The Effect of Corn Stalk Microcrystalline Cellulose on Thermal and Mechanical Properties of Chitosan Composites

2012 ◽  
Vol 174-177 ◽  
pp. 1038-1041 ◽  
Author(s):  
Chun Guang Li ◽  
Xiang Ping Wang ◽  
Lei Liu ◽  
Jie Hu Cui ◽  
Rui Zhang
Keyword(s):  
Thermal Properties ◽  
Tensile Properties ◽  
Microcrystalline Cellulose ◽  
Loss Rate ◽  
Composite Films ◽  
Corn Stalk ◽  
Weight Loss Rate ◽  
Elongation At Break ◽  
Biodegradable Composite ◽  
Maximum Weight Loss

The biodegradable composite films were prepared from corn stalk microcrystalline cellulose as filler and chitosan as polymeric matrix. The crystallinity, the tensile properties and the thermal properties of the composites were tested. The results show that the tensile properties and thermal properties were improved with the addition of corn stalk microcrystalline cellulose. When corn stalk microcrystalline cellulose account for 10% of the chitosan quality, the initial decomposition and maximum weight loss rate temperature was raised by 13.19°C and 38.84°C, tensile strength increased by 83.55% and elongation at break increased by 77.38% compared to those of pure chitosan

Thermal and Mechanical Properties of Corn Stalk Microcrystalline Cellulose Reinforced PLA Composites

2011 ◽  
Vol 233-235 ◽  
pp. 1726-1729
Author(s):  
Chun Guang Li ◽  
Rui Zhang ◽  
Yun Xia Li ◽  
Peng Fei Xu ◽  
Yan Qiu Wang
Keyword(s):  
Thermal Properties ◽  
Tensile Properties ◽  
Microcrystalline Cellulose ◽  
Composite Films ◽  
Decomposition Temperature ◽  
Corn Stalk ◽  
Thermal And Mechanical Properties ◽  
Initial Decomposition Temperature ◽  
Elongation At Break ◽  
Biodegradable Composite

The biodegradable composite films were prepared from corn stalk microcrystalline cellulose as filler and polylactic acid (PLA) as polymeric matrix. The crystallinity, the tensile properties and the thermal properties of the composites were tested. The results show that the tensile properties and thermal properties were improved with the addition of corn stalk microcrystalline cellulose. When corn stalk microcrystalline cellulose account for 10% of the PLA quality, the initial decomposition temperature was raised by 34.38, tensile strength increased by 58.3% and elongation at break increased by 31.1% compared to those of pure PLA.

Preparation and Properties of Bagasses Cellulose Microcrystal Reinforced Poly(Vinyl alcohol) Composite Film

2011 ◽  
Vol 399-401 ◽  
pp. 381-384
Author(s):  
Chun Guang Li ◽  
Bin Guo Zheng ◽  
Wei Gong Peng ◽  
Wei Tian ◽  
Rui Zhang
Keyword(s):  
Thermal Properties ◽  
Composite Film ◽  
Tensile Properties ◽  
Microcrystalline Cellulose ◽  
Vinyl Alcohol ◽  
Composite Films ◽  
Poly Vinyl Alcohol ◽  
Elongation At Break ◽  
Biodegradable Composite ◽  
Cellulose Microcrystal

The biodegradable composite films were prepared from bagasse microcrystalline cellulose as filler and poly(vinyl alcohol)(PVA) as polymeric matrix. The crystallinity, the tensile properties and the thermal properties of the composites were tested. Bagasse microcrystalline cellulose was distributed in PVA films as the crystalline state. The results show that the tensile properties and thermal properties were improved with the addition of bagasse microcrystalline cellulose. When bagasse microcrystalline cellulose mass fraction was 5%, both temperature of initial decomposition and maximum weight loss rate of composite film were raised by 11.71°C and 36.86°C, and the tensile strength increased by 17.88%, and the elongation at break increased by 36.62% compared to those of pure PVA.

Thermal and Mechanical Properties of Bagasse Microcrystalline Cellulose Reinforced PLA Composites

2011 ◽  
Vol 284-286 ◽  
pp. 1786-1789
Author(s):  
Chun Guang Li ◽  
Wei Gong Peng ◽  
Yun Xia Li ◽  
Peng Fei Xu ◽  
Wei Tian ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Tensile Properties ◽  
Microcrystalline Cellulose ◽  
Mass Fraction ◽  
Composite Films ◽  
Decomposition Temperature ◽  
Thermal And Mechanical Properties ◽  
Initial Decomposition Temperature ◽  
Elongation At Break ◽  
Biodegradable Composite

The biodegradable composite films were prepared from bagasse microcrystalline cellulose as filler and polylactic acid (PLA) as polymeric matrix. The crystallinity, the tensile properties and the thermal properties of the composites were tested. The results show that the tensile properties and thermal properties were improved with the addition of bagasse microcrystalline cellulose. When bagasse microcrystalline cellulose mass fraction was 5%, the initial decomposition temperature was raised by 30.73°C, and the tensile strength increased by 50.98%, and the elongation at break increased by 16.25% compared to those of pure PLA.

Preparation and Properties of Corn Stalk Cellulose Microcrystal Reinforced Poly(Vinyl Alcohol) Composite Film

2012 ◽  
Vol 487 ◽  
pp. 781-784
Author(s):  
Chun Guang Li ◽  
Chun Li Li ◽  
Jie Hu Cui ◽  
Lei Liu ◽  
Rui Zhang
Keyword(s):  
Thermal Properties ◽  
Composite Film ◽  
Tensile Properties ◽  
Microcrystalline Cellulose ◽  
Vinyl Alcohol ◽  
Composite Films ◽  
Poly Vinyl Alcohol ◽  
Corn Stalk ◽  
Biodegradable Composite ◽  
Cellulose Microcrystal

The biodegradable composite films were prepared from corn stalk microcrystalline cellulose as filler and poly(vinyl alcohol)(PVA) as polymeric matrix. The crystallinity, the tensile properties and the thermal properties of the composites were tested. Corn stalk microcrystalline cellulose was distributed in PVA films as the crystalline state. The results show that the tensile properties and thermal properties were improved with the addition of corn stalk microcrystalline cellulose. When corn stalk microcrystalline cellulose mass fraction was 10%, both temperature of initial decomposition and maximum weight loss rate of composite film were raised by 19.25°C and 17.17°C, and the tensile strength increased by 37.91%, and the elongation at break increased by 58.93% compared to those of pure PVA.

Effects of Calcium Carbonate on the Thermal Properties of Acrylonitrile-Butadiene-Styrene/Calcium Carbonate Composites

2013 ◽  
Vol 834-836 ◽  
pp. 276-280
Author(s):  
Xiao Juan Bai ◽  
Ling Wang
Keyword(s):  
Thermal Properties ◽  
Calcium Carbonate ◽  
Loss Rate ◽  
Acrylonitrile Butadiene Styrene ◽  
Mixed Gas ◽  
Scanning Calorimetry ◽  
Weight Loss Rate ◽  
Thermal Stability Of ◽  
Butadiene Styrene ◽  
Maximum Weight Loss

Calcium carbonate (CaCO3) is a filler widely used in plastics. In this study, the effects of CaCO3content and size on the thermal properties of acrylonitrile-butadiene-styrene (ABS)/CaCO3composites were determined by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). TGA results in nitrogen showed that the maximum weight loss rate of the composites gradually decreased with increasing CaCO3content. TGA results in a mixed gas containing oxygen showed that CaCO3addition facilitated the degradation of ABS, and ABS degradation was completed at relatively low temperatures. The effect of nano-CaCO3on the thermal stability of the composites was similar to that of microsized CaCO3.

scholarly journals Thermogravimetric analysis of empty fruit bunch

2018 ◽  
Vol 225 ◽  
pp. 02002 ◽  
Author(s):  
Girma T. Chala ◽  
Ying P. Lim ◽  
Shaharin A. Sulaiman ◽  
Chin L. Liew
Keyword(s):  
Thermogravimetric Analysis ◽  
Heat Flow ◽  
Loss Rate ◽  
Renewable Energy Sources ◽  
Thermal Reaction ◽  
Maximum Temperature ◽  
Empty Fruit Bunch ◽  
Weight Loss Rate ◽  
Minimum Heat ◽  
Maximum Weight Loss

This paper presents the characteristics of empty fruit bunch (EFB) using thermogravimetric analysis (TGA) and shows its potential as a renewable energy sources. A set of data were collected from the thermal reaction and plotted in mass or percentage of the initial mass against either temperature or time, respectively. In the thermogravimetric analysis, mass, temperature and time were considered as base measurements and important data for derivative thermogravimetric (DTG) curve were analysed while many additional measures could be derived from these three base measurements. It was observed that heating rate of 8.5°C/min and air flow rate of 85mL/min provided a maximum weight loss rate of 0.209%/°C at the temperature of 313.5°C and the derivative weight peak of -0.1895mg/°C at 292°C. The time taken to reach the maximum temperature of 899.9°C was 46.74 minutes, and ΔT endo-up reflected minimum point of -0.2°C at 15.82 minutes and maximum ΔT endo-up of 888°C at 42 minutes. Heat flow endo-up also showed that the minimum heat flow was 15.39mW at 15.85 minutes and reaching the peak heat flow endo-up of 47.73mW at 43.27 minutes.

scholarly journals Mechanical and Thermal Properties of Poly(urethane urea) Nanocomposites Prepared with Diamine-Modified Laponite

2008 ◽  
Vol 2008 ◽  
pp. 1-9 ◽  
Author(s):  
Joe-Lahai Sormana ◽  
Santanu Chattopadhyay ◽  
J. Carson Meredith
Keyword(s):  
Tensile Strength ◽  
Thermal Properties ◽  
Tensile Properties ◽  
Particle Concentration ◽  
Chain Extender ◽  
Mechanical And Thermal Properties ◽  
Elongation At Break ◽  
Hard Domain ◽  
A Chain

Nanocomposites based on segmented poly(urethane urea) were prepared by reacting a poly(diisocyanate) with diamine-modified Laponite-RD nanoparticles that served as a chain extender. The nanocomposites were prepared at a constantNH2to NCO mole ratio of 0.95, while varying the fraction of diamine-modified Laponite relative to the free diamine chain extender. Compared to neat poly(urethane urea), all nanocomposites showed increased tensile strength and elongation at break. As Laponite loading increased, tensile properties passed through a maximum at a particle concentration of 1 mass%, at which a 300% increase in tensile strength and 40% increase in elongation at break were observed. A maximum in urea and urethane hard-domain melting endotherms was also observed at this Laponite loading. Optimal mechanical and thermal properties coincided with a minimum in the size of the inorganic Laponite phase. Nanocomposites containing diamine-modified Laponite had higher tensile strengths than those with nonreactive monoamine-modified Laponite or diamine-modified Cloisite.

Effects of Catalysts on Pyrolysis of Chlorella

2012 ◽  
Vol 433-440 ◽  
pp. 161-165
Author(s):  
Gui Ju Li ◽  
Ru Yu Zhao ◽  
Li Ping Bai
Keyword(s):  
Weight Loss ◽  
Loss Rate ◽  
Inorganic Compounds ◽  
Optimal Dosage ◽  
Maximum Weight ◽  
Weight Loss Rate ◽  
Two Factors ◽  
Catalytic Effects ◽  
Derivative Thermogravimetry ◽  
Maximum Weight Loss

Sodium compounds, Na2CO3，Na2SO4，NaCl, have been investigated with regard to their catalytic effects on chlorella pyrolysis by thermal analysis experiments. The influence of catalyst categories and dosage on chlorella pyrolysis were studied by the comparison and analysis of the TG（thermogravimetry）and DTG(derivative thermogravimetry) curves derived from tests of differential thermal balance of untreated chlorelal and chlorella mixed with three inorganic compounds of certain scale.The results show that the catalytic effect of the sodium compounds follow Na2CO3>Na2SO4>NaCl, Catalysts of Na2SO4，NaCl decreased the maximum weight loss rates while Na2CO3 increased them. And all the three additives lowered the pyrolysis temperature of chlorella，of which Na2CO3 made the highest conversion of chlorella pyrolysis. As the dosage of carbonate increased, the pyrolysis temperatures decreases and the maximum weight loss rate increases, but the conversion rate of chlorella pyrolysis decreases, considering these two factors, 5%wt is chosen as the optimal dosage of the catalysts.

scholarly journals Development of technology for producing biodegradable hybrid composites based on polyethylene, starch, and monoglycerides

2021 ◽  
Vol 15 (6) ◽  
pp. 44-55
Author(s):  
I. Yu. Vasilyev ◽  
V. V. Ananyev ◽  
V. V. Kolpakova ◽  
A. S. Sardzhveladze
Keyword(s):  
Tensile Strength ◽  
Mechanical Performance ◽  
Hybrid Composites ◽  
Composite Films ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Elongation At Break ◽  
Biodegradable Composite ◽  
Develop Technology ◽  
Distilled Monoglycerides

Objectives. This work aimed to develop technology to produce biodegradable hybrid composite (BHC) films based on low-density polyethylene (LDPE) 115030-070 and thermoplastic starches (TPS) of various origins (corn, pea, and rice), with distilled monoglycerides as the plasticizer. The properties of the produced BHC films were studied and the optimal native starch : glycerol : monoglycerides ratio is proposed.Methods. TPS and BHC films based on this material were produced from different types of native starches in laboratory extruders (Brabender and MashPlast, Russia), and the extruded melts were subjected to ultrasonic vibrations. The structure and appearance of the BHC films were studied using scanning electron microscopy and rheology. Their biodegradability was assessed by immersing them in biocompost for three months. To evaluate the mechanical performance of the BHC films produced with and without ultrasound, the changes in tensile stress and elongation at break were determined during the biodegradation process.Results. The BHC films had a homogeneous structure, except small agglomerates (non-melted starch grains), which did not reduce their quality. The films with monoglycerides had high tensile strength, which was comparable with low-density polyethylene. After removing samples of the BHC films from the biocompost, their tensile strength decreased by 20%, which shows their biodegradability.Conclusions. The produced biodegradable composite films and the technology used to produce them will be applicable for the packaging industry to reduce environmental impact.

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