Preparation of Bromine Carbon Alkyd Resin Retardant Coatings for Steel Structure

2013 ◽  
Vol 275-277 ◽  
pp. 1921-1924
Author(s):  
Jin Feng Cui ◽  
Bi Bi Chen ◽  
Jun Hong Guo ◽  
Ying Ping Zhou ◽  
Bao Ping Yang
Keyword(s):  
Infrared Spectroscopy ◽  
Alkyd Resin ◽  
Impact Resistance ◽  
Steel Structure ◽  
Adhesive Force ◽  
Esterification Reaction ◽  
Drying Time ◽  
Soya Oil ◽  
Brominated Epoxy Resin ◽  
Optimal Formula

Bromine carbon alkyd resin was synthesized with soya oil acid, pentaerythritol, phthalic anhydride and brominated epoxy resin as materials under the condition which reaction temperature for 200 °C, usage of catalyst was 0.1% and period of esterification reaction lasted 3 h. And then bromine carbon alkyd resin retardant coatings for steel structure was prepared using bromine carbon alkyd resin as binder which compounded with flame retardant additives through stirred, grinded and dispersed homogeneously. Resin and coatings were analyzed by infrared spectroscopy and TG-DSC. The optimal formula of bromine carbon alkyd resin retardant coatings for steel structure was achieved through testing impact resistance, adhesive force, hardness, gloss, drying time and fire resistance time of film.

scholarly journals Modification of Alkyd with Epoxy and its Application for Paint Part 1: Epoxy Alkyd Ester Manufacturing and some Properties of Paint made from this Ester

2020 ◽  
Vol 36 (1) ◽  
Author(s):  
Nguyen Trung Thanh
Keyword(s):  
Mechanical Properties ◽  
Paint Film ◽  
Impact Resistance ◽  
Esterification Reaction ◽  
Paint Sample ◽  
Drying Time ◽  
Alkyd Paint ◽  
Acidity Index ◽  
Reaction Processing ◽  
Thermal Stability Of

The article introduces the modification of alkyd resin by epoxy resin to make epoxy alkyd ester. The study investigated the effects of reflux xylene content, the proportion of the constituents participating in the esterification reaction on the reaction processing and acidity index of the product. The infrared (IR) spectroscopy results confirmed the formation of ester bonds after the reaction. The paper also studied the mechanical properties of paint film based on the synthesized ester epoxy alkyd and compared them with the alkyd paint, the results showed that impact resistance and hardness of the study sample were higher than those of the alkyd paint sample. In addition, investigation, comparison of thermal stability of alkyd paint and epoxy alkyd paint film were also mentioned. Keywords: Epoxy alkyd esters, mechanical properties, thermal endurance, drying time.

scholarly journals Forensic Examination of Inks Extracted from Printed Documents using Fourier Transform Infrared Spectroscopy

2018 ◽  
pp. 10-17
Author(s):  
Paul Ocheje Ameh ◽  
Musa Suud Ozovehe
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Fourier Transform Infrared Spectroscopy ◽  
Alkyd Resin ◽  
Epoxy Resins ◽  
Ftir Spectra ◽  
Absorption Bands ◽  
Triarylmethane Dyes ◽  
Infra Red ◽  
Aliphatic Ester

Yellow, cyan, magenta and black inks were extracted from documents printed using two common brands of printing cartridge in Nigerian market and analyzed to identify / compare the functional groups present using Fourier Transform Infra-red Spectroscopy (FTIR). The FTIR spectra obtained were found to show highly characteristic absorption bands depending on the composition of the printer inks. Also, the results indicated the presence of triarylmethane dyes, epoxy resins, alkyd resin and esters in all the inks as they are peaks assigned to the vibration of aliphatic ester, asymmetrical and symmetrical stretching. The pure ink and its extract from the same band were also found to exhibit similar FTIR spectra while inks extract from different brands exhibits marked difference in absorption bands. This research can provide valuable information if an admitted sample is provided for comparing with the suspect printed document.

scholarly journals Manufacture and Characteristics of Oil-Modified Refined Lacquer for Wood Coatings

2018 ◽  
Author(s):  
Chia-Wei Chang ◽  
Hsiu-Ling Lee ◽  
Kun-Tsung Lu
Keyword(s):  
Linseed Oil ◽  
Impact Resistance ◽  
Polymeric Coating ◽  
Drying Time ◽  
Nitrogenous Compounds ◽  
Drying Oils ◽  
Drying Oil ◽  
Wood Coatings ◽  
Speed Up ◽  
Oriental Lacquer

Oriental lacquer, a natural and renewable polymeric coating, comes from the sap produced by lacquer trees. For practical application, oriental lacquer must be refined to reduce excess water and enhance its quality. In this study, drying oils were blended with oriental lacquer during the refining process to prepare an oil-modified refined lacquer (OMRL). The type and adding amount (0, 10, and 20% by wt.) of drying oils for wood coatings utilization were evaluated. Rhus succedanea oriental lacquer is composed of 54.1% urushiols, 34.3% water, 7.2% plant gum, and 4.4% nitrogenous compounds, and drying oils, including tung oil (TO), linseed oil (LO), and dehydrated castor oil (DCO) were used as materials in this study. The results show that the drying oil acts as a diluent, which reduces the viscosity and enhances the workability and could shorten the touch-free drying time and speed up the hardened drying of the OMRL. The results also indicate that the hardness, mass retention, Tg, tensile strength, abrasion resistance, and lightfastness of OMRL films decrease as more drying oils are blended. Conversely, the bending resistance, elongation at break, impact resistance increase, and particularly, the gloss, is greatly improved through the blending of more drying oils. In conclusion, the LO-modified refined lacquer (RL) has the highest film gloss and the DCO-modified RL has the shortest drying time for coating; otherwise, the film properties are similar among the three types of drying oil.

scholarly journals Preparation and Characterization of Low Infrared Emissive Aluminum/Waterborne Acrylic Coatings

Coatings ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 35 ◽  
Author(s):  
Xiaoxing Yan ◽  
Lin Wang ◽  
Xingyu Qian
Keyword(s):  
Corrosion Resistance ◽  
Impact Resistance ◽  
Infrared Emissivity ◽  
Drying Time ◽  
Powder Concentration ◽  
Orthogonal Experiments ◽  
Adhesion Level ◽  
Small Change ◽  
Silica Slurry ◽  
The Impact

An aluminum/waterborne acrylic coating was developed by orthogonal experiments, and the gloss, emissivity, chromatic distortion, hardness, adhesion, impact resistance, and corrosion resistance of the coatings were examined. The results showed that the effect of drying time on the infrared emissivity of coatings was more significant than that of the Al powder concentration and nano-silica slurry. When the drying time was prolonged from 0.5 to 6.0 min, the gloss of the coating decreased slowly and the gloss remained low. The infrared emissivity first decreased and then increased. The infrared emissivity of coatings dried for 2.0 min was better. The L’ value gradually decreased and showed a small change of range. With the increasing of the drying time, the hardness of the coating gradually decreased and was the highest at 0.5–2.0 min. The drying time had no effect on the adhesion level. The impact resistance of the coating was better during the drying period of 1.0–3.0 min. The corrosion resistance of the coating was better at 2.0 min. When the drying time was 2.0 min, the waterborne coating showed the better comprehensive performance. This study provides new prospects in using low infrared emissive coatings for infrared stealth and compatibility with visible light.

scholarly journals Identification of Coatings on Persian Lacquer Papier Mache Penboxes by Fourier Transform Infrared Spectroscopy and Luminescence Imaging

Heritage ◽  
2021 ◽  
Vol 4 (3) ◽  
pp. 1962-1970
Author(s):  
Alireza Koochakzaei ◽  
Ali Nemati Babaylou ◽  
Behrooz Jelodarian Bidgoli
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Fourier Transform Infrared Spectroscopy ◽  
Alkyd Resin ◽  
Fourier Transform Infrared ◽  
Organic Coatings ◽  
Luminescence Imaging ◽  
Combined Use ◽  
Historical Objects ◽  
Spectral Ranges

In this study, Fourier transform infrared spectroscopy (FTIR) and luminescence imaging were used to identify the coatings of seven Persian lacquer papier mache penboxes, of which two were contemporary, one was from the Pahlavi era, and four belonged to the Qajar era. First, FTIR was used to identify the nature of the coating. Then, visible-induced luminescence imaging at the spectral ranges of 420–680 nm (UVL), 425–495 nm (UVIBL), and 615–645 nm (UVIRL) was performed for further examination. The FTIR results showed that the coatings were made of alkyd resin, oil-resin varnish (Kaman oil), and shellac. In visible-induced luminescence images, synthetic alkyd resin showed no fluorescence, which made it distinguishable from the natural organic coatings. While it is slightly challenging to differentiate Kaman oil from shellac based on FTIR results, these two coatings can be easily distinguished by their fluorescence in UVL and UVIBL images. The results suggest that the combined use of spectroscopy and spectral imaging methods can provide substantial information about the organic coatings of historical objects.

scholarly journals Synthesis and Improvement of Activity of Cobalt Organic Salts as Drier

2013 ◽  
Vol 2013 ◽  
pp. 1-4
Author(s):  
Nader Zabarjad Shiraz ◽  
Bahram Letafat ◽  
Elaheh Sadat Sharifzadeh ◽  
Anahita Rabii
Keyword(s):  
Alkyd Resin ◽  
Environmental Aspects ◽  
Organic Salts ◽  
Drying Time ◽  
Ethyl Methyl ◽  
Precipitation Processes ◽  
Methods Of Synthesis

Organic salts of cobalt were synthesized in the presence of amine, ethanol, and ethyl methyl ketoxime and were used as drier for alkyd resin. Considering the drying time of alkyd resin containing synthesized compound showed that amines, as electron releasing groups (ERG), increased the oxidizing activity of drier and shortened drying time about an hour, whereas ethyl methyl ketoxime delayed the drying of resin 2 hours. Two methods of synthesis, including solution and precipitation processes of synthesis, were compared in terms of convenience, cost, and environmental aspects.

Synthesis and Properties of a Castor Oil-Based UV-Oligomer Comprising of Side-Chain Benzophenone

2013 ◽  
Vol 690-693 ◽  
pp. 1628-1631
Author(s):  
Chang Qing Fu ◽  
Zheng Yang ◽  
Zong Xiang Lu ◽  
Liang Shen
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Magnetic Resonance ◽  
Castor Oil ◽  
Side Chain ◽  
Esterification Reaction ◽  
Trimethylolpropane Triacrylate ◽  
Ft Ir ◽  
Diisopropyl Carbodiimide

A castor oil-based UV-oligomer bearing benzophenone side chains (LU-5)was synthesis through two-step partial esterification reaction of polyacrylic acid with 4-hydroxy benzophenone and castor oil in the presence of N, N-diisopropyl carbodiimide and 4-(dimethylamino) pyridinium 4-toluenesulfonate(DPTS), then LU-5 was cured by UV irradiation with trimethylolpropane triacrylate(TMPTA) without any photoinitiator. The structure of the productions of the esterification reaction was characterized by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance(NMR) and ultraviolet and visible spectrophotometer (UV-Vis), and the properties of UV cured polymer(FUV) has been studied. The results show that LU-5 has a certain light initiator activity, and it can be used as a macromolecular photoinitiator, the film of polymer has a certain degree of crosslinking.

scholarly journals Forensic Examination of Inks Extracted from Printed Documents using Fourier Transform Infrared Spectroscopy

2018 ◽  
pp. 10-17
Author(s):  
Paul Ocheje Ameh ◽  
Musa Suud Ozovehe
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Fourier Transform Infrared Spectroscopy ◽  
Alkyd Resin ◽  
Epoxy Resins ◽  
Ftir Spectra ◽  
Absorption Bands ◽  
Triarylmethane Dyes ◽  
Infra Red ◽  
Aliphatic Ester

Yellow, cyan, magenta and black inks were extracted from documents printed using two common brands of printing cartridge in Nigerian market and analyzed to identify/compare the functional groups present using Fourier Transform Infra-red Spectroscopy (FTIR). The FTIR spectra obtained were found to show highly characteristic absorption bands depending on the composition of the printer inks. Also, the results indicated the presence of triarylmethane dyes, epoxy resins, alkyd resin and esters in all the inks as they are peaks assigned to the vibration of aliphatic ester, asymmetrical and symmetrical stretching. The pure ink and its extract from the same band were also found to exhibit similar FTIR spectra while inks extract from different brands exhibits marked difference in absorption bands. This research can provide valuable information if an admitted sample is provided for comparing with the suspect printed document.

Influence of a Catalyst in Obtaining a Post-Consumer Pet-Based Alkyd Resin That Meets Circular Economy Principles

2021 ◽  
Author(s):  
Elaine Meireles Senra ◽  
Antônio E. F. A. da Silva ◽  
Leila Lea Yuan Visconte ◽  
Elen Beatriz Acordi Vasques Pacheco
Keyword(s):  
Reaction Time ◽  
Alkyd Resin ◽  
Circular Economy ◽  
Raw Materials ◽  
Lithium Hydroxide ◽  
Esterification Reaction ◽  
Alcoholysis Reaction ◽  
Renewable Material ◽  
Two Phases ◽  
Soybean Oil Alcoholysis

Abstract The paper studied the influence of a catalyst, comparing it with its traditional counterparts, in the process of obtaining a polyethylene terephthalate (PET)-based alkyd resin from post-consumer beverage bottles and how it consumes raw materials and generates waste. The resin was obtained in two phases: 1) glycerol and soybean oil alcoholysis reaction, a renewable material, for polyalcohol production, and 2) polyalcohol and polyacid esterification reaction to obtain the alkyd resin (reaction via solvent). A lithium octoate catalyst (OctLi) was used, not traditional in the alcoholysis reaction, and a fraction of the polyacid replaced by post-consumer PET at a proportion of up to 24% by weight in the esterification reaction. The OctLi catalyst caused a reaction in 30 min, compared to zinc acetate (120 min) and lithium hydroxide (LiOH, 60 min). Using post-consumer PET in obtaining the alkyd resin also decreased the esterification reaction time by 22% (8% PET), 67% (16% PET) and 72% (24% PET), compared to esterification without PET. The reaction time, considering alcoholysis with OctLi and partial esterification with PET (with 24% PET), was 180 min. Adding alcoholysis time with the LiOH catalyst and esterification without PET raises the reaction time to 600 min. Process water formed during the esterification stage declined by 15% (8% PET), 50% (16% PET) and 77% (24% PET), compared to the reaction without PET. The shorter reaction time resulted in less equipment use and consequent lower energy consumption. Another result was that the alkyd resin obtained with 8% PET was adequate for paint formulations.

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