustainable environment.

scholarly journals Bioecological and statistical risk assessment of toxic metals in sediments of a worldwide important wetland: Gala Lake National Park (Turkey)

2017 ◽  
Vol 43 (1) ◽  
pp. 34-47 ◽  
Author(s):  
Cem Tokatli
Keyword(s):  
Ecological Risk ◽  
National Park ◽  
Risk Index ◽  
Sediment Quality ◽  
Potential Ecological Risk ◽  
Irrigation Canal ◽  
Anthropogenic Pressure ◽  
Ecological Risk Index ◽  
Potential Ecological Risk Index ◽  
Biological Risk

Abstract Gala Lake National Park that has an international importance is one of the most important wetland ecosystems for Turkey. As same as many aquatic habitats, Gala Lake is under a significant anthropogenic pressure originated from agricultural activities conducted around the lake and from industrial discharges by means of Ergene River. The aim of this study was to evaluate the sediment quality of Gala Lake and Irrigation Canal by investigating some toxic element accumulations (As, B, Ni, Cr, Pb, Cd, Zn and Cu) from a statistical perspective. Pearson Correlation Index (PCI) and Factor Analysis (FA) were applied to detected data in order to determine the associated contaminants and effective factors on the system. Potential Ecological Risk Index (RI) and Biological Risk Index based sediment quality guidelines (mERM-Q) applied to detected data in order to assess the ecological and biological risks of heavy metals in the ecosystem. Also Geographic Information System (GIS) technology was used to make visual explanations by presenting distribution maps of investigated elements. According to the results of PCI, significant positive correlations were recorded among the investigated toxic elements at 0.01 significance level. According to the results of FA, two factors, which were named as “Agricultural Factor” and “Industrial Factor”, explained 86.6% of the total variance. According to the results of Potential Ecological Risk Index, cadmium was found to be the highest risk factor and according to results of Biological Risk Index, nickel and chromium were found to be the highest risk factors for Gala Lake and Irrigation Canal. As a result of the present study, it was also determined that heavy metal contents in sediments of Gala Lake National Park reached to critical levels and the system is intensively under effect of agricultural and industrial originated pollution.

scholarly journals Contamination and ecological risk assessment of trace elements in sediments of the Anzali Wetland, Northern Iran

2021 ◽  
Author(s):  
Marjan Esmaeilzadeh ◽  
Elham Mahmoudpuor ◽  
Somayeh Haghighat Ziabari ◽  
Sara Esmaeilzadeh ◽  
Hamideh Aliani ◽  
...  
Keyword(s):  
Ecological Risk ◽  
Risk Index ◽  
Sediment Quality ◽  
Aquatic Organisms ◽  
Pollution Load Index ◽  
Pollution Indices ◽  
Anzali Wetland ◽  
Northern Iran ◽  
Pollution Levels ◽  
Quality Guidelines

Abstract In this paper, concentrations of some heavy metals in surficial sediments of the International Anzali Wetland were measured, this wetland is located in northern part of Iran. Sediment pollution levels were examined and analyzed using reliable pollution indices including Pollution Load Index (PLI), Geoaccumulation Index (Igeo) and Enrichment Factor (CF), and finally it was revealed that heavy metal pollution ranged from low to moderated loads in the wetland. According to Sediment Quality Guidelines (SQGs) and Ecological Risk Index (ERI), it was concluded that As and Ni may have significant toxic impacts on aquatic organisms and also according to Effect Range Median (ERM), the toxicity probability of sediments in the Anzali wetland was estimated at 21%.

scholarly journals Geochemistry pollution status and ecotoxicological risk assessment of heavy metals in the Pahang River sediment after the high magnitude of flood event

2020 ◽  
Author(s):  
K. Y. Lim ◽  
N. A. Zakaria ◽  
K. Y. Foo
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
River Sediment ◽  
Risk Index ◽  
River Sediments ◽  
Sediment Quality ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
Flood Event ◽  
Pollution Status

Abstract The present work is aimed at assessing the aftermath effects of the 2014 flood tragedy on the distribution, pollution status and ecological risks of the heavy metals deposited in the surface river sediment. A series of environmental pollution indexes, specifically the enrichment factor (EF), geo-accumulation index (Igeo), contamination factor (CF), modified degree of contamination (mCd), pollution load index (PLI), potential ecological risk index (PERI) and sediment quality guidelines (SQGs) have been adopted. Results revealed that the freshly deposited sediments collected soon after the flood event were dominated by Cu, Fe, Pb, Ni, Zn, Cr and Cd, with the average concentrations of 38.74, 16,892, 17.71, 4.65, 29.22, 42.36 and 0.29 mg/kg, respectively. According to the heavy metal pollution indexes, Pahang River sediments were moderately to severely contaminated with Pb, Ni, Cu, Zn and Cr, while Cd with the highest risk of 91.09 was the predominant element that illustrated an aesthetic ecological risk to the water body after the tragic flood event. The findings highlighted a critical deterioration of the heavy metals content, driven by the catastrophic flood event, which has drastically altered their geochemical cycles, sedimentary pollution status and biochemical balance of the river's environment.

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