Preparation and properties of melamine-formaldehyde rigid closed-cell foam toughened by ethylene glycol/carbon fiber

2020 ◽  
pp. 026248932092923
Author(s):  
Chunhui Li ◽  
Haihong Ma ◽  
Zhengfa Zhou ◽  
Weibing Xu ◽  
Fengmei Ren ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Stability ◽  
Compressive Strength ◽  
Water Absorption ◽  
Cellular Structure ◽  
Bending Strength ◽  
Melamine Formaldehyde ◽  
Cell Ratio ◽  
Closed Cell ◽  
Rigid Foams

Toughing melamine-formaldehyde (MF) rigid closed-cell foams were prepared by using ethylene glycol (EG) and carbon fiber (CF) as composite toughening agents. The pulverization rate, compressive strength, bending strength, cellular structure, closed-cell ratio, water absorption ratio, thermal conductivity, thermal stability, limiting oxygen index (LOI), and char yield were characterized to study the morphology, mechanical, thermal, and fire-retardant properties of as-prepared toughing MF rigid foams. The pulverization rate result showed that introduction of composite modifier can obviously improve the toughness of MF rigid foams. The cellular structure, closed-cell ratio, and water absorption results showed that the addition of EG/CF can increase the closed-cell ratio and control the cell size of MF rigid foams. The compressive strength and bending strength results showed that the incorporation of composite modifier of MF rigid foams dramatically improved the mechanical properties. The LOI, char yield, and thermal stability results showed that the toughing MF rigid foams remained more intact char skeleton with flame-retardant effect, thus reducing the fire hazards. The as-prepared toughing MF rigid foams showed the best comprehensive performance with pulverization rate of 5.21%, compressive strength of 355.3 kPa, bending strength of 0.44 MPa, closed-cell ratio of 79.1%, water absorption of 9%, thermal conductivity of 0.031 W m−1 K−1, and LOI of 39.6%. Compared with unmodified MF rigid foams, toughing rigid closed-cell MF foams possess excellent pulverization rate, compressive strength, bending strength, cellular structure, thermal insulation, and flame retardancy.

Preparation and performance of melamine-formaldehyde rigid foams with high closed cell content

2021 ◽  
pp. 026248932110171
Author(s):  
Chunhui Li ◽  
Haihong Ma ◽  
Congqiang Song ◽  
Zhengfa Zhou ◽  
Weibing Xu ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Water Absorption ◽  
Thermal Insulation ◽  
Apparent Density ◽  
Insulation Material ◽  
Melamine Formaldehyde ◽  
Cell Content ◽  
Closed Cell ◽  
Rigid Foams ◽  
Foaming Temperature

Melamine-formaldehyde (MF)rigid foams with high closed cell content were prepared via oven heating process, using MF prepolymer prepared from melamine and paraformaldehyde as a matrix, cyclohexane as the foaming agent, dimethyl silicon oil as the foam stabilizers, hydrochloric acid as the catalyst. The effect of MF prepolymer viscosity, foaming temperature, amount of catalyst on morphology, closed cell content, apparent density, water absorption and compressive strength of MF rigid foams were systematically studied. The optimized foaming conditions are as follows: the viscosity of MF prepolymer ranges from 35 Pa·s to 45 Pa·s, the foaming temperature is 125°C and the content of the catalyst is 0.65 wt%. The as-prepared MF foams showed the best comprehensive performance with closed cell content of 83.5%, apparent density of 62 kg·m−3, water absorption of 12.0%, compressive strength of 292kPa, thermal conductivity of 0.033 W m−1 K−1 and limiting oxygen index (LOI) of 36%. Compared to conventional organic foams, MF rigid foams possess low water absorption, excellent thermal insulation and flame retardancy due to high closed cell content, and can be expected to be used as thermal insulation material for building exterior walls.

The Synthesis and Application of a Novel Class of Polyols for Preparation of Polyurethane

2013 ◽  
Vol 357-360 ◽  
pp. 1441-1445
Author(s):  
Xiao Lin Li ◽  
Zheng Fang ◽  
Dong Ji ◽  
Zhi Dong Wan ◽  
Kai Guo
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Polyurethane Foams ◽  
Low Density ◽  
Cell Content ◽  
Low Thermal Conductivity ◽  
High Compressive Strength ◽  
Rigid Polyurethane Foams ◽  
Closed Cell ◽  
Rigid Foams

The synthesis of a novel class of diamine-based polyols derivatives and the potentials and the limitations of these polyols were reported. This class of diamine-based polyols with high hydroxyl values and no acid values can be used in rigid polyurethane foams. The prepared rigid foams show the properties of low density, high closed cell content, low thermal conductivity, and high compressive strength.

scholarly journals Vacuum-Based Impregnation of Liquid Glass into Sunflower Press Cake Particles and Their Use in Bio-Based Rigid Polyurethane Foam

Materials ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5351
Author(s):  
Agnė Kairytė ◽  
Sylwia Członka ◽  
Renata Boris ◽  
Sigitas Vėjelis
Keyword(s):  
Thermal Conductivity ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Compressive Strength ◽  
Water Absorption ◽  
Liquid Glass ◽  
Press Cake ◽  
Short Term ◽  
Average Cell Size ◽  
Average Cell

The study analyses rigid polyurethane (PUR) foam modified with 10–30 wt.% sunflower press cake (SFP) and liquid glass-impregnated sunflower press cake (LG-SFP) particles and their impact on performance characteristics of PUR foams—foaming behaviour, rheology, thermal conductivity, compressive strength parallel and perpendicular to the foaming directions, tensile strength, dimensional stability, short-term water absorption by partial immersion, and thermal stability. Even though the dynamic viscosity and apparent density were increased for SFP and LG-SFP formulations, thermal conductivity values improved by 17% and 10%, respectively, when 30 wt.% of particles were incorporated. The addition of SFP and LG-SFP particles resulted in the formation of more structurally and dimensionally stable PUR foams with a smaller average cell size and a greater content of closed cells. At 30 wt.% of SFP and LG-SFP particles, compressive strength increased by 114% and 46% in the perpendicular direction, respectively, and by 71% and 67% in the parallel direction, respectively, while tensile strength showed an 89% and 85% higher performance at 30 wt.% SFP and LG-SFP particles loading. Furthermore, short-term water absorption for all SFP and LG-SFP modified PUR foam formulations was almost two times lower compared to the control foam. SFP particles reduced the thermal stability of modified PUR foams, but LG-SFP particles shifted the thermal decomposition temperatures towards higher ones.

scholarly journals Production of Lightweight Thermal Insulating Clay Bricks using Papyrus

2019 ◽  
Vol 9 (1) ◽  
pp. 74-81 ◽  
Author(s):  
Hussein Muhamad Ali Karim
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Bending Strength ◽  
Content Increase ◽  
Clay Bricks ◽  
Thermal Insulating ◽  
Opposite Behavior ◽  
Different Temperatures ◽  
Firing Shrinkage

The paper presents an experimental investigation into the possibility of producing lightweight clay bricks by adding flakes of papyrus, locally called (Bardy). The flakes were sieved to obtain a powder with maximum particle size of 2.5 mm. The bricks were prepared with the addition of increasing amounts of flakes of papyrus (0, 10, 20, 30, and 40 mass%) to the clay slurry. Different temperatures of 650, 900, and 1050°C were embayed to fire the specimens. The thermal conductivity, water absorption, porosity, bulk density, firing shrinkage, compressive strength, and bending strength of the samples were measured. It was observed that the apparent compressive strength, bending strength, firing shrinkage, thermal conductivity, and density increased with the firing temperature increase and decreased with the papyrus flakes content increase; however, water absorption and porosity showed an opposite behavior.

Chemical Modification of Poplar Wood on the Mechanical Properties

2011 ◽  
Vol 194-196 ◽  
pp. 1815-1818
Author(s):  
Guo Feng Wu ◽  
Qian Lang ◽  
Bin Wang ◽  
Yi Fei Jiang ◽  
Jun Wen Pu
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Compressive Strength ◽  
Chemical Modification ◽  
Water Absorption ◽  
Bending Strength ◽  
Poplar Wood ◽  
Hot Press ◽  
Drying Treatment ◽  
Natural Wood

In this research, the chemical and multilayer hot-press drying was used to modify poplar wood. The timbers were compressed and dried in the multilayer hot-press drying kiln. The combination of chemical modification and hot-press drying can improve the mechanical properties. The influence of chemical and hot-press drying on the compressive strength parallel to grain, the bending strength, the density, the water absorbent and the crystallinity of poplar wood have been investigated in this study. The chemical treated conditions close to real technological regimes selected. The samples were impregnated with three conditions. The samples were dried in a hot-press drying kiln for 130hrs. It was showed that the urea carbamate and hot-press drying treatment increase the properties. The density and mechanical properties increased with increasing urea carbamate, while the water absorption decreased. The crystallinity is 37.03%, 37.11%, 37.78%, separately, compared with the natural wood of 35.09%. The TAG showed the thermal stability increased.

scholarly journals Effect of Expanded Perlite Aggregate Size on Physical and Mechanical Properties of Ultra Lightweight Concrete Produced with Expanded Perlite Aggregate

2019 ◽  
Author(s):  
Mucip Tapan ◽  
Celil Engin
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Bending Strength ◽  
Lightweight Concrete ◽  
Unit Weight ◽  
Ultra Sound ◽  
Expanded Perlite ◽  
Freezing And Thawing ◽  
Freezing And Thawing Cycles

In this study, ultra-light weight concrete (ULWC) with heat-insulating properties is produced by using different size expanded perlite aggregates and various admixtures. The compressive strength, 4 point bending strength, freezing and thawing resistance, water absorption, dry unit weight, ultra sound velocities and thermal conductivity of the samples were determined by applying appropriate tests. The effect of different size expanded perlite aggregate on the properties of ULWC were also investigated in this study and it was found that as the expanded perlite aggregate diameter increased, the void volume uniformity, water absorption percentage and freezing-thawing resistance increased while the unit volume weight of ULWC samples, ultrasound speed velocities, thermal conductivity and compressive strength were decreased. The changes in the masses and compressive strength of ULWC samples subjected to freezing and thawing cycles were examined. The compressive strength loss was found to be between 5 % and 47 % while the weight loss was between 1 % and 3.5 % after 15 freezing and thawing cycles. Finally, the effects of the admixtures on the fresh properties of ULWC were examined and it was determined that the use of 4.5 kg of air-entraining material in one cubic meter of concrete mix is the most ideal ratio and the use of more than 0.01 % by volume of polypropylene fiber is caused settlements in fresh concrete mixtures.

Incorporation of Iraqi Rocks in the Production of Eco-Friendly Cement Mortar

2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Structural Properties ◽  
Mechanical Milling ◽  
Cement Mortar ◽  
Cement Mortars

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.

Temperature dependency of the long-term thermal conductivity of spray polyurethane foam

2021 ◽  
pp. 174425912110454
Author(s):  
Neal Holcroft
Keyword(s):  
Thermal Conductivity ◽  
Polyurethane Foam ◽  
Cellular Structure ◽  
Gas Diffusion ◽  
Temperature Dependent ◽  
Blowing Agent ◽  
Closed Cell ◽  
Wall Assembly ◽  
Cell Foam

The thermal properties of closed-cell foam insulation display a more complex behaviour than other construction materials due to the properties of the blowing agent captured in their cellular structure. Over time, blowing agent diffuses out from and air into the cellular structure resulting in an increase in thermal conductivity, a process that is temperature dependent. Some blowing agents also condense at temperatures within the in-service range of the insulation, resulting in non-linear temperature dependent relationships. Moreover, diffusion of moisture into the cellular structure increases thermal conductivity. Standards exist to quantify the effect of gas diffusion on thermal conductivity, however only at standard laboratory conditions. In this paper a new test procedure is described that includes calculation methods to determine Temperature Dependent Long-Term Thermal Conductivity (LTTC(T)) functions for closed-cell foam insulation using as a test material, a Medium-Density Spray Polyurethane Foam (MDSPF). Tests results are provided to show the validity of the method and to investigate the effects of both conditioning and mean test temperature on change in thermal conductivity. In addition, testing was conducted to produce a moisture dependent thermal conductivity function. The resulting functions were used in hygrothermal simulations to assess the effect of foam aging, in-service temperature and moisture content on the performance of a typical wall assembly incorporating MDSPF located in four Canadian climate zones. Results show that after 1 year, mean thermal conductivity increased 15%–16% and after 5 years 23%–24%, depending on climate zone. Furthermore, the use of the LTTC(T) function to calculate the wall assembly U-value improved accuracy between 3% and 5%.

scholarly journals Biodegradable, Flame-Retardant, and Bio-Based Rigid Polyurethane/Polyisocyanurate Foams for Thermal Insulation Application

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1816 ◽  
Author(s):  
Marcin Borowicz ◽  
Joanna Paciorek-Sadowska ◽  
Jacek Lubczak ◽  
Bogusław Czupryński
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Flame Retardant ◽  
Functional Properties ◽  
Apparent Density ◽  
Seed Oil ◽  
Mustard Seed ◽  
Hydroxyl Groups ◽  
Processing Times

This article raised the issue of studies on the use of new bio-polyol based on white mustard seed oil and 2,2’-thiodiethanol (3-thiapentane-1,5-diol) for the synthesis of rigid polyurethane/polyisocyanurate (RPU/PIR) foams. For this purpose, new formulations of polyurethane materials were prepared. Formulations contained bio-polyol content from 0 to 0.4 chemical equivalents of hydroxyl groups. An industrial flame retardant, tri(2-chloro-1-methylethyl) phosphate (Antiblaze TCMP), was added to half of the formulations. Basic foaming process parameters and functional properties, such as apparent density, compressive strength, brittleness, absorbability and water absorption, aging resistance, thermal conductivity coefficient λ, structure of materials, and flammability were examined. The susceptibility of the foams to biodegradation in soil was also examined. The increase in the bio-polyol content caused a slight increase in processing times. Also, it was noted that the use of bio-polyol had a positive effect on the functional properties of obtained RPU/PIR foams. Foams modified by bio-polyol based on mustard seed oil showed lower apparent density, brittleness, compressive strength, and absorbability and water absorption, as well as thermal conductivity, compared to the reference (unmodified) foams. Furthermore, the obtained materials were more resistant to aging and more susceptible to biodegradation.

Performance Study of Fiber Reinforced New Lightweight Insulation Materials

2013 ◽  
Vol 662 ◽  
pp. 331-334
Author(s):  
Huan Qi Zhao ◽  
Guo Zhong Li
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Bending Strength ◽  
Raw Materials ◽  
The Self ◽  
Performance Study ◽  
Foaming Agent ◽  
Insulation Materials ◽  
Influencing Mechanism ◽  
Coefficient Of Thermal Conductivity

Cement-based lightweight insulation materials were made. Cement and fly ash are main raw materials. The self-developed composite excitation agent and foaming agent are used. The method of foaming is the physical foaming. The inflection of fiber dosage on the performance of lightweight insulation materials was researched. Its influencing mechanism was discussed. Experiments show that foaming lightweight insulation materials were made with 1.22MPa bending strength, 2.95MPa compressive strength and the 0.072W/mk coefficient of thermal conductivity when the fiber mixing content is 1.2%.

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