Effect of Partial Replacement of Fly Ash by Metakaolin on Strength Development of Fly Ash Based Geopolymer Mortar

2017 ◽  
Vol 744 ◽  
pp. 131-135 ◽  
Author(s):  
Muhammad Zahid ◽  
Nasir Shafiq ◽  
Mohd Fadhil Nuruddin ◽  
Ehsan Nikbakht ◽  
Asif Jalal
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide Solution ◽  
Base Material ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Partial Replacement ◽  
Strength Development ◽  
Class C ◽  
Class F

This article aims to investigate the compressive strength variation by the addition of metakaolin as a substitute of fly ash in the fly ash based geopolymer mortar. Five, ten and fifteen percent by weight of fly ash was replaced by highly reactive metakaolin. Two type of fly ashes namely, ASTM class F and ASTM class C were used as a base material for the synthesis of geopolymer mortar. Eight molar sodium hydroxide solution mixed with sodium silicate solution was used as alkaline activator. For optimum geopolymerization, mortar was cured at sixty degree Celsius for twenty four hours duration. Results show different behavior of metakaolin replacement on compressive strength for two different types of fly ash based geopolymer mortar. Improvement in compressive strength was seen by addition of metakaolin in ASTM class F fly ash based geopolymer. On the other hand compressive strength was decreased abruptly in fly ash class C based geopolymer up to certain replacement level.

scholarly journals Artificial Intelligence Approaches for Prediction of Compressive Strength of Geopolymer Concrete

Materials ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 983 ◽  
Author(s):  
Dong Dao ◽  
Hai-Bang Ly ◽  
Son Trinh ◽  
Tien-Thinh Le ◽  
Binh Pham
Keyword(s):  
Artificial Intelligence ◽  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Steel Slag ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Partial Replacement ◽  
Geopolymer Concrete

Geopolymer concrete (GPC) has been used as a partial replacement of Portland cement concrete (PCC) in various construction applications. In this paper, two artificial intelligence approaches, namely adaptive neuro fuzzy inference (ANFIS) and artificial neural network (ANN), were used to predict the compressive strength of GPC, where coarse and fine waste steel slag were used as aggregates. The prepared mixtures contained fly ash, sodium hydroxide in solid state, sodium silicate solution, coarse and fine steel slag aggregates as well as water, in which four variables (fly ash, sodium hydroxide, sodium silicate solution, and water) were used as input parameters for modeling. A total number of 210 samples were prepared with target-specified compressive strength at standard age of 28 days of 25, 35, and 45 MPa. Such values were obtained and used as targets for the two AI prediction tools. Evaluation of the model’s performance was achieved via criteria such as mean absolute error (MAE), root mean square error (RMSE), and coefficient of determination (R2). The results showed that both ANN and ANFIS models have strong potential for predicting the compressive strength of GPC but ANFIS (MAE = 1.655 MPa, RMSE = 2.265 MPa, and R2 = 0.879) is better than ANN (MAE = 1.989 MPa, RMSE = 2.423 MPa, and R2 = 0.851). Sensitivity analysis was then carried out, and it was found that reducing one input parameter could only make a small change to the prediction performance.

scholarly journals Effect of Concentration of Sodium Hydroxide and Degree of Heat Curing on Fly Ash-Based Geopolymer Mortar

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Subhash V. Patankar ◽  
Yuwaraj M. Ghugal ◽  
Sanjay S. Jamkar
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Hydroxide Solution ◽  
Large Change ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Test Period ◽  
Hydroxide Solution ◽  
Increase With Increase

Geopolymer concrete/mortar is the new development in the field of building constructions in which cement is totally replaced by pozzolanic material like fly ash and activated by alkaline solution. This paper presented the effect of concentration of sodium hydroxide, temperature, and duration of oven heating on compressive strength of fly ash-based geopolymer mortar. Sodium silicate solution containing Na2O of 16.45%, SiO2 of 34.35%, and H2O of 49.20% and sodium hydroxide solution of 2.91, 5.60, 8.10, 11.01, 13.11, and 15.08. Moles concentrations were used as alkaline activators. Geopolymer mortar mixes were prepared by considering solution-to-fly ash ratio of 0.35, 0.40, and 0.45. The temperature of oven curing was maintained at 40, 60, 90, and 120°C each for a heating period of 24 hours and tested for compressive strength at the age of 3 days as test period after specified degree of heating. Test results show that the workability and compressive strength both increase with increase in concentration of sodium hydroxide solution for all solution-to-fly ash ratios. Degree of heating also plays vital role in accelerating the strength; however there is no large change in compressive strength beyond test period of three days after specified period of oven heating.

The Effect of Activators on the Fly Ash-Based Geopolymers

2011 ◽  
Vol 477 ◽  
pp. 85-90
Author(s):  
Yun Fen Hou ◽  
Dong Min Wang
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Silicate ◽  
Sodium Silicate Solution ◽  
Solution Concentration ◽  
Silicate Solution ◽  
Strength Development ◽  
X Ray Diffraction ◽  
Sodium Potassium ◽  
Class F Fly Ash

This paper studies the influences of concentration and modulus of sodium silicate solution (Na activator) and sodium potassium silicate solution (Na-K activator) on the phase composition, microstructure and strength development in the geopolymers prepared using Class F fly ash. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and MAS NMR were utilized. It shows that the compressive strength increases while Na activator solution modulus increases, but when modulus exceeds 1.4, the compressive strength decreases, and it decreases markedly while modulus is greater than 2.0. The compressive strength improves with increase of sodium silicate solution concentration, and when concentration is 32%, compressive strength reaches the maximum, and then it reduces with concentration increment. It shows that the compressive strength increases while Na-K activator solution modulus increases, but when modulus exceeds 1.7, the compressive strength decreases, and it decreases markedly while modulus is greater than 2.0. The compressive strength improves with increase of Na-K activator solution concentration, and when concentration is 36%, compressive strength reaches the maximum. The main product of reaction in the geopolymeric material is amorphous alkali aluminosilicate gel.

Effect of Curing Conditions on the Mechanical Properties of Fly Ash-Based Geopolymer without Sodium Silicate Solution

2014 ◽  
Vol 699 ◽  
pp. 15-19 ◽  
Author(s):  
Rosniza Hanim Abdul Rahim ◽  
Khairun Azizi Azizli ◽  
Zakaria Man ◽  
Muhd Fadhil Nuruddin
Keyword(s):  
Compressive Strength ◽  
Elevated Temperature ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Room Temperature ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Curing Temperature ◽  
Curing Time

Geopolymer is associated with the alkali activation of materials rich in Si and Al, and alkali activator such as sodium hydroxide is used for the dissolution of raw material with the addition of sodium silicate solution to increase the dissolution process. However, the trend of strength development of geopolymer using sodium hydroxide alone is not well established. This paper presents an evaluation on compressive strength of fly ash–based geopolymer by varying curing time with respect to different curing temperature using sodium hydroxide as the only activator. The samples were cured at room temperature and at an elevated temperature (60°C). Further analysis on the microstructure of geopolymer products cured at 60°C was carried out using Field Emission Scanning Microscopy (FESEM). It can be observed that the compressive strength increased as the curing time increased when cured at room temperature; whereas at elevated temperature, the strength increased up to a maximum 65.28 MPa at 14 days but gradually decreased at longer curing time. Better compressive strength can be obtained when the geopolymer was cured at an elevated temperature compared to curing at room temperature.

A Study on Relationship between Porosity and Compressive Strength for Geopolymer Paste

2013 ◽  
Vol 594-595 ◽  
pp. 1112-1116 ◽  
Author(s):  
Z.F. Farhana ◽  
H. Kamarudin ◽  
Azmi Rahmat ◽  
A.M. Mustafa Al Bakri
Keyword(s):  
Compressive Strength ◽  
Sodium Hydroxide Solution ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Pulse Velocity ◽  
Strength Test ◽  
Compressive Strength Test ◽  
Alkaline Activator ◽  
The Relationship ◽  
Geopolymer Paste

This paper presents a study on the relationship between porosity and compressive strength for geopolymer paste. In this research, geopolymer paste was made from fly ash class F based geopolymer mixed with alkaline activator; sodium hydroxide solution and sodium silicate solution. Twelve mixes were cast in 50mm x 50mm x 50mm moulds and the samples were cured for 24 hrs at 60 °C in the oven. The samples were examined after 7, 14, 28 and 90 days in terms of porosity test, pulse velocity test and compressive strength test. It was concluded that the sample at day 90 had the highest compressive strength of 56.50 N/mm2had porosity 3.77%. Thus, the sample with lowest porosity had highest pulse velocity 3303 m/s during ultrasonic testing with lowest transmission time 15.17 μs. Keywords: porosity, compression strength, geopolymer, pulse velocity

Effects of Alkaline Solution on the Properties of Slag Based Geopolymer

2018 ◽  
Vol 877 ◽  
pp. 193-199 ◽  
Author(s):  
Suman Saha ◽  
C. Rajasekaran
Keyword(s):  
Compressive Strength ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Alkaline Solution ◽  
Sodium Hydroxide Solution ◽  
Setting Time ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Hydroxide Solution ◽  
Geopolymer Paste

Production of Ordinary Portland Cement (OPC) requires huge quantity of natural resources and energy and it releases large amount of carbon - di - oxide to the environment. Therefore, enormous studies have been carried out throughout the world to establish geopolymer as an alternative binder material for the replacement of OPC to protect the environment. This study intends to explore the effects of alkaline solution on the properties of geopolymer produced with ground granulated blast furnace slag. Properties such as Standard consistency, setting time of slag based geopolymer paste has been determined using Vicat’s apparatus (according to the guidelines given by Indian Standards for OPC). In order to determine the effects of alkaline solution on the properties of geopolymers, the concentration of sodium hydroxide solution has been varied from 6M to 16M and the ratio of sodium silicate solution to sodium hydroxide solution is also varied from 1.0 to 2.0. Results indicate higher standard consistency and significant less setting time for slag based geopolymer paste than that of OPC paste. Compressive strength of the geopolymer paste and mortar cube samples, cured in ambient conditions till the day of testing, is increasing with the increase of the concentration of sodium hydroxide solution. Highest compressive strength is obtained for the samples prepared with alkaline solution having the ratio of sodium silicate solution to sodium hydroxide solution as 1.5. But when the concentration of sodium hydroxide solution is beyond 14M, decreasing trend in compressive strength is observed.

scholarly journals A Comparative Study on the Effect of Class C and Class F Fly Ashes on Geotechnical Properties of High-Plasticity Clay

CivilEng ◽  
2021 ◽  
Vol 2 (4) ◽  
pp. 1009-1018
Author(s):  
Salar Shirkhanloo ◽  
Mohammad Najafi ◽  
Vinayak Kaushal ◽  
Mehrdad Rajabi
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Unconfined Compressive Strength ◽  
Geotechnical Properties ◽  
Dry Density ◽  
High Plasticity ◽  
Fly Ashes ◽  
High Plasticity Clay ◽  
Class C ◽  
Class F

Clays generally have a low strength and capacity, and additives are usually used to stabilize them. In recent years, using fly ash to stabilize soil has decreased environmental pollution while also having an economic benefit. The objective of this study is to perform a comparative investigation on the effect of class C and class F fly ashes on geotechnical properties of high-plasticity clay using the Atterberg’s limit, compaction, California Bearing Ratio (CBR), and unconfined compressive strength tests. The results showed that with an increase in the amount of fly ash, there was a decrease in the maximum dry density and an increase in the optimum moisture content. Moreover, an addition of fly ashes of up to 25% caused a reduction of the liquid limit and plasticity index, and an increase in the maximum unconfined compressive strength and CBR. Lengthening the curing time had a positive impact on the unconfined compressive strength of the soil. The soil samples with class C fly ash were seen to possess more efficient geotechnical properties as compared to class F fly ash.

Effect of Nano Silica and Ultrafine Fly Ash on Compressive Strength of High Volume Fly Ash Mortar

2013 ◽  
Vol 368-370 ◽  
pp. 1061-1065 ◽  
Author(s):  
Steve W.M. Supit ◽  
Faiz U.A. Shaikh ◽  
Prabir K. Sarker
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
High Volume ◽  
Partial Replacement ◽  
Strength Development ◽  
Test Results ◽  
X Ray Diffraction ◽  
Nano Silica ◽  
High Volume Fly Ash ◽  
Class F Fly Ash

This paper evaluates the effect of Ultrafine Fly Ash (UFFA) and nanoSilica (NS) on compressive strength of high volume fly ash (HVFA) mortar at 7 days and 28 days. Three series of mortar mixes are considered in the first part of this study. In the first series the effect of high content of class F fly ash as partial replacement of cement at 40, 50 and 60% (by wt.) are considered. While in the second and third series, the UFFA and NS are used as partial replacement of cement at 5%, 8%, 10%, 12% and 15% and 1%, 2%, 4%, 6% and 8% (by wt.) of cement, respectively. The UFFA and the NS content which exhibited highest compressive strength in the above series are used in the second part where their effects on the compressive strength of HVFA mortars are evaluated. Results show that the mortar containing 10% UFFA as partial replacement of cement exhibited the highest compressive strength at both 7 and 28 days among all UFFA contents. Similarly, the mortar containing 2% NS as partial replacement of cement exhibited the best performance. Interestingly, the use of UFFA in HVFA mortars did not improve the compressive strength. However, the use of 2% and 4% NS showed improvement in the compressive strength of HVFA mortar containing 40% and 50% fly ash at both ages. The effects of NS and UFFA on the hydration and strength development of HVFA mortar is also evaluated through X-Ray Diffraction (XRD) test. Results also show that the UFFA and NS can significantly reduce the calcium hydroxide (CH) in HVFA mortars.

Effect of Solid to Liquid Ratio on the Mechanical and Physical Properties of Fly Ash Geopolymer without Sodium Silicate

2014 ◽  
Vol 625 ◽  
pp. 46-49 ◽  
Author(s):  
Rosniza Hanim Abdul Rahim ◽  
Khairun Azizi Azizli ◽  
Zakaria Man ◽  
Tia Rahmiati ◽  
Lukman Ismail
Keyword(s):  
Mechanical Property ◽  
Compressive Strength ◽  
Fly Ash ◽  
Physical Properties ◽  
Silicate Solution ◽  
Strength Development ◽  
Alkali Activation ◽  
Liquid Ratio ◽  
Mechanical And Physical Properties ◽  
Solid Liquid

Geopolymer is produced from the alkali activation of materials rich in Si and Al with addition of silicate solution in order to improve the mechanical property. Limited research has been done with the absence of silicate solution in the geopolymerization process by varying solid/liquid ratio and on how it works for that condition on mechanical and physical properties. This paper presents an investigation on the mechanical and physical properties of fly ash based geopolymer by varying solid to liquid ratio using sodium hydroxide as the only activator. In addition, the strength development also been investigated. The samples were prepared using 50mm x 50mm x 50mm mould and cured at an elevated temperature (60oC). It can be observed that the optimum compressive strength and density were obtained at solid/ liquid ratio of 4. In addition, the compressive strength of fly ash based geopolymer for all the solid to liquid ratio increased until 14 days and started to decrease later.

Immobilization of MSWI Fly Ash with Geopolymers

2010 ◽  
Vol 150-151 ◽  
pp. 1564-1569 ◽  
Author(s):  
Man Tong Jin ◽  
Cai Ju Huang ◽  
Liang Chen ◽  
Xin Sun ◽  
Lian Jun Wang
Keyword(s):  
Heavy Metals ◽  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Silicate Solution ◽  
Waste Incineration ◽  
Silicate Solution ◽  
Hazardous Wastes ◽  
Municipal Solid Waste Incineration ◽  
Mswi Fly Ash ◽  
Solidified Body

The geopolymer was chosen to immobilize the municipal solid waste incineration (MSWI) fly ash because of its strong fixing capacity for heavy metals. The fly ash-based geopolymer was synthesized from metakaolinite with MSWI fly ash under activation of sodium silicate solution, and then cured at relative humidity (RH) between 40% and 90% at 20°C. The ability of immobilization of heavy metals in MSWI fly ash with the geopolymer was evaluated in terms of the compressive strength and leaching concentration. The experimental results confirmed that the compressive strength of the resulting solidified body could achieve 35.13 MPa after 7 days of curing. Meanwhile, the leaching concentrations of Pb, Zn, Cu and Cr were 0.0230 mg/kg, 0.186 mg/kg, 0.231 mg/kg, and 6.56 mg/kg, respectively. We confirm that geopolymerisation is an effective alternative in the disposal of various hazardous wastes containing heavy metals.

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