Influence of Lime Dust on Chloride Binding Capacity of Fly Ash-Cement Paste

2011 ◽  
Vol 399-401 ◽  
pp. 1191-1195
Author(s):  
Xiang Hao Wu ◽  
Shan Shan Yang ◽  
Cong Kai Zhang ◽  
Pan Yuan

The influence of the way and the volume of adding lime dust to fly ash-cement pastes on chloride physical adsorption capacity, chemical combination capacity and binding capacity of fly ash-cement pastes is investigated by adsorption equilibrium method. The results show that with the volume of lime dust as cement replacement raising, the amount of chloride physically adsorbed by fly ash-cement pastes reduces, while the amount of chloride chemical combining is firstly increase, and then decrease, and it reaches the maximum when the lime dust content is 10% , that of chloride binding is firstly increase, and then decrease, which reaches the maximum when the lime dust content is 5%. In addition, with the volume of lime dust as fly ash replacement increasing , the volume of chloride physically adsorbed by fly ash-cement pastes reduces firstly, and then raises, reaching the minimum when the lime dust content is 6%. Whereas, volume of chloride chemical combining and binding both decrease gradually with the increase of lime dust contents. When the population of lime dust as cement or fly ash replacement is low(less than 15% for cement and 9% for fly ash), effect of lime dust content on chloride binding capacity of fly ash-cement pastes is not obvious (under 7.5%).

Author(s):  
Yibiao Teng ◽  
Songhui Liu ◽  
Zhaocai Zhang ◽  
Jiangwei Xue ◽  
Xuemao Guan

2020 ◽  
Vol 232 ◽  
pp. 117219 ◽  
Author(s):  
Zhiqiang Yang ◽  
Shiyu Sui ◽  
Liguo Wang ◽  
Taotao Feng ◽  
Yun Gao ◽  
...  

2019 ◽  
Vol 195 ◽  
pp. 415-422 ◽  
Author(s):  
Zhiqiang Yang ◽  
Yun Gao ◽  
Song Mu ◽  
Honglei Chang ◽  
Wei Sun ◽  
...  

2019 ◽  
Vol 967 ◽  
pp. 205-213
Author(s):  
Faiz U.A. Shaikh ◽  
Anwar Hosan

This paper presents the effect of nanosilica (NS) on compressive strength and microstructure of cement paste containing high volume slag and high volume slag-fly ash blend as partial replacement of ordinary Portland cement (OPC). Results show that high volume slag (HVS) cement paste containing 60% slag exhibited about 4% higher compressive strength than control cement paste, while the HVS cement paste containing 70% slag maintained the similar compressive strength to control cement paste. However, about 9% and 37% reduction in compressive strength in HVS cement pastes is observed due to use of 80% and 90% slag, respectively. The high volume slag-fly ash (HVSFA) cement pastes containing total slag and fly ash content of 60% exhibited about 5%-16% higher compressive strength than control cement paste. However, significant reduction in compressive strength is observed in higher slag-fly ash blends with increasing in fly ash contents. Results also show that the addition of 1-4% NS improves the compressive strength of HVS cement paste containing 70% slag by about 9-24%. However, at higher slag contents of 80% and 90% this improvement is even higher e.g. 11-29% and 17-41%, respectively. The NS addition also improves the compressive strength by about 1-59% and 5-21% in high volume slag-fly ash cement pastes containing 21% fly ash+49%slag and 24% fly ash+56%slag, respectively. The thermogravimetric analysis (TGA) results confirm the reduction of calcium hydroxide (CH) in HVS/HVSFA pastes containing NS indicating the formation of additional calcium silicate hydrate (CSH) gels in the system. By combining slag, fly ash and NS in high volumes e.g. 70-80%, the carbon footprint of cement paste is reduced by 66-76% while maintains the similar compressive strength of control cement paste. Keywords: high volume slag, nanosilica, compressive strength, TGA, high volume slag-fly ash blend, CO2 emission.


2020 ◽  
Vol 10 (18) ◽  
pp. 6271 ◽  
Author(s):  
Jun Liu ◽  
Jiaying Liu ◽  
Zhenyu Huang ◽  
Jihua Zhu ◽  
Wei Liu ◽  
...  

This paper experimentally studies the effects of fly ash on the diffusion, bonding, and micro-properties of chloride penetration in concrete in a water soaking environment based on the natural diffusion law. Different fly ash replacement ratio of cement in normal concrete was investigated. The effect of fly ash on chloride transportation, diffusion, coefficient, free chloride content, and binding chloride content were quantified, and the concrete porosity and microstructure were also reported through mercury intrusion perimetry and scanning electron microscopy, respectively. It was concluded from the test results that fly ash particles and hydration products (filling and pozzolanic effects) led to the densification of microstructures in concrete. The addition of fly ash greatly reduced the deposition of chloride ions. The chloride ion diffusion coefficient considerably decreased with increasing fly ash replacement, and fly ash benefits the binding of chloride in concrete. Additionally, a new equation is proposed to predict chloride binding capacity based on the test results.


2013 ◽  
Vol 539 ◽  
pp. 55-59
Author(s):  
Yi Chen ◽  
Wu Yao ◽  
Dan Jin

Mineral additions such as fly ash and silica fume are industrial by products, and play an important role in properties improvement for construction materials. In this work, the shrinkage of cement paste blended with fly ash and silica fume by different substitute ratio was studied. Pore structures of specimens at different ages were determined by mercury intrusion porosimetry (MIP) and shrinkage deformation was measured by standard shrinkage tests. The effects of mineral addtions on shrinkage were discussed. The results show that the fly ash was significantly effective on shrinkage at early ages. Based on the research, several suitable advices were offered to optimize the performances of materials and reduce the shrinkage.


2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Yunsu Lee ◽  
Mingyun Kim ◽  
Zhengxin Chen ◽  
Hanseung Lee ◽  
Seungmin Lim

A chloride-binding capacity is the major factor to mitigate the ingress of chloride into concrete. This paper presents the chloride-binding capacity of Portland cement paste containing synthesized CA2 (CaO·2Al2O3). The CA2 was synthesized in the high-temperature furnace and characterized by X-ray diffraction for inspecting the purity. The synthesized CA2 was substituted for Portland cement by 0%, 5%, and 10% by weight, and the NaCl solution was used as an internal chloride, which is assumed as a total chloride. The chloride-binding capacity of cement paste was calculated from a water-soluble chloride extraction method by the application of the Langmuir isotherm equation. And the hydration products were analyzed using X-ray diffraction and thermogravimetric analysis. We demonstrate that the CA2 increases an AFm phase in the Portland cement system, and the incorporation of CA2 consequently enhances the chloride-binding capacity of cement paste samples.


2010 ◽  
Vol 61 (9) ◽  
pp. 2293-2301 ◽  
Author(s):  
Danielle Bonenfant ◽  
Patrick Niquette ◽  
Murielle Mimeault ◽  
Robert Hausler

A study of adsorption/recovery of nonylphenol 9 mole ethoxylate (NP9EO) on a crosslinked β-cyclodextrin-carboxymethylcellulose (β-CD-CMC) polymer was carried out by ultraviolet-visible (UV-vis) and Fourier transform infrared (FTIR) spectroscopies. The adsorption was performed in mixtures containing 500 mg of the β-CD-CMC polymer and aqueous NP9EO solutions at concentrations 12–82 mg/L, whereas the recovery of NP9EO was effectuated by shaking the β-CD-CMC polymer loaded with methanol. The assays were made at 25°C and atmospheric pressure under agitation. The results have shown that the adsorption is a rapid process and the β-CD-CMC polymer exhibits a high NP9EO adsorption capacity of 83–92 w% (1.1–6.8 mg NP9EO/g β-CD-CMC polymer) dependent of the initial NP9EO concentration in liquid phase. This adsorption may involve the formation of an inclusion complex β-CD-NP9EO and a physical adsorption in the polymer network. The adsorption equilibrium measurements, which were analyzed using the Langmuir isotherm, have indicated a monolayer coverage and the homogeneous distribution of active sites at the surface of the β-CD-CMC polymer. Moreover, the negative value obtained for the free energy change (−13.2 kJ/mol) has indicated that the adsorption process is spontaneous. In parallel, the β-CD-CMC polymer exhibited a high NP9EO recovery efficiency of 97 w% that may occur through a decrease of binding strength between β-CD-CMC polymer and NP9EO. Together, these results suggest that the β-CD-CMC polymer could constitute a good adsorbent for removing nonylphenol ethoxylates from wastewater due to its high adsorption capacity and non-toxic character of β-CD and CMC to environment.


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