scholarly journals EFFECT OF CHITOSAN ADDITION DURING PAPER-MAKING ON AGEING STABILITY OF DOCUMENT PAPER

2021 ◽  
Vol 55 (9-10) ◽  
pp. 1083-1094
Author(s):  
DIMITRINA TODOROVA ◽  
◽  
VESKA LASHEVA ◽  

The aim of the present work has been to study the influence of chitosan addition into the composition of paper intended for documents on its ageing stability, with a view of enhancing the resistance of paper strength and optical properties over time. The chitosan solution was added during the formation of the paper sheets in various amounts: 0.2%, 1% and 2% o.d.f. Paper samples of different fibrous compositions were prepared from bleached sulphate softwood pulp (BSWP) and bleached sulphate hardwood pulp (BHWP) in the following ratios: 50% BSWP:50% BHWP, 80% BSWP:20% BHWP, 100% BSWP and 100% BHWP. Then, paper samples were subjected to accelerated thermal ageing for 24 hours at 105 °C. It was found that the use of chitosan as additive in the composition of bleached cellulose paper samples led to improved strength and hygroscopic properties. The study showed that chitosan could be used in the production of kraft document papers comprising aluminium sulphate, as the presence of aluminium sulphate had no negative effect on the action of the biopolymer. Regarding the complex evaluation of the properties of the obtained papers, it could be summarized that, for the studied fibrous compositions, the optimum amount of the additive was 1% chitosan for a fibrous composition of 50% bleached softwood pulp and 50% bleached hardwood cellulose. Therefore, preparing document paper with the addition of chitosan is a convenient procedure to enhance a number of paper properties, even after the ageing process.

TAPPI Journal ◽  
2016 ◽  
Vol 15 (10) ◽  
pp. 643-651 ◽  
Author(s):  
ROBERT J. OGLESBY ◽  
HUMPHREY J. MOYNIHAN ◽  
RICARDO B. SANTOS ◽  
ASHOK GHOSH ◽  
PETER W. HART

The impact of commercially prepared, fully bleached pulp viscosity variation on handsheet physical properties was evaluated at different levels of pulp refining. Hardwood pulps from the same brownstock species mix, cooking parameters, and kappa numbers were processed through two different commercial bleach plants: one with a D0(EP)D1D2 sequence and the second with an OD0(EOP)D1 sequence. Additionally, a commercial softwood (predominately Scotts pine) brownstock pulp bleached by an OD0(EP)D1D2 sequence was employed in this study. Pulps with viscosities ranging from 14 to 21 mPa∙s were refined in a Valley beater to two freeness levels, and the associated handsheet physical properties were measured in this study. Over the pulp viscosity range of 14 to 21 mPa∙s, no clear correlation was found to exist between pulp viscosity and related paper physical properties. Finally, a series of laboratory prepared bleached pulps were purposely prepared under non-ideal conditions to reduce their final viscosities to lower values. Handsheets made from these pulps were tested in their unbeaten condition for physical strength properties. Significant and rapid strength loss occurred when the measured pulp viscosity dropped below 12 mPa∙s; overall strength properties showed no correlation to viscosity above the critical 12 mPa∙s value.


TAPPI Journal ◽  
2019 ◽  
Vol 18 (4) ◽  
pp. 233-241
Author(s):  
CHENGGUI SUN ◽  
RICHARD CHANDRA ◽  
YAMAN BOLUK

This study investigates the use of pretreatment and enzymatic hydrolysis side streams and conversion to lignocellulose nanofibers. We used a steam-exploded and partial enzymatic hydrolyzed hardwood pulp and an organosolv pretreated softwood pulp to prepare lignocellulose nanofibers (LCNF) via microfluidization. The energies applied on fibrillation were estimated to examine the energy consumption levels of LCNF production. The energy consumptions of the fibrillation processes of the hardwood LCNF production and the softwood LCNF production were about 7040-14080 kWh/ton and 4640 kWh/ton on a dry material basis, respectively. The morphology and dimension of developed hardwood and softwood LCNFs and the stability and rheological behavior of their suspensions were investigated and are discussed.


TAPPI Journal ◽  
2009 ◽  
Vol 8 (6) ◽  
pp. 29-35 ◽  
Author(s):  
PEDRAM FATEHI ◽  
LIYING QIAN ◽  
RATTANA KITITERAKUN ◽  
THIRASAK RIRKSOMBOON ◽  
HUINING XIAO

The application of an oppositely charged dual polymer system is a promising approach to enhance paper strength. In this work, modified chitosan (MCN), a cationic polymer, and carboxymethyl cellulose (CMC), an anionic polymer, were used sequentially to improve paper strength. The adsorption of MCN on cellulose fibers was analyzed via polyelectrolyte titration. The formation of MCN/CMC complex in water and the deposition of this complex on silicon wafers were investigated by means of atomic force microscope and quasi-elastic light scattering techniques. The results showed that paper strength was enhanced slightly with a layer-by-layer assembly of the polymers. However, if the washing stage, which was required for layer-by-layer assembly, was eliminated, the MCN/CMC complex was deposited on fibers more efficiently, and the paper strength was improved more significantly. The significant improvement was attributed to the extra development of fiber bonding, confirmed further by scanning electron microscope observation of the bonding area of fibers treated with or without washing. However, the brightness of papers was somewhat decreased by the deposition of the complex on fibers. Higher paper strength also was achieved using rapid drying rather than air drying.


2011 ◽  
Vol 391-392 ◽  
pp. 692-696
Author(s):  
Min Du ◽  
Xin Ping Li ◽  
Wu Guang Li

The influences of endo-cellulase pretreatment of bleached softwood pulp before refining was investigated in this paper. Refining energy consumption, paper properties, wetting properties, electric charge and aggregation structure of fiber were investigated. The results showed that pretreated with endo-cellulase at the dosage of 0.4ECG/g before refining could increase the refining degree by 53.09%, and it would reduce refining energy consumption significantly. At this dosage, the tensile index of the paper sheet increased while the tear index of paper sheet decreased slightly. Additionally, enzymatic pretreatment could raise fiber surface wettability, lower the absolute value of Zeta potential and decrease the crystallinity of fiber, which was help to improve refining performance.


2018 ◽  
Author(s):  
Imtiaz Ali

Incorporation of recycled fibres in high value paper products can reduce cost and environmental loads. Papermaking potential of cellulosic fibres decreases with recycling. The phenomenon of fibre hornification during pressing and drying is normally held responsible for the loss in strength. To study the impacts of recycling on pulp, fibre and paper properties some non conventional characterisation techniques like fibre saturation point, X-rays microtomography, environmental scanning electron microscopic observations, atomic forcemicroscope (PeakForce QNM mode) and inverse size exclusion chromatography(ISEC) were used. In order to achieve good reproducibility of ISEC measurements,a semi-automatic column fabrication pilot system was built. The techniques were first validated on refining process before being applied to the recycling process. In this study, it was found that fibre hornification alone cannot fully explain loss in strength during recycling. The loss in strength is much more complex and it is required to understand the morphological and ultrastructural changes associated with recycling. Fibre width, cell wall thickness,curl, kink, irregularities decreased during recycling. Fibre became hard and brittle in dry state. Number of weak points in the fibre wall were increased initially and in the later recyclings. The increase in wet breaking length indicates increased surface friction and capillary forces with recycling. Decrease in bonded area during first recycle may be caused by the loss of fines and fibre flexibility whereas the increase afterwards may be linked to the lumen collapse.The strength of fibres did not decrease with recycling as shown by zero-span breaking lengths therefore the quality of bond may be deteriorated. It was thought that the partially delaminated P/S1 layers may be responsible for the loss of paper strength. It is suggested since the significant change is associated with the pressing and drying of never dried pulp therefore the drying process needs to be revisited. The delaminated layer should be restored so as to increase the recyclability of the recovered fibres for high value paper. Influence of recycled pulp blends on physical properties of paper was also studied. It was revealed that small quantity of recycled pulp can be used without significantly affecting the mechanical strength properties.


TAPPI Journal ◽  
2014 ◽  
Vol 13 (4) ◽  
pp. 17-26 ◽  
Author(s):  
VIPUL SINGH CHAUHAN ◽  
NISHI KANT BHARDWAJ

Mineral fillers are added during papermaking to improve the optical and printing properties of paper and decrease energy costs. Filler loading using conventional approaches has some disadvantages, such as reduction in paper strength. The finer filler, the more the strength loss. Several methods and materials have been reported to overcome or alleviate the same, but with higher costs. Our approach provides an economically viable solution to the problem, using conventional papermaking materials. Talc filler of different particle sizes, preflocculated using different doses of cooked amphoteric starch, were used for papermaking. Relatively higher filler retention, paper strength, and hydrophobicity of paper were obtained with preflocculated talc compared to native talc. The optical properties of paper were unchanged on the loading of similar talc after preflocculation. The preflocculated talc of finer particle size provided higher opacity at similar ash, as well as paper strength, than the native talc of coarser size.


Wood Research ◽  
2020 ◽  
Vol 65 (3) ◽  
pp. 447-458
Author(s):  
MONIKA STANKOVSKÁ ◽  
MÁRIA FIŠEROVÁ ◽  
JURAJ GIGAC ◽  
ELENA OPÁLENÁ

BioResources ◽  
2011 ◽  
Vol 6 (1) ◽  
pp. 570-583
Author(s):  
Paulina Mocchiutti ◽  
María V. Galván ◽  
María C. Inalbon ◽  
Miguel A. Zanuttini

Polyelectrolytes containing amine functional groups such as PAH (poly(allylamine hydrochloride)) can be useful, under certain conditions, for improving paper strength. In this work, the charge density of PAH was determined at different pH and ionic strengths; PAH adsorption onto the cellulosic fibers was characterized, and the effects of low PAH dosage on the papermaking properties were evaluated. It was found that the ionization of PAH is complete in acid media, but it is partial and depends on the ionic strength in neutral media. The adsorption isotherms of PAH on a recycled pulp from kraft liner allowed us to determine the amount needed to saturate the adsorption capacity of the fibers. For the three ionic strengths analyzed, the swelling of the fibers decreased when PAH was added in an amount corresponding to saturation (0.23% PAH on dried pulp). Nevertheless, the swelling was recovered when the amount of PAH was the double the saturation level (0.46% PAH on dried pulp). At these levels of addition, the papermaking properties were clearly improved, especially compressive strengths SCT (short compressive test) and CMT (concora medium test). The Page equation of tensile strength showed that PAH improved the shear bond strength, while the relative bonding area slightly decreased.


2020 ◽  
Vol 110 ◽  
pp. 16-24
Author(s):  
Anhelina Nikalaichyk ◽  
Edyta Małachowska

The influence of screening process parameters on paper properties produced from wastepaper. Wastepaper processing is of pivotal importance for environmental protection; it is also crucial for the economy and the management of raw materials. Not only does recycling save space at landfills, it also saves an extremely valuable raw material used for paper production, i.e. wood. Unlike primary pulps, however, wastepaper contains much more than just cellulose fibres and fillers. The fact that recycled paper contains many contaminants, such as metal staples, paper clips, plastic film, glass fragments, and others, makes it necessary to develop a much more complex pulp preparation systems compared to the ones used for primary pulps. Contaminants affect not only the usable quality of paper made of wastepaper, but also cause the wear and tear of paper processing equipment. Thus, the purifying and screening of secondary pulps for further processing is very important. Considering the above, the authors’ objective was to study the impact of the width of screen slots on paper properties if produced from screened wastepaper pulp. Paper strength and paper surface properties were used as the main evaluation criteria. White and mixed wastepaper was used as research material. Based on the tests, the screen slot width was found not to have any significant impact on either paper mechanical strength or paper surface properties.


2020 ◽  
Vol 35 (2) ◽  
pp. 251-260
Author(s):  
Hyun Kang ◽  
Jong Myoung Won ◽  
Byoung-Uk Cho

AbstractA composite filler was developed by pre-flocculation of fiber fines and precipitated calcium carbonate (PCC) particles with flocculants such as cationic polyacrylamide (cPAM) and bentonite. The composite filler was compared with a conventional loading method in terms of physical properties of handsheet and filler retention. The handsheets using the composite filler showed higher strength properties than that using a conventional loading at a similar paper ash content level, implying that paper ash content can be increased maintaining same level of paper strength. Optical properties such as opacity and brightness of the paper with the composite were quite similar with the paper with the conventional loading. Filler retention of the composite filler was slightly higher than that of the conventional loading even though retention aids were not used for the composite filler. Paper formation of the composite filler was better than the case of the conventional loading. However, the sheet with the composite filler showed lower bulk than that with the conventional loading. Conclusively, the composite filler technology by pre-flocculation of fines and filler has a potential to be utilized to produce a high loaded paper.


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