Study on Competitive Sorption Capacity of Sr2+/Cs+ in Zeolite and Palygorskite

2011 ◽  
Vol 347-353 ◽  
pp. 2515-2518
Author(s):  
Jin Ming Wang

Competitive sorption capacity of equal concentration of Cs+ and Sr2+ in zeolite and palygorskite were studied by the intermittence method. zeolite and palygorskite of adsorbed Cs+ and Sr2+ were analysed with the XRD. They could offer some references for the sake of valuing mid-lower radwaste disposition. The results showed that adsorptive equilibrium time of NF to Cs+ and Sr2+ was about seven day, that of ZF was about three day, and that of CA was about fourteen day. Equilibrium adsorptive quantity of ZF to Cs+ and Sr2+ was the best, and that of NF was second, and that of CA was third. Sorption capacity of NF to Cs+ was the better than that to Sr2+, and selection of CA to Cs+ and Sr2+ was the little, and that of ZF was the lest. Equilibrium adsorptive rate of ZF to Sr2+ was almost the 100% and that of ZF to Cs+ was about 71.8% and that of NF to Cs+ was 66% and that of NF to Sr2+ was only 15% and that of CA to Sr2+ was about 28.6% and that of CA to Cs+ was only 16.4%. Crystal unit cell cubage and parameter a of zeolite and palygorskite adsorbed Cs+ and Sr2+ decreased and change of crystal unit cell parameter a、b and β of zeolite and palygorskite were ruleless.

Crystals ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 541 ◽  
Author(s):  
Kuang ◽  
Xu ◽  
Li ◽  
Ye ◽  
Huang ◽  
...  

Crystal-chemical properties of synthetic Almandine-Pyrope (Alm-Pyr) solid solutions were investigated by X-ray single-crystal diffraction and Raman spectroscopy. Garnet solid solution with different compositions were synthesized from powder at 4.0 GPa and annealed at 1200 °C for 48 h by a multi-anvil pressure apparatus. Garnet crystals with different sizes (about 60-1000 μm) were obtained from synthesis. The results of X-ray single-crystal diffraction show that the unit cell constants decrease with increasing Pyr contents in the synthetic Alm-Pyr crystals due to the smaller ionic radius of Mg2+ in eightfold coordination than that of Fe2+. The data exhibit obviously positive deviations from ideal mixing volumes across the Alm-Pyr join which may be caused by the distortion of the SiO4 tetrahedron. Moreover, the significant decrease in the average M-O bond length and volume of the [MgO8]/[FeO8] dodecahedron with increasing Pyr contents are the most important factors to the decrease in the Alm-Pyr crystal unit cell constant and volume. On the other hand, selected bond distances (average <M-O>, <Al-O>, and <D-O> distances) have a linear correlation with the unit-cell parameter, but the <Si-O> distance has nonlinear correlation. With increasing the unit-cell parameter, the average <M-O> distance increases significantly, followed by the average <D-O> and <Al-O> distances. While the <Si-O> distance changes negligibly further confirming the conclusion that the significant decrease of the average M-O bond length of the [MgO8]/[FeO8] dodecahedron with increasing Pyr contents are the most important factors to the decrease in the Alm-Pyr crystal unit cell volume. In the Raman spectra collected for the Alm-Pyr solid solutions, Raman vibration mode assignments indicate that the Raman vibrational spectra change along the Alm-Pyr binary solution. The mode frequencies of Si-O stretching, Si-O bending, and the rotation of the SiO4-tetrahedron (R(SiO4)) decrease linearly, while the translational modes of the SiO4-tetrahedron (T(SiO4)) increase with increasing Alm contents.


2019 ◽  
Vol 9 (01) ◽  
pp. 47-54
Author(s):  
Rabbai San Arif ◽  
Yuli Fitrisia ◽  
Agus Urip Ari Wibowo

Voice over Internet Protocol (VoIP) is a telecommunications technology that is able to pass the communication service in Internet Protocol networks so as to allow communicating between users in an IP network. However VoIP technology still has weakness in the Quality of Service (QoS). VOPI weaknesses is affected by the selection of the physical servers used. In this research, VoIP is configured on Linux operating system with Asterisk as VoIP application server and integrated on a Raspberry Pi by using wired and wireless network as the transmission medium. Because of depletion of IPv4 capacity that can be used on the network, it needs to be applied to VoIP system using the IPv6 network protocol with supports devices. The test results by using a wired transmission medium that has obtained are the average delay is 117.851 ms, jitter is 5.796 ms, packet loss is 0.38%, throughput is 962.861 kbps, 8.33% of CPU usage and 59.33% of memory usage. The analysis shows that the wired transmission media is better than the wireless transmission media and wireless-wired.


1996 ◽  
Vol 118 (3) ◽  
pp. 439-443 ◽  
Author(s):  
Chuen-Huei Liou ◽  
Hsiang Hsi Lin ◽  
F. B. Oswald ◽  
D. P. Townsend

This paper presents a computer simulation showing how the gear contact ratio affects the dynamic load on a spur gear transmission. The contact ratio can be affected by the tooth addendum, the pressure angle, the tooth size (diametral pitch), and the center distance. The analysis presented in this paper was performed by using the NASA gear dynamics code DANST. In the analysis, the contact ratio was varied over the range 1.20 to 2.40 by changing the length of the tooth addendum. In order to simplify the analysis, other parameters related to contact ratio were held constant. The contact ratio was found to have a significant influence on gear dynamics. Over a wide range of operating speeds, a contact ratio close to 2.0 minimized dynamic load. For low-contact-ratio gears (contact ratio less than two), increasing the contact ratio reduced gear dynamic load. For high-contact-ratio gears (contact ratio equal to or greater than 2.0), the selection of contact ratio should take into consideration the intended operating speeds. In general, high-contact-ratio gears minimized dynamic load better than low-contact-ratio gears.


2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Pia Montanucci ◽  
Silvia Terenzi ◽  
Claudio Santi ◽  
Ilaria Pennoni ◽  
Vittorio Bini ◽  
...  

Alginate-based microencapsulation of live cells may offer the opportunity to treat chronic and degenerative disorders. So far, a thorough assessment of physical-chemical behavior of alginate-based microbeads remains cloudy. A disputed issue is which divalent cation to choose for a high performing alginate gelling process. Having selected, in our system, high mannuronic (M) enriched alginates, we studied different gelling cations and their combinations to determine their eventual influence on physical-chemical properties of the final microcapsules preparation,in vitroandin vivo. We have shown that used of ultrapure alginate allows for high biocompatibility of the formed microcapsules, regardless of gelation agents, while use of different gelling cations is associated with corresponding variable effects on the capsules’ basic architecture, as originally reported in this work. However, only the final application which the capsules are destined to will ultimately guide the selection of the ideal, specific gelling divalent cations, since in principle there are no capsules that are better than others.


2015 ◽  
Vol 47 (1) ◽  
pp. 5-17
Author(s):  
Jolanta Korycka-Skorupa

Abstract The author discuss effectiveness of cartographic presentations. The article includes opinions of cartographers regarding effectiveness, readability and efficiency of a map. It reminds the principles of map graphic design in order to verify them using examples of small-scale thematic maps. The following questions have been asked: Is the map effective? Why is the map effective? How do cartographic presentation methods affect effectiveness of the cartographic message? What else can influence effectiveness of a map? Each graphic presentation should be effective, as its purpose is to complete written word, draw the recipients’ attention, make text more readable, expose the most important information. Such a significant role of graphics results in the fact that graphic presentations (maps, diagrams) require proper preparation. Users need to have a chance to understand the graphics language in order to draw correct conclusions about the presented phenomenon. Graphics should demonstrate the most important elements, some tendencies, and directions of changes. It should generalize and present a given subject from a slightly different perspective. There are numerous examples of well-edited and poorly edited small-scale thematic maps. They include maps, which are impossible to interpret correctly. They are burdened with methodological defects and they cannot fulfill their task. Cartography practice indicates that the principles related to graphic design of cartographic presentation are frequently omitted during the process of developing small-scale thematic maps used – among others – in the press and on the Internet. The purpose of such presentations is to quickly interpret them. On such maps editors’ problems with the selection of an appropriate symbol and graphic variable (fig. 1A, 9B) are visible. Sometimes they use symbols which are not sufficiently distinguishable nor demonstrative (fig. 11), it does not increase their readability. Sometime authors try too hard to reflect presented phenomenon and therefore the map becomes more difficult to interpret (fig. 4A,B). The lack of graphic sense resulting in the lack of graphic balance and aesthetics constitutes a weak point of numerous cartographic presentations (fig. 13). Effectiveness of cartographic presentations consists of knowledge and skills of the map editor, as well as the recipients’ perception capabilities and their readiness to read and interpret maps. The qualifications of the map editor should include methodological qualifications supported by the knowledge of the principles for cartographic symbol design, as well as relevant technical qualifications, which allow to properly use the tools to edit a map. Maps facilitate the understanding of texts they accompany and they present relationships between phenomenon better than texts, appealing to the senses.


2014 ◽  
Vol 952 ◽  
pp. 20-24 ◽  
Author(s):  
Xue Jun Xie

The selection of an optimal material is an important aspect of design for mechanical, electrical, thermal, chemical or other application. Many factors (attributes) need to be considered in material selection process, and thus material selection problem is a multi-attribute decision making (MADM) problem. This paper proposes a new MADM method for material selection problem. G1 method does not need to test consistency of the judgment matrix. Thus it is better than AHP. In this paper, firstly, we use the G1 method to determine the attribute weight. Then TOPSIS method is used to calculate the closeness of the candidate materials with respect positive solution. A practical material selection case is used to demonstrate the effectiveness and feasibility of the proposed method.


Minerals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 325
Author(s):  
Sytle Antao

Synchrotron high-resolution powder X-ray diffraction (HRPXRD) and Rietveld structure refinements were used to examine the crystal structure of single phases and intergrowths (either two or three phases) in 13 samples of the helvine-group minerals, (Zn,Fe,Mn)8[Be6Si6O24]S2. The helvine structure was refined in the cubic space group P4¯3n. For the intergrowths, simultaneous refinements were carried out for each phase. The structural parameters for each phase in an intergrowth are only slightly different from each other. Each phase in an intergrowth has well-defined unit-cell and structural parameters that are significantly different from the three endmembers and these do not represent exsolution or immiscibility gaps in the ternary solid-solution series. The reason for the intergrowths in the helvine-group minerals is not clear considering the similar radii, identical charge, and diffusion among the interstitial M cations (Zn2+, Fe2+, and Mn2+) that are characteristic of elongated tetrahedral coordination. The difference between the radii of Zn2+ and Mn2+ cations is 10%. Depending on the availability of the M cations, intergrowths may occur as the temperature, pressure, fugacity fS2, and fluid composition change on crystallization. The Be–Si atoms are fully ordered. The Be–O and Si–O distances are nearly constant. Several structural parameters (Be–O–Si bridging angle, M–O, M–S, average <M–O/S>[4] distances, and TO4 rotational angles) vary linearly with the a unit-cell parameter across the series because of the size of the M cation.


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