Studies on Pyrolysis of Rice Husk Using Taguchi's L9 Orthogonal Array

2014 ◽  
Vol 625 ◽  
pp. 630-634
Author(s):  
Khanh Vi Dang ◽  
Suzana Yusup ◽  
Yoshimitsu Uemura

Conversion and yield of liquid product using semi-batch reactor are investigated. Selected reaction parameters were optimized, using Taguchi L9 Orthogonal Array method for the design of experiments, to yield the highest liquid product. The investigated parameters include nitrogen flow rate, sample particle size, temperature and heating rate. The effects and significance of each parameter was studied and verified through repetitive experiments. Optimum conditions for the reaction were established. Optimum conditions for pyrolysis process were at 100 ml/min of nitrogen flow rate, temperature at 500oC, 20oC/min of heating rate and 250μm - 500μm of particle size with liquid yield of 35.48wt%.

2020 ◽  
Vol 16 (1) ◽  
pp. 61-80
Author(s):  
M.Y. Guida ◽  
S.E. Lanaya ◽  
F.E. Laghchioua ◽  
Z. Rbihi ◽  
A. Hannioui

AbstractThis study deals with fast pyrolysis of sawdust wood waste (SWW) at the range of temperature 300–700 °C in a stainless steel tubular reactor. The aim was to experimentally investigate how the temperature, the particle size, the nitrogen flow rate (N2) and the heating rate affect bio-oil, bio-char and gaseous products. These parameters were varied in the ranges of 5–20 °C/min, below 0.1–1.5 mm and 20–200 mL min−1, respectively. It was concluded that both the temperature and heating rate have a significant effect on both yield of bio-oil and bio-char resulting from pyrolysis of SWW. The liquid products obtained at various pyrolysis temperatures were subjected into column chromatography after removal of asphaltenes (hexane insoluble). Obtained bio-oils (maltenes or hexane soluble) were classified as aliphatic, aromatic and polar sub-fractions. The maximum of bio-oil yield of 39.5 wt% was obtained at a pyrolysis temperature of 500 °C, particle size between 0.5 and 1 mm, nitrogen flow rate (N2) of 100 mL min−1 and heating rate of 5 °C/min. Liquid product (bio-oil) obtained under the most suitable and optimal condition was characterized by elemental analysis, Nuclear magnetic resonance spectroscopy (1H NMR and 13C NMR), Fourier transformed infrared spectroscopy (FT-IR). The analysis of liquid showed that bio-oil from SWW could be a potential source of renewable fuel production and value added chemical. The yield of char generally decreases with increasing the temperature, the char yield passes from 54.61 to 29.47 wt% at the heating rate of 5 °C/min and from 50.01 to 24.5 wt% at the heating rate of 20 °C/min at the same range of temperature (300–700 °C). Solid products (bio-char) obtained in the presence of nitrogen (N2) contain a very important percentage of carbon and high heating values (HHVs).


2021 ◽  
Vol 287 ◽  
pp. 02004
Author(s):  
MNZ Moni ◽  
Suzana Yusuf ◽  
ASA Manaf ◽  
Waqiuddin Rahman

This paper investigates the effects of three parameters (reaction temperature, feedstock particle size and nitrogen flow rate) towards the solid (char) yield from the pyrolysis of bamboo. Three-factor, three-level Taguchi’s L9 Orthogonal Array was used as the experimental design. The char yield at reaction temperatures of 300-500°C, feedstock particle size of 100-1000 μm, and nitrogen flow rate of 100-300 ml min−1 were investigated. The maximum solid yield was predicted based on signal-to-noise (S/N) ratio and was found to be at 300°C reaction temperature, 1000 μm feedstock particle size and 100 ml min−1 of nitrogen flow rate. Confirmation runs were conducted to validate the prediction at corresponding predicted conditions.


2018 ◽  
Vol 14 (1) ◽  
pp. 31-60 ◽  
Author(s):  
M. Y. Guida ◽  
F. E. Laghchioua ◽  
A. Hannioui

This article deals with fast pyrolysis of brown algae, such as Bifurcaria Bifurcata at the range of temperature 300–800 °C in a stainless steel tubular reactor. After a literature review on algae and its importance in renewable sector, a case study was done on pyrolysis of brown algae especially, Bifurcaria Bifurcata. The aim was to experimentally investigate how the temperature, the particle size, the nitrogen flow rate (N2) and the heating rate affect bio-oil, bio-char and gaseous products. These parameters were varied in the ranges of 5–50 °C/min, below 0.2–1 mm and 20–200 mL. min–1, respectively. The maximum bio-oil yield of 41.3wt% was obtained at a pyrolysis temperature of 600 °C, particle size between 0.2–0.5 mm, nitrogen flow rate (N2) of 100 mL. min–1 and heating rate of 5 °C/min. Liquid product obtained under the most suitable and optimal condition was characterized by elemental analysis, 1H-NMR, FT-IR and GC-MS. The analysis of bio-oil showed that bio-oil from Bifurcaria Bifurcata could be a potential source of renewable fuel production and value added chemicals.


Energies ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2778 ◽  
Author(s):  
Mari Rowena C. Tanquilut ◽  
Homer C. Genuino ◽  
Erwin Wilbers ◽  
Rossana Marie C. Amongo ◽  
Delfin C. Suministrado ◽  
...  

Pyrolysis is an important technology to convert lignocellulosic biomass to a renewable liquid energy carrier known as pyrolysis oil or bio-oil. Herein we report the pyrolysis of pigeon pea wood, a widely available biomass in the Philippines, in a semi-continuous reactor at gram scale. The effects of process conditions such as temperature (400–600 °C), nitrogen flow rate (7–15 mL min−1) and particle size of the biomass feed (0.5–1.3 mm) on the product yields were determined. A Box-Behnken three-level, three-factor fractional factorial design was carried out to establish process-product yield relations. Of particular interest is the liquid product (bio-oil), of which the yield was shown to depend on all independent variables in a complex manner. The optimal conditions for highest bio-oil yield (54 wt.% on dry feed intake) were a temperature of 466 °C, a nitrogen flow rate of 14 mL min−1 and a particle size of 1.3 mm. Validation of the optimized conditions proved that the average (n = 3) experimental bio-oil yield (52 wt.%) is in good agreement with the predicted value from the model. The properties of product oils were determined using various analytical techniques including gas chromatography-mass spectrometry (GC–MS), gel-permeation chromatography (GPC), nuclear magnetic resonance spectroscopy (13C- and HSQC-NMR) and elemental and proximate analyses. The bio-oils were shown to have low ash content (0.2%), high heating value (29 MJ kg−1) and contain high value-added phenolics compounds (41%, GC peak area) as well as low molecular weight aldehydes and carboxylic acids. GPC analysis indicated the presence of a considerable amount of higher molecular weight compounds. NMR measurements showed that a large proportion of bio-oil contains aliphatic carbons (~60%), likely formed from the decomposition of (hemi)cellulose components, which are abundantly present in the starting pigeon pea wood. Subsequent preliminary scale-up pyrolysis experiments in a fluidized bed reactor (~100 gfeed h−1, 475 °C and N2 flow rate of 1.5 L min−1) gave a non-optimized bio-oil yield of 44 wt.%. Further fractionation and/or processing are required to upgrade these bio-oils to biofuels and biobased chemicals.


2014 ◽  
Vol 50 (21) ◽  
pp. 1545-1547
Author(s):  
Dae‐Myeong Geum ◽  
Seungheon Shin ◽  
Min‐Su Park ◽  
Jae‐Hyung Jang

2012 ◽  
Vol 258 (22) ◽  
pp. 8498-8505 ◽  
Author(s):  
Nishat Arshi ◽  
Junqing Lu ◽  
Bon Heun Koo ◽  
Chan Gyu Lee ◽  
Faheem Ahmed

2016 ◽  
Vol 2016 ◽  
pp. 1-12 ◽  
Author(s):  
Yu-Wei Lin ◽  
Chia-Wei Lu ◽  
Ge-Ping Yu ◽  
Jia-Hong Huang

This study aims to investigate the effects of nitrogen flow rate (0–2.5 sccm) on the structure and properties of TiZrN films. Nanocrystalline TiZrN thin films were deposited on Si (001) substrates by unbalanced magnetron sputtering. The major effects of the nitrogen flow rate were on the phase, texture, N/(Ti + Zr) ratio, thickness, hardness, residual stress, and resistivity of the TiZrN films. The nitrogen content played an important role in the phase transition. With increasing nitrogen flow rate, the phase changed from mixed TiZr and TiZrN phases to a single TiZrN phase. The X-ray diffraction results indicated that (111) was the preferred orientation for all TiZrN specimens. The N/(Ti + Zr) ratio of the TiZrN films first increased with increasing nitrogen flow rate and then stabilized when the flow rate further increased. When the nitrogen flow rate increased from 0.4 to 1.0 sccm, the hardness and residual stress of the TiZrN thin film increased, whereas the electrical resistivity decreased. None of the properties of the TiZrN thin films changed with nitrogen flow rate above 1.0 sccm because the films contained a stable single phase (TiZrN). At high nitrogen flow rates (1.0–2.5 sccm), the average hardness and resistivity of the TiZrN thin films were approximately 36 GPa and 36.5 μΩ·cm, respectively.


2013 ◽  
Vol 787 ◽  
pp. 184-189 ◽  
Author(s):  
Khanh Vi Dang ◽  
Suzana Yusup ◽  
Yoshimitsu Uemura ◽  
Mohd Fadhil Nuruddin

The market demand of bio-fuel is 11,8 billion litters based on recent reported data. Hence, with the high demand of bio-fuel, the bio-fuel production utilizing rice husk can be one of the solutions. Beside, bio-oil can be produced by pyrolysis process utilizing rice husk as the feedstock. In this research, the optimization condition in producing bio-oil from rice husk by catalytic pyrolysis process was studied. The effect of catalyst type (H-β, H-Y, HZSM-5), catalyst loading (1wt%, 5wt%, 12wt%), temperature (400-500°C) and flow rate (60-100ml/min) were investigated through repetitive experiments using L9 Taguchi Orthogonal Array. The highest liquid yield of 38wt% was obtained at the optimum conditions with temperature of 500°C with nitrogen flow rate of 60ml/min and 12wt% of H-ZSM-5.


2019 ◽  
Vol 27 (01) ◽  
pp. 1950091 ◽  
Author(s):  
JIAOJIAO DU ◽  
HAIBIN ZHOU ◽  
CAIXIA SUN ◽  
HAIJIANG KOU ◽  
ZHONGWEI MA ◽  
...  

A new approach was adopted to improve the corrosion behavior of the chromium nitride (CrNx) hard coating through magnetron sputtering deposition at different nitrogen flow rates. The influence of the nitrogen flow rates on the chemical composition, microstructure, mechanical property and corrosion behavior in artificial seawater of the CrNx coatings was investigated. The results show that with the increase of the nitrogen flow rates, the growth structure of the coatings varied from dense granular growth to coarse columnar growth. Increasing the nitrogen flow rates was helpful to decrease the Cr/N ratio and induce the phase transforming from mixed hexagonal Cr2N and face-centered cubic CrN to single CrN. However, the coatings under different nitrogen flow rates significantly improved the corrosion resistance and hardness of the steel substrate. Furthermore, at high nitrogen flow rate, the coating had high corrosion velocity and low protective capability against the substrate corrosion due to the fast corrosion channels acted by the columnar grain boundaries. While at the middle nitrogen flow rate, the coating with CrN phase, densely granular growth structure and moderate grain size resulted in excellent corrosion resistance and highest hardness.


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