scholarly journals FEATURES OF APPLICATION OF GAS-THERMAL AND PLASMA METHODS FOR OBTAINING FUNCTIONAL COATINGS

2022 ◽  
Vol 1 (1) ◽  
pp. 25-32
Author(s):  
Anvar Kadirmetov ◽  
Yuliya Simonova
Keyword(s):  
Plasma Coating ◽  
Functional Coatings ◽  
Plasma Methods

The article provides recommendations for the modes and parameters of gas-thermal and plasma coating technologies in relation to flat friction pairs subject to uneven operational loads

Ferrozine Assay for Simple and Cheap Iron Analysis of Silica-Coated Iron Oxide Nanoparticles

2018 ◽  
Author(s):  
Hattie Ring ◽  
Zhe Gao ◽  
Nathan D. Klein ◽  
Michael Garwood ◽  
John C. Bischof ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Iron Oxide Nanoparticles ◽  
Hydrofluoric Acid ◽  
Inductively Coupled Plasma ◽  
Silica Shell ◽  
Oxide Nanoparticles ◽  
Inductively Coupled ◽  
Digestion Process ◽  
Plasma Methods ◽  
Iron Analysis

The Ferrozinen assay is applied as an accurate and rapid method to quantify the iron content of iron oxide nanoparticles (IONPs) and can be used in biological matrices. The addition of ascorbic aqcid accelerates the digestion process and can penetrate an IONP core within a mesoporous and solid silica shell. This new digestion protocol avoids the need for hydrofluoric acid to digest the surrounding silica shell and provides and accessible alternative to inductively coupled plasma methods. With the updated digestion protocol, the quantitative range of the Ferrozine assay is 1 - 14 ppm. <br>

Ferrozine Assay for Simple and Cheap Iron Analysis of Silica-Coated Iron Oxide Nanoparticles

2018 ◽  
Author(s):  
Hattie Ring ◽  
Zhe Gao ◽  
Nathan D. Klein ◽  
Michael Garwood ◽  
John C. Bischof ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Iron Oxide Nanoparticles ◽  
Hydrofluoric Acid ◽  
Inductively Coupled Plasma ◽  
Silica Shell ◽  
Oxide Nanoparticles ◽  
Inductively Coupled ◽  
Digestion Process ◽  
Plasma Methods ◽  
Iron Analysis

The Ferrozinen assay is applied as an accurate and rapid method to quantify the iron content of iron oxide nanoparticles (IONPs) and can be used in biological matrices. The addition of ascorbic aqcid accelerates the digestion process and can penetrate an IONP core within a mesoporous and solid silica shell. This new digestion protocol avoids the need for hydrofluoric acid to digest the surrounding silica shell and provides and accessible alternative to inductively coupled plasma methods. With the updated digestion protocol, the quantitative range of the Ferrozine assay is 1 - 14 ppm. <br>

Composite alloy based on Co–Cr–Si–Zr–TiB2–BN system for nanostructured powders and functional coatings

2019 ◽  
pp. 50-56
Author(s):  
A. N. Skvortsova ◽  
T. I. Bobkova ◽  
B. V. Farmakovsky ◽  
V. N. Klimov ◽  
A. I. Dmitryuk
Keyword(s):  
Corrosion Resistance ◽  
Composite Alloy ◽  
Functional Coatings ◽  
Nanostructured Powder ◽  
High Microhardness ◽  
Nanostructured Powders

The paper studies the preparation of a composite nanostructured powder manufactured from an alloy of Co–Cr–Si–Zr–TiB2–BN system and describes functional coatings with high microhardness and corrosion resistance based on that powder. 

Catalytically active coatings for steam reforming systems: synthesis and catalytic properties

2019 ◽  
pp. 96-105
Author(s):  
M. L. Shishkova ◽  
N. V. Yakovleva
Keyword(s):  
Catalytic Properties ◽  
Raw Materials ◽  
Cold Gas Dynamic Spraying ◽  
Hydrogen Fuel ◽  
Functional Coatings ◽  
Science And Engineering ◽  
Powder Mixtures ◽  
Conversion Of Methane ◽  
Catalytically Active ◽  
Metal Support

The paper considers science and engineering aspects of catalytically active compositions creation as regards immobilized catalysts for reforming hydrocarbon raw materials into hydrogen fuel. The authors investigate synthesis of catalytic powder mixtures and manufacturing of functional coatings by supersonic cold gas dynamic spraying. Research results in the field of creation of catalysts for steam conversion of methane to hydrogenous fuel on the metal support (Cr15Al15 tape support) are given. Composite powder mixtures (Ni–Al–Al(OH)3– Ca(OH)2–Mg(OH)2) were used as starting materials.

On the Hydrogen Permeability and Adhesion of TiN/Ti Coatings Produced on Zr–1% Nb Alloy by Vacuum Ion-Plasma Methods

2020 ◽  
Vol 14 (5) ◽  
pp. 929-934
Author(s):  
Zhang Le ◽  
N. N. Nikitenkov ◽  
V. S. Sypchenko ◽  
O. S. Korneva ◽  
E. B. Kashkarov ◽  
...  
Keyword(s):  
Hydrogen Permeability ◽  
Ion Plasma ◽  
Plasma Methods

Quantitative Measurement of Fluorescent Layers with Respect to Spatial Thickness Variations and Substrate Properties

2020 ◽  
Vol 74 (4) ◽  
pp. 439-451
Author(s):  
Philipp Holz ◽  
Christoph Pönisch ◽  
Albrecht Brandenburg
Keyword(s):  
Manufacturing Industry ◽  
Quantitative Measurement ◽  
Fluorescence Emission ◽  
Fluorescence Analysis ◽  
Thin Layers ◽  
Fluorescence Signal ◽  
Functional Coatings ◽  
Custom Made ◽  
Substrate Properties ◽  
Thickness Variations

Imaging fluorescence spectroscopy proves to be a fast and sensitive method for measuring the thickness of thin coatings in the manufacturing industry. This encouraged us to systematically study, theoretically and experimentally, parameters that influence the fluorescence of thin layers. We analyzed the fluorescence signal as a function of the scattering and reflectance properties of the sample substrate. In addition, we investigated effects of the layer properties on fluorescence emission. A ray-tracing software is used to describe the influence of these parameters on the fluorescence emission of thin layers. Experiments using a custom-made system for imaging fluorescence analysis verify the simulations. This work shows a factor five variation of fluorescence intensity as a function of the reflectance of the sample substrate. Simulations show variations by a factor of up to eight for samples with different surface roughness. Results on tilted samples indicate a significant increase of the detected fluorescence signal, for fluorescent droplets on reflective substrates, if illuminated and coaxially observed at angles greater than 25°. These findings are of utmost relevance for all applications which utilize the fluorescence emission to quantify thin layers. These applications range from in-line lubricant monitoring in press plants to monitoring of functional coatings in medical technology and the detection of filmic contaminations.

scholarly journals Low-Temperature Mineralisation of Titania-Siloxane Composite Layers

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 50
Author(s):  
Tomáš Svoboda ◽  
Michal Veselý ◽  
Radim Bartoš ◽  
Tomáš Homola ◽  
Petr Dzik
Keyword(s):  
Low Temperature ◽  
Great Influence ◽  
Gel Permeation Chromatography ◽  
Photocatalytic Decomposition ◽  
Acid Orange 7 ◽  
Composite Layers ◽  
Nonthermal Treatment ◽  
Plasma Methods ◽  
Voltammetric Measurements ◽  
Thermally Treated

This paper deals with low-temperature mineralisation of coatings made with titania-siloxane compositions (TSC). Methyltriethoxysilane has been adopted as the precursor for the siloxane, and during its synthesis, an oligomeric siloxane condensate with methyl moieties acting as TiO2 binder has been produced. These methyl moieties, contained in TSC, provide solubility and prevent gelling, but reduce the hydrophilicity of the system, reduce the transfer of electrons and holes generated in the TiO2. In order to avoid these unfavourable effects, TSC mineralisation can be achieved by nonthermal treatment, for example, by using UV-radiation or plasma treatment. Characterisation of the siloxane was performed by gel permeation chromatography (GPC), which showed the size of the siloxane chain. Thermogravimetric analysis revealed a temperature at which the siloxane mineralises to SiO2. Printed layers of two types of TSC with different siloxane contents were studied by a scanning electron microscope (SEM), where a difference in the porosity of the samples was observed. TSC on fluorine-doped tin oxide (FTO) coated glass and microscopic glass were treated with non-thermal UV and plasma methods. TSC on FTO glass were tested by voltammetric measurements, which showed that the non-thermally treated layers have better properties and the amount of siloxane in the TSC has a great influence on their efficiency. Samples on microscopic glass were subjected to a photocatalytic decomposition test of the model pollutant Acid orange 7 (AO7). Non-thermally treated samples show higher photocatalytic activity than the raw sample.

scholarly journals Current Research Status on Cold Sprayed Amorphous Alloy Coatings: A Review

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 206
Author(s):  
Qiang Wang ◽  
Peng Han ◽  
Shuo Yin ◽  
Wen-Juan Niu ◽  
Le Zhai ◽  
...  
Keyword(s):  
High Temperature ◽  
Amorphous Alloy ◽  
Amorphous Alloys ◽  
Composite Coatings ◽  
Thermal Spraying ◽  
Functional Coatings ◽  
Research Status ◽  
Key Issues ◽  
Wear And Corrosion Resistance ◽  
Amorphous Coatings

Compared with traditional crystalline materials, amorphous alloys have excellent corrosion and wear resistance and high elastic modulus, due to their unique short-range ordered and long-range disordered atomic arrangement as well as absence of defects, such as grain boundaries and dislocations. Owing to the limitation of the bulk size of amorphous alloys as structural materials, the application as functional coatings can widely extend their use in various engineering fields. This review first briefly introduces the problems involved during high temperature preparation processes of amorphous coatings, including laser cladding and thermal spraying. Cold spray (CS) is characterized by a low-temperature solid-state deposition, and thus the oxidation and crystallization related with a high temperature environment can be avoided during the formation of coatings. Therefore, CS has unique advantages in the preparation of fully amorphous alloy coatings. The research status of Fe-, Al-, Ni-, and Zr-based amorphous alloy coatings and amorphous composite coatings are reviewed. The influence of CS process parameters, and powders and substrate conditions on the microstructure, hardness, as well as wear and corrosion resistance of amorphous coatings is analyzed. Meanwhile, the deposition mechanism of amorphous alloy coatings is discussed by simulation and experiment. Finally, the key issues involved in the preparation of amorphous alloy coatings via CS technology are summarized, and the future development is also being prospected.

scholarly journals Functional Antimicrobial Surface Coatings Deposited onto Nanostructured 316L Food-Grade Stainless Steel

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1055
Author(s):  
Gonzalez A. S. ◽  
Riego Á. ◽  
Vega V. ◽  
García J. ◽  
Galié S. ◽  
...  
Keyword(s):  
Stainless Steel ◽  
316L Stainless Steel ◽  
Electrochemical Techniques ◽  
Functional Materials ◽  
Atomic Layer ◽  
Thin Layers ◽  
Nanoporous Structure ◽  
Stainless Steel Surface ◽  
Functional Coatings ◽  
Food Grade

In our study, we demonstrated the performance of antimicrobial coatings on properly functionalized and nanostructured 316L food-grade stainless steel pipelines. For the fabrication of these functional coatings, we employed facile and low-cost electrochemical techniques and surface modification processes. The development of a nanoporous structure on the 316L stainless steel surface was performed by following an electropolishing process in an electrolytic bath, at a constant anodic voltage of 40 V for 10 min, while the temperature was maintained between 0 and 10 °C. Subsequently, we incorporated on this nanostructure additional coatings with antimicrobial and bactericide properties, such as Ag nanoparticles, Ag films, or TiO2 thin layers. These functional coatings were grown on the nanostructured substrate by following electroless process, electrochemical deposition, and atomic layer deposition (ALD) techniques. Then, we analyzed the antimicrobial efficiency of these functionalized materials against different biofilms types (Candida parapsilosis, Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and Staphylococcus epidermidis). The results of the present study demonstrate that the nanostructuring and surface functionalization processes constitute a promising route to fabricate novel functional materials exhibiting highly efficient antimicrobial features. In fact, we have shown that our use of an appropriated association of TiO2 layer and Ag nanoparticle coatings over the nanostructured 316L stainless steel exhibited an excellent antimicrobial behavior for all biofilms examined.

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