scholarly journals Study of 4,4‘-Methylene Diisocyanate Phenyl Ester-Modified Cassava Residues/Polybutylene Succinate Biodegradable Composites: Preparation and Performance Research

Processes ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 588
Author(s):  
Lijie Huang ◽  
Hanyu Zhao ◽  
Hao Xu ◽  
Shuxiang An ◽  
Chunying Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Contact Angle ◽  
Tensile Strength ◽  
Water Absorption ◽  
Bending Strength ◽  
Phenyl Ester ◽  
Biodegradable Composites ◽  
Polybutylene Succinate ◽  
Thermal Stability Of

Biomass materials have become a research focus for humankind, due to the decreasing availability of fossil fuels and the increasing release of greenhouse gas. In this work, we prepared biodegradable composites with waste cassava residues and polybutylene succinate (PBS) by modifying cassava residues using 4,4’-methylene diisocyanate phenyl ester (MDI) and tested their properties. The effects of MDI modification on the structure, mechanical properties, water absorption, microstructure, and thermal stability of the composites were studied via Fourier transform infrared spectroscopy, contact angle measurement, mechanical property testing, water absorption analysis, scanning electron microscopy, and thermogravimetric analysis, respectively. The results showed that the tensile strength and flexural strength of the material increased by 72% and 20.89%, respectively, when the MDI-modified cassava residue content was 30%. When 10% MDI-modified cassava residues were added, the tensile strength increased by 19.46% from 16.96 MPa to 20.26 MPa, while the bending strength did not change significantly. The water contact angle of the MDI-treated cassava residues exceeded 100°, indicating excellent hydrophobicity. Thus, MDI modification can significantly improve the mechanical properties and thermal stability of the biocomposite. The composites were immersed in distilled water for 96 h. The water absorption of the cassava residues/PBS composite was 2.19%, while that of the MDI-modified cassava residues/PBS composite was 1.6%; hence, the water absorption of the MDI-modified cassava residues/PBS composite was reduced to 26.94%. This technology has wide application potential in packaging, construction, and allied fields.

scholarly journals Study on Thermal Properties and Mechanical Properties of Short-cut Polyimide-Fiber Reinforced Polyphenyl Sulfone Composites

2019 ◽  
Vol 264 ◽  
pp. 02003
Author(s):  
Weizhou Yao ◽  
Jianan Yao ◽  
Qing Jiao ◽  
Yunhai Wei ◽  
Tianpeng Yu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Mechanical Property ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Heat Resistance ◽  
Bending Strength ◽  
Limited Effect ◽  
Polyimide Fiber ◽  
Heat Deformation ◽  
Thermal Stability Of

In order to increase the thermal stability and mechanical property of PPSU, two different polyimide (PI) short cut fibers reinforced polyphenyl sulfone (PPSU) composites were prepared by melt extrusion using a threescrew extruder. In addition, the effects of fiber lengths on thermal stability, heat resistance and mechanical properties of the composites was studied. The results indicate that the addition of polyimide chopped fiber can greatly improve the heat resistance of the composites. Comparing with PPSU, with the increasing of fiber content, the heat deformation temperature (HDT) of composites increased from 205 °C to 229 °C, but the addition of polyimide fiber has limited effect on the thermal stability of the composites. Meanwhile, the addition of polyimide chopped fiber can also improve the mechanical properties of the composites. Compared with PPSU, the tensile strength of composites can be increased by 102%, and the bending strength can be raised by 117%.

Thermal Stability of Mechanical Properties of Copper after Equal-Channel Angular Pressing

2008 ◽  
Vol 584-586 ◽  
pp. 960-965 ◽  
Author(s):  
Tamara Kravchenko ◽  
Alexander Korshunov ◽  
Natalia Zhdanova ◽  
Lev Polyakov ◽  
Irina Kaganova
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Chemical Composition ◽  
Yield Strength ◽  
Equal Channel Angular Pressing ◽  
Angular Pressing ◽  
Different Temperatures ◽  
Thermal Stability Of

Annealed oxygen-free and tough-pitch copper samples have been processed by equalchannel angular pressing (ECAP) by route BC. The samples included 8 x 8 mm section pieces and a 40 mm diameter bar. Thermal stability was assessed based on the changes in the standard mechanical properties (conventional yield strength, tensile strength, elongation, proportional elongation and contraction) after annealing at different temperatures for 1 hour. Thermal stability of the same grade of material has been found to be different for different batches and to depend on the structural conditions of deformed material. The zone of thermal stability for copper of the two grades of interest does not depend on the material’s chemical composition.

scholarly journals Surface Response Methodology-Based Mixture Design to Study the Influence of Polyol Blend Composition on Polyurethanes Properties

2018 ◽  
Author(s):  
Said Arévalo-Alquichire ◽  
María Morales-González ◽  
Luis E. Barrera ◽  
Manuel F. Valero
Keyword(s):  
Thermal Stability ◽  
Contact Angle ◽  
Tensile Strength ◽  
Water Absorption ◽  
Hydrolytic Degradation ◽  
Mixture Design ◽  
Structure Property ◽  
Blend Composition ◽  
Property Relationship ◽  
Structure Property Relationship

Polyurethanes are materials with a strong structure-property relationship. The goal of this research was to study the effect of a polyol blend composition of polyurethanes on its properties using a mixture design and setting mathematic models for each property. Water absorption, hydrolytic degradation, contact angle, tensile stretch, hardness and modulus were studied. Additionally, Thermal stability was studied by thermogravimetric analysis. Area under the curve was used to evaluate the effect of polyol blend composition on thermal stability and kinetics of water absorption and hydrolytic degradation. Least squares were used to calculate the regression coefficients. Models for the properties were significant, and lack of fit was not (P<0.05). Fit statistics suggest both good fitting and prediction. Water absorption, hydrolytic degradation and contact angle were mediated by the hydrophilic nature of the polyols. Tensile strength, modulus and hardness could be regulated by the molecular weight and hydroxyl index of the polyols. Regression of DTG curves from thermal analysis showed improvement of thermal stability with the increase of PCL and PE. An ANOVA test of the model terms demonstrated that three component effects on bulk properties like water absorption, hydrolytic degradation, hardness, tensile strength and modulus, and the PEG*PCL interaction with the contact angle, which is a surface property. Mixture design application allowed for an understanding of the structure-property relationship through mathematic models.     

scholarly journals Surface Response Methodology-Based Mixture Design to Study the Influence of Polyol Blend Composition on Polyurethanes’ Properties

Molecules ◽  
2018 ◽  
Vol 23 (8) ◽  
pp. 1942 ◽  
Author(s):  
Said Arévalo-Alquichire ◽  
Maria Morales-Gonzalez ◽  
Luis Diaz ◽  
Manuel Valero
Keyword(s):  
Thermal Stability ◽  
Contact Angle ◽  
Tensile Strength ◽  
Water Absorption ◽  
Hydrolytic Degradation ◽  
Mixture Design ◽  
Structure Property ◽  
Blend Composition ◽  
Property Relationship ◽  
Structure Property Relationship

Polyurethanes are materials with a strong structure-property relationship. The goal of this research was to study the effect of a polyol blend composition of polyurethanes on its properties using a mixture design and setting mathematic models for each property. Water absorption, hydrolytic degradation, contact angle, tensile strength hardness and modulus were studied. Additionally, thermal stability was studied by thermogravimetric analysis. Area under the curve was used to evaluate the effect of polyol blend composition on thermal stability and kinetics of water absorption and hydrolytic degradation. Least squares were used to calculate the regression coefficients. Models for the properties were significant, and lack of fit was not (p < 0.05). Fit statistics suggest both good fitting and prediction. Water absorption, hydrolytic degradation and contact angle were mediated by the hydrophilic nature of the polyols. Tensile strength, modulus and hardness could be regulated by the PE content and the characteristics of polyols. Regression of DTG curves from thermal analysis showed improvement of thermal stability with the increase of PCL and PE. An ANOVA test of the model terms demonstrated that three component influences on bulk properties like water absorption, hydrolytic degradation, hardness, tensile strength and modulus. The PEG*PCL interaction influences on the contact angle, which is a surface property. Mixture design application allowed for an understanding of the structure-property relationship through mathematic models.

Effect of layered silicates on rheological and mechanical properties and thermal stability of high-molar mass polydimethylsiloxane matrix

e-Polymers ◽  
2011 ◽  
Vol 11 (1) ◽  
Author(s):  
Veronika Rabova ◽  
Petr Hron
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Silicone Rubber ◽  
Molar Mass ◽  
Strength Increase ◽  
Weight Decay ◽  
High Molar Mass ◽  
Surface Modified ◽  
Thermal Stability Of

AbstractThe effect of surface modified fillers based on montmorillonite on rheological and mechanical properties and thermal stability of high-molar mass polydimethylsiloxane matrix was evaluated. Silicone rubber/clay composites were prepared via homogenisation on open two roll-mill followed by torque measurement at two different temperatures. At 30 °C and 100 °C the torque did not extremely differ excepting the mixtures containing Cloisite 15A where it achieved the maximum at 3 phr montmorillonite content, but the tensile strength reached the similar values in all mixtures. Thermogravimetric analysis was utilized to find out the differences in weight decay of composites in silicone rubber/montmorillonite mixtures and in unfilled silicone rubber. Synergism of fillers was also studied and led to tensile strength increase.

scholarly journals THE EFFECT OF FIBER CONTENT ON COTTON REINFORCED ALBUMEN COMPOSITES

2011 ◽  
Vol 12 (2) ◽  
pp. 131-144 ◽  
Author(s):  
Yusof Yusliza ◽  
Ahmad Zuraida
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Cotton Fiber ◽  
Mechanical Performance ◽  
Impact Resistance ◽  
Morphological Structure ◽  
Fiber Content ◽  
X Ray ◽  
Thermal Stability Of

ABSTRACT : The effect of fiber content on mechanical properties and thermal stability of the cotton/albumen composites (CAC) were investigated and presented in this paper. The composites having 0%, 3%, 6%, 10%, 13 %, and 16% w/w of cotton fiber were considered.  Hands lay-up technique was used to prepare the CAC specimens and dried for 24 hours before characterised and evaluated for their mechanical performance. The structure and thermal stability of the composites were characterized by using x-ray and thermogravimetry analysis, respectively. The tensile strength and impact resistance of CAC are found maximum with the value of 8.7 MPa and 19.0 kJ/m2, respectively. Analysis on the morphological structure by SEM revealed that the mechanical properties of the composites depend on good wettability and adhesion between fiber/matrix.

Improvement of Mechanical Properties of CNT/Epoxy Nano Composites Using the B4C by Taguchi Method

2017 ◽  
Vol 900 ◽  
pp. 105-109
Author(s):  
Mustafa Taşyürek ◽  
Cihad Nazik
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Taguchi Method ◽  
Hybrid Nanocomposites ◽  
Nano Composites ◽  
Hybrid Nanocomposite ◽  
Multi Walled Carbon Nanotube ◽  
Optimum Sample ◽  
Thermal Stability Of

In this study, production and mechanical properties of the hybrid nanocomposite were investigated experimentally and estimated. Hybrid nanocomposites include boron carbide (B4C) and multi walled carbon nanotube (CNT) in the epoxy resin. B4C and CNT mixed into the epoxy with different percentages and produced. Tensile strength values of the produced samples was determined and compared. Thermal stability of the samples was analyzed by TGA. Samples are diversified by Taguchi method. The optimum sample was determined by comparison of the experimental and estimated results. Finally, the effects on each of the parameters were determined.

Preparation and Characterization of Cassava Starch-Chitosan/Montmorillonite Nanocomposites

2011 ◽  
Vol 194-196 ◽  
pp. 484-487 ◽  
Author(s):  
Xian Zhong Mo ◽  
Chen Mo ◽  
Xiang Qi ◽  
Ren Huan Li
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Cassava Starch ◽  
Elongation At Break ◽  
The Matrix ◽  
Mechanical Properties Testing ◽  
Thermal Stability Of ◽  
Xrd And Tem

Biopolymer cassava starch(ST)-chitosan(CS)/montmorillonite(MMT) nanocomposites were prepared in which MMT was used as nanofiller and diluted acetic acid was used as solvent for dissolving and dispersing cassava starch, chitosan and MMT. XRD and TEM results indicated the formation of an exfoliated nanostructure of ST-CS/MMT nanocomposites. Mechanical properties testing revealed that at the range of the MMT content from 1wt% to 5wt%, tensile strength of the composites increased from 30MPa to 37.5MPa. But the elongation at break fall from 28% to 22% with the increasing of MMT. Obviously, MMT had an enforced effect to the composites. TGA results showed that the nano-dispersed MMT improved the thermal stability of the matrix systematically with the increasing of MMT.

Chemical Modification of Poplar Wood on the Mechanical Properties

2011 ◽  
Vol 194-196 ◽  
pp. 1815-1818
Author(s):  
Guo Feng Wu ◽  
Qian Lang ◽  
Bin Wang ◽  
Yi Fei Jiang ◽  
Jun Wen Pu
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Compressive Strength ◽  
Chemical Modification ◽  
Water Absorption ◽  
Bending Strength ◽  
Poplar Wood ◽  
Hot Press ◽  
Drying Treatment ◽  
Natural Wood

In this research, the chemical and multilayer hot-press drying was used to modify poplar wood. The timbers were compressed and dried in the multilayer hot-press drying kiln. The combination of chemical modification and hot-press drying can improve the mechanical properties. The influence of chemical and hot-press drying on the compressive strength parallel to grain, the bending strength, the density, the water absorbent and the crystallinity of poplar wood have been investigated in this study. The chemical treated conditions close to real technological regimes selected. The samples were impregnated with three conditions. The samples were dried in a hot-press drying kiln for 130hrs. It was showed that the urea carbamate and hot-press drying treatment increase the properties. The density and mechanical properties increased with increasing urea carbamate, while the water absorption decreased. The crystallinity is 37.03%, 37.11%, 37.78%, separately, compared with the natural wood of 35.09%. The TAG showed the thermal stability increased.

The Damping Properties of the Natural Rubber Filled with ZnO

2014 ◽  
Vol 912-914 ◽  
pp. 390-394 ◽  
Author(s):  
Yan Fang Zhao ◽  
Dan Liu ◽  
Shuang Quan Liao ◽  
Xiao Xue Liao ◽  
Sheng Bo Lin
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Zinc Oxide ◽  
Natural Rubber ◽  
Damping Properties ◽  
Tear Strength ◽  
Thermal Stability Of

The research on the mechanical properties and thermal stability of the natural rubber filled with different dosage of Zinc oxide (ZnO). The results showed that with the increase of the content of the ZnO, the tensile strength first increased, then decreased the, but the tear strength showed a trend of increase,the thermal stability had improved; When the amount of ZnO added was 9, damping performance was better.

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