scholarly journals Effect of Liquid Flow Rate and Amine Concentration on CO2 Removal from Natural Gas at High Pressure Operation in Packed Absorption Column

2015 ◽  
Vol 773-774 ◽  
pp. 1291-1295 ◽  
Author(s):  
Hairul Nazirah Abdul Halim ◽  
Mohd Shariff Azmi ◽  
Mohammad Azmi Bustam

Greenhouse gas (GHG) emissions such as carbon dioxide (CO2) and methane (CH4) from oil and natural gas operation at offshore platforms have significant contribution to global warming. The reduction of these GHG emissions is possible through CO2 capture technology. This study reports the absorption performance of monoethanolamine (MEA) for the removal of CO2 from natural gas (NG) at high pressure conditions. The absorption experiments were performed in an absorption column packed with Sulzer Metal Gauze Packing at 5.0 MPa operating pressure. The absorption performance was evaluated in terms of CO2 removal (%) with liquid flow rate ranging from 1.81 to 4.51 m3/m2.h and MEA concentration of 1.0 - 4.0 kmol/m3. It was found that CO2 removal (%) had increased with increasing liquid flow rate and MEA concentration.

2019 ◽  
Vol 1 (2) ◽  
pp. 55-57
Author(s):  
NUR FARHANA AJUA MUSTAFA ◽  
Azmi bin Mohd Shariff ◽  
WeeHorng Tay ◽  
Hairul Nazirah Abdul Halim ◽  
Siti Munirah Mhd Yusof

This article reports the absorption removal efficiency for carbon dioxide (CO2) capture from natural gas using an environmental friendly solvent, potassium carbonate promoted with glycine. Recently, CO2 capture using this solvent (with precipitating) was studied by previous researchers. However, the precipitates of the solvent increase the potential of blockage in the packing and piping thus result failure in absorption processes. Therefore, this study focused to assess the CO2 removal efficiency of non-precipitating potassium carbonate promoted with glycine. This green solvent contains aqueous blend of 20 wt% potassium carbonate and 8 wt% glycine. The absorption performance of the solvent was obtained by demonstrated a few experimental works using a bench scale packed absorption column. The packing type was Sulzer metal gauze and the column consisted of six sampling point which located equidistance along the packing The system was running over a range of liquid flow rate 1.81-7.22 m3/m2.h at fixed operating pressure (4 Mpa), CO2 inlet concentration (20%), gas flow rate (33 kmol/m2.h) and solvent temperature (60 . The effect of liquid flow rate was assessed in term of its CO2 removal efficiency and concentration profile along the packing. The study shows the increasing trend of CO2 removal as liquid flow rate increases. Higher liquid/molar flow rate gas (L/G) offers a better absorption performance compared to lower L/G ratio. This study demonstrated the efficient absorption up to 77 % using non-precipitating potassium carbonate promoted with glycine.


2020 ◽  
Vol 17 (2) ◽  
pp. 957-960
Author(s):  
Nur Farhana Ajua Mustafa ◽  
Azmi Mohd Shariff ◽  
WeeHorng Tay ◽  
Hairul Nazirah Abdul Halim ◽  
Siti Munirah Mhd Yusof ◽  
...  

This paper presented the absorption removal efficiency for carbon dioxide (CO2) removal from natural gas using an environmental friendly solvent, potassium carbonate promoted with glycine. Recently, CO2 capture using this solvent (with precipitating) was studied by previous researchers. However, the precipitates of the solvent increase the potential of blockage in the packing and piping thus result failure in absorption processes. Therefore, this study focused to assess the CO2 removal efficiency of non-precipitating potassium carbonate promoted with glycine. This green solvent contains aqueous blend of 20 wt% potassium carbonate and 8 wt% glycine. The absorption performance of the solvent was obtained by demonstrated a few experimental works using a bench scale packed absorption column. The packing type was Sulzer metal gauze and the column consisted of six sampling point which located equidistance along the packing. The effect of liquid flow rate was assessed in term of its CO2 removal efficiency and concentration profile along the packing. The study shows the increasing trend of CO2 removal as liquid flow rate increases. Higher liquid/molar flow rate gas (L/G) offers a better absorption performance compared to lower L/G ratio. The results demonstrated the efficient absorption up to 77% using non-precipitating potassium carbonate promoted with glycine.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Hamza A. Ahmed ◽  
Harith N. Mohammed ◽  
Omar S. Lateef ◽  
Ghassan H. Abdullah

AbstractDespite the importance of natural gas (NG) as an energy source, there is a lot of pressurized landfill gas not exploited so far because it contains high CO2 concentration. Therefore, this study aimed to develop a 2-D mathematical model to simulate CO2 removal from NG stream contains high CO2 concentration up to 70% at high-pressure up to 60 bar using three different dimensions of polyvinylidene fluoride (PVDF) hollow fiber membrane contactors. Aqueous solutions of activated methyldiethanolamine (MDEA) with piperazine (PZ) were adopted. The performance of considered absorbent at high-pressure was evaluated at the non-wetting mode condition of membrane contactor. Moreover, the effect of pressure, contact area, gas flow rate, MDEA concentration into the amine mixture, PZ concentration, temperature and membrane properties were theoretically investigated. The findings stated that activated MDEA had different performance in terms of membrane wetting compared with other amines, which used at high pressure in previous studies. In addition, the simulation results showed that CO2 removal efficiency was significantly enhanced, when the operating pressure, contact area, PZ concentration and temperature were increased. However, increasing gas flow rate leads to reduce CO2 removal efficiency. Furthermore, the CO2 absorption was significantly improved by adding a small amount of PZ to MDEA. The predicted model results showed a good agreement with experimental data obtained from the literature.


1986 ◽  
Vol 51 (10) ◽  
pp. 2127-2134 ◽  
Author(s):  
František Potůček ◽  
Jiří Stejskal

Absorption of oxygen into water and aqueous solutions of poly(acrylamides) was studied in an absorber with a wetted sphere. The effects of changes in the liquid flow rate and the polymer concentration on the liquid side mass transfer coefficient were examined. The results are expressed by correlations between dimensionless criteria modified for non-Newtonian liquids whose flow curve can be described by the Ostwald-de Waele model.


Author(s):  
Svetlana Rudyk ◽  
Sami Al-Khamisi ◽  
Yahya Al-Wahaibi

AbstractFactors limiting foam injection for EOR application are exceptionally low rock permeability and exceedingly high salinity of the formation water. In this regard, foam formation using internal olefin sulfonate is investigated over a wide salinity range (1, 5, 8, 10, and 12% NaCl) through 10 mD limestone. The relationships between pressure drop (dP), apparent viscosity, liquid flow rate, total flow rate, salinity, foam texture, and length of foam drops at the outlet used as an indicator of viscosity are studied. Foaming is observed up to 12% NaCl, compared to a maximum of 8% NaCl in similar core-flooding experiments with 50 mD limestone and 255 mD sandstone. Thus, the salinity limit of foam formation has increased significantly due to the low permeability, which can be explained by the fact that the narrow porous system acts like a membrane with smaller holes. Compared to the increasing dP reported for highly permeable rocks, dP linearly decreases in almost the entire range of gas fraction (fg) at 1–10% NaCl. As fg increases, dP at higher total flow rate is higher at all salinities, but the magnitude of dP controls the dependence of apparent viscosity on total flow rate. Low dP is measured at 1% and 10% NaCl, and high dP is measured at 5, 8, and 12% NaCl. In the case of low dP, the apparent viscosity is higher at higher total flow rate with increasing gas fraction, but similar at two total flow rates with increasing liquid flow rate. In the case of high dP, the apparent viscosity is higher at lower total flow rate, both with an increase in the gas fraction and with an increase in the liquid flow rate. A linear correlation is found between dP or apparent viscosity and liquid flow rate, which defines it as a governing factor of foam flow and can be considered when modeling foam flow.


Author(s):  
Yoshiyuki Iso ◽  
Xi Chen

Gas-liquid two-phase flows on the wall like liquid film flows, which are the so-called wetted wall flows, are observed in many industrial processes such as absorption, desorption, distillation and others. For the optimum design of packed columns widely used in those kind of processes, the accurate predictions of the details on the wetted wall flow behavior in packing elements are important, especially in order to enhance the mass transfer between the gas and liquid and to prevent flooding and channeling of the liquid flow. The present study focused on the effects of the change of liquid flow rate and the wall surface texture treatments on the characteristics of wetted wall flows which have the drastic flow transition between the film flow and rivulet flow. In this paper, the three-dimensional gas-liquid two-phase flow simulation by using the volume of fluid (VOF) model is applied into wetted wall flows. Firstly, as one of new interesting findings in this paper, present results showed that the hysteresis of the flow transition between the film flow and rivulet flow arose against the increasing or decreasing stages of the liquid flow rate. It was supposed that this transition phenomenon depends on the history of flow pattern as the change of curvature of interphase surface which leads to the surface tension. Additionally, the applicability and accuracy of the present numerical simulation were validated by using the existing experimental and theoretical studies with smooth wall surface. Secondary, referring to the texture geometry used in an industrial packing element, the present simulations showed that surface texture treatments added on the wall can improve the prevention of liquid channeling and can increase the wetted area.


Author(s):  
N.I. Mikheev ◽  
V.M. Molochnikov ◽  
D.V. Kratirov ◽  
O.A. Dushina ◽  
A.A. Paereliy ◽  
...  

2007 ◽  
Vol 50 (6) ◽  
pp. 641-650
Author(s):  
V. B. Bol’shakov ◽  
N. I. Kosach

Author(s):  
Yuanyuan Chen ◽  
Jing Gong ◽  
Xiaoping Li ◽  
Nan Zhang ◽  
Shaojun He ◽  
...  

Pipeline commissioning, which is a key link from engineering construction to production operation, is aim to fill an empty pipe by injecting water or oil to push air out of it. For a large-slope crude oil pipeline with great elevation differences, air is fairly easy to entrap at downward inclined parts. The entrapped air, which is also called air pocket, will cause considerable damage on pumps and pipes. The presence of it may also bring difficulties in tracking the location of the liquid head or the interface between oil and water. It is the accumulated air that needed to be exhausted in time during commissioning. This paper focuses on the simulation of liquid-gas replacement in commissioning process that only liquid flow rate exists while gas stays stagnant in the pipe and is demanded to be replaced by liquid. Few previous researches have been found yet in this area. Consequently, the flow in a V-section pipeline consisted of a downhill segment and a subsequent uphill one is used here for studying both the formation and exhaustion behaviors of the intake air. The existing two-fluid model and simplified non-pressure wave model for gas-liquid stratified flow are applied to performance the gas formation and accumulation. The exhausting process is deemed to be a period in which the elongated bubble (Taylor bubble) is fragmented into dispersed small bubbles. A mathematical model to account for gas entrainment into liquid slug is proposed, implemented and incorporated in a computational procedure. By taking into account the comprehensive effects of liquid flow rate, fluid properties, surface tension, and inclination angle, the characteristics of the air section such as the length, pressure and mass can be calculated accurately. The model was found to show satisfactory predictions when tested in a pipeline. The simulation studies can provide theoretical support and guidance for field engineering application, which are meanwhile capable of helping detect changes in parameters of gas section. Thus corresponding control measures can be adopted timely and appropriately in commissioning process.


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