Synthesis and Property of Water-Soluble Hyperbranched Polyacrylate Emulsion

2012 ◽  
Vol 262 ◽  
pp. 460-463
Author(s):  
Yang Yu ◽  
Xiu Lan Xin ◽  
Ya Na Wei ◽  
Hong Qin Liu ◽  
Shao Xiang Yang
Keyword(s):  
Hyperbranched Polymer ◽  
Low Cost ◽  
High Reactivity ◽  
Solid Content ◽  
Water Soluble ◽  
Polymerization Reaction ◽  
Linear Polymers ◽  
Low Viscosity ◽  
Smooth Film ◽  
Type Water

Hyperbranched polymer is a kind of non-linear polymers with highly branched structure and a lot of terminal groups. It has many advantages, such as high reactivity, good solubility and low viscosity. Hyperbranched polymer has become a focus in modern scientific domain. In this paper, polyester-type water-soluble hyperbranched monomer is prepared by the ring-opening polymerization reaction of maleic anhydride with polyol. Hyperbranched polyacrylate emulsion with 70-110nm was synthesized by emulsion polymerization using methyl methacrylate (MMA), butyl acrylate (BA), acrylic acid (AA) and hyperbranched polymer as comonomer. The effects of dosages and adding order of monomers, concentration of initator, type and amount of chain transfer agent on the polymerization are discussed. The as-prepared emusions were analyzed by FTIR, DSC, SEM. The solid content, particle size, stability of emulsion and morphology and water absorption of film were measured. The results showed that hyperbranched polyacrylate emulsion had low viscosity, high stability and can form very flat and smooth film. Hyperbranched polyacrylate emulsion can be widely applied in modern ink industry for its low cost,simple process and stable quality.

Synthesis, Characterization, and Application of Chalcone Derivatives as Chemosensors for Cyanide Anions

2021 ◽  
Vol 01 ◽  
Author(s):  
Ankush Gupta ◽  
Akshay Kumar ◽  
Nidhi Choudhary ◽  
Bharti Gupta ◽  
Harminder Singh ◽  
...  
Keyword(s):  
Low Cost ◽  
Condensation Reaction ◽  
High Reactivity ◽  
Water Soluble ◽  
Conjugation System ◽  
Chalcone Derivatives ◽  
Real Time Analysis ◽  
Vis Spectroscopy ◽  
Living Organisms ◽  
Interfering Ions

Research Background: The extreme toxicity of cyanide ions to living organisms encourages the researcher to develop new chemosensors for their sensitive and selective detection. Among various classes of chemosensors, chalcones are believed to be a promising candidate for designing new chemosensors for anions due to easy modification in its skeleton and conjugation system. Research Gap and Problem Statement: Despite having various medical applications and properties, the recognition ability of chalcone derivatives is not widely explored. The traditional methods known for the sensing of cyanide ions are ion chromatography or cyanide selective electrodes. However, these methods need skilled operators and are found to be expensive and time-consuming. Also, the available methods for detection of cyanide ions are not suitable for on-site monitoring and show interference from other competitive anions such as fluoride, acetate, and hydroxide ions. Hence, this encouraged us to explore the chalcone derivatives as chemical sensors that are capable of detecting the cyanide ions in presence of competitive anions such as fluoride, acetate, and hydroxide ions. Objectives of the study: The development of new chalcone analogs (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) and (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6), which are particularly important for the future development of chemosensors for the detection of cyanide ions in presence of various interfering ions such as fluoride, acetate, and hydroxide ions. Methods: The sensing behavior of chalcone derivatives (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) and (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6) have been investigated toward various anions (CN-, F-, Cl-, Br-, NO3-, SO42-, PO42-, OH-, OAc-) using UV-vis spectroscopy. Interestingly, among various anions tested, derivatives (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) and (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6) function as highly selective chemosensors for the detection of cyanide ions. Results: We have synthesized two chalcone based derivatives (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) and (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6) with simple condensation reaction for the detection of cyanide ions. The various results indicated the quick response of (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) and (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6) toward cyanide anions. These two chalcone derivatives (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) and (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6) showed not only spectral change with selectivity but also showed sensitivity for the detection of cyanide anions. The developed chalcone derivatives (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) and (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6) detect cyanide ions in presence of various interfering ions such as fluoride, acetate, and hydroxide ions. The chemosensors (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) and (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6) for the detection of cyanide ions are particularly smart due to their real-time analysis, simplicity, and low cost in comparison to other closely related processes such as fluorescence. Conclusion: The sensitivity studies show the high reactivity of derivative 1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) as compared to (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6). The detection limit for derivatives (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) and (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6) was 1.2 µM and 300 µM, respectively. The results of (1E,4E)-1,5-bis(4-chlorophenyl)penta-1,4-dien-3-one (3) and (E)-3-phenyl-1-(pyridin-2-yl)prop-2-en-1-one (6) for cyanide detection were satisfying and suggesting their potential application for cyanide detection. Future direction: Further research of this field is to develop water soluble chalcone based probes, which show emission in the Near Infra-Red (NIR) region to provide favorable conditions for biological applications.

Aqueous Degradable Polyurethane Elastomers for Oil & Gas Applications

2021 ◽  
Author(s):  
Matthew Peter Burdzy
Keyword(s):  
Mechanical Properties ◽  
Service Life ◽  
Product Life Cycle ◽  
Low Cost ◽  
High Strength ◽  
Compression Modulus ◽  
Water Soluble ◽  
Stable Set ◽  
Polyurethane Elastomers ◽  
Low Viscosity

Abstract A new class of patent pending aqueous degradable polyurethane elastomers have been developed that can be used in oil & gas exploration, drilling, completion and production where a degradable part is needed to provide a useful service life then quickly degrade when exposed to heat and water. This polyurethane technology eliminates the need for costly secondary operations such as milling, drilling or removing tools in downhole applications saving time and reducing cost. The degradable polyurethane is a low viscosity two-part heat cured elastomer that is easy to mold using low cost hot cast tooling techniques. The novel liquid polyurethane prepolymer can be formed into films, seals, sealing elements, tools, complex geometries or other aqueous degradable elastomeric components. The polymer is a tough tear resistant high strength elastomer with a tensile strength exceeding 5000 psi, elongation over 500%, and a 70% compression modulus greater than 13,000 psi. When integrated as a sealing element in a degradable hydraulic fracturing plug, the polyurethane is designed to be pumped down-hole, set and seal then degrade once the operation is complete. Once placed into service, the useful operating lifetime of this polyurethane chemistry is more than six hours when immersed in aqueous fluids at 80°C (176°F) (i.e. water or 3% potassium chloride). The elastomer can be compressed over 70% during its service-life providing a stable set of mechanical properties during use. The elastomer beings to fracture within two days and quickly degrades at 80°C (176°F) providing consistent and reliable results. Approximately 70% is completely water soluble while the remaining 30% fractures into small particles that can be easily removed or remain in the well. This paper reviews the development of the technology, applications, mechanical properties, service life, degradation profile and product life cycle.

Study on Preparation and Property of Acrylic Resins Used for Water-Based Ink

2012 ◽  
Vol 262 ◽  
pp. 491-496 ◽  
Author(s):  
Wen Tao Huang ◽  
Guang Xue Chen ◽  
Bao Ling Tang ◽  
Ming Guang Yu
Keyword(s):  
Acrylic Resin ◽  
Ammonium Persulfate ◽  
Solid Content ◽  
Water Soluble ◽  
Acrylic Emulsion ◽  
Low Viscosity ◽  
Acrylic Resins ◽  
Film Forming ◽  
Water Based ◽  
Relationship Of

In this paper, a kind of water-soluble acrylic emulsion with methyl methacrylate (MMA) and butyl acrylate (BA) as hard and soft monomer respectively, acrylic acid (AA) and hydroxypropyl methacrylate as functional monomers, ammonium persulfate (APS) and ammonia as initiator and neutralizer respectively, was prepared by emulsion polymerization. The resulting emulsion possesses high solid content, low viscosity, high stability and film-forming properties, indicating that it would be applicable to water-based ink. The effect of the ratio of MMA to BA on the film-forming properties of resin and the influence of AA and HPA on the water-soluble property and viscosity of resin were investigated, and the relationship of reaction temperature and the emulsion stability was also studied. This paper can provides a certain reference to synthesis of acrylic resin and application of acrylic resin to the water-based ink.

scholarly journals Influence of the Active Layer Structure on the Photovoltaic Performance of Water-Soluble Polythiophene-Based Solar Cells

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1640
Author(s):  
Massimiliano Lanzi ◽  
Debora Quadretti ◽  
Martina Marinelli ◽  
Yasamin Ziai ◽  
Elisabetta Salatelli ◽  
...  
Keyword(s):  
Solar Cells ◽  
Layer Structure ◽  
Photovoltaic Performance ◽  
Phase Segregation ◽  
Water Soluble ◽  
Polymerization Reaction ◽  
Fullerene Derivative ◽  
C60 Fullerene ◽  
Photovoltaic Efficiency ◽  
Single Material

A new side-chain C60-fullerene functionalized thiophene copolymer bearing tributylphosphine-substituted hexylic lateral groups was successfully synthesized by means of a fast and effective post-polymerization reaction on a regioregular ω-alkylbrominated polymeric precursor. The growth of the polymeric intermediate was followed by NMR spectrometry in order to determine the most convenient reaction time. The obtained copolymer was soluble in water and polar solvents and was used as a photoactive layer in single-material organic photovoltaic (OPV) solar cells. The copolymer photovoltaic efficiency was compared with that of an OPV cell containing a water-soluble polythiophenic homopolymer, functionalized with the same tributylphosphine-substituted hexylic side chains, in a blend with a water-soluble C60-fullerene derivative. The use of a water-soluble double-cable copolymer made it possible to enhance the control on the nanomorphology of the active blend, thus reducing phase-segregation phenomena, as well as the macroscale separation between the electron acceptor and donor components. Indeed, the power conversion efficiency of OPV cells based on a single material was higher than that obtained with the classical architecture, involving the presence of two distinct ED and EA materials (PCE: 3.11% vs. 2.29%, respectively). Moreover, the synthetic procedure adopted to obtain single material-based cells is more straightforward and easier than that used for the preparation of the homopolymer-based BHJ solar cell, thus making it possible to completely avoid the long synthetic pathway which is required to prepare water-soluble fullerene derivatives.

scholarly journals Synthesis of poly (n-butyl acrylate) with tempo by nitroxide mediated polymerization method

2021 ◽  
pp. 096739112110245
Author(s):  
Amrita Sharma ◽  
PP Pande
Keyword(s):  
Butyl Acrylate ◽  
Low Cost ◽  
Polymerization Process ◽  
Polymerization Reaction ◽  
High Concentration ◽  
Acrylate Monomer ◽  
Controlled Polymerization ◽  
Acrylate Monomers ◽  
Nitroxide Mediated Polymerization ◽  
Polymerization Method

It has been observed that acrylate monomers are very difficult to polymerize with the low cost nitroxide catalyst 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO). Therefore, costly acyclic nitroxides such as N-tert-butyl-N-(1-diethylphosphono-2,2-dimethyl)-N-oxyl, (SG1), 2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide (TIPNO) and TIPNO derivatives have to be used for the polymerization of the acrylic acid derivatives. There are very few reports on the use of TEMPO-derivatives toward the polymerization of n-butyl acrylate. Generally different reducing agents viz. glucose, ascorbic acid, hydroxyacetone etc. have been used to destroy excess TEMPO during the polymerization reaction. The acrylate polymerizations fail in the presence of TEMPO due to the strong C–O bond formed between the acrylate chain end and nitroxide. To the best of our knowledge, no literature report is available on the use of TEMPO without reducing agent or high temperature initiators, toward the polymerization of n-butyl acrylate. The present study has been carried out with a view to re-examine the application of low cost nitroxide TEMPO, so that it can be utilized towards the polymerization of acrylate monomers (e.g. n-butyl acrylate). We have been able to polymerize n-butyl acrylate using the nitroxide TEMPO as initiator (via a macroinitiator). In this synthesis, a polystyrene macroinitiator was synthesized in the first step from TEMPO, after this TEMPO end-capped styrene macroinitiator (PSt-TEMPO) is used to polymerize n-butyl acrylate monomer. The amount of macroinitiator taken was varied from 0.05% to 50% by weight of n-butyl acrylate monomer. The polymerization was carried out at 120°C by bulk polymerization method. The experimental findings showed a gradual increase in molecular weight of the polymer formed and decrease in the polydispersity index (PDI) with increase in amount of PSt-TEMPO macroinitiator taken. In all experiments conversion was more than 80%. These results indicate that the polymerization takes place through controlled polymerization process. Effect of different solvents on polymerization has also been investigated. In the following experiments TEMPO capped styrene has been used as macroinitiator leading to the successful synthesis of poly n-Butyl acrylate. It has been found that styrene macroinitiator is highly efficient for the nitroxide mediated polymerization, even in very small concentration for the synthesis of poly n-butyl acrylate. High concentration of macroinitiator results in the formation of block copolymers of polystyrene and poly ( n-butyl acrylate) viz. polystyrene-block-poly-( n-butyl acrylate). The use of TEMPO toward controlled polymerization is of much importance, because it is the nitroxide commercially available at the lowest cost.

scholarly journals Redox initiation in semicontinuous polymerization to search for specific mechanical properties of copolymers

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 613-623
Author(s):  
José Manuel Sandoval-Díaz ◽  
Francisco Javier Rivera-Gálvez ◽  
Marta Fernández-García ◽  
Carlos Federico Jasso-Gastinel
Keyword(s):  
Low Cost ◽  
Mechanical Analysis ◽  
Industrial Applications ◽  
Size Exclusion ◽  
Proton Nuclear Magnetic Resonance ◽  
Polymerization Reaction ◽  
Redox Initiation ◽  
Initiation System ◽  
Feeding Profile ◽  
Chain Composition

AbstractIn this work, for a semicontinuous emulsion polymerization reaction, it is shown that using a redox initiation system at 40°C, substantial modifications in copolymer chain composition with conversion can be easily obtained. To test controllable trajectories for comonomer feeding, linear and parabolic profiles were chosen to get different types of chain composition variations for the 50/50 w/w styrene/n-butyl acrylate system. For the “forced composition copolymers,” the molecular weight averages and distribution were obtained by size exclusion chromatography. The composition along conversion was followed by proton nuclear magnetic resonance to determine the weight composition distribution (WCD) of the copolymer chains. Mechanodynamic (dynamic-mechanical analysis), tensile, and hardness tests exhibited consistent results depending on the WCD that outcomes from the respective feeding profile. The results confirm that this methodology is of great potential for industrial applications when looking for synergy in copolymer properties, and low-cost processes.

scholarly journals Effects of corn steep liquor on β-poly(l-malic acid) production in Aureobasidium melanogenum

AMB Express ◽  
2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Genan Wang ◽  
Bingyi Shi ◽  
Pan Zhang ◽  
Tingbin Zhao ◽  
Haisong Yin ◽  
...  
Keyword(s):  
Malic Acid ◽  
Low Cost ◽  
Corn Steep Liquor ◽  
Enrichment Analysis ◽  
Tca Cycle ◽  
Water Soluble ◽  
Growth And Yield ◽  
The Tca Cycle ◽  
Steep Liquor ◽  
Aureobasidium Melanogenum

Abstractβ-poly(l-malic acid) (PMLA) is a water-soluble biopolymer used in medicine, food, and other industries. However, the low level of PMLA biosynthesis in microorganisms limits its further application in the biotechnological industry. In this study, corn steep liquor (CSL), which processes high nutritional value and low-cost characteristics, was selected as a growth factor to increase the PMLA production in strain, Aureobasidium melanogenum, and its metabolomics change under the CSL addition was investigated. The results indicated that, with 3 g/L CSL, PMLA production, cell growth, and yield (Yp/x) were increased by 32.76%, 41.82%, and 47.43%, respectively. The intracellular metabolites of A. melanogenum, such as amino acids, organic acids, and key intermediates in the TCA cycle, increased after the addition of CSL, and the enrichment analysis showed that tyrosine may play a major role in the PMLA biosynthesis. The results presented in this study demonstrated that the addition of CSL would be an efficient approach to improve PMLA production.

Fluorescence turn-on detection of cyanide anion based on viologen-quenched water-soluble hyperbranched polymer

Polymer ◽  
2013 ◽  
Vol 54 (4) ◽  
pp. 1323-1328 ◽  
Author(s):  
Seongwon Seo ◽  
Daigeun Kim ◽  
Geunseok Jang ◽  
Jongho Kim ◽  
Taek Seung Lee
Keyword(s):  
Hyperbranched Polymer ◽  
Water Soluble ◽  
Cyanide Anion ◽  
Turn On ◽  
Fluorescence Turn On

New Gel Aggregates To Improve Sweep Efficiency During Waterflooding

2011 ◽  
Vol 14 (01) ◽  
pp. 120-128 ◽  
Author(s):  
Guanglun Lei ◽  
Lingling Li ◽  
Hisham A. Nasr-El-Din
Keyword(s):  
Low Cost ◽  
Oil Production ◽  
High Water ◽  
Resistance Factor ◽  
Water Production ◽  
Sweep Efficiency ◽  
Low Viscosity ◽  
Productivity Decline ◽  
High Water Cut ◽  
Water Cut

Summary A common problem for oil production is excessive water production, which can lead to rapid productivity decline and significant increases in operating costs. The result is often a premature shut-in of wells because production has become uneconomical. In water injectors, the injection profiles are uneven and, as a result, large amounts of oil are left behind the water front. Many chemical systems have been used to control water production and improve recovery from reservoirs with high water cut. Inorganic gels have low viscosity and can be pumped using typical field mixing and injection equipment. Polymer or crosslinked gels, especially polyacrylamide-based systems, are mainly used because of their relatively low cost and their supposed selectivity. In this paper, microspheres (5–30 μm) were synthesized using acrylamide monomers crosslinked with an organic crosslinker. They can be suspended in water and can be pumped in sandstone formations. They can plug some of the pore throats and, thus, force injected water to change its direction and increase the sweep efficiency. A high-pressure/high-temperature (HP/HT) rheometer was used to measure G (elastic modulus) and G" (viscous modulus) of these aggregates. Experimental results indicate that these microspheres are stable in solutions with 20,000 ppm NaCl at 175°F. They can expand up to five times their original size in deionized water and show good elasticity. The results of sandpack tests show that the microspheres can flow through cores with permeability greater than 500 md and can increase the resistance factor by eight to 25 times and the residual resistance factor by nine times. The addition of microspheres to polymer solutions increased the resistance factor beyond that obtained with the polymer solution alone. Field data using microspheres showed significant improvements in the injection profile and enhancements in oil production.

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