Assessing Cellulose Micro/Nanofibre Morphology Using a High Throughput Fibre Analysis Device to Predict Nanopaper Performance

Characterising cellulose nanofibre (CNF) morphology has been identified as a grand challenge for the nanocellulose research field. Direct techniques for CNF morphology characterisation exhibit various difficulties related to the material network structure and equipment cost, while indirect techniques that investigate fibre-light interaction, fibre-solvent interaction, fibre-fibre interaction, or specific fibre surface area involve relatively facile methods but may be more unreliable. Nanopaper mechanical testing is a prevalent metric for assessing fibre-fibre interaction, but is an off-line, time-consuming, and destructive methodology. In this study, an optical fibre morphology analyser (MorFi, TechPap) was employed as an on-line, high throughput, fast turnaround tool to assess micro/nanofibre pulp morphology and predict the properties of nanopaper material. Correlation analysis identified fibre content and fibre kink properties as most correlated with nanopaper strength and toughness, while fibre width and coarseness were most inversely correlated with nanopaper performance. Principal component analysis (PCA) was employed to visualise interdependent morphological and mechanical data. Subsequently, two data driven statistical models - multiple linear regression (MLR) and machine learning based support vector regression (SVR) - were established to predict nanopaper properties from fibre morphology data, with SVR generating a more accurate prediction across all nanopaper properties (NRMSE = 0.13-0.33) compared to the MLR model (NRMSE = 0.33-0.51). This study highlights that statistical methods are useful to disentangle and visualise interdependent morphological data from an on-line fibre analysis device, while regression models are also capable of predicting paper mechanical properties from CNF samples even though these devices do not operate at nanoscale resolution.

Anatomical characterization of Chimonobambusa quadrangularis based on circumferential and radial variation patterns in cross-sections

The anatomical structure of the bamboo stem is characterized by vascular bundles comprising the xylem, phloem, and sclerenchyma fibrous sheaths as well as parenchymatous ground tissue in which the vascular bundles are embedded. The composition of the stem is the main factor influencing the anatomical characteristics of circular bamboo, which shows considerable variation in the radial direction. However, most species of Chimonobambusa have square stems. Here, we tested the hypothesis that circumferential variation exists in the cross-sectional anatomy of this species. We analysed fibre morphology and the cross-sectional structural characteristics of vascular bundles of Chimonobambusa quadrangularis (Fenzi) Makino and their associated circumferential and radial variation in cross-sections. Microscopic observations were conducted to identify, measure, and compare fibre morphology and the structural characteristics of vascular bundles, including both circumferential and radial anatomical variation. Vascular bundles occurred as undifferentiated, semi-differentiated, and open types in the radial direction with no changes in the circumferential direction. The average length, width, and ratio of fibre length to width were 1463.6 μm, 12.3 μm and 119.3 in the corner region, and 1452.7 μm, 12.8 μm, and 111.3 in the side region, and there were significant circumferential and radial differences in length, width, and the ratio of fibre length to width (). The circumferential variation in density of vascular bundles, the ratio of fibre length to width, radial to tangential diameter ratio of vascular bundles, and the proportion of sclerenchyma were greater in the corner regions than the side regions. The variation in fibre width and the proportion of parenchyma were greater in the corner regions than in the side regions. The density of vascular bundles and proportions of sclerenchyma were greater in the outer stem compared to the inner stem, whereas the length, width, and ratio of fibre length to width were greatest in the centre compared to the inner and outer zones. Circumferential variation of the density of vascular bundles, fibre length and fibre width occurred in the central and outer stem zones. These findings confirm that there are significant anatomical variations in both the circumferential and radial directions and provide a scientific basis for the rational use of Chimonobambusa quadrangularis.

Variation in morphological and wood cell traits in coppice stems of Populus nigra L. and Salix alba L.

Coppice management is an ecologically important silvicultural practice to provide the quicker and higher potential of wood biomass production for industrial demands. Understanding morphological and anatomical responses of coppiced trees could help to determine the quantity and quality of wood and thus provide better management of coppiced tree plantations for short-time biomass production. However, there is a little investigation in morphological and anatomical adaptation in different fast-growing tree species. The present study, therefore, studied how morphology and anatomy vary between two fast-growing coppices of Populus nigra L. (black poplar) and Salix alba L. (white willow). Each coppiced tree was grown in a similar habitat and was at a similar age. However, each coppiced tree showed different morphological and anatomical plasticity in their stems in response to environmental factors. Poplar coppices showed better anatomical properties due to greater vessel diameter, fibre length, fibre width, fibre wall thickness, and ray height; however willow coppices had better morphological plasticity which had higher average stem height and ring width. The results suggest that willow coppices had the greater height growth potential even at 2 years of age than poplar coppices.

Radial variation studies on wood properties of Populus deltoides parents and their hybrids

The radial variation and the genetic variation of wood properties between the parents and offspring of Populus deltoides were studied in this work. The chemical composition, density, and anatomical characteristics of Populus deltoides cl. ‘Danhong’ and its offspring exhibited the phenomenon of transgressive segregation. The chemical compositions of the parents and offspring were decreased in several attributes (benzene alcohol extract, hemicelluloses, lignin) with the increase of the cambial age. Moreover, the fibre length, fibre width, ratio of fibre length to width, and wall thickness to lumen ratio of parents and offspring were increased with cambial age. In addition, the densities of parents and offspring were increased with the increase of cambial age. There were significant differences in wood properties among Populus deltoides and its hybrids. These results indicated that Populus deltoides cl. ‘Danhong’ could be considered as pulp material and Populus deltoides cl. ‘Nanyang’ as building material. According to the radial variation rule of each material character, the rotation cutting period can be selected as years 7 or 8.

Analysis of deterioration characteristics in oil-immersed insulation pressboard with different durations of aging based on an image-processing method

Insulation pressboard samples were obtained by thermal aging (according to Montsinger’s formula, at 130 °C, the pressboard is heated for 0 to 32 days) and discharge experiments. SEM images of samples were analysed. Image segmentation was applied to calculate the fibre width, cross-sectional porosity, and carbon-trace area. Inter-layer fibre models were established to observe fibre morphology using 3-D reconstruction. The initial discharge voltage decreased with age, and the discharge amounts increased. After 16 days of aging, the fibre width had decreased to between 68.1% and 81.8% of unaged pressboard. As the aging increased, cellulose hydrogen bonds were broken, which affected the expansion of interlayer pores, increasing the porosity of the pressboard. After 32 days of aging, the porosity increased to 2.38 times that of a new pressboard. In addition, the longer the aging, the larger the area of carbon marks caused by the discharge breakdown. With the aggravation of thermal aging, the insulating property of pressboard decreased due to the decrease of fibre width and increase of porosity that further accelerated the damage to the fibre structure. It was concluded that the fibre width and porosity could be used as criteria to judge the degradation of pressboard.

Failure modes of insulating pressboard subjected to high electric fields and durations: Evidence of partial discharge and changes at the microscopic scale

The deterioration of insulation pressboard under needle-plate discharge was tested, and the degradation stage was divided according to observed experimental phenomena. Based on the improved Top-hat watershed image segmentation method, the white marks area of the pressboard were tested. Fibres with different discharge states were extracted from SEM images. The fibre width was calculated, and the porosity of the surface of the insulation pressboard at different degradation stages was calculated. Simultaneously, the 3D reconstruction technique was used to observe the 3D morphology of fibres at different discharge stages. The study found that with the deepening of the discharge process, the discharge of the pressboard increased, and the white marks of the pressboard continued to expand from point to surface. In addition, the diameter of the fibre of the insulating pressboard decreased obviously with the increase of the pressing time, and the fibre diameter was 89.6% after the breakdown. Moreover, the electrical stress had a great effect on the expansion of the interlayer pores of the pressboard; the cross-section porosity of the insulating pressboard gradually increased with the deepening of the discharge process, and after breakdown, the interlayer porosity reached 12.5%.

Study of the mechanical behavior of recycled fibers. Applications to papers and paperboards.

Incorporation of recycled fibres in high value paper products can reduce cost and environmental loads. Papermaking potential of cellulosic fibres decreases with recycling. The phenomenon of fibre hornification during pressing and drying is normally held responsible for the loss in strength. To study the impacts of recycling on pulp, fibre and paper properties some non conventional characterisation techniques like fibre saturation point, X-rays microtomography, environmental scanning electron microscopic observations, atomic forcemicroscope (PeakForce QNM mode) and inverse size exclusion chromatography(ISEC) were used. In order to achieve good reproducibility of ISEC measurements,a semi-automatic column fabrication pilot system was built. The techniques were first validated on refining process before being applied to the recycling process. In this study, it was found that fibre hornification alone cannot fully explain loss in strength during recycling. The loss in strength is much more complex and it is required to understand the morphological and ultrastructural changes associated with recycling. Fibre width, cell wall thickness,curl, kink, irregularities decreased during recycling. Fibre became hard and brittle in dry state. Number of weak points in the fibre wall were increased initially and in the later recyclings. The increase in wet breaking length indicates increased surface friction and capillary forces with recycling. Decrease in bonded area during first recycle may be caused by the loss of fines and fibre flexibility whereas the increase afterwards may be linked to the lumen collapse.The strength of fibres did not decrease with recycling as shown by zero-span breaking lengths therefore the quality of bond may be deteriorated. It was thought that the partially delaminated P/S1 layers may be responsible for the loss of paper strength. It is suggested since the significant change is associated with the pressing and drying of never dried pulp therefore the drying process needs to be revisited. The delaminated layer should be restored so as to increase the recyclability of the recovered fibres for high value paper. Influence of recycled pulp blends on physical properties of paper was also studied. It was revealed that small quantity of recycled pulp can be used without significantly affecting the mechanical strength properties.

Anthophyllite Asbestos: The Role of Fiber Width in Mesothelioma Induction Part 1: Epidemiological Studies of Finnish Anthophyllite Asbestos

Anthophyllite asbestos only occurs in a few parts of the world in sufficient quantities to be mined. The largest deposits of anthophyllite asbestos occur in Finland where it was mined for more than 75 years and very extensively used and distributed, anciently, for more than six millennia. Anthophyllite is one of the five minerals known collectively as amphibole asbestos. Studies of the effect of these five mineral fibre types when inhaled have shown that fibre width is an important determinant of mesothelioma induction. Only the “thinner” fibres or those with fiber diameter dimensional profiles predominantly less than 0.25 – 0.30 µm, are clearly mesotheliogenic. The “thicker” ones or those whose predominant widths are greater than these diameters do not appear to show an observable attendant risk of mesothelioma. Observations based on studies of at least, two “thick” forms of amphibole asbestos support these hypotheses. The one is Bolivian crocidolite; the other Finnish anthophyllite. The Finnish anthophyllite industry presents an important opportunity to study the robustness of the theory that fibre width is key to mesothelioma genesis as vast numbers of people in all sectors of the Finnish industry and their families have historically incurred massive fiber exposures sufficient to cause a gross excess of asbestosis. Nonetheless, in spite of these long term, high dose exposures clear evidence for a mesothelioma risk due to anthophyllite asbestos is still lacking.

Characterization of packaging grade papers from recycled raw materials through the study of fibre morphology and composition

The restrictions in availability of forest-based raw materials along with favourable environmental policies towards alternative sources of raw materials have forced corrugated packaging industry to shift towards recycled paper and other fibre sources such as non-wood and agro-residues. The variability in raw pulp materials with increasing percentages of recycled fibres is a very common technical problem for the corrugated packaging industry worldwide. Corrugating packaging production is facing the challenge to ensure a satisfactory strength of packages despite the increase of recycled paper as the main fibrous component. Sustainable manufacturing of papers of consistent and acceptable quality requests comprehensive characterization of the fibrous components, which are becoming more heterogeneous. Understanding the influence that heterogeneous recycled raw materials have on packaging grade paper properties offers great potential value to the corrugated board and packaging industry. 57 linerboards and corrugating medium were selected to represent all the variety of paper grades available on the market at the moment for the production of corrugated board in Spain. The papers were analyzed for their fibre morphology (fibre length, fibre width, lumen diameter, cell wall width and flexibility) and fibre composition (softwood to hardwood and nonwood fibre count and weight) and their strength (compression, bursting and crushing resistance) was evaluated. All the determinations were in accordance with the relevant TAPPI Test Methods. The significant differences found in most of the anatomical characteristics, fibre composition and strength properties among the paper grades reflected the diverse raw materials used for their production as well as their qualitative differences. By means of simple correlation the influence of fibre characteristics and composition on the strength of the papers was determined under two different conditions, at 23 oC and 50% RH and at 20 oC and 90% RH. The results demonstrate that besides the physical-mechanical characterization of packaging grade papers, fibre anatomy and composition can be used successfully as a complementary practical test to predict the performance of papers. The application of the predicting correlations is proposed for the evaluation of the fibre supplies for the packaging industry. An enormous potential for cost reduction can be created by the selection of the most appropriate and inexpensive combination of grade papers for a specific packaging use.