Synthesis and Luminescence Property of Sr3Al2O6:Eu3+ Red Phosph or Prepared by Co-Precipitation Technique

2015 ◽  
Vol 1096 ◽  
pp. 486-491 ◽  
Author(s):  
Hong Mei Gao ◽  
Feng Yun Yan ◽  
Ling He
Keyword(s):  
Emission Spectrum ◽  
Thermal Quenching ◽  
Luminescent Properties ◽  
Average Diameter ◽  
Cubic Phase ◽  
X Ray Diffraction ◽  
Red Phosphor ◽  
Ultraviolet Excitation ◽  
Near Ultraviolet ◽  
Co Precipitation

Sr3Al2O6:Eu3+ red phosphor was synthesized by co-precipitation and investigated their crystal structures and luminescent properties in detail. EuCl3 was used as rare earth sources to replace Eu2O3, which saving cost significantly. X-ray diffraction(XRD) and scanning electron microscopy (SEM) result indicated that the as-prepared phosphors was calcined at 1150 oC for 2h crystalized in cubic phase with space group of Pa-3 and uniform morphology. The average diameter of the phosphors were 1.8um. Excitation spectrum and emission spectrum results shows when Boric acid was added 3wt% and Eu3+ was added x=0.04((Sr1-xEux)3Al2O6), the red emission of Eu3+ centers was shown at peak of 611nm under near ultraviolet excitation with wavelength of 393nm. The emission spectrum was line spectrum. Luminous intensity achieved the optimum. The thermal quenching experiments indicated that it had thermal stability in the temperature of 20 oC -80 oC.

Fabrication and Up-Conversion Luminescence of Er3+:Y2O3 Nanoparticles

2008 ◽  
Vol 8 (3) ◽  
pp. 1211-1213 ◽  
Author(s):  
Luo Jun-Ming ◽  
Li Yong-Xiu ◽  
Deng Li-Ping ◽  
Yuan Yong-Rui ◽  
Chen Wei-Fan
Keyword(s):  
Doping Concentration ◽  
Green Emission ◽  
Average Diameter ◽  
Precipitation Method ◽  
Cubic Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Radiative Transitions ◽  
Transmission Electron ◽  
Co Precipitation

Y2O3 nanoparticles doped with different concentrations of Er3+ were prepared by the co-precipitation method. X-ray diffraction and transmission electron microscopy results show that Er3+ dissolves completely in the Y2O3 cubic phase. The Er3+:Y2O3 nanoparticles are homogeneous in size and nearly spherical, and the average diameter of the particles after being calcined at 1,000 °C for 2 h is in the range of 40–60 nm. When Er3+:Y2O3 nanoparticles are excited under a 980 nm diode laser, there are two main emission bands: green emission centered at 562 nm corresponding to the 4S3/2/2H11/2 → 4I15/2 radiative transitions and red emission centered at 660 nm corresponding to the 4F9/2 ∼ 4I15/2 radiative transitions. By changing the doping concentration of Er3+ ions, the up-conversion luminescence can be gradually tuned from green to red.

Highly efficient green-emitting phosphor Sr4Al14O25:Ce,Tb with low thermal quenching and wide color gamut upon UV-light excitation for backlighting display applications

2020 ◽  
Author(s):  
Haoran Li ◽  
Yujun Liang ◽  
Shiqi Liu ◽  
Weilun Zhang ◽  
Yanying Bi ◽  
...  
Keyword(s):  
Performance Enhancement ◽  
Uv Light ◽  
Thermal Quenching ◽  
High Response ◽  
Color Gamut ◽  
Ultraviolet Excitation ◽  
Highly Efficient ◽  
Near Ultraviolet ◽  
Wide Color Gamut ◽  
Light Excitation

Highly-efficient and stable inorganic phosphors with high response to near-ultraviolet excitation are essential to the performance enhancement of the phosphor converted backlighting devices. Herein, highly-efficient green-emitting phosphors Sr4Al14O25:Ce,Tb (SAO:Ce3+,Tb3+) with...

Preparation and Luminescence Properties of Sr2CeO4 Doped with Ho3+

2013 ◽  
Vol 591 ◽  
pp. 272-276
Author(s):  
Fang Zhang ◽  
Chao Song ◽  
Ling Li Ma ◽  
Xiao Li Xu ◽  
Zi Fei Peng
Keyword(s):  
Sintering Temperature ◽  
Average Particle Size ◽  
Average Particle ◽  
X Ray Diffraction ◽  
Solid State Method ◽  
X Ray ◽  
Ultraviolet Excitation ◽  
Near Ultraviolet ◽  
State Method ◽  
Photo Luminescent

Sr2CeO4: Ho3+ was prepared by high-temperature solid-state method. The products were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and photo luminescent (PL). The Sr2CeO4:Ho3+ phosphors showed a red emission under the near-ultraviolet excitation (280 nm) and the main emission centered at 475 nm. It has been found that A+ (A+ = Li+, Na+ or K+) codoped Sr2CeO4: Ho3+ phosphors could lead to a remarkable increase of photoluminescence. Luminous intensity was the highest when doping Li+ ions. Investigation indicated that Sr2Ce0.989O4: 0.001Ho3+, 0.01Li+ exhibited the strongest emission. The average particle size was about 6 um. The optimum sintering temperature was 1200 °C and the possible mechanism was also discussed.

Synthesis, Morphology Control and Luminescent Properties of Rare Earth Ion-Doped CaWO4 Microstructures

2016 ◽  
Vol 16 (4) ◽  
pp. 4029-4034 ◽  
Author(s):  
Chunxia Liu ◽  
Lixia Yang ◽  
Dan Yue ◽  
Mengnan Wang ◽  
Lin Jin ◽  
...  
Keyword(s):  
Rare Earth ◽  
Uv Light ◽  
Luminescent Properties ◽  
Average Diameter ◽  
Rare Earth Ions ◽  
X Ray Diffraction ◽  
Hydrothermal Route ◽  
Rare Earth Ion ◽  
X Ray ◽  
Facile Hydrothermal Route

Rare earth ions (Tb3+, Eu3+) doped CaWO4 microstructures were synthesized by a facile hydrothermal route without using any templates and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence (PL) spectrum. The results indicate that the asprepared samples are well crystallized with scheelite structure of CaWO4, and the average diameter of the microstructures is 2∼4 μm. The morphology of CaWO4:Eu3+ microstructures can be controllably changed from microspheres to microflowers through altering the doping concentration of Eu3+ from 3% to 35%, and the microflowers are constructed by a number of CaWO4:Eu3+ nanoflakes. Under the excitation of UV light, the emission spectrum of CaWO4:Eu3+ is composed of the characteristics emission of Eu3+ 5D0-7FJ (J = 1, 2, 3, 4) transitions, and that of CaWO4:Tb3+ is composed of Tb3+ 5D4-7FJ (J = 6, 5, 4, 3) transitions. Both of the optimal doping concentrations of Tb3+ and Eu3+ in CaWO4 microstructures are about 5%.

Synthesis and luminescence properties of the red phosphor CaZrO3:Eu3+ for white light-emitting diode application

Open Physics ◽  
2011 ◽  
Vol 9 (4) ◽  
Author(s):  
Junli Huang ◽  
Liya Zhou ◽  
Yuwei Lan ◽  
Fuzhong Gong ◽  
Qunliang Li ◽  
...  
Keyword(s):  
White Light ◽  
Light Emitting Diode ◽  
Red Light ◽  
Average Diameter ◽  
Xrd Analysis ◽  
X Ray Diffraction ◽  
Solid State Method ◽  
Light Emitting ◽  
Near Ultraviolet ◽  
Light Region

AbstractEu3+-doped CaZrO3 phosphor with perovskite-type structure was synthesized by the high temperature solid-state method. The samples were characterized by X-ray diffraction, scanning electron microscopy, fluorescence spectrophotometer and UV-vis spectrophotometer, respectively. XRD analysis showed that the formation of CaZrO3 was at the calcinations temperature of 1400°C. The average diameter of CaZrO3 with 4 mol% doped-Eu3+ was 2µm. The PL spectra demonstrated that CaZrO3:Eu3+ phosphor could be excited effectively in the near ultraviolet light region (397 nm) and emitted strong red-emission lines at 616 nm corresponding to the forced electric dipole 5 D 0 → 7 F 2 transitions of Eu3+. Meanwhile, the light-emitting diode was fabricated with the Ca0.96ZrO3:Eu0.043+ phosphor, which can efficiently absorb ∼ 400 nm irradiation and emit red light. Therefore Ca0.96ZrO3:Eu0.043+ may have applications for a near ultraviolet InGaN chip-based white light-emitting diode.

Synthesis and upconversion luminescence properties of CaF2:Yb3+,Er3+ nanoparticles obtained from SBA-15 template

2010 ◽  
Vol 25 (10) ◽  
pp. 2035-2041 ◽  
Author(s):  
Zhiguo Xia ◽  
Peng Du
Keyword(s):  
Electron Microscopy ◽  
Upconversion Luminescence ◽  
Emission Spectra ◽  
Average Diameter ◽  
Cubic Phase ◽  
Pumping Power ◽  
X Ray Diffraction ◽  
Temperature Dependent ◽  
X Ray ◽  
Transmission Electron

CaF2:Yb3+,Er3+ upconversion (UC) luminescence nanoparticles have been synthesized using mesoporous silica (SBA-15) as a hard template. The samples were characterized by x-ray diffraction, Fourier transform infrared spectra, field-emission scanning electron microscopy, transmission electron microscopy, and UC emission spectra, respectively. Highly crystalline cubic phase CaF2:Yb3+,Er3+ nanoparticles are uniformly distributed with an average diameter of about 40–50 nm, and the formation process is also demonstrated. The UC fluorescence has been realized in the as-prepared CaF2:Yb3+,Er3+ nanoparticles on 980-nm excitation. The UC emission transitions for 4F9/2–4I15/2 (red), 2H11/2–4I15/2 (green), 4S3/2–4I15/2 (green), and 2H9/2–4I15/2 (violet) in the Yb3+/Er3+ codoped CaF2 nanoparticles depending on pumping power and temperature have been discussed. The UC mechanism, especially the origin on the temperature-dependent UC emission intensities ratio between 2H11/2 and 4S3/2 levels, have been proposed.

Synthesis and Activity of Co-doped Barium Cerium Zirconate for Hydrogen Reforming and Purification

2008 ◽  
Vol 1126 ◽  
Author(s):  
Aravind Suresh ◽  
Joysurya Basu ◽  
Nigel M Sammes ◽  
Barry C Carter ◽  
Benjamin A Wilhite
Keyword(s):  
Hydrogen Generation ◽  
Ac Impedance ◽  
Cubic Phase ◽  
X Ray Diffraction ◽  
Ac Impedance Spectroscopy ◽  
Methanol Partial Oxidation ◽  
Transmission Electron ◽  
Catalytically Active ◽  
Different Temperatures ◽  
Co Precipitation

AbstractBaCe0.25Zr0.60Co0.15O3-x (BCZC) was synthesized via oxalate co-precipitation route. Material was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Catalytic activity of BCZC with respect to hydrogen generation via methanol partial oxidation was determined. Conductivity of the material at different temperatures and under different environments was determined by AC impedance spectroscopy. XRD and TEM results indicated that BCZC was synthesized as a homogeneous cubic phase material. Catalyst tests indicated that BCZC was catalytically active towards hydrogen generation and AC impedance results were positive enough to warrant further electrochemical studies.

Luminescent properties of Y2O3:Eu3+ nanophosphor prepared from urea added precursor using flame spray pyrolysis

2009 ◽  
Vol 24 (8) ◽  
pp. 2584-2588 ◽  
Author(s):  
Jae Seok Lee ◽  
Se Jin Kim ◽  
Tae Kon Kim ◽  
Rajiv K. Singh ◽  
Madhav B. Ranade
Keyword(s):  
Electron Microscopy ◽  
Spray Pyrolysis ◽  
Red Light ◽  
Luminescent Properties ◽  
Flame Spray Pyrolysis ◽  
Cubic Phase ◽  
Flame Spray ◽  
X Ray Diffraction ◽  
Synthesis Conditions ◽  
Transmission Electron

Y2O3:Eu3+ nanophosphor was synthesized by flame spray pyrolysis (FSP) from urea added nitrate based liquid precursor. In this study, urea serves as fuel and subsequently provides additional heat in the flame zone during the synthesis of phosphor particles. The end product shows cubic phase Y2O3:Eu3+ nanophosphor successfully prepared by FSP without heat treatment. The influence of synthesis conditions such as different mol of urea and nitrate source materials in aqueous solution, and doping concentration on luminescent properties, were investigated. The characteristics of nanophosphor such as crystallinity and morphology under various experiments of conditions were carried out by x-ray diffraction (XRD) and field emission-scanning electron microscopy (FE-SEM). The particle size of product was found to be in the range of 20–30 nm from transmission electron microscopy (TEM). In photoluminescence (PL) properties, Y2O3:Eu3+ nanophosphor emitted red light with a peak wavelength of 609 nm when excited with 398 nm wavelength photons.

Synthesis and Up-Conversion Luminescent Properties of Na(Y1.5Na0.5)F6 Hexagonal Prism

2016 ◽  
Vol 697 ◽  
pp. 318-321
Author(s):  
Cui Ping Zhong ◽  
Jie Jun Zhang ◽  
Shu Wang Duo
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Chelating Agent ◽  
Luminescent Properties ◽  
Hexagonal Prism ◽  
X Ray Diffraction ◽  
X Ray ◽  
Near Ultraviolet ◽  
Fluorescence Spectrometer ◽  
Scanning Electron

Na (Y1.5Na0.5)F6 microparticks were prepared by hydrothermal method. EDTA as the chelating agent. The samples were characterized by X-ray diffraction, scanning electron microscopy and fluorescence spectrometer. The X-ray diffraction indicates that the crystal shows a hexagon phase structure. Under the excitation of 980nm laser, the Na (Y1.5Na0.5)F6 exhibited strong up-conversion light: 4F9/2→4I15/2(red), 4H11/2/4S3/2→4I15/2(green) and 4G11/2→2H9/2 (near-ultraviolet).

A novel orange-red phosphor Ca3B2O6:Sm3+, A+(A = Li, Na, K) for white light emitting diodes

2014 ◽  
Vol 07 (03) ◽  
pp. 1450033 ◽  
Author(s):  
Qingbo Liu ◽  
Yufeng Liu ◽  
Fu Yang ◽  
Bing Han ◽  
Hao Feng ◽  
...  
Keyword(s):  
Emission Spectrum ◽  
Integral Intensity ◽  
Red Light ◽  
Red Phosphor ◽  
Light Emitting ◽  
Red Phosphors ◽  
Near Ultraviolet ◽  
Bright Orange ◽  
Cie Chromaticity ◽  
White Light Emitting Diodes

A novel orange-red phosphor Ca 3 B 2 O 6: Sm 3+, A+( A = Li , Na , K ) has been synthesized by solid-state reaction at 950°C. The phase purity and photoluminescence (PL) behavior of the phosphor are studied in detail using the powder X-ray diffraction (XRD) technique and PL measurements. Ca 3 B 2 O 6: Sm 3+ phosphor can be efficiently excited by near ultraviolet (n-UV) and blue light, and the emission spectrum consists of four emission peaks at 563, 599, 646 and 709 nm, generating bright orange-red light. When a cation A+ is introduced into Ca 3 B 2 O 6: Sm 3+ as charge compensator, the emission intensity of Ca 3 B 2 O 6: Sm 3+ is evidently enhanced, but the PL spectral profile is unchanged. The integral intensity of the emission spectrum of Ca 2.96 Sm 0.02 Na 0.02 B 2 O 6 excited at 401 nm is about 1.2 times than that of Y 2 O 2 S : Eu 3+ commercial red phosphor. The CIE chromaticity coordinates of Ca 2.96 Sm 0.02 Na 0.02 B 2 O 6 phosphor were (0.608, 0.365), which are close to that of the commercial red phosphors Y 2 O 3: Eu 3+ (0.655, 0.345), Y 2 O 2 S : Eu 3+ (0.622, 0.351) and Sr 2 Si 5 N 8: Eu 2+ (0.620, 0.370).

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