Research on the Controllable Preparation of Silver Nanowires in Conductive Adhesives

2014 ◽  
Vol 1004-1005 ◽  
pp. 59-62
Author(s):  
Zhao Zhang ◽  
Da Peng Sheng ◽  
Zhao Zhen Wei ◽  
Guo Hui Li ◽  
Yong Li ◽  
...  
Keyword(s):  
Reaction Time ◽  
Reaction Temperature ◽  
Silver Nanowires ◽  
Silver Nanowire ◽  
Conductive Particle ◽  
Conductive Adhesives ◽  
One Dimensional ◽  
Controllable Preparation

One dimensional nanomaterials are used as the basic and significant parts to fabricate nanodevices. Silver nanowire is a promising conductive particle, which can be used in conductive adhensives. The research is about the effects of the control agents, reaction temperature, and reaction time on the morphology and size of the product. And figure out an effective way to control the nucleation and the morphology of silver nanowires.

Well-controlled silver nanowire/graphene hybrid from full solution process

2016 ◽  
Vol 51 (8) ◽  
pp. 1149-1154 ◽  
Author(s):  
Jeong Eon Park ◽  
Dong Hack Suh
Keyword(s):  
Mass Production ◽  
Silver Nanowires ◽  
Solution Process ◽  
Silver Nanowire ◽  
Ultrasonic Power ◽  
Two Dimensional ◽  
One Dimensional ◽  
Conductive Materials ◽  
Full Solution

The surface of a one-dimensional silver nanowire was covered with amphiphilic materials, N-(2-aminoethyl)-3a-hydroxy-5b-cholan-24-amide, and patched with two-dimensional graphene to form individually controlled hybrid. Graphene was prepared from ultrasonic in o-dichlorobenzene without any additives. As N-(2-aminoethyl)-3a-hydroxy-5b-cholan-24-amide between silver nanowires and graphene tightly held each other, silver nanowire was individually covered with graphene without introducing ultrasonic power, the necessary process to evenly mix silver nanowires and graphene but lead to damage and oxidize silver nanowires. Although the quality of graphene was inferior, the properties of hybrid were superior compared with pristine silver nanowire/graphene except introducing N-(2-aminoethyl)-3a-hydroxy-5b-cholan-24-amide. All processes to form the hybrid were carried out in solution. Therefore, this makes the processes less expensive and more useful and opens up opportunities for the mass production for conductive materials.

scholarly journals Synthesis and electrical properties of silver nanoplates for electronic applications

2015 ◽  
Vol 33 (2) ◽  
pp. 242-250 ◽  
Author(s):  
Nana Xiong ◽  
Zhili Li ◽  
Hui Xie ◽  
Yuzhen Zhao ◽  
Mei Li ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Reaction Time ◽  
Ferric Chloride ◽  
Reaction Temperature ◽  
Curing Temperature ◽  
Sintering Behavior ◽  
Conductive Adhesives ◽  
Silver Nanoplates ◽  
Vis Spectroscopy ◽  
Silver Flakes

AbstractIn this paper, silver nanoplates of 100 to 500 nm size were synthesized by reduction of silver nitrate with N,Ndimethylformamide, using poly(vinylpyrolidone) as a surfactant and ferric chloride as a controlling agent, at 120 to 160 °C for 5 to 24 hours. The influence of the concentration of ferric chloride, the reaction temperature and reaction time on the morphology of the product has been investigated by transmission electron microscopy, scanning electron microscopy and UV-Vis spectroscopy. The results indicated that the products obtained at the low reaction temperature and short reaction time in the presence of FeCl3 in the reaction solution were in the form of silver nanoplates, whose morphology was mainly triangular and hexagonal. In addition, the size and thickness of the nanoplates increased with increasing of the FeCl3 concentration. At a high reaction temperature and long reaction time, the truncated triangle and hexagonal nanoplates were mainly produced. Furthermore, the sintering behavior of nanoplates was studied and the results showed that sintering of the silver nanoplates started at 180 °C, and a typical sintering behavior was observed at higher temperatures. The incorporation of the silver nanoplates into the polymer matrix with micro-sized silver flakes led to an increase in the matrix resistivity in almost all cases, especially at high fractions and low curing temperatures. The curing temperature had an influence on the resistivity of the conductive adhesives filled with micro-sized silver flakes and silver nanoplates due to sintering of the silver nanoplates.

Preparation and Antibacterial Properties of Silver Nanowires

2019 ◽  
Vol 944 ◽  
pp. 686-691 ◽  
Author(s):  
Yi Han Zhou
Keyword(s):  
Reaction Time ◽  
Reaction Temperature ◽  
Silver Nanowires ◽  
Antibacterial Properties ◽  
Chemical Properties ◽  
Silver Ions ◽  
Silver Wire ◽  
Polyol Method ◽  
Silver Particles ◽  
Nano Silver

Silver ions have superior bactericidal properties, and their bactericidal activity ranks second among all metals (mercury ranks first, toxic, not used now). Due to its unique physical and chemical properties, nano-silver has also received increasing attention from researchers, and its antibacterial properties are far superior to traditional silver ion bactericides, such as silver nitrate and silver sulfadiazine. But the properties and performance of nanosilver materials depend on their size and morphology.In this paper, the nano-silver line was prepared by the polyol method. By controlling the ratio of AgNO3and PVP, the concentration of NaCl and the acidity and alkalinity of the reaction solution, the effects of reaction time and reaction temperature on the morphology and diameter of the silver wire were investigated. The antibacterial properties of nanosilver were determined by the perforation inhibition method. The experimental results showed that as the reaction temperature increased, the silver particles in the product decreased significantly, the diameter of the silver wire tended to be uniform, but the diameter increased. Finally, the optimal reaction temperature for preparing the silver oxide wire by the polyol method was 150 °C, the reaction time was 10 hours, and the diameter of the silver wire was 100 nm to 200 nm. Based on the measurement of the antibacterial diameter of nano-silver with different morphologies on Escherichia coli and Staphylococcus aureus, it can be found that nano-silver with different morphologies has excellent antibacterial effect, and silver cube is superior to silver particles and nano-silver lines.

scholarly journals Recycling silver nanoparticle debris from laser ablation of silver nanowire in liquid media toward minimum material waste

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
June Sik Hwang ◽  
Jong-Eun Park ◽  
Gun Woo Kim ◽  
Hyeono Nam ◽  
Sangseok Yu ◽  
...  
Keyword(s):  
Laser Ablation ◽  
Silver Nanoparticle ◽  
Building Materials ◽  
Raw Materials ◽  
Silver Nanowires ◽  
Silver Nanowire ◽  
Liquid Media ◽  
Ag Nps ◽  
Laser Patterning ◽  
Inexpensive Procedure

AbstractAs silver nanowires (Ag NWs) are usually manufactured by chemical synthesis, a patterning process is needed to use them as functional devices. Pulsed laser ablation is a promising Ag NW patterning process because it is a simple and inexpensive procedure. However, this process has a disadvantage in that target materials are wasted owing to the subtractive nature of the process involving the removal of unnecessary materials, and large quantities of raw materials are required. In this study, we report a minimum-waste laser patterning process utilizing silver nanoparticle (Ag NP) debris obtained through laser ablation of Ag NWs in liquid media. Since the generated Ag NPs can be used for several applications, wastage of Ag NWs, which is inevitable in conventional laser patterning processes, is dramatically reduced. In addition, electrophoretic deposition of the recycled Ag NPs onto non-ablated Ag NWs allows easy fabrication of junction-enhanced Ag NWs from the deposited Ag NPs. The unique advantage of this method lies in using recycled Ag NPs as building materials, eliminating the additional cost of junction welding Ag NWs. These fabricated Ag NW substrates could be utilized as transparent heaters and stretchable TCEs, thereby validating the effectiveness of the proposed process.

scholarly journals Effects of Concentration and Spin Speed on the Optical and Electrical Properties of Silver Nanowire Transparent Electrodes

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2219
Author(s):  
Xiaopeng Li ◽  
Jiayue Zhou ◽  
Dejun Yan ◽  
Yong Peng ◽  
Yong Wang ◽  
...  
Keyword(s):  
Sheet Resistance ◽  
Spin Coating ◽  
Figure Of Merit ◽  
Silver Nanowires ◽  
Solution Concentration ◽  
Ethanol Solution ◽  
Silver Nanowire ◽  
Optical And Electrical Properties ◽  
Transparent Electrodes ◽  
Spin Speed

In this paper, silver nanowires (AgNWs) with a diameter of 40 nm and a length of 45 μm were dispersed into an ethanol solution to prepare AgNW solutions with concentrations of 1, 2, and 3 mg/mL, respectively. The AgNW solutions were then deposited on a glass substrate using spin-coating at 1000, 2000, and 3000 rpm for 45 s, respectively, to prepare transparent electrodes. The results showed that the distribution of AgNWs on the substrate increased in density with the increase in the AgNW solution concentration and the decrease in spin speed. The effect of concentration on the distribution of AgNWs was greater than that of the spin speed. The transmittance of each electrode was between 84.19% and 88.12% at 550 nm, the average sheet resistance was between 20.09 and 358.11 Ω/sq, the highest figure of merit (FoM) was 104.42, and the lowest haze value was 1.48%. The electrode prepared at 1000 rpm with a concentration of 2 mg/mL and that prepared at 3000 rpm with a concentration of 3 mg/mL were very similar in terms of the average sheet resistance, transmittance at 550 nm, FoM, and haze value; thus, these two electrodes could be considered equivalent. The haze value of the electrode was positively correlated with the spin speed at low concentration, but that relationship became inverse as the concentration rose. For the AgNWs used in this experiment with an aspect ratio of 1125, the concentration of the AgNW solution should reach at least 2 mg/mL to ensure that the FoM of the electrode is greater than 35.

Optimization of Magnesium Separation and Extraction from Boron Slurry Using Response Surface Methodology

2011 ◽  
Vol 366 ◽  
pp. 366-369
Author(s):  
Feng Gao ◽  
Rong Fu ◽  
Ming Yang Qian ◽  
Zhu Min Wang ◽  
Xiang Zhang
Keyword(s):  
Response Surface Methodology ◽  
Reaction Time ◽  
Factorial Design ◽  
Response Surface ◽  
Reaction Temperature ◽  
Fractional Factorial Design ◽  
Design Criterion ◽  
Fractional Factorial ◽  
Effective Factors

Response surface methodology was used to optimize the soaking Mg leaching ratio from the boron slurry screened by 25 fractional factorial design. Five effective factors such as H2SO4 concentrations, reaction time, reaction temperature and stir velocity were tested by using 25 fractional factorial design criterion and three effective factors H2SO4 concentrations, reaction time and reaction temperature showed significant effect(P2SO4 concentrations of 0.29mol/l, reaction time of 90 min and reaction temperature of 50°C. Three runs of additional confirmation experiments were conducted. The mixture magnesium leaching value was 58.20%.

Ring-Opening Polymerization of Lactide Using Aluminum Salen-Type Initiators

2014 ◽  
Vol 915-916 ◽  
pp. 713-716
Author(s):  
Qing Zhang ◽  
Jing Tian ◽  
Zhi Qi Cao ◽  
Ru Xia Xu ◽  
Zhen Zhen Sun ◽  
...  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Infrared Spectroscopy ◽  
Reaction Time ◽  
Magnetic Resonance ◽  
Schiff Bases ◽  
Reaction Temperature ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Resonance Spectroscopy ◽  
Aluminum Complex

In this investigation, Schiff bases aluminum complex was synthesized and used as the initiator in the polymerization of D,L-lactide. The aluminum complex was characterized by infrared spectroscopy (IR), and nuclear magnetic resonance spectroscopy (NMR). The influences of different factors, including reaction time, reaction temperature, and the ratio of D, L-lactide/Al3+ on the synthesis of polylactide were described. The results showed that Schiff bases aluminum complex could be successfully applied in the ring opening polymerization. The optimum condition of the ring opening polymerization of D,L-lactide, which included D,L-lactide/Al3+ (mol/mol) ratio of 250, reaction temperature of 120 °C, and reaction time of 16 hours.

scholarly journals Synthesis of propylene carbonate from urea and 1,2-propylene glycol over metal carbonates

2011 ◽  
Vol 17 (3) ◽  
pp. 323-331 ◽  
Author(s):  
Jiancheng Zhou ◽  
Wu Dongfang ◽  
Birong Zhang ◽  
Yali Guo
Keyword(s):  
Reaction Time ◽  
Propylene Glycol ◽  
Propylene Carbonate ◽  
Reaction Temperature ◽  
Reaction Conditions ◽  
Lead Carbonate ◽  
Synthetic Process ◽  
Metal Carbonates ◽  
Optimal Reaction ◽  
Mixed Carbonate

A series of single-metal carbonates and Pb-Zn mixed-metal carbonates were prepared as catalysts for alcoholysis of urea with 1,2-propylene glycol (PG) for the synthesis of propylene carbonate (PC). The mixed carbonates all show much better catalytic activities than the single carbonates, arising from a strong synergistic effect between the two crystalline phases, hydrozincite and lead carbonate. The mixed carbonate with Pb/Zn=1:2 gives the highest yield of PC, followed by the mixed carbonate with Pb/Zn=1:3. Furthermore, Taguchi method was used to optimize the synthetic process for improving the yield of PC. It is shown that the reaction temperature is the most significant factor affecting the yield of PC, followed by the reaction time, and that the optimal reaction conditions are the reaction time at 5 hours, the reaction temperature at 180 oC and the catalyst amount at 1.8 wt%, resulting in the highest PC yield of 96.3%.

Hydrothermal Sintering under Mild Temperature Conditions: Preparation of Calcium-deficient Hydroxyapatite Compacts

2010 ◽  
Vol 65 (8) ◽  
pp. 1038-1044 ◽  
Author(s):  
Kazumichi Yanagisawa ◽  
Jae-Hyen Kim ◽  
Chisato Sakata ◽  
Ayumu Onda ◽  
Eri Sasabe ◽  
...  
Keyword(s):  
Reaction Time ◽  
Reaction Temperature ◽  
Hot Pressing ◽  
Reaction Parameter ◽  
High Bulk Density ◽  
Temperature And Pressure ◽  
Mild Temperature ◽  
Short Time ◽  
High Bulk ◽  
Dissolution And Precipitation

Calcium-deficient hydroxyapatite (CDHA) prepared by the coprecipitation method was solidified by the hydrothermal hot-pressing technique, and compacts of CDHA with high bulk density beyond 80% were obtained at 200 ℃. Each reaction parameter, viz. reaction temperature, pressure, and time, was systematically changed from the standard conditions to investigate its effects on density, Vickers hardness, and Ca/P ratio of the compacts obtained. The reaction temperature and pressure had a large effect on densification, but not the reaction time because the densification proceeds in a short time. The densification by hydrothermal hot-pressing involved dissolution and precipitation of the starting CDHA powder, so that the Ca/P ratio changed from 1.52 of the starting powders to 1.61 of the compact obtained by hydrothermal hot-pressing at 200 ℃ and 35 MPa for 24 h with the addition of 10 wt.-% water

scholarly journals Optimization of Synthesis of Seleno-Sargassum fusiforme(Harv.) Setch. Polysaccharide by Response Surface Methodology, Its Characterization, and Antioxidant Activity

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Yu-Bin Ji ◽  
Fang Dong ◽  
Miao Yu ◽  
Long Qin ◽  
Dan Liu
Keyword(s):  
Antioxidant Activity ◽  
Response Surface Methodology ◽  
Reaction Time ◽  
Response Surface ◽  
Reaction Temperature ◽  
Sargassum Fusiforme ◽  
Synthesis Conditions ◽  
Optimum Reaction ◽  
Series Of Experiments

The response surface methodology was employed to optimize the synthesis conditions of seleno-Sargassum fusiforme(Harv.) Setch. polysaccharide. Three independent variables (reaction time, reaction temperature, and ratio of Na2SeO3to SFPSI) were tested. Furthermore, the characterization and antioxidant activity of Se-SFPSIin vivowere investigated. The result showed that the actual experimental Se content of Se-SFPSI was 3.352 mg/g at the optimum reaction conditions of reaction time 8 h, reaction temperature 71°C, and ratio of Na2SeO3to SFPSIB 1.0 g/g. A series of experiments showed that the characterization of Se-SFPSIB was significantly different from that of SFPSIB. Additionally, antioxidant activity assay indicated that the Se-SFPSIB could increase catalase (CAT), superoxide dismutase (SOD), and glutathione peroxidase (GSH-Px) activity of mice bearing tumor S180in blood, heart, and liver while decreasing malondialdehyde (MDA) levels. It can be concluded that selenylation is a feasible approach to obtain seleno-polysaccharide which was utilized as highly biological medicine or functional food.

Sign in / Sign up

Export Citation Format

Share Document