Thermal Kinetic Analysis of Tert-butyl Peroxybenzoate under Dynamic and Adiabatic Conditions

2012 ◽  
Vol 550-553 ◽  
pp. 2782-2785
Author(s):  
Jia Yu Lv ◽  
Shuiai Wei ◽  
Wang Hua Chen ◽  
Gu Feng Chen ◽  
Li Ping Chen ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Kinetic Analysis ◽  
Decomposition Temperature ◽  
Safety Index ◽  
Scanning Calorimetry ◽  
Accelerating Rate Calorimeter ◽  
Tert Butyl ◽  
Thermal Kinetic Analysis ◽  
Temperature And Pressure

This study demonstrates the thermal actions of tert-butyl peroxybenzoate (TBPB) which is widely used in the plastic and rubber industries. The thermodynamic and kinetic analysis were performed on the basis of dynamic and adiabatic calorimetric applications which had been accepted as good assistants for investigating materials’ thermal decomposition. In essence, TBPB is reactive and exothermically unstable. Differential scanning calorimetry (DSC) and accelerating rate calorimeter (ARC) were employed to supply basic data and safety index. Experiments were taken under different scanning rates as well as various sample mass. The temperature and pressure curves of TBPB during decomposition were recorded. Based on the significant parameters calculated, self-accelerating decomposition temperature (SADT) of TBPB worked out was 50°C.

scholarly journals Comparative thermal research on tetraazapentalene-derived heat-resistant energetic structures

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jing Zhou ◽  
Li Ding ◽  
Yong Zhu ◽  
Bozhou Wang ◽  
Xiangzhi Li ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Fourier Transform ◽  
Energetic Materials ◽  
Great Influence ◽  
Fourier Transform Infrared ◽  
Thermal Decomposition Mechanism ◽  
Scanning Calorimetry ◽  
In Situ Ftir Spectroscopy ◽  
Heat Resistant

AbstractOrganic inner salt structures are ideal backbones for heat-resistant energetic materials and systematic studies towards the thermal properties of energetic organic inner salt structures are crucial to their applications. Herein, we report a comparative thermal research of two energetic organic inner salts with different tetraazapentalene backbones. Detailed thermal decomposition behaviors and kinetics were investigated through differential scanning calorimetry and thermogravimetric analysis (DSC-TG) methods, showing that the thermal stability of the inner salts is higher than most of the traditional heat-resistant energetic materials. Further studies towards the thermal decomposition mechanism were carried out through condensed-phase thermolysis/Fourier-transform infrared (in-situ FTIR) spectroscopy and the combination of differential scanning calorimetry-thermogravimetry-mass spectrometry-Fourier-transform infrared spectroscopy (DSC-TG-MS-FTIR) techniques. The experiment and calculation results prove that the arrangement of the inner salt backbones has great influence on the thermal decompositions of the corresponding energetic materials. The weak N4-N5 bond in “y-” pattern tetraazapentalene backbone lead to early decomposition process and the “z-” pattern tetraazapentalene backbone exhibits more concentrated decomposition behaviors.

The thermal degradation of μ-Diphenylacetylene-bis(tricarbonylcobalt)

1973 ◽  
Vol 26 (8) ◽  
pp. 1791 ◽  
Author(s):  
RS Dickson ◽  
LJ Michel
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Carbon Monoxide ◽  
Thermal Degradation ◽  
Organic Compounds ◽  
Degradation Mechanism ◽  
Scanning Calorimetry ◽  
Organic Products ◽  
Suitable Temperature ◽  
Degradation Reaction

The thermal decomposition of Co2(CO)6(PhC2Ph) has been investigated in detail. Differential scanning calorimetry was used to determine the most suitable temperature range for the study. At 180�, Co2(CO)6(PhC2Ph) decomposes to form cobalt, carbon monoxide, tetraphenylcyclopentadienone, hexaphenylbenzene, and other organic compounds. Variation in the temperature, the time, and the solvent used for the degradation reaction causes significant changes in the yields of the organic products. An investigation of the effects of adding stoichiometric amounts of free alkyne, tetra-phenylcyclopentadienone, and hexaphenylbenzene has been initiated in an attempt to understand the degradation mechanism.

scholarly journals Thermal stability and thermal decomposition of sucralose

2018 ◽  
Vol 39 (4) ◽  
pp. 21
Author(s):  
Gilbert Bannach ◽  
Rafael R. Almeida ◽  
Luis G. Lacerda ◽  
Egon Schnitzler ◽  
Massao Ionashiro
Keyword(s):  
Thermal Stability ◽  
Thermal Analysis ◽  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Differential Thermal Analysis ◽  
Infrared Spectroscopy ◽  
Scanning Calorimetry ◽  
Thermoanalytical Techniques ◽  
Thermal Stability Of

Several papers have been described on the thermal stability of the sweetener, C12H19Cl3O8 (Sucralose). Nevertheless no study using thermoanalytical techniques was found in the literature. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC) and infrared spectroscopy, have been used to study the thermal stability and thermal decomposition of sweetener.

Influence of Cadmium Oxide on Thermal Hazard of AP-CMDB Propellants

2015 ◽  
Vol 1095 ◽  
pp. 419-422 ◽  
Author(s):  
Hao Nan Jia ◽  
Gui E Lu ◽  
Zhen Tao An ◽  
Jin Yong Jiang ◽  
Qiang Ge ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Decomposition Rate ◽  
Initial Temperature ◽  
Cadmium Oxide ◽  
Thermal Hazard ◽  
Test Results ◽  
Thermal Safety ◽  
Scanning Calorimetry ◽  
Two Stages

The influence of cadmium oxide on the thermal decomposition behaviors of AP-CMDB propellants was studied by differential scanning calorimetry (DSC) and accelerating rate calorimetry (ARC). The test results show that the decomposition process of AP-CMDB can be divided into two stages. Cadmium oxide can increase the initial temperature, slow down the decomposition rate and improve the thermal safety of AP-CMDB.

Curing behaviors of cyanate ester/epoxy copolymers and their dielectric properties

2016 ◽  
Vol 29 (10) ◽  
pp. 1175-1184 ◽  
Author(s):  
Yangxue Lei ◽  
Mingzhen Xu ◽  
Mingli Jiang ◽  
Yumin Huang ◽  
Xiaobo Liu
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Fourier Transform ◽  
Dielectric Properties ◽  
Small Extent ◽  
Dielectric Constants ◽  
Cyanate Ester ◽  
Scanning Calorimetry ◽  
Peak Fitting ◽  
Curing Kinetic

The curing behavior and dielectric properties of cyanate ester/epoxy (EP) with a latent initiator imidazole was investigated as a function of blend composition. Differential scanning calorimetry (DSC) was used to investigate the dynamic cure behavior of the blends. Multiheating rate DSC, peak fitting, and iso-conversion method were applied to analyze the curing kinetic parameters. Two distinct peaks were fitted from the dynamic DSC curve and the activation energies of each reaction varied with the increase of curing degrees. Fourier transform infrared spectra revealed that several reactions coexisted during the curing processes of cyanate and EP, resulting in the coexistence of the polymers and copolymers in the final composites. The dielectric properties of the composites were studied and the phenomenon that the dielectric constants for all of the composites are independent of frequency was observed. The thermal decomposition characteristics of the blends were investigated using thermogravimetric analysis. By increasing the content of EP, the thermal properties of the cured blends were improved to a small extent, while the char yield markedly decreased.

scholarly journals Hydrothermal Synthesis of Hematite Nanoparticles Decorated on Carbon Mesospheres and Their Synergetic Action on the Thermal Decomposition of Nitrocellulose

Nanomaterials ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 968 ◽  
Author(s):  
Abdenacer Benhammada ◽  
Djalal Trache ◽  
Mohamed Kesraoui ◽  
Salim Chelouche
Keyword(s):  
Activation Energy ◽  
Thermal Decomposition ◽  
Analytical Techniques ◽  
Decomposition Reaction ◽  
Decomposition Temperature ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Nano Catalyst ◽  
Average Size ◽  
A Minor

In this study, carbon mesospheres (CMS) and iron oxide nanoparticles decorated on carbon mesospheres (Fe2O3-CMS) were effectively synthesized by a direct and simple hydrothermal approach. α-Fe2O3 nanoparticles have been successfully dispersed in situ on a CMS surface. The nanoparticles obtained have been characterized by employing different analytical techniques encompassing Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, X-ray diffraction (XRD) and scanning electron microscopy (SEM). The produced carbon mesospheres, mostly spherical in shape, exhibited an average size of 334.5 nm, whereas that of Fe2O3 supported on CMS is at around 80 nm. The catalytic effect of the nanocatalyst on the thermal behavior of cellulose nitrate (NC) was investigated by utilizing differential scanning calorimetry (DSC). The determination of kinetic parameters has been carried out using four isoconversional kinetic methods based on DSC data obtained at various heating rates. It is demonstrated that Fe2O3-CMS have a minor influence on the decomposition temperature of NC, while a noticeable diminution of the activation energy is acquired. In contrast, pure CMS have a slight stabilizing effect with an increase of apparent activation energy. Furthermore, the decomposition reaction mechanism of NC is affected by the introduction of the nano-catalyst. Lastly, we can infer that Fe2O3-CMS may be securely employed as an effective catalyst for the thermal decomposition of NC.

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