scholarly journals The isotopic geochemistry of CaCO3 encrustations in Taylor Valley, Antarctica: Implications for their origin

2020 ◽  
Vol 60 (2) ◽  
pp. 125-139 ◽  
Author(s):  
Berry Lyons ◽  
Kelly Foley ◽  
Anne Carey ◽  
Melisa Diaz ◽  
Gabriel Bowen ◽  
...  
Keyword(s):  
Calcium Carbonate ◽  
Meteoric Water ◽  
Primary Source ◽  
Dry Valleys ◽  
Isotopic Data ◽  
Calcite Precipitation ◽  
Desert Soils ◽  
Taylor Valley ◽  
Isotopic Geochemistry ◽  
Δ18o And Δ13c

Calcium carbonate (CaCO<sub>3</sub>) encrustations occur in most desert soils, including polar ones, and such encrustations preserve records of geochemical, hydrological, and atmosphere processes affecting these soils. We have collected a series of CaCO3 encrustations found underneath surface rocks in the soils and tills of Taylor Valley, McMurdo Dry Valleys (~78°S lat.), Antarctica. These encrustations were analyzed for 87Sr/86S and δ18O and δ13C to determine what relation they have with the underlying soils, and the material in which they are in contact, and to identify the processes that control their formation. In all but one case, the isotopic data indicate that the source of Sr to these encrustations is not from the rock on which it is associated. The primary source of Sr (and by analogy Ca) is either from dust that has been deposited through aeolian processes or from the aggregate of till material within the soils. The δ13C values for Taylor Valley encrustations ranged from 5.7 to 11.0‰, and are consistent with a carbon source from atmospheric CO<sub>2</sub>. The δ18O values range from –8.1 to –11.2‰ and are heavier than expected for equilibrium calcite precipitation from Taylor Valley meteoric water. Taken together these results indicate that the CaCO<sub>3</sub> was formed by rapid evaporation of films beneath clasts that had become supersaturated with respect to CaCO<sub>3</sub>.

Generation of high-pH groundwaters and H2 gas by groundwater–kimberlite interaction, northeastern Ontario, Canada

2021 ◽  
Vol 59 (5) ◽  
pp. 1261-1276
Author(s):  
Jamil A. Sader ◽  
Anna L. Harrison ◽  
M. Beth McClenaghan ◽  
Stewart M. Hamilton ◽  
Ian D. Clark ◽  
...  
Keyword(s):  
Inorganic Carbon ◽  
Meteoric Water ◽  
Dissolved Inorganic Carbon ◽  
Carbon Sink ◽  
H2 Production ◽  
Hydrogen Gas ◽  
Isotopic Data ◽  
Northern Ontario ◽  
Ch4 Production ◽  
High K

ABSTRACT We report new isotopic data for H2 and CH4 gases and Sr for groundwater collected from Jurassic Kirkland Lake kimberlites in northern Ontario, Canada. Groundwaters interacting with kimberlites have elevated pH (up to 12.4), are reducing (Eh as low as the H2-H2O couple), are dominated by OH− alkalinity, and have non-radiogenic (mantle) 87Sr/86Sr values (∼0.706–0.707). Most significantly, the highest pH groundwaters have low Mg, high K/Mg, and are associated with abundant reduced gases (H2 ± CH4). Open system conditions favor higher dissolved inorganic carbon and CH4 production, whereas under closed system conditions low DIC, elevated OH− alkalinity, and H2 production are enhanced. Hydrogen gas is isotopically depleted (δ2HH2 = −771 to −801‰), which, combined with δ2HH2O, yields geothermometry temperatures of serpentinization of 5–25 °C. Deviation of H2-rich groundwaters (by up to 10‰) from the meteoric water line is consistent with Rayleigh fractionation during reduction of water to H2. Methane is characterized by δ13CCH4 = −35.8 to −68‰ and δ2HCH4 = −434‰. The origin of CH4 is inconclusive and there is evidence to support both biogenic and abiogenic origins. The modeled groundwater–kimberlite reactions and production of elevated concentrations of H2 gas suggest uses for diamond-production tailings, as a source of H2 for fuel cells and as a carbon sink.

scholarly journals Preliminary research for identification of bacteria useful in microbially induced calcium carbonate precipitation

2018 ◽  
Vol 44 ◽  
pp. 00115
Author(s):  
Katarzyna Misiołek ◽  
Paweł Popielski ◽  
Katarzyna Affek
Keyword(s):  
Calcium Carbonate ◽  
Soil Stabilization ◽  
Carbonate Precipitation ◽  
Calcium Carbonate Precipitation ◽  
Construction Sites ◽  
Calcite Precipitation ◽  
Strength Parameters ◽  
Gram Staining ◽  
Identification Of Bacteria

MICP (Microbially Induced Calcite Precipitation) is a new biological method in soil stabilization. This cheap and eco-friendly technique improves strength parameters of the ground such as shear strength and decreases the permeability of gravelly and sandy soil. There are variety of microorganisms that can be used in calcite precipitation. The most popular method is precipitation of calcium carbonate by bacteria. The main purpose of the article is to present the results from Gram staining of bacteria isolated from construction sites, which is the first step of their identification. Gram’s method allows to find out which morphological groups of bacteria are adapted to conditions present in soil from construction sites and therefore are potentially able to produce calcite. The article describes the methodology of isolation, staining and determination of morphological types of bacteria.

scholarly journals Near-surface internal melting: a substantial mass loss on Antarctic Dry Valley glaciers

2014 ◽  
Vol 60 (220) ◽  
pp. 361-374 ◽  
Author(s):  
Matthew J. Hoffman ◽  
Andrew G. Fountain ◽  
Glen E. Liston
Keyword(s):  
Meteorological Data ◽  
Primary Source ◽  
Balance Model ◽  
Weathering Crust ◽  
Field Observations ◽  
Dry Valleys ◽  
Near Surface ◽  
Ice Surface ◽  
Dry Valley ◽  
Glacier Ablation

AbstractThe McMurdo Dry Valleys, southern Victoria Land, East Antarctica, are a polar desert, and melt from glacial ice is the primary source of water to streams, lakes and associated ecosystems. Previous work found that to adequately model glacier ablation and subsurface ice temperatures with a surface energy-balance model required including the transmission of solar radiation into the ice. Here we investigate the contribution of subsurface melt to the mass balance of (and runoff from) Dry Valley glaciers by including a drainage process in the model and applying the model to three glacier sites using 13 years of hourly meteorological data. Model results for the smooth glacier surfaces common to many glaciers in the Dry Valleys showed that sublimation was typically the largest component of surface lowering, with rare episodes of surface melting, consistent with anecdotal field observations. Results also showed extensive internal melting 5–15 cm below the ice surface, the drainage of which accounted for ~50% of summer ablation. This is consistent with field observations of subsurface streams and formation of a weathering crust. We identify an annual cycle of weathering crust formation in summer and its removal during the 10 months of winter sublimation.

scholarly journals Glacier mass balances (1993–2001), Taylor Valley, McMurdo Dry Valleys, Antarctica

2006 ◽  
Vol 52 (178) ◽  
pp. 451-462 ◽  
Author(s):  
Andrew G. Fountain ◽  
Thomas H. Nylen ◽  
Karen L. MacClune ◽  
Gayle L. Dana
Keyword(s):  
Mass Balance ◽  
Piecewise Linear ◽  
Objective Assessment ◽  
Mcmurdo Dry Valleys ◽  
Dry Valleys ◽  
Mass Balances ◽  
Missing Measurements ◽  
Wind Speeds ◽  
Taylor Valley ◽  
Air Temperatures

AbstractMass balances were measured on four glaciers in Taylor Valley, Antarctica, from 1993 to 2001. We used a piecewise linear regression, which provided an objective assessment of error, to estimate the mass balance with elevation. Missing measurements were estimated from linear regressions between points and showed a significant improvement over other methods. Unlike temperate glaciers the accumulation zone of these polar glaciers accumulates mass in summer and winter and the ablation zone loses mass in both seasons. A strong spatial trend of smaller mass-balance values with distance inland (r2 = 0.80) reflects a climatic gradient to warmer air temperatures, faster wind speeds and less precipitation. Annual and seasonal mass-balance values range only several tens of millimeters in magnitude and no temporal trend is evident. The glaciers of Taylor Valley, and probably the entire McMurdo Dry Valleys, are in equilibrium with the current climate, and contrast with glacier trends elsewhere on the Antarctic Peninsula and in temperate latitudes.

scholarly journals Water tracks intensify surface energy and mass exchange in the Antarctic McMurdo Dry Valleys

2019 ◽  
Vol 13 (8) ◽  
pp. 2203-2219 ◽  
Author(s):  
Tobias Linhardt ◽  
Joseph S. Levy ◽  
Christoph K. Thomas
Keyword(s):  
Climate Change ◽  
Energy Balance ◽  
Surface Energy ◽  
Surface Energy Balance ◽  
Heat Fluxes ◽  
Dry Valleys ◽  
Sensible Heat ◽  
Net Radiation ◽  
Taylor Valley ◽  
The Antarctic

Abstract. The hydrologic cycle in the Antarctic McMurdo Dry Valleys (MDV) is mainly controlled by surface energy balance. Water tracks are channel-shaped high-moisture zones in the active layer of permafrost soils and are important solute and water pathways in the MDV. We evaluated the hypothesis that water tracks alter the surface energy balance in this dry, cold, and ice-sheet-free environment during summer warming and may therefore be an increasingly important hydrologic feature in the MDV in the face of landscape response to climate change. The surface energy balance was measured for one water track and two off-track reference locations in Taylor Valley over 26 d of the Antarctic summer of 2012–2013. Turbulent atmospheric fluxes of sensible heat and evaporation were observed using the eddy-covariance method in combination with flux footprint modeling, which was the first application of this technique in the MDV. Soil heat fluxes were analyzed by measuring the heat storage change in the thawed layer and approximating soil heat flux at ice table depth by surface energy balance residuals. For both water track and reference locations over 50 % of net radiation was transferred to sensible heat exchange, about 30 % to melting of the seasonally thawed layer, and the remainder to evaporation. The net energy flux in the thawed layer was zero. For the water track location, evaporation was increased by a factor of 3.0 relative to the reference locations, ground heat fluxes by 1.4, and net radiation by 1.1, while sensible heat fluxes were reduced down to 0.7. Expecting a positive snow and ground ice melt response to climate change in the MDV, we entertained a realistic climate change response scenario in which a doubling of the land cover fraction of water tracks increases the evaporation from soil surfaces in lower Taylor Valley in summer by 6 % to 0.36 mm d−1. Possible climate change pathways leading to this change in landscape are discussed. Considering our results, an expansion of water track area would make new soil habitats accessible, alter soil habitat suitability, and possibly increase biological activity in the MDV. In summary, we show that the surface energy balance of water tracks distinctly differs from that of the dominant dry soils in polar deserts. With an expected increase in area covered by water tracks, our findings have implications for hydrology and soil ecosystems across terrestrial Antarctica.

scholarly journals Biostimulation in Desert Soils for Microbial-Induced Calcite Precipitation

2020 ◽  
Vol 10 (8) ◽  
pp. 2905 ◽  
Author(s):  
Hadas Raveh-Amit ◽  
Michael Tsesarsky
Keyword(s):  
Soil Liquefaction ◽  
Negev Desert ◽  
Total Carbon ◽  
Arid Environments ◽  
Low Carbon ◽  
Calcium Carbonate Precipitation ◽  
Calcite Precipitation ◽  
Total Carbon Content ◽  
Desert Soils ◽  
Precipitation Medium

Microbial-induced calcite precipitation (MICP) is a soil amelioration technique aiming to mitigate different environmental and engineering concerns, including desertification, soil erosion, and soil liquefaction, among others. The hydrolysis of urea, catalyzed by the microbial enzyme urease, is considered the most efficient microbial pathway for MICP. Biostimulated MICP relies on the enhancement of indigenous urea-hydrolyzing bacteria by providing an appropriate enrichment and precipitation medium, as opposed to bioaugmentation, which requires introducing large volumes of exogenous bacterial cultures into the treated soil along with a growth and precipitation medium. Biostimulated MICP in desert soils is challenging as the total carbon content and the bacterial abundance are considerably low. In this study, we examined the biostimulation potential in soils from the Negev Desert, Israel, for the purpose of mitigation of topsoil erosion in arid environments. Incubating soil samples in urea and enrichment media demonstrated effective urea hydrolysis leading to pH increase, which is necessary for calcite precipitation. Biostimulation rates were found to increase with concentrations of energy (carbon) source in the stimulation media, reaching its maximal levels within 3 to 6 days. Following stimulation, calcium carbonate precipitation was induced by spiking stimulated bacteria in precipitation (CaCl2 enriched) media. The results of our research demonstrate that biostimulated MICP is feasible in the low-carbon, mineral soils of the northern Negev Desert in Israel.

scholarly journals A temperature-index model of stream flow at below-freezing temperatures in Taylor Valley, Antarctica

2005 ◽  
Vol 40 ◽  
pp. 76-82 ◽  
Author(s):  
Amy F. Ebnet ◽  
Andrew G. Fountain ◽  
Thomas H. Nylen ◽  
Diane M. Mcknight ◽  
Christopher L. Jaros
Keyword(s):  
Melting Rate ◽  
Coefficient Of Determination ◽  
Dry Valleys ◽  
The South ◽  
Index Model ◽  
The North ◽  
Taylor Valley ◽  
Air Temperatures ◽  
Glacial Runoff ◽  
Summer Temperatures

AbstractWe model runoff from glaciers in the McMurdo Dry Valleys, Antarctica, with summer (December–January) average air temperatures from 1990 to 2002 for the purpose of estimating decades- to millennial-scale glacial runoff into Lakes Fryxell, Hoare and Bonney. The relationship between summer temperatures and melt is found to be exponential near the melting temperature. We propose a variety of simple models that are calibrated using measured discharge from a number of streams draining from ten glaciers in Taylor Valley. The surface melting rate is constrained by mass-balance measurements from four of the glaciers. A model based solely on temperature produced good results (coefficient of determination, r2 = 0.71) for the south-facing glaciers, but poor results for the north-facing glaciers (r2 < 0). The inclusion of a solar radiation index increased the modeled melt from the north-facing glaciers and thus improved the results (r2 = 0.73) for the north-facing glaciers, with little change from the south-facing glaciers. Including a wind index did not improve the correlation between modeled and measured runoff.

Suite subdivision and petrological evolution of granitoids from the Taylor Valley and Ferrar Glacier region, south Victoria Land

1992 ◽  
Vol 4 (1) ◽  
pp. 71-87 ◽  
Author(s):  
Robert W. Smillie
Keyword(s):  
Upper Mantle ◽  
Structural Control ◽  
Geological Mapping ◽  
Dry Valleys ◽  
Crustal Extension ◽  
Calc Alkaline ◽  
Taylor Valley ◽  
Victoria Land ◽  
Early Palaeozoic ◽  
Dyke Swarms

Detailed geological mapping and geochemical analysis of early Palaeozoic granitoid plutons and dykes from the Taylor Valley and Ferrar Glacier region in south Victoria Land reveal two distinct suites. This suite subdivision-approach is a departure from previous lithology-based schemes and can be applied elsewhere in south Victoria Land. The older calc-alkaline Dry Valleys 1 suite is dominated by the compositionally variable Bonney Pluton, a flow-foliated concordant pluton with an inferred length of over 100 km. Plutons of this suite are elongate in a NW-SE direction and appear to have been subjected to major structural control during their emplacement. The younger alkali-calcic Dry Valleys 2 suite comprises discordant plutons and numerous dyke swarms with complex age relationships. Field characteristics of this suite indicate that it was passively emplaced into fractures at higher levels in the crust than the Dry Valleys 1 suite. Whole-rock geochemistry confirms this suite subdivision based on field relationships and indicates that the two suites were derived from different parent magmas by fractional crystallization. The Dry Valleys 1 suite resembles Cordilleran I-type granitoids and is inferred to be derived from partial melting of the upper mantle and/or lower crust above an ancient subduction zone. The Dry Valleys 2 suite resembles Caledonian I-type granitoids and may have resulted from a later episode of crustal extension.

scholarly journals Microbially induced calcite precipitation using Bacillus velezensis with guar gum

2019 ◽  
Author(s):  
Rashmi Dikshit ◽  
Animesh Jain ◽  
Arjun Dey ◽  
Sujit Kamilya ◽  
Abhishake Mondal ◽  
...  
Keyword(s):  
Calcium Carbonate ◽  
Guar Gum ◽  
Microstructural Analysis ◽  
16S Rrna Gene Sequencing ◽  
Rrna Gene ◽  
Bacterial Strains ◽  
Bacillus Velezensis ◽  
Calcite Precipitation ◽  
Ph Profile ◽  
Microbially Induced Calcite Precipitation

AbstractThe present study was performed to explore the efficiency of microbially induced calcite precipitation (MICP) via locally isolated bacterial strains. Strains were isolated from soil and were screened for urease activity as well as microbial precipitation. Among all screened isolates, a carbonate precipitating soil bacterium was subjected for 16S rRNA gene sequencing. This strain was identified as Bacillus velezensis. The MICP characteristics of this strain were explored under three different media compositions and significant amount of precipitation in all cases was observed. Highest amount of precipitation was seen with guar as a biopolymer additive medium under experimented conditions. Activity of isolated strain with reference to pH profile, and ammonia concentration and total reducing sugar was further explored under media supplemented with four concentrations of guar (0.25%, 0.5%, 0.75% and 1% w/v). Microstructural analysis of microbial precipitation was performed with the help of scanning electron microscopy (SEM) and X-ray powder diffraction (XRD) analysis, which confirmed the presence of calcium carbonate in different phases. The strain was subjected to bio-cementation and locally available sand was successfully consolidated. XRD results confirmed the presence of calcium carbonate on consolidated samples.

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