Hydrogen infiltration into BaTiO3-based dielectrics for multi-layer ceramic capacitors under highly accelerated temperature and humidity stress test

Author(s):  
Yoshito Saito ◽  
Toshimi Oguni ◽  
Tomoyuki Nakamura ◽  
Kenichi Nada ◽  
Harunobu Sano ◽  
...  
2018 ◽  
Vol 2018 (HiTEC) ◽  
pp. 000129-000137 ◽  
Author(s):  
Harold L. Snyder

Abstract A highly accelerated life test (HALT) and highly accelerated stress test (HAST) procedure for ceramic capacitors developed by the author in the mid 1980's to early 1990's, and published in 1994, consists of a 400 Volt biased six (6) hour stress sort at 150°C (423K), a methanol current leakage test that located mechanical and structural cracks, a visual inspection at ten times (10×) magnification, and a capacitance and dissipation measurement before and after the test. In over thirty (30) years of use, there has never been a user reported in-circuit failure in industrial, military, and aerospace application at temperatures as high as 500°C (773K). However, reviewing user feedback, two concerns with the original sorting procedure are the stress is performed at 150°C (423K), and the lack of a more detailed ceramic capacitor electrical model. To address the first, the low aging temperature, the stress temperature was increased from 150°C to 300°C, in order to age ceramic solid state crystal mineral phases that may change with temperature. The test results for X7R and NP0/COG multilayer ceramic capacitors (MLCC) at 300°C, are compared to the test results using the original HALT/HAST procedure at 150°C. Differences between X7R/NP0/COG and porcelain capacitors are discussed when applicable. Further, a more detailed ceramic capacitor electrical model that represents the physical and electrical characteristics of the ceramic capacitors is presented, including the electrical current leakage effects with temperature, and the carbonized residue effects from the manufacturing process.


Author(s):  
Abdul Cholid ◽  
Her Gumiwang Ariswati ◽  
Syaifudin Syaifudin

Calibration is a technical activity which consists of the determination, the determination of one or more properties or characteristics of a product, process or service in accordance with a special procedure has been set. The purpose of which is to ensure the calibration measurement results in accordance with national and international standards. The tools used for the calibration of pressure Digital Pressure Meter. This tool is used to measure the pressure and suction pump spygnomanometer or other devices that use parameters for measuring pressure. This module manufacturing system using Arduino system as a controller and as processing analog data into digital data of the sensor MPX5100GP and MPXV4115V using analog signal conditioning circuit and displayed on the LCD Touchscreen with 2 modes of measurement that is positive pressure and vacuum pressure with pressures ranging from 0-300 mmHg for positive pressure and 0 –(-400)  mmHg to vacuum pressure. There are also  DHT22 sensor, As a detector for temperature and humidity for use in the work method in the calibration process. Based on a stress test generated and using comparators Digital Pressure Meter 2 plus brand fluke, this tool has an error value of 0 to 0.58% and has a value increment or correction value of 0 - 3. It can be concluded that the DPM DUA MODE this deserves to be used.


2021 ◽  
pp. 548-562
Author(s):  
Muchtaridi Muchtaridi ◽  
Rini Yulianita ◽  
Iyan Sopyan ◽  
Amirah Mohd Gazzali

Drug stability is one of the most important criteria for producing safe, excellent and effective products. Some environmental factors that influence drug stability are light, temperature, and humidity. Simvastatin is a cholesterol-lowering drug that is known to be sensitive to high temperature and humidity. The purpose of this study is to analyze the effect of 6 months of real-time storage conditions on the stability of generic simvastatin tablets in public pharmacy facilities. This study used simulation method with 4 brands of simvastatin generic tablets with two different strengths (10 mg and 20 mg). In the process, the sample was conditioned in 6 different regions for 6 months. The results of temperature and humidity monitoring showed 2 locations at ≤ 25 ° C, 4 locations had a temperature of ≥ 25 °C and all locations had humidity > 65 %. The drug was evaluated for physical and chemical quality parameters at months 0, 3, and 6. After being stored for 6 months, the tablets showed a decrease in disintegration time and an increase in the friability, showing lack of durability. Similarly, there was a decrease in the content concentration in the tablets but fortunately the level was still within the accepted specification range (90 – 110 %). However, there was one tablet that did not meet the dissolution test requirements after the storage duration (Q ≤ 75 % at 30 minutes). The results of the stress test showed that simvastatin degraded in all conditions. This stress test confirmed the extreme instability of simvastatin.  Poor storage conditions can reduce the quality of generic simvastatin tablets, thus a well-controlled environment is vital in pharmacy facilities.


Author(s):  
Yoshito Saito ◽  
Toshimi Oguni ◽  
Tomoyuki Nakamura ◽  
Kenichi Nada ◽  
Harunobu Sano ◽  
...  

2021 ◽  
Vol 2021 (HiTEC) ◽  
pp. 000094-000099
Author(s):  
Harold L. Snyder

Abstract This is Part 2 of a study initially presented at HiTEC 2018, for context, some introductory material is duplicated. A highly accelerated life test (HALT) and highly accelerated stress test (HAST) procedure for ceramic capacitors developed by the author in the mid 1980’s to early 1990’s, and published in 1994, consists of a 400 Volt biased six (6) hour stress sort at 150°C (423K), a methanol current leakage test that located mechanical and structural cracks, a visual inspection at ten times (10X) magnification, and a capacitance and dissipation measurement before and after the test. In over thirty (30) years of use, there has never been a user reported in-circuit failure in industrial, military, and aerospace application at temperatures as high as 500°C (773K). However, reviewing user feedback, two concerns with the original sorting procedure are the stress is performed at 150°C (423K), and the lack of a more detailed ceramic capacitor electrical model. To address the first, the low aging temperature, the stress temperature was increased from 150°C to 300°C, in order to age ceramic solid state crystal mineral phases that may change with temperature. The test results for X7R and NP0/COG multilayer ceramic capacitors (MLCC) at 300°C, are compared to the test results using the original HALT/HAST procedure at 150°C. Differences between X7R/NP0/COG and porcelain capacitors are discussed when applicable. Further, a more detailed ceramic capacitor electrical model that represents the physical and electrical characteristics of the ceramic capacitors is presented, including the electrical current leakage effects with temperature, and the carbonized residue effects from the manufacturing process.


Author(s):  
Yeshayahu Talmon

To achieve complete microstructural characterization of self-aggregating systems, one needs direct images in addition to quantitative information from non-imaging, e.g., scattering or Theological measurements, techniques. Cryo-TEM enables us to image fluid microstructures at better than one nanometer resolution, with minimal specimen preparation artifacts. Direct images are used to determine the “building blocks” of the fluid microstructure; these are used to build reliable physical models with which quantitative information from techniques such as small-angle x-ray or neutron scattering can be analyzed.To prepare vitrified specimens of microstructured fluids, we have developed the Controlled Environment Vitrification System (CEVS), that enables us to prepare samples under controlled temperature and humidity conditions, thus minimizing microstructural rearrangement due to volatile evaporation or temperature changes. The CEVS may be used to trigger on-the-grid processes to induce formation of new phases, or to study intermediate, transient structures during change of phase (“time-resolved cryo-TEM”). Recently we have developed a new CEVS, where temperature and humidity are controlled by continuous flow of a mixture of humidified and dry air streams.


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