scholarly journals Recycling silver nanoparticle debris from laser ablation of silver nanowire in liquid media toward minimum material waste

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
June Sik Hwang ◽  
Jong-Eun Park ◽  
Gun Woo Kim ◽  
Hyeono Nam ◽  
Sangseok Yu ◽  
...  
Keyword(s):  
Laser Ablation ◽  
Silver Nanoparticle ◽  
Building Materials ◽  
Raw Materials ◽  
Silver Nanowires ◽  
Silver Nanowire ◽  
Liquid Media ◽  
Ag Nps ◽  
Laser Patterning ◽  
Inexpensive Procedure

AbstractAs silver nanowires (Ag NWs) are usually manufactured by chemical synthesis, a patterning process is needed to use them as functional devices. Pulsed laser ablation is a promising Ag NW patterning process because it is a simple and inexpensive procedure. However, this process has a disadvantage in that target materials are wasted owing to the subtractive nature of the process involving the removal of unnecessary materials, and large quantities of raw materials are required. In this study, we report a minimum-waste laser patterning process utilizing silver nanoparticle (Ag NP) debris obtained through laser ablation of Ag NWs in liquid media. Since the generated Ag NPs can be used for several applications, wastage of Ag NWs, which is inevitable in conventional laser patterning processes, is dramatically reduced. In addition, electrophoretic deposition of the recycled Ag NPs onto non-ablated Ag NWs allows easy fabrication of junction-enhanced Ag NWs from the deposited Ag NPs. The unique advantage of this method lies in using recycled Ag NPs as building materials, eliminating the additional cost of junction welding Ag NWs. These fabricated Ag NW substrates could be utilized as transparent heaters and stretchable TCEs, thereby validating the effectiveness of the proposed process.

scholarly journals Synthesis of Ag Nanoparticles-Decorated CNTs via Laser Ablation Method for the Enhancement the Photocatalytic Removal of Naphthalene from Water

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 2142
Author(s):  
Fowzia S. Alamro ◽  
Ayman M. Mostafa ◽  
Khulood A. Abu Abu Al-Ola ◽  
Hoda A. Ahmed ◽  
Arafat Toghan
Keyword(s):  
Carbon Nanotubes ◽  
Laser Ablation ◽  
Analytical Techniques ◽  
Spherical Shape ◽  
Liquid Media ◽  
Ag Nps ◽  
Laser Ablation Method ◽  
Vibrational Characteristic ◽  
Photocatalytic Removal ◽  
Disorder Degree

Silver nanoparticles (Ag NPs) were decorated with different amounts on the exterior walls of carbon nanotubes (CNTs) by a laser ablation assisted method, especially in liquid media to be applied as a good adsorption material against naphthalene. The laser ablation time was controlled the amount of decoration Ag NPs on CNTs. The prepared nanocomposite was analyzed via different analytical techniques. Ag NPs with a small size distribution of 29 nm are uniformly decorated with spherical shape on CNTs walls. The disorder degree of tubular structure and shifting of the vibrational characteristic peaks increase with the increase in the decoration of Ag NPs. After that, the prepared samples were investigated for the removal of naphthalene. These studies of loading Ag NPs with different amounts on the surface of CNTs act as a promising material for water treatment.

scholarly journals Thermal Characterization of Recycled Materials for Building Insulation

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3564
Author(s):  
Arnas Majumder ◽  
Laura Canale ◽  
Costantino Carlo Mastino ◽  
Antonio Pacitto ◽  
Andrea Frattolillo ◽  
...  
Keyword(s):  
Environmental Impact ◽  
Environmental Sustainability ◽  
Building Materials ◽  
Raw Materials ◽  
Natural Fibers ◽  
Thermal Characterization ◽  
Recycled Materials ◽  
Building Insulation ◽  
Operational Phase

The building sector is known to have a significant environmental impact, considering that it is the largest contributor to global greenhouse gas emissions of around 36% and is also responsible for about 40% of global energy consumption. Of this, about 50% takes place during the building operational phase, while around 10–20% is consumed in materials manufacturing, transport and building construction, maintenance, and demolition. Increasing the necessity of reducing the environmental impact of buildings has led to enhancing not only the thermal performances of building materials, but also the environmental sustainability of their production chains and waste prevention. As a consequence, novel thermo-insulating building materials or products have been developed by using both locally produced natural and waste/recycled materials that are able to provide good thermal performances while also having a lower environmental impact. In this context, the aim of this work is to provide a detailed analysis for the thermal characterization of recycled materials for building insulation. To this end, the thermal behavior of different materials representing industrial residual or wastes collected or recycled using Sardinian zero-km locally available raw materials was investigated, namely: (1) plasters with recycled materials; (2) plasters with natural fibers; and (3) building insulation materials with natural fibers. Results indicate that the investigated materials were able to improve not only the energy performances but also the environmental comfort in both new and in existing buildings. In particular, plasters and mortars with recycled materials and with natural fibers showed, respectively, values of thermal conductivity (at 20 °C) lower than 0.475 and 0.272 W/(m⋅K), while that of building materials with natural fibers was always lower than 0.162 W/(m⋅K) with lower values for compounds with recycled materials (0.107 W/(m⋅K)). Further developments are underway to analyze the mechanical properties of these materials.

scholarly journals Architectural ruins: geoculture of the anatomy of buildings as illustrated by Casa Ippolito, Malta

2021 ◽  
Vol 9 (1) ◽  
Author(s):  
Lino Bianco
Keyword(s):  
Material Culture ◽  
Building Materials ◽  
Raw Materials ◽  
Primary Source ◽  
Secondary Sources ◽  
Non Invasive ◽  
History Of ◽  
Aerial Vehicle ◽  
Materials Used ◽  
Building Physics

AbstractRuins are a statement on the building materials used and the construction method employed. Casa Ippolito, now in ruins, is typical of 17th-century Maltese aristocratic country residences. It represents an illustration of secondary or anthropogenic geodiversity. This paper scrutinises these ruins as a primary source in reconstructing the building’s architecture. The methodology involved on-site geographical surveying, including visual inspection and non-invasive tests, a geological survey of the local lithostratigraphy, and examination of notarial deeds and secondary sources to support findings about the building’s history as read from its ruins. An unmanned aerial vehicle was used to digitally record the parlous state of the architectural structure and karsten tubes were used to quantify the surface porosity of the limestone. The results are expressed from four perspectives. The anatomy of Casa Ippolito, as revealed in its ruins, provides a cross-section of its building history and shows two distinct phases in its construction. The tissue of Casa Ippolito—the building elements and materials—speaks of the knowledge of raw materials and their properties among the builders who worked on both phases. The architectural history of Casa Ippolito reveals how it supported its inhabitants’ wellbeing in terms of shelter, water and food. Finally, the ruins in their present state bring to the fore the site’s potential for cultural tourism. This case study aims to show that such ruins are not just geocultural remains of historical built fabric. They are open wounds in the built structure; they underpin the anatomy of the building and support insights into its former dynamics. Ruins offer an essay in material culture and building physics. Architectural ruins of masonry structures are anthropogenic discourse rendered in stone which facilitate not only the reconstruction of spaces but also places for human users; they are a statement on the wellbeing of humanity throughout history.

scholarly journals Crushed Bricks: Demolition Waste as a Sustainable Raw Material for Geopolymers

2021 ◽  
Vol 13 (14) ◽  
pp. 7572
Author(s):  
Gigliola D’Angelo ◽  
Marina Fumo ◽  
Mercedes del Rio Merino ◽  
Ilaria Capasso ◽  
Assunta Campanile ◽  
...  
Keyword(s):  
Energy Consumption ◽  
Building Materials ◽  
Mechanical Performance ◽  
Raw Materials ◽  
Construction Material ◽  
Raw Material ◽  
The European Union ◽  
Total Energy Consumption ◽  
Demolition Waste ◽  
Crushed Brick

Demolition activity plays an important role in the total energy consumption of the construction industry in the European Union. The indiscriminate use of non-renewable raw materials, energy consumption, and unsustainable design has led to a redefinition of the criteria to ensure environmental protection. This article introduces an experimental plan that determines the viability of a new type of construction material, obtained from crushed brick waste, to be introduced into the construction market. The potential of crushed brick waste as a raw material in the production of building precast products, obtained by curing a geopolymeric blend at 60 °C for 3 days, has been exploited. Geopolymers represent an important alternative in reducing emissions and energy consumption, whilst, at the same time, achieving a considerable mechanical performance. The results obtained from this study show that the geopolymers produced from crushed brick were characterized by good properties in terms of open porosity, water absorption, mechanical strength, and surface resistance values when compared to building materials produced using traditional technologies.

scholarly journals Effects of Concentration and Spin Speed on the Optical and Electrical Properties of Silver Nanowire Transparent Electrodes

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2219
Author(s):  
Xiaopeng Li ◽  
Jiayue Zhou ◽  
Dejun Yan ◽  
Yong Peng ◽  
Yong Wang ◽  
...  
Keyword(s):  
Sheet Resistance ◽  
Spin Coating ◽  
Figure Of Merit ◽  
Silver Nanowires ◽  
Solution Concentration ◽  
Ethanol Solution ◽  
Silver Nanowire ◽  
Optical And Electrical Properties ◽  
Transparent Electrodes ◽  
Spin Speed

In this paper, silver nanowires (AgNWs) with a diameter of 40 nm and a length of 45 μm were dispersed into an ethanol solution to prepare AgNW solutions with concentrations of 1, 2, and 3 mg/mL, respectively. The AgNW solutions were then deposited on a glass substrate using spin-coating at 1000, 2000, and 3000 rpm for 45 s, respectively, to prepare transparent electrodes. The results showed that the distribution of AgNWs on the substrate increased in density with the increase in the AgNW solution concentration and the decrease in spin speed. The effect of concentration on the distribution of AgNWs was greater than that of the spin speed. The transmittance of each electrode was between 84.19% and 88.12% at 550 nm, the average sheet resistance was between 20.09 and 358.11 Ω/sq, the highest figure of merit (FoM) was 104.42, and the lowest haze value was 1.48%. The electrode prepared at 1000 rpm with a concentration of 2 mg/mL and that prepared at 3000 rpm with a concentration of 3 mg/mL were very similar in terms of the average sheet resistance, transmittance at 550 nm, FoM, and haze value; thus, these two electrodes could be considered equivalent. The haze value of the electrode was positively correlated with the spin speed at low concentration, but that relationship became inverse as the concentration rose. For the AgNWs used in this experiment with an aspect ratio of 1125, the concentration of the AgNW solution should reach at least 2 mg/mL to ensure that the FoM of the electrode is greater than 35.

scholarly journals The Influence of Cement Substitution by Biomass Fly Ash on the Polymer–Cement Composites Properties

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3079
Author(s):  
Beata Jaworska ◽  
Dominika Stańczak ◽  
Joanna Tarańska ◽  
Jerzy Jaworski
Keyword(s):  
Fly Ash ◽  
Building Materials ◽  
Raw Materials ◽  
Combustion Process ◽  
Biomass Combustion ◽  
Cement Composites ◽  
Cement Mortars ◽  
Mineral Additive ◽  
Biomass Fly Ash

The generation of energy for the needs of the population is currently a problem. In consideration of that, the biomass combustion process has started to be implemented as a new source of energy. The dynamic increase in the use of biomass for energy generation also resulted in the formation of waste in the form of fly ash. This paper presents an efficient way to manage this troublesome material in the polymer–cement composites (PCC), which have investigated to a lesser extent. The research outlined in this article consists of the characterization of biomass fly ash (BFA) as well as PCC containing this waste. The characteristics of PCC with BFA after 3, 7, 14, and 28 days of curing were analyzed. Our main findings are that biomass fly ash is suitable as a mineral additive in polymer–cement composites. The most interesting result is that the addition of biomass fly ash did not affect the rheological properties of the polymer–cement mortars, but it especially influenced its compressive strength. Most importantly, our findings can help prevent this byproduct from being placed in landfills, prevent the mining of new raw materials, and promote the manufacture of durable building materials.

Development of Mixture "Clay – Electro-Smelting Slag" for Ceramic Brick

2014 ◽  
Vol 682 ◽  
pp. 480-484 ◽  
Author(s):  
V.F. Torosyan ◽  
E.S. Torosyan
Keyword(s):  
Building Materials ◽  
Raw Materials ◽  
Ceramic Brick ◽  
Ceramic Samples ◽  
Manufactured Products ◽  
Smelting Slag ◽  
Compression Resistance ◽  
Mixing Water ◽  
Melting Slag

Industrial transition to a totally new level of resources and energy saving necessitates improving the technical level of building materials manufacturing, growing their raw materials base, the assortment, enhancing the quality of manufactured products, cutting their cost price. It requires, first of all, carrying out more detailed research in properties of clay and clay loams, and selecting optimal additives for pottery works. Such disadvantages of clays as burning sensitivity, low compression resistance and flexural strength in a burnt state, low frost resistance cause the impossibility of their application without corrective additives. It is quite difficult to find an additive which can solve all the technological problems mentioned above. This paper provides the development of mixture "clay – electro-melting slag" for ceramic brick, moreover, addition of a steel-smelting slag in the fusion mixture results in the change in mixing water content of ceramic masses, strength and coloration of ceramic samples.

scholarly journals Physicochemical Properties of Handere Clays and Their Use as a Building Material

2015 ◽  
Vol 2015 ◽  
pp. 1-6 ◽  
Author(s):  
Yasin Erdoğan
Keyword(s):  
Physicochemical Properties ◽  
Building Materials ◽  
Raw Materials ◽  
Organic Matter Content ◽  
Volcanic Glass ◽  
Mineralogical Composition ◽  
Matter Content ◽  
Loss On Ignition ◽  
X Ray Diffraction ◽  
Clay Deposits

Handere clay deposits were discovered at Adana in Turkey. These clay units primarily consist of uncoloured claystone, pebbly sandstone, sandstone, siltstone, and mudstone marl and include gypsum lenses and clay levels of various thicknesses in places. The physicochemical properties of these clays have been investigated by different techniques including Scanning Electron and Elemental Analysis (SEM and EDS), mineralogical analyses, chemical and physical analyses, X-ray diffraction (XRD), thermogravimetric differential thermal analysis (TG-DTA), and Atterberg (Consistency) Limits Test. The mineralogical composition deduced from XRD is wide (smectite + palygorskite + illite ± feldspar ± chlorite ± quartz ± calcite ± serpentine) due to the high smectite contents (≈85%). SEM studies reveal that smectite minerals are composed of irregular platy leaves and show honeycomb pattern in the form of wavy leaves in places. The leaves presenting an array with surface edge contact are usually concentrated in the dissolution voids and fractures of volcanic glass. Organic matter content and loss on ignition analysis of raw materials are good for all the studied samples. In summary, Handere clays can be used as building materials in bricks, roof tiles, and cement and as a binder.

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