scholarly journals Analyzing Oxygen Ionization in the Circumgalactic Medium

2021 ◽  
Vol 5 (12) ◽  
pp. 278
Author(s):  
Sally Zhu ◽  
Rahul Sharma ◽  
Clayton J. Strawn
Keyword(s):  
Galaxy Evolution ◽  
Column Density ◽  
Local Minimum ◽  
Temperature Dependent ◽  
Mass Distributions ◽  
Density Distributions ◽  
Circumgalactic Medium ◽  
Collisional Ionization ◽  
Oxygen Ionization ◽  
Insight Into

Abstract Galaxies are surrounded by low-density, highly-ionized clouds of gas, called the Circumgalactic Medium (CGM), which provides insight into galaxy evolution. CGM observations are sensitive to ionization levels, which requires studying ionization types: photoionization (PI), more density-dependent and associated with cooler gas, and collisional ionization (CI), more temperature-dependent and associated with hotter gas. We analyzed PI and CI components for oxygen ionization states using cosmological galaxy simulations. For each ion, we plotted mass distributions into PI and CI phases and created 2D covering-fraction projections of column density at different thresholds. We analyzed changes for different mass-bin galaxies. Our results are: O vii and O ix are the only predominantly-CI ion states. O vi is a local minimum in both PI and CI gas. Column density distributions greatly emphasize higher ion states. Shapes of covering-fraction plots at higher thresholds resemble the 3D-plots. CI gas dominates more in higher mass galaxy simulations.

scholarly journals The warm-hot circumgalactic medium around EAGLE-simulation galaxies and its detection prospects with X-ray and UV line absorption

2020 ◽  
Vol 498 (1) ◽  
pp. 574-598 ◽  
Author(s):  
Nastasha A Wijers ◽  
Joop Schaye ◽  
Benjamin D Oppenheimer
Keyword(s):  
Column Density ◽  
Extreme Ultraviolet ◽  
Gas Well ◽  
X Ray ◽  
Filling Phase ◽  
Circumgalactic Medium ◽  
Halo Masses ◽  
Collisional Ionization ◽  
Far Ultraviolet ◽  
Halo Gas

ABSTRACT We use the EAGLE (Evolution and Assembly of GaLaxies and their Environments) cosmological simulation to study the distribution of baryons, and far-ultraviolet (O vi), extreme-ultraviolet (Ne viii), and X-ray (O vii, O viii, Ne ix, and Fe xvii) line absorbers, around galaxies and haloes of mass $\,{M}_{\rm {200c}}= 10^{11}$–$10^{14.5} \, \rm {M}_{\odot}$ at redshift 0.1. EAGLE predicts that the circumgalactic medium (CGM) contains more metals than the interstellar medium across halo masses. The ions we study here trace the warm-hot, volume-filling phase of the CGM, but are biased towards temperatures corresponding to the collisional ionization peak for each ion, and towards high metallicities. Gas well within the virial radius is mostly collisionally ionized, but around and beyond this radius, and for O vi, photoionization becomes significant. When presenting observables, we work with column densities, but quantify their relation with equivalent widths by analysing virtual spectra. Virial-temperature collisional ionization equilibrium ion fractions are good predictors of column density trends with halo mass, but underestimate the diversity of ions in haloes. Halo gas dominates the highest column density absorption for X-ray lines, but lower density gas contributes to strong UV absorption lines from O vi and Ne viii. Of the O vii (O viii) absorbers detectable in an Athena X-IFU blind survey, we find that 41 (56) per cent arise from haloes with $\,{M}_{\rm {200c}}= 10^{12.0}{-}10^{13.5} \, \rm {M}_{\odot}$. We predict that the X-IFU will detect O vii (O viii) in 77 (46) per cent of the sightlines passing $\,{M}_{\star }= 10^{10.5}{-}10^{11.0} \, \rm {M}_{\odot}$ galaxies within $100 \, \rm {pkpc}$ (59 (82) per cent for $\,{M}_{\star }\gt 10^{11.0} \, \rm {M}_{\odot}$). Hence, the X-IFU will probe covering fractions comparable to those detected with the Cosmic Origins Spectrograph for O vi.

scholarly journals The density distribution of accreting cosmic filaments as shaped by Kelvin–Helmholtz instability

2019 ◽  
Vol 489 (2) ◽  
pp. 2130-2141 ◽  
Author(s):  
Ann-Christine E Vossberg ◽  
Sebastiano Cantalupo ◽  
Gabriele Pezzulli
Keyword(s):  
Mach Number ◽  
Density Distribution ◽  
Galaxy Evolution ◽  
Initial Perturbation ◽  
Helmholtz Instability ◽  
Gas Density ◽  
Density Distributions ◽  
Circumgalactic Medium ◽  
Hydrodynamical Simulations ◽  
High Mach

ABSTRACT Cosmic filaments play a crucial role in galaxy evolution, transporting gas from the intergalactic medium into galaxies. However, little is known about the efficiency of this process and whether the gas is accreted in a homogenous or clumpy way. Recent observations suggest the presence of broad gas density distributions in the circumgalactic medium, which could be related to the accretion of filaments. By means of two-dimensional high-resolution hydrodynamical simulations, we explore here the evolution of cold accreting filaments flowing through the hot circumgalactic medium (CGM) of high-z galaxies. We focus on the purely adiabatic case, not including cooling, gravity, or magnetic fields. In particular, we examine the non-linear effects of Kelvin–Helmholtz instability on the development of broad gas density distributions and on the formation of cold, dense clumps. We explore a large parameter space in the filament and perturbation properties, such as filament Mach number, initial perturbation wavelength, and thickness of the interface between the filament and the halo. We find that the time-averaged density distribution of the cold gas is qualitatively consistent with a skewed lognormal probability distribution function plus an additional component in the form of a high-density tail for high Mach numbers. Our results suggest a tight correlation between the accreting velocity and the maximum densities developing in the filament, which is consistent with the variance–Mach number relation for turbulence. Therefore, cosmological accretion could be a viable mechanism to produce turbulence and broad gas density distributions within the CGM.

Mechanistic insight into the influence of O2 on N2O formation in the selective catalytic reduction of NO with NH3 over Pd/CeO2 catalyst

2021 ◽  
Author(s):  
Liping Sheng ◽  
Songda Li ◽  
Zhaoxia Ma ◽  
Fei Wang ◽  
Hu He ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
No Reduction ◽  
Catalytic Reduction ◽  
Temperature Dependent ◽  
N2o Formation ◽  
Reduction Of No ◽  
Mechanistic Insight ◽  
Insight Into

O2 greatly affected the pathway for NO reduction over the Pd/CeO2 catalyst and resulted in a temperature-dependent NH3-SCR performance and formation of N2O.

scholarly journals 4-hydroxyphenylpyruvate dioxygenase thermolability is responsible for temperature-dependent melanogenesis inAeromonas salmonicidasubsp.salmonicida

2018 ◽  
Author(s):  
Yunqian Qiao ◽  
Jiao Wang ◽  
He Wang ◽  
Baozhong Chai ◽  
Chufeng Rao ◽  
...  
Keyword(s):  
Cold Water ◽  
Biological Significance ◽  
Adaptive Strategy ◽  
Aeromonas Salmonicida ◽  
Temperature Dependent ◽  
Ideal Model ◽  
Melanin Production ◽  
Water Fish ◽  
Insight Into

AbstractAeromonas salmonicidasubsp.salmonicida(A.s.s) is a major pathogen affecting fisheries worldwide. It is a well-known member of the pigmentedAeromonasspecies, which produces melanin at ≤ 22 °C. However, melanogenesis decreases as the culture temperature increases and is completely suppressed at 30-35 °C while bacterial growth is not affected. The mechanism and biological significance of this temperature-dependent melanogenesis are not clear. Heterologous expression of anA.s.s.4-hydroxyphenylpyruvate dioxygenase (HppD), the most crucial enzyme in the HGA-melanin synthesis pathway, results in thermosensitive pigmentation inEscherichia coli, suggesting that HppD plays a key role in this process. In the current study, we demonstrated that the extreme thermolability of HppD is responsible for the temperature-dependent melanization ofA.s.s.Substitutions in three residues, Ser18, Pro103, or Leu119 of HppD fromA.s.sincreases the thermolability of this enzyme and results in temperature-independent melanogenesis. Moreover, replacing the corresponding residues of HppD fromAeromonasmedia strain WS, which forms pigment independent of temperature, with those ofA.s.sHppD leads to thermosensitive melanogenesis. Structural analysis suggested that mutations at these sites, especially at position P103, can strengthen the secondary structure of HppD and greatly improve its thermal stability. In addition, we found that HppD sequences of allA.s.sisolates are identical and that two of the three residues are completely conserved withinA.s.sisolates, which clearly distinguishes these from otherAeromonasstrains. We suggest that this property represents an adaptive strategy to the psychrophilic lifestyle ofA.s.s.ImportanceAeromonas salmonicidasubsp.salmonicida(A.s.s) is the causative agent of furunculosis, a bacterial septicemia of cold water fish of theSalmonidaefamily. As it has a well-defined host range,A.s.shas become an ideal model to investigate the co-evolution of host and pathogen. For many pathogens, melanin production is associated with virulence. Although other species ofAeromonascan produce melanin,A.s.sis the only member of this genus that has been reported to exhibit temperature-dependent melanization. Here we demonstrate that thermosensitive melanogenesis inA.s.sstrains is due to the thermolability of 4-hydroxyphenylpyruvate dioxygenase (HppD). The strictly conservedhppDsequences amongA.s.sand the exclusive thermosensitive pigmentation of these strains might provide insight into the role of melanin in the adaptation to a particular host, and offer a novel molecular marker to readily differentiateA.s.sstrains from otherA. salmonicidasubspecies andAeromonasspecies.

Quick temperature-sweep pure-shift NMR: the case of solvent effects in atorvastatin

2019 ◽  
Vol 21 (35) ◽  
pp. 19209-19215 ◽  
Author(s):  
Małgorzata Rytel ◽  
Paweł Kasprzak ◽  
Piotr Setny ◽  
Krzysztof Kazimierczuk
Keyword(s):  
Solvent Effects ◽  
Temperature Dependent ◽  
Insight Into

Quick and sensitive serial pseudo-2D pure-shift NMR experiments provide novel insight into the temperature-dependent solvent distribution.

scholarly journals Magnetized filament models for diverging plasma lenses

2020 ◽  
Vol 493 (2) ◽  
pp. 1736-1752
Author(s):  
Adam Rogers ◽  
Abdul Mohamed ◽  
Bailey Preston ◽  
Jason D Fiege ◽  
Xinzhong Er
Keyword(s):  
Magnetic Field ◽  
Column Density ◽  
Volume Density ◽  
Magnetized Plasma ◽  
Gravitational Lens ◽  
Line Of Sight ◽  
Density Distributions ◽  
Rotation Measure ◽  
Spherical Plasma ◽  
Helical Magnetic Field

ABSTRACT Spherical plasma lens models are known to suffer from a severe overpressure problem, with some observations requiring lenses with central pressures up to millions of times in excess of the ambient interstellar medium. There are two ways that lens models can solve the overpressure problem: a confinement mechanism exists to counter the internal pressure of the lens, or the lens has a unique geometry, such that the projected column-density appears large to an observer. This occurs with highly asymmetric models, such as edge-on sheets or filaments, with potentially low volume–density. In the first part of this work we investigate the ability of non-magnetized plasma filaments to mimic the magnification of sources seen behind spherical lenses and we extend a theorem from gravitational lens studies regarding this model degeneracy. We find that for plasma lenses, the theorem produces unphysical charge density distributions. In the second part of the work, we consider the plasma lens overpressure problem. Using magnetohydrodynamics, we develop a non self-gravitating model filament confined by a helical magnetic field. We use toy models in the force-free limit to illustrate novel lensing properties. Generally, magnetized filaments may act as lenses in any orientation with respect to the observer, with the most high-density events produced from filaments with axes near the line of sight. We focus on filaments that are perpendicular to the line of sight that show the toroidal magnetic field component may be observed via the lens rotation measure.

Conformational and aggregation properties of PffBT4T polymers: atomistic insight into the impact of alkyl-chain branching positions

2019 ◽  
Vol 7 (45) ◽  
pp. 14198-14204
Author(s):  
Lu Ning ◽  
Guangchao Han ◽  
Yuanping Yi
Keyword(s):  
Molecular Dynamics ◽  
Molecular Dynamics Simulations ◽  
Alkyl Chain ◽  
Temperature Dependent ◽  
Chain Branching ◽  
Alkyl Chains ◽  
Dynamics Simulations ◽  
The Impact ◽  
Insight Into

The impact of the branching positions of alkyl chains on temperature dependent aggregation is rationalized by atomistic molecular dynamics simulations.

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