The Preparation of Coatings with Codepositon Plating on A3 Steel and its Corrosion Resistance

2010 ◽  
Vol 150-151 ◽  
pp. 1034-1038
Author(s):  
Shang Dong Chen ◽  
Ting Sun ◽  
Hong Nian

A new method for preparation of coatings with codeposition plating on the ordinary A3 steel and heat treatment later. Research the coatings on electrochemical corrosion behavior variation in Q-sun. Results show that corrosion potential shuffle, corrosion current density reduced nearly two number magnitudes value, polarization resistance increased, the cathode polarization effect enhanced obviously in polarization curves, and self-corrosion current reduced, impedance increased twenty times in alternating current impedance atlas than A3 steel substrate without coatings. It was indicated that the coating improve effectively the corrosion resistance of plain carbon steel.

2017 ◽  
Vol 62 (4) ◽  
pp. 2101-2106
Author(s):  
M. Kciuk ◽  
S. Lasok

AbstractThe paper presents the influence of heat treatment on the structure and corrosion resistance of X5CrNi18-10 steel. To determine the structure which has been obtained after heat treatment the methods of light and scanning electron microscopy with EDS microanalysis were used. The electrochemical corrosion properties of the investigated steel were studied in 3.5% NaCl solution using potentiodynamic polarization tests. Basing on the registered curves, the corrosion current, polarization resistance and corrosion potential were determined. The corrosion tests were followed by fractographic researches.


2009 ◽  
Vol 79-82 ◽  
pp. 1075-1078
Author(s):  
Nai Ming Lin ◽  
Fa Qin Xie ◽  
Tao Zhong ◽  
Xiang Qing Wu ◽  
Wei Tian

The rare earth (RE) modified chromizing coating was obtained on P110 oil casing tube steel (P110 steel) substrate by means of pack cementation technique to enhance the resistance against corrosion of P110 steel. Scanning Electron Microscopy (SEM), Energy Dispersive X-ray analysis (EDX) and X-ray diffraction (XRD) were employed to research microstructure, composition distribution and phase constitution of the chromizing coating. The effect of minor addition of RE on the microstructure of chromizing was discussed. Corrosion resistance of chromizing coating was investigated and compared with that of bare P110 steel via electrochemical corrosion and immersion corrosion in simulated oilfield brine solution, respectively. The results showed that a uniform, continuous and compact coating was formed on P110 steel. The coating with RE addition was more compact than that of the coating added no RE, and a small amount of RE addition could promote the chromizing procedure notably. From SEM and EDX investigation, it had been confirmed that the coating was composed of two different layers, an out layer and an inner layer; the coating mainly contains Fe and Cr; the concentration of Cr decreased as the distance from the surface increased, yet Fe presented the inverse trend. XRD analysis indicated the coating was built up by (Cr, Fe)23C6 referring to the out layer, (Cr, Fe)7C3, Cr7C3 and α-(Cr, Fe) corresponding to the inner layer. Electrochemical corrosion consequence was obtained as follows: the self-corroding electric potential of chromizing coating was higher, and the corrosion current density was lower than that of bare P110 steel, which revealed that chromizing coating had better anti-corrosion performance; immersion corrosion results demonstrated the mass loss of chromized P110 steel was lower, and this meant that chromizing coating had a better corrosion resistance than that of bare P110 steel on the experimental condition. A compact (Cr, Fe)xCy coating can be fabricated by pack cementation technique. As a result of minor RE addition, microstructure and corrosion resistance of the chromizing coating are improved obviously.


2011 ◽  
Vol 189-193 ◽  
pp. 571-574
Author(s):  
Peng Li

HIPIB irradiation experiment is carried out at a specific ion current density of 1.1 J/cm2 with shot number from one to ten in order to explore the effect of shot number on electrochemical corrosion behavior of magnesium alloy. Surface morphologies, microstructure and corrosion resistance of the irradiated samples are examined by scanning electron microscopy (SEM), transmission electron microscope (TEM) and potentiodynamic polarization technique, respectively. It is found that HIPIB irradiation leads to the increase in open circuit potential, corrosion potential and breakdown potential, and the decrease in the corrosion current density and the corrosion rate as compared to the original sample. The improved corrosion resistance is mainly attributed to the grain refinement and surface purification induced by HIPIB irradiation.


CORROSION ◽  
10.5006/3760 ◽  
2021 ◽  
Author(s):  
Thanyalux Wanotayan ◽  
Tongjai Chookajorn ◽  
Sirikarn Sattawitchayapit ◽  
Piya Khamsuk ◽  
Kanokwan Saengkiettiyut ◽  
...  

The effects of alkaline non-cyanide zinc plating bath formulation on the plating characteristics and deposit properties are investigated. Scanning electron microscope and X-ray diffractometer are used to study the surface morphology and texture of the zinc deposits respectively. Uniform and compact coatings with a dominant (110) texture are obtained for all of the bath formulations. Nevertheless, significant differences in surface morphology and relative preferences for the (110) and (100) planes were found to result from the concentrations of zinc and sodium hydroxide in the bath. Electrochemical impedance spectroscopy and potentiodynamic polarization scan were employed to evaluate the corrosion resistance. The coatings with a moderate Zn (8-11 g/L) and controlled NaOH (120 g/L) contents show good corrosion resistance, with the corrosion current and corrosion rate being the lowest at 8 g/L of Zn and 120 g/L of NaOH. The ratio of texture coefficient, morphology, and compressive residual stress from different bath composition contribute to the corrosion resistant property. The findings from this work should provide useful information of electrogalvanized zinc coatings with enhanced corrosion resistance.


1999 ◽  
Vol 14 (2) ◽  
pp. 615-618 ◽  
Author(s):  
Xiao-Ming He ◽  
Li Shu ◽  
Hai-Bo Li ◽  
Duan Weng

ZrC films with high hardness were deposited on A3 steel by ion-beam-assisted deposition and had a corrosion rate more than two orders less and a corrosion potential 0.19 V greater than those of the bare A3 steel. The corrosion current of ZrC films was 10 times less and the polarization resistance at least 7.82 times higher than those of both Teflon and ZrN films, respectively. The experimental results confirmed that ZrC films notably enhanced the corrosion resistance of steels.


2016 ◽  
Vol 44 ◽  
pp. 29-35
Author(s):  
Abul Hossain ◽  
M. A. Gafur ◽  
Fahmida Gulshan ◽  
A. S. W. Kurny

The purpose of this study is to understand the electrochemical corrosion behavior of 1wt% Cu content Al-6Si-0.5Mg alloy in 0.1M NaCl solution. The potentiodynamic polarization curves reveal that 1wt% Cu content alloy is less prone to corrosion than the Cu free alloy. The EIS test results show that corrosion resistance or polarization resistance (Rct) increases with the addition of 1wt% Cu to Al-6Si-0.5Mg alloy. Higher polarization resistance (Rp) has been obtained with the addition of 1wt% Cu to the Al-6Si-0.5Mg alloy. Due to addition of Cu and thermal modification, the magnitude of open circuit potential (OCP), corrosion potential (Ecorr) and pitting corrosion potential (Epit) of Al-6Si-0.5Mg alloy in NaCl solution were shifted to the more noble direction.


Materials ◽  
2018 ◽  
Vol 12 (1) ◽  
pp. 117 ◽  
Author(s):  
Guoqiang Ma ◽  
Qiongyao He ◽  
Xuan Luo ◽  
Guilin Wu ◽  
Qiang Chen

The effect of recrystallization annealing on corrosion behavior of Ta-4%W alloy was studied. It is found that the deformed sample contains high dense dislocations and dislocation boundaries. During annealing, these dislocations and dislocation boundaries are replaced by recrystallizing grains until the alloy is fully recrystallized. Both the anodic dissolution and the cathodic activity is much more blocked. The corrosion potential gradual shift towards negative values and corrosion current density decrease, while polarization resistance increases after annealing, indicating enhanced corrosion resistance of the alloy. Such an enhancement is caused by the increase of low-Σ coincide site lattice boundaries and decrease of dislocations and dislocation boundaries.


2013 ◽  
Vol 328 ◽  
pp. 882-885
Author(s):  
Cun Ren Ma ◽  
Hai Wei Lu ◽  
Guo Hua Lu ◽  
Wei Su ◽  
Tian Sheng Chen ◽  
...  

The electrochemical corrosion behavior of ultra-supercritical unit waterwall tube material in simulated solution of oxygenated treatment (OT) with different concentration of Cl- and SO42- at room temperature was investigated by electrochemical impedance spectroscopy and Tafel slopes. The results showed that the polarization resistance Rp values decreased and corrosion current density (icorr) increased with increasing Cl-/ SO42- concentration in solution. Corrosion potentials (Ecorr) decreased with increasing Cl-/ SO42- concentration in solution.


2014 ◽  
Vol 633 ◽  
pp. 402-405
Author(s):  
Mu Qin Li ◽  
Jiang Liu ◽  
Jun Gang Li ◽  
Ding Sen Cai ◽  
Yong Hui Zhao

Ceramic coatings were fabricated on pure magnesium in silicate electrolyte system by ultrasonic micro-arc oxidation (UMAO) process, and then silica sol (CSG) and HF-CSG treatment were carried out on micro-arc oxidation coatings. The corrosion potential (Ecorr) and corrosion current density (Icorr) of the compound coatings were analyzed by electrochemical corrosion workstation. The corrosive morphology of the coatings was observed by scanning electron microscopy (SEM). Results showed that the Ecorr of the coating with CSG and HF-CSG treatment increased by 55 mV and 69 mV respectively in comparison with that of single UMAO coating, and its Icorr reduced an order of magnitude, which had enhanced the corrosion resistance.


2015 ◽  
Vol 1095 ◽  
pp. 95-98
Author(s):  
Li Ma ◽  
Qiang Hu ◽  
Yan Bin Sun

The electrochemical corrosion behavior of the Sn-8Zn-3Bi-xCu lead-free solder in 3.5%NaCl solution was studied to reveal effect of Cu addition on the corrosion resistance of Sn-8Zn-3Bi solder alloy. The results showed that adding Cu element increased the corrosion potential of Sn-8Zn-3Bi-xCu solder alloysThe corrosion resistance of Sn-8Zn-3Bi-xCu solder alloys was improved correspondingly. The corrousion product of Sn-8Zn-3Bi-xCu alloy was mainly zinc oxide. More corrosion products were observed with the increse of Cu content.


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