Corrosion Behavior of Cu50Zr40Ti10 Metallic Glass in HCl and NaCl

2013 ◽  
Vol 643 ◽  
pp. 33-36
Author(s):  
Wei Ke An ◽  
An Hui Cai ◽  
Guo Jun Zhou ◽  
Yun Luo ◽  
Tie Lin Li ◽  
...  
Keyword(s):  
Metallic Glass ◽  
Corrosion Behavior ◽  
Corrosion Potential ◽  
Chloride Ion ◽  
Corrosion Current ◽  
Ion Concentration ◽  
Nacl Solution ◽  
Current Densities

The corrosion behavior of Cu50Zr40Ti10 (at. %) in HCl and NaCl solutions was investigated. The corrosion current densities icorr in HCl and NaCl solutions increase with increasing Clconcentration when the Cl- concentration is <0.5 molL-1, then continuously increase in the former and decrease in the latter. The icorr is larger in the latter than in the former when the Clconcentration is <0.5 molL-1, while inversely for in 1 molL-1 Cl- solution. The corrosion potential Ecorr decreases with increasing Cl- concentration in HCl. However, the change of the Ecorr vs. the chloride ion concentration in NaCl solution appears down-up-down.

Corrosion Behavior of Zr53.5Cu26.5Ni5Al12Ag3 Bulk Amorphous Alloy in 3.5% NaCl Solution

2011 ◽  
Vol 299-300 ◽  
pp. 427-431
Author(s):  
Yun Li ◽  
Shi Zhi Shang ◽  
Ming Cheng ◽  
Liang Xu ◽  
Shi Hong Zhang
Keyword(s):  
Corrosion Resistance ◽  
Amorphous Alloy ◽  
Passive Film ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Corrosion Current ◽  
Bulk Amorphous Alloy ◽  
Nacl Solution ◽  
Current Densities ◽  
Resistance Decrease

The corrosion behavior of Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy in 3.5% NaCl solution was investigated by using potentiodynamic polarization experiments and electrochemical impedance spectroscopy (EIS). The results show that Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy has the better corrosion resistance than its corresponding crystal alloy. During the bath in the 3.5% NaCl solution at 25°C, Zr53.5Cu26.5Ni5Al12Ag3 alloy has the lower corrosion current density than the corresponding crystal alloy. After 100h, the corrosion current densities of Zr53.5Cu26.5Ni5Al12Ag3 and the corresponding crystal alloy are 3.8415×10-8A/cm2 and 5.2827×10-7A/cm2, respectively. The results of EIS test indicate that Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy has the excellent corrosion resistance because passive film with stable structure formed on the surface in 3.5% NaCl solution. With an increase in the immersion time, the passive film becomes thicker. It leads to impedance resistance and corrosion resistance decrease. The surface of Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy in 3.5% NaCl solution for 100h was analyzed by SEM and EDS. The results show that the corrosive pitting can be found at both the amorphous alloy and the corresponding crystal alloy. However, the amorphous alloy has the better corrosive pitting resistance than the crystal one because the corrosion products formed by selective dissolving of Zr and Al elements. Moreover, the addition of Ag element helps to improve the corrosion resistance of the amorphous alloy greatly.

scholarly journals Study of corrosion ofAI- bronze in Sodium Chioride Solution in the Presence ofbenzotriazole

2004 ◽  
Vol 1 (2) ◽  
pp. 289-294
Author(s):  
Baghdad Science Journal
Keyword(s):  
Corrosion Potential ◽  
Corrosion Current ◽  
Aluminum Bronze ◽  
Nacl Solution ◽  
Transfer Coefficients ◽  
Kinetics Parameters ◽  
Protection Efficiency ◽  
Corrosion Reaction ◽  
Current Densities ◽  
Increasing Temperature

The corcosion behoviour of Aluminum bronze in sodium chloride solution has been studied ^tentiostatically at five temperatures in the range 293-313K.The corrosion potential shifted to more negative values with increasing temperature. The corrosion current density increased with increasing temperature. Values of Tal'el slopes and the transfer coefficients indicated hydrogen evolution reaction to occur at the cathode and mainly the dissolution at the anode.Benzotriazole (BTA) had an inhibiting effect ??? the corrosion of the Al-bronze in deaerated NaCl solution at a concentration (1*10'?- IxlO‘1) mol dm'^ over the temperature range 293-313K. Values of the protection efficiency and kinetics parameters were obtained from the corrosion current densities. 'I’he results indicated that corrosion reaction on Al-bronze occurred on surface sites having different energies of activation.

Studies on the Influence of Chloride Ion Concentration on the Corrosion Behavior of ZSMX Magnesium Alloy

2010 ◽  
Vol 95 ◽  
pp. 47-50 ◽  
Author(s):  
Guy Ben-Hamu ◽  
D. Eliezer ◽  
Kwang Seon Shin
Keyword(s):  
Magnesium Alloy ◽  
Corrosion Rate ◽  
Corrosion Behavior ◽  
Potentiodynamic Polarization ◽  
Electrochemical Behavior ◽  
Chloride Ion ◽  
Ion Concentration ◽  
Experimental Techniques ◽  
Nacl Solution ◽  
Wrought Magnesium Alloy

The paper presented reveals the influence of chloride ion concentration on the corrosion and electrochemical behavior of new ZSMX wrought magnesium alloy in NaCl solution. The experimental techniques used include potentiodynamic polarization tests. The corrosion rate usually increased with the increase in chloride ion concentration. This result can be explained by the distribution of intermetalics.

scholarly journals Chemical Composition and Corrosion Behavior of a-C:H/DLC Film-Coated Titanium Substrate in Simulated PEMFC Environment

Coatings ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 820
Author(s):  
Beibei Han ◽  
Mengyuan Yan ◽  
Dongying Ju ◽  
Maorong Chai ◽  
Susumu Sato
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Metal Ion ◽  
Ion Beam ◽  
Titanium Substrate ◽  
Corrosion Current ◽  
Ion Concentration ◽  
Bipolar Plates ◽  
High Adhesion ◽  
Corrosion Behaviors

The amorphous hydrogenated (a-C:H) film-coated titanium, using different CH4/H2 and deposition times, was prepared by the ion beam deposition (IBD) method, which has the advantage of high adhesion because of the graded interface mixes at the atomic level. The chemical characterizations and corrosion behaviors of a-C:H film were investigated and evaluated by SEM, AFM, Raman spectroscopy, EPMA, TEM and XPS. An a-C:H film-coated titanium was corroded at 0.8 V, 90 °C in a 0.5 mol/L H2SO4 solution for 168 h. The metal ion concentration in the H2SO4 corrosion solution and the potentiodynamic polarization behavior were evaluated. Results indicate that a higher CH4/H2 of 1:0 and a deposition time of 12 h can result in a minimum ID/IG ratio of 0.827, Ra of 5.76 nm, metal ion concentration of 0.34 ppm in the corrosion solution and a corrosion current of 0.23 µA/cm2. The current density in this work meets the DOE’s 2020 target of 1 µA/cm2. Electrical conductivity is inversely proportional to the corrosion resistance. The significant improvement in the corrosion resistance of the a-C:H film was mainly attributed to the increased sp3 element and nanocrystalline TiC phase in the penetration layer. As a result, the a-C:H film-coated titanium at CH4/H2 = 1:0 with improved anti-corrosion behavior creates a great potential for PEMFC bipolar plates.

scholarly journals A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering

DYNA ◽  
2018 ◽  
Vol 85 (207) ◽  
pp. 192-197 ◽  
Author(s):  
Estrella Natali Borja-Goyeneche ◽  
Jhon Jairo Olaya-Florez
Keyword(s):  
Corrosion Resistance ◽  
Nickel Content ◽  
Corrosion Current ◽  
Nacl Solution ◽  
X Ray Diffraction ◽  
X Ray ◽  
X Ray Scattering ◽  
Current Densities ◽  
Fcc Phase

This work researches the influence of the nickel content on the structural and anticorrosive properties of ZrSiTiN films deposited by means of reactive co-sputtering on alloys of Ti6Al4V. The morphology and structure were analyzed by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD), and the chemical composition was identified via X-ray scattering spectroscopy (EDS). The corrosion resistance was studied using potentiodynamic polarization (PP) tests employing a 3.5% by weight NaCl solution. In the films, an increase of Ni up to 6.97 at% was observed, while in XRD the FCC phase of (Zr, Ti) N was identified, with a mixed orientation in planes (111) and (200), which tended to diminish with the increase of Ni. Finally, with the addition of Ni, the corrosion current densities were reduced from 5.56 𝑥 10−8 to 2.64 𝑥 10−9 𝐴/𝑐m2. The improvement in the corrosion resistance is due to the effect of the Ni on the microstructure of the system (Zr, Ti) N, which can improve the quality of the passive film and prevent crystalline defects and corrosion zones.

Electrochemical Characteristics of Lanthanum Hexaboride in the Environments Containing S2-

2010 ◽  
Vol 663-665 ◽  
pp. 473-476
Author(s):  
Shu Qi Zheng ◽  
Chang Feng Chen ◽  
Rui Jing Jiang ◽  
Dan Ni Wang
Keyword(s):  
Partial Pressure ◽  
Corrosion Behavior ◽  
Current Density ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
Lanthanum Hexaboride ◽  
Electrochemical Characteristics

In the environment with H2S/CO2 or Na2S, the corrosion behavior of Lanthanum hexaboride (LaB6) was investigated by electrochemistry methods. The results indicated that the corrosion potential (Ecorr) and Rf of LaB6 increased as the partial pressure of H2S increased, while the corrosion current density (Icorr) decreased. In the environment containing Na2S, as the content of Na2S increased, the corrosion potential (Ecorr) and Rf of LaB6 decreased, while the corrosion current density (Icorr) increased. Thus, the addition of H2S into the environment with H2S/CO2 would inhibit the corrosion of LaB6; while in the environment containing Na2S, the increasing of the content of Na2S would accelerate the corrosion of LaB6.

Effect of Osmotic Pressure by Salt Concentration on Corrosion Resistance of Anti-Corrosive Paint

2018 ◽  
Vol 926 ◽  
pp. 31-36
Author(s):  
Kyung Man Moon ◽  
Myeong Hoon Lee ◽  
Tae Sil Baek
Keyword(s):  
Corrosion Resistance ◽  
Osmotic Pressure ◽  
Salt Concentration ◽  
Corrosion Current Density ◽  
Steel Plate ◽  
Chloride Ion ◽  
Corrosion Current ◽  
Coating Film ◽  
Coated Steel ◽  
Nacl Solution

Recently, many types of constructional steels have been often exposed to severely corrosive environments due to acid rain with increasing environmental contamination. To control corrosion problems, a painting protection method has been widely applied to numerous constructional steels on land as well as offshore. Therefore, development of anti-corrosive paint with good quality of corrosion resistance is very important from an economical perspective. In this study, four types of anti-corrosive paint were coated to test specimens, and then, were immersed in various salt solutions (0.1, 3 and 9% NaCl solution) for 11 days. Corrosion resistance of these samples by effect of osmotic pressure with various salt concentration was investigated with electrochemical methods such as measurement of corrosion potential, impedance and corrosion current density. Corrosion current density of these samples submerged in 0.1% NaCl solution exhibited highest value than those immersed in 3% and 9% NaCl solutions because water, dissolved oxygen and chloride ion etc. is easily to invade towards inner side of coating film due to increasing osmotic pressure compared to 3% and 9% NaCl solutions. However, corrosion current densities of all samples in the case of submerged in 9% NaCl solution exhibited higher values compared to 3% NaCl solution.Thus, a large amount of chloride ion dissolved in 9% NaCl solution plays a more critical role in corrosion behavior of coated steel rather than osmotic pressure. Consequently, the corrosion mechanism between coated steel and bare steel plates is different from each other because of presence of osmotic pressure between salt solution and coating film of coated steel plate. As a result, corrosion resistance of tcoated steel plate may be depend on the osmotic pressure as well as salt concentration

Microstructure and Electrochemical Properties of Ce-Containing 7072 Al Alloy

2013 ◽  
Vol 704 ◽  
pp. 114-119
Author(s):  
Jing Feng ◽  
Dong Yan Ding ◽  
Wen Long Zhang ◽  
Yong Jin Gao ◽  
Guo Zhen Chen ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Electrochemical Properties ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
Al Alloy ◽  
Nacl Solution ◽  
Tafel Polarization ◽  
Electrochemical Testing ◽  
Transmission Electron ◽  
Positive Effect

The microstructure and electrochemical properties of Ce-containing 7072 Al alloy were investigated through transmission electron microscopy (TEM), scanning electron microscopy (SEM) and Tafel polarization analysis. It was found that Ce alloying could result in a formation of finer grains in the simulated brazing alloys. The 7072 Al alloy with 0.15% Ce had desirable distribution of precipitates. The electrochemical testing results indicated that Ce element had a great impact on the corrosion potential of the alloy tested in 0.5% NaCl solution. Alloying with 0.15% Ce element could make the corrosion potential shift to inert direction and reduce the corrosion current density. An excessive Ce addition could weaken its positive effect on the corrosion resistance of the Ce-containing alloy.

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