Chemical Modification of Poplar Wood on the Mechanical Properties

2011 ◽  
Vol 194-196 ◽  
pp. 1815-1818
Author(s):  
Guo Feng Wu ◽  
Qian Lang ◽  
Bin Wang ◽  
Yi Fei Jiang ◽  
Jun Wen Pu

In this research, the chemical and multilayer hot-press drying was used to modify poplar wood. The timbers were compressed and dried in the multilayer hot-press drying kiln. The combination of chemical modification and hot-press drying can improve the mechanical properties. The influence of chemical and hot-press drying on the compressive strength parallel to grain, the bending strength, the density, the water absorbent and the crystallinity of poplar wood have been investigated in this study. The chemical treated conditions close to real technological regimes selected. The samples were impregnated with three conditions. The samples were dried in a hot-press drying kiln for 130hrs. It was showed that the urea carbamate and hot-press drying treatment increase the properties. The density and mechanical properties increased with increasing urea carbamate, while the water absorption decreased. The crystallinity is 37.03%, 37.11%, 37.78%, separately, compared with the natural wood of 35.09%. The TAG showed the thermal stability increased.

2020 ◽  
pp. 026248932092923
Author(s):  
Chunhui Li ◽  
Haihong Ma ◽  
Zhengfa Zhou ◽  
Weibing Xu ◽  
Fengmei Ren ◽  
...  

Toughing melamine-formaldehyde (MF) rigid closed-cell foams were prepared by using ethylene glycol (EG) and carbon fiber (CF) as composite toughening agents. The pulverization rate, compressive strength, bending strength, cellular structure, closed-cell ratio, water absorption ratio, thermal conductivity, thermal stability, limiting oxygen index (LOI), and char yield were characterized to study the morphology, mechanical, thermal, and fire-retardant properties of as-prepared toughing MF rigid foams. The pulverization rate result showed that introduction of composite modifier can obviously improve the toughness of MF rigid foams. The cellular structure, closed-cell ratio, and water absorption results showed that the addition of EG/CF can increase the closed-cell ratio and control the cell size of MF rigid foams. The compressive strength and bending strength results showed that the incorporation of composite modifier of MF rigid foams dramatically improved the mechanical properties. The LOI, char yield, and thermal stability results showed that the toughing MF rigid foams remained more intact char skeleton with flame-retardant effect, thus reducing the fire hazards. The as-prepared toughing MF rigid foams showed the best comprehensive performance with pulverization rate of 5.21%, compressive strength of 355.3 kPa, bending strength of 0.44 MPa, closed-cell ratio of 79.1%, water absorption of 9%, thermal conductivity of 0.031 W m−1 K−1, and LOI of 39.6%. Compared with unmodified MF rigid foams, toughing rigid closed-cell MF foams possess excellent pulverization rate, compressive strength, bending strength, cellular structure, thermal insulation, and flame retardancy.


Processes ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 588
Author(s):  
Lijie Huang ◽  
Hanyu Zhao ◽  
Hao Xu ◽  
Shuxiang An ◽  
Chunying Li ◽  
...  

Biomass materials have become a research focus for humankind, due to the decreasing availability of fossil fuels and the increasing release of greenhouse gas. In this work, we prepared biodegradable composites with waste cassava residues and polybutylene succinate (PBS) by modifying cassava residues using 4,4’-methylene diisocyanate phenyl ester (MDI) and tested their properties. The effects of MDI modification on the structure, mechanical properties, water absorption, microstructure, and thermal stability of the composites were studied via Fourier transform infrared spectroscopy, contact angle measurement, mechanical property testing, water absorption analysis, scanning electron microscopy, and thermogravimetric analysis, respectively. The results showed that the tensile strength and flexural strength of the material increased by 72% and 20.89%, respectively, when the MDI-modified cassava residue content was 30%. When 10% MDI-modified cassava residues were added, the tensile strength increased by 19.46% from 16.96 MPa to 20.26 MPa, while the bending strength did not change significantly. The water contact angle of the MDI-treated cassava residues exceeded 100°, indicating excellent hydrophobicity. Thus, MDI modification can significantly improve the mechanical properties and thermal stability of the biocomposite. The composites were immersed in distilled water for 96 h. The water absorption of the cassava residues/PBS composite was 2.19%, while that of the MDI-modified cassava residues/PBS composite was 1.6%; hence, the water absorption of the MDI-modified cassava residues/PBS composite was reduced to 26.94%. This technology has wide application potential in packaging, construction, and allied fields.


Author(s):  
O. V. Kovalenko

The technological properties of polymer-cement mixtures and the physical and mechanical properties of polymer-cement waterproofing coatings, depending on their quantitative and qualitative composition: the ratio of cement:sand (C:S), water-cement ratio (W/C) and the content of modifying additives, have been investigated using the method of experimental-statistical modeling. As a result of the implementation of B3 plan and the processing of experimental data, experimental statistical models were obtained that express the effect of the recipy on the properties of polymer-cement waterproofing mixtures and coatings: mobility, compressive strength, bending strength, adhesion and impact strength and water absorption. It was found that having the constant values of C:S and W/C modifying additives, namely redispersing polymer powder, powder polycarboxylate superplasticizer and microsilica are an important factor in the formation of the structure and properties of waterproofing coatings. The analysis of the models showed that the redispersing polymer powder and superplasticizer have a positive effect on he mobility of polymer-cement waterproofing mixtures, while silica fume has a negative effect on this indicator. The effect of modifiers on the physical and mechanical properties of waterproofing coatings is following: redispersing polymer powder and superplasticizer have a negative effect on the compressive strength, while microsilica increases this indicator; redispersing polymer powder and microsilica increase the flexural strength, while the superplasticizer has a negative effect on this indicator; all investigated modifiers increase adhesion and impact strength and decrease water absorption. Based on experimental-statistical models, diagrams were constructed, which are a graphical representation of the effect of the recipe on the properties of polymer-cement waterproofing mixtures, which enables to determine the areas of the recipe use with specified properties.


2021 ◽  
Vol 887 ◽  
pp. 528-535
Author(s):  
V.A. Kalneus ◽  
D.A. Nemushchenko ◽  
V.V. Larichkin ◽  
A.A. Briutov

The article analyses the influence of SiO2 and Al2O3 nanopowders on properties of ceramics consisting of fly ash from thermal power plants, glass waste, and clay binder. Based on studies of physical and mechanical properties of the obtained ceramics (ultimate compressive strength, ultimate three-point bending strength, wear resistance, and water absorption), the paper shows the positive influence of the nanoadditives. The optimal number of SiO2 and Al2O3 nanopowders in the formulation is 0.5 wt. % that has the strongest effect on ultimate compressive strength and water absorption of the fly ash ceramics samples. The direction of further research on improving the properties of ceramic products is an application of the Al2O3 nanopowder as more perspective nanoadditive using clay dispersant.


2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.


Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 220
Author(s):  
Petar Antov ◽  
Viktor Savov ◽  
Ľuboš Krišťák ◽  
Roman Réh ◽  
George I. Mantanis

The potential of producing eco-friendly, formaldehyde-free, high-density fiberboard (HDF) panels from hardwood fibers bonded with urea-formaldehyde (UF) resin and a novel ammonium lignosulfonate (ALS) is investigated in this paper. HDF panels were fabricated in the laboratory by applying a very low UF gluing factor (3%) and ALS content varying from 6% to 10% (based on the dry fibers). The physical and mechanical properties of the fiberboards, such as water absorption (WA), thickness swelling (TS), modulus of elasticity (MOE), bending strength (MOR), internal bond strength (IB), as well as formaldehyde content, were determined in accordance with the corresponding European standards. Overall, the HDF panels exhibited very satisfactory physical and mechanical properties, fully complying with the standard requirements of HDF for use in load-bearing applications in humid conditions. Markedly, the formaldehyde content of the laboratory fabricated panels was extremely low, ranging between 0.7–1.0 mg/100 g, which is, in fact, equivalent to the formaldehyde release of natural wood.


Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 422
Author(s):  
Kuai Zhang ◽  
Yungang Li ◽  
Hongyan Yan ◽  
Chuang Wang ◽  
Hui Li ◽  
...  

An Fe/FeAl2O4 composite was prepared with Fe-Fe2O3-Al2O3 powder by a hot press sintering method. The mass ratio was 6:1:2, sintering pressure was 30 MPa, and holding time was 120 min. The raw materials for the powder particles were respectively 1 µm (Fe), 0.5 µm (Fe2O3), and 1 µm (Al2O3) in diameter. The effect of sintering temperature on the microstructure and mechanical properties of Fe/FeAl2O4 composite was studied. The results showed that Fe/FeAl2O4 composite was formed by in situ reaction at 1300 °C–1500 °C. With the increased sintering temperature, the microstructure and mechanical properties of the Fe/FeAl2O4 composite showed a change law that initially became better and then became worse. The best microstructure and optimal mechanical properties were obtained at 1400 °C. At this temperature, the grain size of Fe and FeAl2O4 phases in Fe/FeAl2O4 composite was uniform, the relative density was 96.7%, and the Vickers hardness and bending strength were 1.88 GPa and 280.0 MPa, respectively. The wettability between Fe and FeAl2O4 was enhanced with increased sintering temperature. And then the densification process was accelerated. Finally, the microstructure and mechanical properties of the Fe/FeAl2O4 composite were improved.


2013 ◽  
Vol 589-590 ◽  
pp. 590-593 ◽  
Author(s):  
Min Wang ◽  
Jun Zhao

In order to investigate the effects of TiN content on Al2O3/TiN ceramic material (ATN), the ATN ceramic materials were prepared of TiN content in 30%, 40%, 50%, 60% in the condition of hot press sintering. The sintering temperature is 1700°C, the sintering press is 32MPa, and the holding time are 5min, 10min, 15min. The effects of TiN content on mechanical properties and microstructure of ATN ceramic materials were investigated by analyzing the bending strength, hardness, fracture toughness. The results show that ATN50 has the best mechanical property, its bending strength is 659.41MPa, vickers hardness is 13.79GPa, fracture toughness is 7.06MPa·m1/2. It is indicated that the TiN content has important effect on microstructure and mechanical properties of ATN ceramic materials.


2008 ◽  
Vol 1 (2) ◽  
pp. 113-120 ◽  
Author(s):  
A. C. Marques ◽  
J. L. Akasaki ◽  
A. P. M. Trigo ◽  
M. L. Marques

In this work it was evaluated the influence tire rubber addition in mortars in order to replace part of the sand (12% by volume). It was also intended to verify if the tire rubber treatment with NaOH saturated aqueous solution causes interference on the mechanical properties of the mixture. Compressive strength, splitting tensile strength, water absorption, modulus of elasticity, and flow test were made in specimens of 5cmx10cm and the tests were carried out to 7, 28, 56, 90, and 180 days. The results show reduction on mechanical properties values after addition of tire rubber and decrease of the workability. It was also observed that the tire rubber treatment does not cause any alteration on the results compared to the rubber without treatment.


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