scholarly journals SILICOTHERMIC REDUCTION OF THANHHOA DOLOMITE: THERMODYNAMIC AND EXPERIMENTAL

2021 ◽  
Vol 27 (3) ◽  
pp. 109-113
Author(s):  
Ngoc Binh Duong ◽  
Quyen Vu ◽  
Trang Vu ◽  
Cuong Doan ◽  
Huy Tran
Keyword(s):  
Temperature Increase ◽  
Thermodynamic Calculation ◽  
Experimental Studies ◽  
Vacuum Pressure ◽  
Process Efficiency ◽  
Reduction Temperature ◽  
Effect Of Pressure ◽  
Silicothermic Reduction ◽  
Lower Temperature ◽  
Very High

Thermodynamic and experimental studies was carried out on the process of Thanhhoa dolomite reduction to produce magnesium. Thermodynamically studied on the effect of pressure and temperature on reduction was carried out together with verification experiment. Results show that at appropriate temperature and vacuum pressure, Thanhhoa dolomite can be reduced using ferrosilicon as the reductant. The higher level of vacuum, the lower temperature required for reduction. Thermodynamic calculation pointed out that at a vacuum pressure of 600 Pa, the reduction temperature could be as low as 1140 °C. Experiment results indicated that at although reduction could be done at 1150 °C, the process efficiency was low, generally below 20%. Process efficiency enhanced as temperature increase and reaches the highest value of 85,8% at 1250 °C (25 wt.% ferrosilicon). The amount of ferrosilicon used also has influenced the process efficiency. After three hours of reduction, the obtained magnesium was very high in purity, 99.3%.

Experimental Studies Concerning the Semipermeable Membrane Separation Efficiency for 134Cs, 137Cs, 57Co, 58Co, 60Co, 54Mn in Liquid Radioactive Waste I. Treatment of secondary waste from POD decontamination procedure

2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Mirela Dulama ◽  
Nicoleta Deneanu ◽  
Cristian Dulama ◽  
Margarit Pavelescu
Keyword(s):  
Membrane Separation ◽  
Separation Efficiency ◽  
Liquid Radioactive Waste ◽  
Experimental Studies ◽  
Experimental Tests ◽  
Suspended Solid ◽  
Process Efficiency ◽  
Active Charcoal ◽  
Precipitation Process ◽  
Pre Treatment

The paper presents the experimental tests concerning the treatment by membrane techniques of radioactive aqueous waste. Solutions, which have been treated by using the bench-scale installation, were radioactive simulated secondary wastes from the decontamination process with modified POD. Generally, an increasing of the retention is observed for most of the contaminants in the reverse osmosis experiments with pre-treatment steps. The main reason for taking a chemical treatment approach was to selectively remove soluble contaminants from the waste. In the optimization part of the precipitation step, several precipitation processes were compared. Based on this comparison, mixed [Fe(CN)6]4-/Al3+/Fe2+ was selected as a precipitation process applicable for precipitation of radionuclides and flocculation of suspended solid. Increased efficiencies for cesium radionuclides removal were obtained in natural zeolite adsorption pre-treatment stages and this was due to the fact that volcanic tuff used has a special affinity for this element. Usually, the addition of powdered active charcoal serves as an advanced purifying method used to remove organic compounds and residual radionuclides; thus by analyzing the experimental data (for POD wastes) one can observe a decreasing of about 50% for cobalt isotopes subsequently to the active charcoal adsorption.. The semipermeable membranes were used, which were prepared by the researchers from the Research Center for Macromolecular Materials and Membranes, Bucharest. The process efficiency was monitored by gamma spectrometry.

scholarly journals Conversion of biomass to biofuels and life cycle assessment: a review

2021 ◽  
Author(s):  
Ahmed I. Osman ◽  
Neha Mehta ◽  
Ahmed M. Elgarahy ◽  
Amer Al-Hinai ◽  
Ala’a H. Al-Muhtaseb ◽  
...  
Keyword(s):  
Life Cycle Assessment ◽  
Life Cycle ◽  
Energy Demand ◽  
Fossil Fuels ◽  
Biomass Conversion ◽  
Biofuel Production ◽  
Process Efficiency ◽  
Liquid Fuels ◽  
Thermochemical Processes ◽  
Lower Temperature

AbstractThe global energy demand is projected to rise by almost 28% by 2040 compared to current levels. Biomass is a promising energy source for producing either solid or liquid fuels. Biofuels are alternatives to fossil fuels to reduce anthropogenic greenhouse gas emissions. Nonetheless, policy decisions for biofuels should be based on evidence that biofuels are produced in a sustainable manner. To this end, life cycle assessment (LCA) provides information on environmental impacts associated with biofuel production chains. Here, we review advances in biomass conversion to biofuels and their environmental impact by life cycle assessment. Processes are gasification, combustion, pyrolysis, enzymatic hydrolysis routes and fermentation. Thermochemical processes are classified into low temperature, below 300 °C, and high temperature, higher than 300 °C, i.e. gasification, combustion and pyrolysis. Pyrolysis is promising because it operates at a relatively lower temperature of up to 500 °C, compared to gasification, which operates at 800–1300 °C. We focus on 1) the drawbacks and advantages of the thermochemical and biochemical conversion routes of biomass into various fuels and the possibility of integrating these routes for better process efficiency; 2) methodological approaches and key findings from 40 LCA studies on biomass to biofuel conversion pathways published from 2019 to 2021; and 3) bibliometric trends and knowledge gaps in biomass conversion into biofuels using thermochemical and biochemical routes. The integration of hydrothermal and biochemical routes is promising for the circular economy.

Methanol Reforming Over PT Catalysts for Polymer Electrolyte Membrane Fuel Cells

2006 ◽  
Author(s):  
Taehee Lee ◽  
Joongmyeon Bae ◽  
Ju-Yong Kim
Keyword(s):  
Hydrogen Generation ◽  
Polymer Electrolyte Membrane ◽  
High Energy ◽  
High Energy Density ◽  
Pt Catalysts ◽  
Methanol Reforming ◽  
Electrolyte Membrane ◽  
Cerium Oxides ◽  
Lower Temperature ◽  
Very High

An experimental investigation on hydrogen generation from methanol using Pt catalysts is presented in this paper. Methanol has the advantages of high energy density, high reforming activity and low CO selectivity at low temperatures. At present Cu-based catalysts are widely used for methanol reforming. But they are pyrophoric and thermally unstable, which causes issues in operating a real system. Pt catalysts dispersed on cerium oxides were tested for methanol reforming to resolve the problems. Steam reforming over Pt/cerium oxides showed the low conversion ratio less than 90% and the high CO concentration of about 15% at 400 °C. Autothermal reforming by adding O2 rapidly promoted the conversion of methanol and reduced the concentration of CO at lower temperature. Increasing the amount of dispersed Pt, the range of 0.5–3.0 wt%, shifted the reforming trends towards lower temperature and decreased the concentration of CO. To achieve more production rate within a given catalyst bed, catalysts coated monolithic honeycomb is prepared. It showed very high conversion at space velocities of up to 60,000/h.

scholarly journals Physico-technical approach to design of composites from mineral and polymer technogenic resources

2015 ◽  
Vol 1 ◽  
pp. 162 ◽  
Author(s):  
Gotfrīds Noviks
Keyword(s):  
Composite Materials ◽  
Experimental Studies ◽  
Process Efficiency ◽  
Operating Characteristics ◽  
Forming Process ◽  
Polymer Waste ◽  
Composite Forming ◽  
Different Types ◽  
Low Levels

<p class="R-AbstractKeywords"><span lang="EN-US">Artificial composite materials are currently being produced in large quantities, they are diverse and they are widely used in the economy. There have been extensive theoretical and experimental studies of different types of components, developed the calculation methods of composites production with predefined properties.</span></p><p class="R-AbstractKeywords"><span lang="EN-US">At the same time industry produces a lot of mineral and polymer waste, which are practically technogenic resources, but their use is currently at quite low levels. The paper examines the possibilities to use technogenic resources- mineral (such as ash and clay) and organic (polymers -PET containers) for producing qualitative composite materials. For this purpose theoretical analysis and calculations of the physical properties of components and process parameters that determine the operating characteristics of the composite material were carried out.</span></p><p class="R-AbstractKeywords"><span lang="EN-US">Composite-forming process efficiency determinative parameters were analysed: adhesion, the specific surface energy, specific free surface, adsorption capacity and the degree of dispersion of the particles.</span></p><p class="R-AbstractKeywords"><span lang="EN-US">The role of external factors in processing of composite were examined – temperature, concentration of components.</span></p><p class="R-AbstractKeywords"><span lang="EN-US">The characteristics of prepared samples of composites showed the possibility to use these waste for the development of qualitative products for different purposes.</span></p>

In vitro characterisation of ultrasound-induced heating effects in the mother and fetus: A clinical perspective

Ultrasound ◽  
2020 ◽  
pp. 1742271X2095319
Author(s):  
Stephanie F Smith ◽  
Piero Miloro ◽  
Richard Axell ◽  
Gail ter Haar ◽  
Christoph Lees
Keyword(s):  
Temperature Increase ◽  
Skin Surface ◽  
Maximum Temperature ◽  
Factors Affecting ◽  
Bone Interface ◽  
Heating Effects ◽  
Power Setting ◽  
Lower Temperature

Introduction The quantification of heating effects during exposure to ultrasound is usually based on laboratory experiments in water and is assessed using extrapolated parameters such as the thermal index. In our study, we have measured the temperature increase directly in a simulator of the maternal–fetal environment, the ‘ISUOG Phantom’, using clinically relevant ultrasound scanners, transducers and exposure conditions. Methods The study was carried out using an instrumented phantom designed to represent the pregnant maternal abdomen and which enabled temperature recordings at positions in tissue mimics which represented the skin surface, sub-surface, amniotic fluid and fetal bone interface. We tested four different transducers on a commercial diagnostic scanner. The effects of scan duration, presence of a circulating fluid, pre-set and power were recorded. Results The highest temperature increase was always at the transducer–skin interface, where temperature increases between 1.4°C and 9.5°C were observed; lower temperature rises, between 0.1°C and 1.0°C, were observed deeper in tissue and at the bone interface. Doppler modes generated the highest temperature increases. Most of the heating occurred in the first 3 minutes of exposure, with the presence of a circulating fluid having a limited effect. The power setting affected the maximum temperature increase proportionally, with peak temperature increasing from 4.3°C to 6.7°C when power was increased from 63% to 100%. Conclusions Although this phantom provides a crude mimic of the in vivo conditions, the overall results showed good repeatability and agreement with previously published experiments. All studies showed that the temperature rises observed fell within the recommendations of international regulatory bodies. However, it is important that the operator should be aware of factors affecting the temperature increase.

Experimental Studies on Galling Onset in OCTG Connections: A Review

Tribology ◽  
2006 ◽  
Author(s):  
S. Ekwaro-Osire ◽  
F. Karpat
Keyword(s):  
Natural Gas ◽  
Experimental Studies ◽  
Oil Industry ◽  
Superior Performance ◽  
Review Of Literature ◽  
Performance Properties ◽  
Operational Costs ◽  
Concise Review ◽  
Mode Of Failure ◽  
Very High

With today's high prices for natural gas and oil, the demand for oil and country tubular goods (OCTG), with superior performance properties, is very high. Failures in OCTG can be attributed to numerous sources, for example, makeup torque, corrosion, and galling. Thread galling is the most common mode of failure. This failure often leads to leakage, corrosion of the material, and loss of mechanical integrity. The failure of OCTG eventually amounts to excessive operational costs for the gas and oil industry. The have been numerous approaches taken to improve the galling resistance of OCTG connections. The advocacy of these approaches is often achieved through experimental studies using galling testers. In this paper, it is proposed to classify the galling testers in seven distinct groups. There is a need to design and use effective galling testers to understand and improve the performance of OCTG connections. Thus, the objective of this paper was to present a concise review of literature related to the galling testers that may have applications to OCTG.

scholarly journals The Pathophysiology of Post-Traumatic Glioma

2018 ◽  
Vol 19 (8) ◽  
pp. 2445 ◽  
Author(s):  
Donata Simińska ◽  
Klaudyna Kojder ◽  
Dariusz Jeżewski ◽  
Ireneusz Kojder ◽  
Marta Skórka ◽  
...  
Keyword(s):  
Brain Tumor ◽  
Immune System ◽  
Experimental Studies ◽  
Epidemiological Studies ◽  
Detection Rates ◽  
Expression Of Genes ◽  
Specific Morphology ◽  
Post Traumatic ◽  
The Brain ◽  
Very High

Malignant glioma is a brain tumor with a very high mortality rate resulting from the specific morphology of its infiltrative growth and poor early detection rates. The causes of one of its very specific types, i.e., post-traumatic glioma, have been discussed for many years, with some studies providing evidence for mechanisms where the reaction to an injury may in some cases lead to the onset of carcinogenesis in the brain. In this review of the available literature, we discuss the consequences of breaking the blood–brain barrier and consequences of the influx of immune-system cells to the site of injury. We also analyze the influence of inflammatory mediators on the expression of genes controlling the process of apoptosis and the effect of chemical mutagenic factors on glial cells in the brain. We present the results of experimental studies indicating a relationship between injury and glioma development. However, epidemiological studies on post-traumatic glioma, of which only a few confirm the conclusions of experimental research, indicate that any potential relationship between injury and glioma, if any, is indirect.

Effect of charge and deformation parameter on energy extraction in charged non-Kerr black holes

2019 ◽  
Vol 28 (16) ◽  
pp. 2040012
Author(s):  
Rehana Rahim ◽  
Khalid Saifullah
Keyword(s):  
Black Holes ◽  
Black Hole ◽  
Deformation Parameter ◽  
High Efficiency ◽  
Process Efficiency ◽  
Energy Extraction ◽  
Penrose Process ◽  
Kerr Black Holes ◽  
Very High

We analyze the charged Johannsen–Psaltis black hole for energy extraction via the Penrose process. Efficiency of the Penrose process is found to be dependent on the deformation parameter of the metric and charge. Doing the calculations numerically, we find that, in the nonextremal limit, presence of charge leads to lesser efficiency than the Kerr. In the extremal cases with negative deformation parameter, charge leads to a very high efficiency, higher than that of the Kerr and Johannsen–Psaltis black holes.

scholarly journals Modelling ion populations in astrophysical plasmas: carbon in the solar transition region

2019 ◽  
Vol 626 ◽  
pp. A123 ◽  
Author(s):  
R. P. Dufresne ◽  
G. Del Zanna
Keyword(s):  
Transition Region ◽  
Experimental Studies ◽  
Charge State Distribution ◽  
Dielectronic Recombination ◽  
Stellar Atmospheres ◽  
Astrophysical Plasmas ◽  
Atomic Process ◽  
Solar Transition Region ◽  
Solar Transition ◽  
Lower Temperature

The aim of this work is to improve the modelling of ion populations in higher density, lower temperature astrophysical plasmas, of the type commonly found in lower solar and stellar atmospheres. Ion population models for these regions frequently employ the coronal approximation, which assumes conditions more suitable to the upper solar atmosphere, where high temperatures and lower densities prevail. The assumed conditions include all ions being in the ground state and steady-state equilibrium, where there is sufficient time for ionisation and recombination to take place. Using the coronal approximation for modelling the solar transition region gives theoretical lines intensities for the Li-like and Na-like isoelectronic sequences which are often factors of two to five times lower than observed. The works of Burgess & Summers (1969, ApJ, 157, 1007) and Nussbaumer & Storey (1975, A&A, 44, 321) show the important part ions in excited levels play when included in the modelling. As density increases metastable levels become populated and ionisation rates increase, whereas dielectronic recombination through highly excited levels is suppressed. Photo-ionisation is also shown by Nussbaumer & Storey to have an effect on the charge-state distribution of carbon in these regions. Their models, however, use approximations for the atomic rates to determine the ion balance. Presented here is the first stage in updating these earlier models of carbon by using rates from up-to-date atomic calculations and more recent photo-ionising radiances. Where atomic rates were not readily available, in the case of electron impact direct ionisation and excitation–auto-ionisation, new calculations were made using the Flexible Atomic Code and Autostructure, and compared to theoretical and experimental studies. The effects each atomic process has on the ion populations as density changes is illustrated, and final results from the modelling are compared to the earlier works. Lastly, the new results for ion populations were used to predict line intensities for the solar transition region in the quiet Sun. In comparison to coronal approximation modelling the new results show significantly improved agreement with observations.

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