Effect of Solid to Liquid Ratio on the Mechanical and Physical Properties of Fly Ash Geopolymer without Sodium Silicate

2014 ◽  
Vol 625 ◽  
pp. 46-49 ◽  
Author(s):  
Rosniza Hanim Abdul Rahim ◽  
Khairun Azizi Azizli ◽  
Zakaria Man ◽  
Tia Rahmiati ◽  
Lukman Ismail

Geopolymer is produced from the alkali activation of materials rich in Si and Al with addition of silicate solution in order to improve the mechanical property. Limited research has been done with the absence of silicate solution in the geopolymerization process by varying solid/liquid ratio and on how it works for that condition on mechanical and physical properties. This paper presents an investigation on the mechanical and physical properties of fly ash based geopolymer by varying solid to liquid ratio using sodium hydroxide as the only activator. In addition, the strength development also been investigated. The samples were prepared using 50mm x 50mm x 50mm mould and cured at an elevated temperature (60oC). It can be observed that the optimum compressive strength and density were obtained at solid/ liquid ratio of 4. In addition, the compressive strength of fly ash based geopolymer for all the solid to liquid ratio increased until 14 days and started to decrease later.

2014 ◽  
Vol 803 ◽  
pp. 120-124 ◽  
Author(s):  
Tia Rahmiati ◽  
Khairun Azizi Azizli ◽  
Zakaria Man ◽  
Lukman Ismail ◽  
Mohd Fadhil Nuruddin

Geopolymer is produced from the alkali activation of materials rich in Si and Al such as fly ash. Based on the experimental and characterization result, solid to liquid ratio influenced the setting time and compressive strength of geopolymer in order to have good mechanical property. The optimum setting time and compressive strength were obtained at 3 : 1 solid to liquid ratio. Optimum curing time reach at 14 days.


2017 ◽  
Vol 744 ◽  
pp. 131-135 ◽  
Author(s):  
Muhammad Zahid ◽  
Nasir Shafiq ◽  
Mohd Fadhil Nuruddin ◽  
Ehsan Nikbakht ◽  
Asif Jalal

This article aims to investigate the compressive strength variation by the addition of metakaolin as a substitute of fly ash in the fly ash based geopolymer mortar. Five, ten and fifteen percent by weight of fly ash was replaced by highly reactive metakaolin. Two type of fly ashes namely, ASTM class F and ASTM class C were used as a base material for the synthesis of geopolymer mortar. Eight molar sodium hydroxide solution mixed with sodium silicate solution was used as alkaline activator. For optimum geopolymerization, mortar was cured at sixty degree Celsius for twenty four hours duration. Results show different behavior of metakaolin replacement on compressive strength for two different types of fly ash based geopolymer mortar. Improvement in compressive strength was seen by addition of metakaolin in ASTM class F fly ash based geopolymer. On the other hand compressive strength was decreased abruptly in fly ash class C based geopolymer up to certain replacement level.


2021 ◽  
Vol 2021 ◽  
pp. 1-17
Author(s):  
Shaise K. John ◽  
Alessio Cascardi ◽  
Yashida Nadir ◽  
Maria Antonietta Aiello ◽  
K. Girija

Geopolymers are inorganic polymers produced by the alkali activation of alumina-silicate minerals. Geopolymer is an alternative cementitious binder to traditional Ordinary Portland Cement (OPC) leading to economical and sustainable construction technique by the utilisation of alumina-silicate waste materials. The strength development in fly ash-slag geopolymer mortar is dependent on the chemical composition of the raw materials. An effective way to study the effect of chemical components in geopolymer is through the evaluation of molar ratios. In this study, an Artificial Neural Network (ANN) model has been applied to predict the effect of molar ratios on the 28-day compressive strength of fly ash-slag geopolymer mortar. For this purpose, geopolymer mortar samples were prepared with different fly ash-slag composition, activator concentration, and alkaline solution ratios. The molar ratios of the geopolymer mortar samples were evaluated and given as input to ANN, and the compressive strength was obtained as the output. The accuracy of the assessed model was investigated by statistical parameters; the mean, median, and mode values of the ratio between actual and predicted strength are equal to 0.991, 0.973, and 0.991, respectively, with a 14% coefficient of variation and a correlation coefficient of 89%. Based on the mentioned findings, the proposed novel model seems reliable enough and could be used for the prediction of compressive strength of fly ash-slag geopolymer. In addition, the influence of molar compositions on the compressive strength was further investigated through parametric studies utilizing the proposed model. The percentages of Na2O and SiO2 of the source materials were observed as the dominant chemical compounds in the mix affecting the compressive strength. The influence of CaO was significant when combined with a high amount of SiO2 in alkaline solution.


Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1394 ◽  
Author(s):  
Agus Maryoto ◽  
Buntara Sthenly Gan ◽  
Nor Intang Setyo Hermanto ◽  
Rachmad Setijadi

This work aims to study the effect of Ca(C18H35O2)2 (calcium stearate) on the properties of concrete by using Portland composite cement (PCC) and fly ash as binders. The calcium stearate content used in the concrete here consists of 0, 1, 5, and 10 kg per m3 of concrete volume, or alternatively, 0 to 2.85% by the weight of cement. We have performed several tests for each of the contents, namely, compressive strength, water absorption, chloride ion infiltration, and accelerated corrosion tests. According to the testing, we have found that with the addition of calcium stearate at 1 kg/m3 in self-compacting concrete (SCC) with 10% fly ash, the mechanical and physical properties of SCC can be improved significantly when compared to the SCC without fly ash and calcium stearate, resulting in a stable compressive strength, lower water absorption, lower chloride ion infiltration, and lower degree of corrosion attack.


2018 ◽  
Vol 2 (1) ◽  
pp. 26
Author(s):  
Ufafa Anggarini

The optimization synthezised of geopolymer based on fly ash materials have been done by using Taguchi method. The experimental design was done with 4 factors and 3 levels, that were the influence of Si/Al ratio, solid/liquid ratio, NaOH and the type of aggregate. Geopolymers were synthesized by sol gel method at room temperature, using fly ash as aluminasilica source and alkaline activator solutions thain consist of NaOH and Na2SiO3. The influence of Si/Al ratio studied at level of 4.00, 4.25, 4,50, solid/liquid ratio at level of 1.50, 2.33, 4.00. NaOH (%wt/%v) of 0.24, 0.40, 0.56, and the type of aggregate of Malang sand, Bojonegoro sand and granite. Based on SNR analysis and the characterization determination of higher is better, the geopolymer optimum composition was Si/Al factor at level of 3 (4.50), solid/liquid ratio level at 2 (2.33), NaOH level at 1 (0.24) and type of aggregate level at 3 (granite). The calculation of compressive strength prediction was determined at 21.01 Mpa, while the optimum compressive strength of the experimental result was found at 21 Mpa. Keywords: Geopolymer, Taguchi Method, Si/Al, Solid/Liquid, NaOH, Type of agreggate


2018 ◽  
Vol 5 (14) ◽  
pp. 27441-27445
Author(s):  
N. Nikoloutsopoulos ◽  
A. Sotiropoulou ◽  
G. Kakali ◽  
S. Tsivilis

2013 ◽  
Vol 78 (6) ◽  
pp. 851-863 ◽  
Author(s):  
Irena Nikolic ◽  
Dijana Djurovic ◽  
Radomir Zejak ◽  
Ljiljana Karanovic ◽  
Milena Tadic ◽  
...  

The process of geopolymerization involves the reaction of solid aluminosilicate materials with highly alkaline silicate solution yielding an aluminosilicate inorganic polymer named geopolymer, which may be successfully applied in civil engineering as a replacement for cement. In this paper we have investigated the influence of synthesis parameters: solid to liquid ratio, NaOH concentration and the ratio of Na2SiO3/NaOH, on the mechanical properties and hydrolytic stability of fly ash based geopolymers in distilled water, sea water and simulated acid rain. The highest value of compressive strength was obtained using 10 mol dm-3 NaOH and at the Na2SiO3/NaOH ratio of 1.5. Moreover, the results have shown that mechanical properties of fly ash based geopolymers are in correlation with their hydrolytic stability. Factors that increase the compressive strength also increase the hydrolytic stability of fly ash based geopolymers. The best hydrolytic stability of fly ash based geopolymers was shown in sea water while the lowest stability was recorded in simulated acid rain.


2011 ◽  
Vol 477 ◽  
pp. 85-90
Author(s):  
Yun Fen Hou ◽  
Dong Min Wang

This paper studies the influences of concentration and modulus of sodium silicate solution (Na activator) and sodium potassium silicate solution (Na-K activator) on the phase composition, microstructure and strength development in the geopolymers prepared using Class F fly ash. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and MAS NMR were utilized. It shows that the compressive strength increases while Na activator solution modulus increases, but when modulus exceeds 1.4, the compressive strength decreases, and it decreases markedly while modulus is greater than 2.0. The compressive strength improves with increase of sodium silicate solution concentration, and when concentration is 32%, compressive strength reaches the maximum, and then it reduces with concentration increment. It shows that the compressive strength increases while Na-K activator solution modulus increases, but when modulus exceeds 1.7, the compressive strength decreases, and it decreases markedly while modulus is greater than 2.0. The compressive strength improves with increase of Na-K activator solution concentration, and when concentration is 36%, compressive strength reaches the maximum. The main product of reaction in the geopolymeric material is amorphous alkali aluminosilicate gel.


2017 ◽  
Vol 26 (2) ◽  
pp. 234-240
Author(s):  
Jakub Jura ◽  
Małgorzata Ulewicz

Paper presents the possibility of using fly ash from the combustion of two types biomass in fluidized bed boiler to modifications cement mortars composition. The influence of the use of ashes on their mechanical and physical properties (compressive strength, frost resistance, water absorption) of cement mortars. In research part of standarized sand was replaced by fly ash from the combustion of wood with coconut husks and wood with sunflower in the amount of 10, 20 and 30% by weight of cement. The addition of ash, depending on the composition, increase the compressive strength about 17%, decrease a reduction compressive strength after frost resistance tests to 0,5% and slightly increases weight loss and absorbency.


2012 ◽  
Vol 4 (1) ◽  
pp. 1
Author(s):  
Djoko Purwanto

Timber Acacia mangium (Acacia mangium, Willd) for Furniture. The study aims to determine the mechanical and physical properties and the decorative value (color and fiber) wood of acacia mangium with using finishing materials. This type of finishing material used is ultran lasur natural dof ,ultran lasur classic teak, aqua politur clear dof, aqua politur akasia dan aqua politur cherry. After finishing the wood is stored for 3 months. Test parameters were observed, namely, physical and mechanical properties of wood, adhesion of finishing materials, color and appearance of the fiber, and timber dimensions expansion. The results showed that the mechanical physical properties of acacia wood qualified SNI. 01-0608-89 about the physical and mechanical properties of wood for furniture, air dry the moisture content from 13.78 to 14.89%, flexural strength from 509.25 to 680.50 kg/cm2, and compressive strength parallel to fiber 342.1 - 412.9 kg/cm2. Finishing the treatment process using five types of finishing materials can increase the decorative value (color and fiber) wood. Before finishing the process of acacia mangium wood has the appearance of colors and fibers and less attractive (scale scores 2-3), after finishing acacia wood fibers have the appearance of colors and interesting and very interesting (scale 4-5).Keywords: mangium wood, mechanical properties, decorative value, finishing, furniture.


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