Effects of Kenaf and Rice Husk on Thermal Properties of Kenaf/CaCO3/HDPE and Rice Husk/CaCO3/HDPE Hybrid Composites

2013 ◽  
Vol 748 ◽  
pp. 201-205
Author(s):  
Abd Aziz Noor Zuhaira ◽  
Rahmah Mohamed
Keyword(s):  
Thermal Stability ◽  
Thermal Properties ◽  
Rice Husk ◽  
Natural Fiber ◽  
Hybrid Composites ◽  
Degree Of Crystallinity ◽  
Differential Scanning Calorimetric ◽  
Kenaf Fiber ◽  
Twin Screw ◽  
Thermal Stability Of

In this research, rice husk and kenaf fiber were compounded with calcium carbonate (CaCO3)/high density polyethylene (HDPE) composite.Different loadings of up to 30 parts of 50 mesh sizes of rice husk particulate and kenaf fiber were compounded using twin-screw extruder with fixed 30 parts of CaCO3 fillerto produce hybrid composites of rice husk/CaCO3/HDPE and kenaf/CaCO3/HDPE.Compounded hybrid composites were prepared and tested for thermal properties. The thermal stability of the components was examined by thermogravimetricanalysis (TGA) and differential scanning calorimetric (DSC). The DSC results showed a slightly changes in melting temperature (Tm), crystallization temperature (Tc) and the degree of crystallinity (Xc) with addition of natural fiber. TGA indicates thermal stability of hybrid composite filled with kenaf or rice husk is better than unfilledCaCO3/HDPE composite.

Effect of Calcium Carbonate on Thermal Properties of CaCO3/Kenaf/HDPE and CaCO3/Rice Husk/HDPE Composites

2013 ◽  
Vol 812 ◽  
pp. 175-180 ◽  
Author(s):  
Abd Aziz Noor Zuhaira ◽  
Mohamed Rahmah
Keyword(s):  
Thermal Stability ◽  
Thermal Properties ◽  
Calcium Carbonate ◽  
Rice Husk ◽  
Hybrid Composite ◽  
Hybrid Composites ◽  
Natural Fibers ◽  
Filler Loading ◽  
Degree Of Crystallinity ◽  
Differential Scanning Calorimetric

In this research, the thermal properties of 30% filler loading of natural fibers with varying filler loadings of calcium carbonate (CaCO3) were studied. CaCO3 was compounded using twin-screw extruder with rice husk/high density polyethylene (HDPE) and kenaf/HDPE composites to produce composites. Compounded composites were prepared and tested for thermal properties. The thermal stability of the components was examined by thermogravimetric analysis (TGA) and differential scanning calorimetric (DSC) to identify the influence of CaCO3 filler loading on thermal properties of the composites. The cycle heating for TGA was 30-800°C while for differential scanning calorimetric (DSC) was 30-300°C. Melting temperature (Tm) of kenaf/HDPE hybrid composites increased slightly with addition of 10% CaCO3. However, decreasing Tm was found for all CaCO3 filler loading in rice husk/HDPE composites. The DSC analysis showed that the degree of crystallinity (Xc) of hybrid composite decrease with the addition of CaCO3 filler loading. From TGA result, CaCO3/kenaf/HDPE hybrid composite showed better thermal stability compared to CaCO3/rice husk/HDPE hybrid composite.

The Influence of Moisture Absorption on the Mechanical and Thermal Properties of Chemically Treated DPL Reinforced Hybrid Composite

2020 ◽  
Vol 978 ◽  
pp. 316-322 ◽  
Author(s):  
Priyadarshi Tapas Ranjan Swain ◽  
Sankar Narayan Das ◽  
Prabina Kumar Patnaik ◽  
Abhilash Purohit
Keyword(s):  
Thermal Properties ◽  
Glass Fiber ◽  
Moisture Absorption ◽  
Natural Fiber ◽  
Hybrid Composites ◽  
Synthetic Fiber ◽  
Differential Scanning Calorimetric ◽  
Mechanical And Thermal Properties ◽  
Weight Percentage ◽  
Chemically Treated

Moisture absorption of natural fiber-based composites is one of the major problems in outdoor applications. The present study deals with the effect of moisture absorption on mechanical and thermal properties of unmodified/modified Date Palm Leaf (DPL) with glass fiber-based hybrid composites. Natural fibers were modified with alkaline treatment to improve fiber and matrix bonding. Conventional hand lay-up technique is used to fabricate the composites with varying different wt.% of treated and untreated short DPL with constant wt.% of glass fiber and prepared with random oriented manner. The combine effect of hydrophilic and hydrophobic nature find out as the study based upon the natural with synthetic fiber hybrid composites. Mechanical behaviour of the epoxy-based hybrid composites were characterized by using tensile, flexural and hardness test. The results revealed that significant improvement in mechanical properties by the addition of different weight percentage of modified DPL. Different thermal properties of the composites were described by using Thermo Gravimetric Analyzer (TGA) and Differential Scanning Calorimetric (DSC). Morphological investigation was carried out to by using scanning electron microscope. All the properties of untreated natural fiber reinforced composites were mostly affected by the influence of water absorption as compared with chemically treated based composites.

Thermal Stability of PALF-PP and PALF-PLA for Natural Fiber Honeycomb Core Materials

2021 ◽  
Vol 87 (1) ◽  
pp. 20-29
Author(s):  
Amira Syuhada Zainudin ◽  
Abdul Rahim Othman
Keyword(s):  
Thermal Stability ◽  
Natural Fiber ◽  
Thermal Characteristic ◽  
Inert Atmosphere ◽  
Filler Loading ◽  
Differential Scanning Calorimetric ◽  
Dsc Analysis ◽  
Honeycomb Core ◽  
Nitrogen Gas ◽  
Thermal Stability Of

This paper studied the thermal behaviour of pineapple leaf fiber (PALF) reinforced with polypropylene (PP) and polylactic acid (PLA) composite, used for natural fiber honeycomb core. Thermogravimetric analysis (TGA) and differential scanning calorimetric (DSC) analysis were used to measure the thermal characteristic of PALF-PP/PLA composites. In particular, the TGA analysis was utilized to measure the degradation and decomposition of materials in different composition (NF-PP/PLA (0%, 15%, 30% and 50%). The measurements were carried out in the temperature of 0oC- 900oC, at a heating rate of 10oCmin-1 and under an inert atmosphere (nitrogen gas). The temperature of DSC analysis was programmed to between 25oC- 500oC. The result shows the thermal stability of PALF-PP/PLA decreased as the PALF filler-loading increased. While from the DSC analysis this study clearly shows in the graph plot, the sample have glass transition temperature, crystallization and melting temperature. So that means the sample in this study is crystalline and amorphous domains.

scholarly journals Mechanical and Thermal Properties of Montmorillonite-Reinforced Polypropylene/Rice Husk Hybrid Nanocomposites

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1557 ◽  
Author(s):  
Khaliq Majeed ◽  
Ashfaq Ahmed ◽  
Muhammad Saifullah Abu Bakar ◽  
Teuku Meurah Indra Mahlia ◽  
Naheed Saba ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Thermal Properties ◽  
Rice Husk ◽  
Hybrid Nanocomposites ◽  
Commercial Application ◽  
Mechanical And Thermal Properties ◽  
Melt Mixing ◽  
Compatibilizing Agent ◽  
Thermal Stability Of

In recent years, there has been considerable interest in the use of natural fibers as potential reinforcing fillers in polymer composites despite their hydrophilicity, which limits their widespread commercial application. The present study explored the fabrication of nanocomposites by melt mixing, using an internal mixer followed by a compression molding technique, and incorporating rice husk (RH) as a renewable natural filler, montmorillonite (MMT) nanoclay as water-resistant reinforcing nanoparticles, and polypropylene-grafted maleic anhydride (PP-g-MAH) as a compatibilizing agent. To correlate the effect of MMT delamination and MMT/RH dispersion in the composites, the mechanical and thermal properties of the composites were studied. XRD analysis revealed delamination of MMT platelets due to an increase in their interlayer spacing, and SEM micrographs indicated improved dispersion of the filler(s) from the use of compatibilizers. The mechanical properties were improved by the incorporation of MMT into the PP/RH system and the reinforcing effect was remarkable as a result of the use of compatibilizing agent. Prolonged water exposure of the prepared samples decreased their tensile and flexural properties. Interestingly, the maximum decrease was observed for PP/RH composites and the minimum was for MMT-reinforced and PP-g-MAH-compatibilized PP/RH composites. DSC results revealed an increase in crystallinity with the addition of filler(s), while the melting and crystallization temperatures remained unaltered. TGA revealed that MMT addition and its delamination in the composite systems improved the thermal stability of the developed nanocomposites. Overall, we conclude that MMT nanoclay is an effective water-resistant reinforcing nanoparticle that enhances the durability, mechanical properties, and thermal stability of composites.

scholarly journals Impact of Spherical Anatase TiO2 Nanoparticles on Thermal Properties of Polypropylene Resin

2021 ◽  
Author(s):  
Ahlem Bendaoued ◽  
Mouna Messaoud ◽  
Omar Harzallah ◽  
Sophie Bistac ◽  
Rached Salhi
Keyword(s):  
Thermal Stability ◽  
Thermal Properties ◽  
Sol Gel ◽  
Thermal Characterization ◽  
Degree Of Crystallinity ◽  
Molar Ratio ◽  
Excellent Thermal Stability ◽  
Energy Applications ◽  
Production Of Hydrogen ◽  
Thermal Stability Of

Abstract Ceramics nanometric reinforced polymer composite is a significant material for catalysis, solar cells, production of hydrogen and energy applications, etc. In order to take benefit from the interesting mechanical properties and thermal stability of TiO2, these ceramic nanomaterials was synthesized by the Sol-Gel process in attempt to study the thermal stability, structure, and morphology of the resulting nanoparticles powders. The obtained results revealed that, the sphere is composed of 20-30 nm nanoparticles with excellent thermal stability of nano-TiO2. This work focused on the thermal characterization and the study of nanocomposite xWt. %TiO2/PP (x=0, 2.5, 5, 7.5 mol%). In this study, the obtained results revealed that the molar ratio of TiO2 influences the final thermal stability and degree of crystallinity of the composite. It was found that the use of TiO2 seems to be an effective and very promising way to increase the thermal properties of the resulting composite. The greatest degree of crystallinity (54.80%) and thermal degradation stability are obtained for composite reinforced by 7.5Wt. %TiO2.

Mechanical and Thermal Properties of Hybrid Non-Woven Kenaf Fibre Mat-Graphene Nanoplatelets reinforced Polypropylene Composites

2020 ◽  
Vol 1010 ◽  
pp. 124-129 ◽  
Author(s):  
Haziq Amri Mohd ◽  
Mohamad Bashree Abu Bakar ◽  
Mohamad Najmi Masri ◽  
Muhammad Azwadi Sulaiman ◽  
Mohd Hazim Mohamad Amini ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Thermal Properties ◽  
Hybrid Composites ◽  
Promising Result ◽  
Testing Machine ◽  
Graphene Nanoplatelets ◽  
Mechanical And Thermal Properties ◽  
Compression Moulding ◽  
Kenaf Fibre ◽  
Thermal Stability Of

In this study, kenaf fibre mat (NWKFM)-graphene nanoplatelets (GNP) reinforced polypropylene (PP) composites were fabricated by using compression moulding. The hybridization was done to enhance the mechanical and thermal properties by adding different amount of graphene nanoplatelets as filler in the biocomposite samples. Pure PP and nanocomposite samples of PP+GNP were also fabricated. Maleic anhydride grafted polypropylene (MAPP) was used as a coupling agent to increase the interfacial adhesion of matrix and reinforcement of the biocomposites and hybrid composites samples. The chemical composition and constituent changes were studied by using Fourier transform infrared spectroscopy (FTIR) analysis. The mechanical properties in term of flexural and tensile were tested using a universal testing machine (UTM). Thermogravimetric analysis (TGA) was carried out to determine the thermal stability of the composite’s samples. Overall, the results show that the stiffness properties (young’s and tensile modulus) of pure PP and biocomposites enhanced with addition of GNP. The flexural strength also shows promising result with the inclusion of GNP. However, the tensile strength shows a reduction with the addition of GNP. The TGA results reveal that the addition of GNP increases the thermal stability of pure PP and the biocomposites based on the comparison of Tonset values.

Investigation of Thermal and Rheological Properties of Polypropylene and Montmorillonite (MMT) Nanocomposites

2015 ◽  
Vol 1105 ◽  
pp. 3-6
Author(s):  
A.A. Yussuf ◽  
M.A. Al-Saleh ◽  
S.T. Al-Enezi
Keyword(s):  
Thermal Stability ◽  
Thermal Properties ◽  
Rheological Properties ◽  
Low Frequency ◽  
Complex Viscosity ◽  
Nanocomposite Films ◽  
Twin Screw Extruder ◽  
Screw Extruder ◽  
Twin Screw ◽  
Thermal Stability Of

The performances of PP/MMT nanocomposite (70μm thick films), in terms of thermal and rheological properties were investigated. A twin-screw extruder was used to compound PP, MMT, compatibilizer, and extruded nanocomposite films were collected for test. All results were compared and the influence of MMT contents on the final properties were observed and reported. The thermal properties of PP had improved by increasing MMT content from 0-3 phr. However at 4 phr thermal stability of the nanocomposite had slightly dropped. In terms of rhelogical properties, the addition of MMT to the PP blend increased the complex viscosity of the nanocomposites, particularly at low frequency regions.

scholarly journals Thermal and Flammability Properties of Kenaf/Recycled Carbon Filled with Cardanol Hybrid Composites

2019 ◽  
Vol 2019 ◽  
pp. 1-7 ◽  
Author(s):  
Zahra Dashtizadeh ◽  
K. Abdan ◽  
M. Jawaid ◽  
Masoud Dashtizadeh
Keyword(s):  
Thermal Stability ◽  
Thermal Properties ◽  
Flame Retardancy ◽  
Hybrid Composites ◽  
Cashew Nut Shell Liquid ◽  
Fiber Loading ◽  
Cashew Nut ◽  
The Matrix ◽  
Cashew Nut Shell ◽  
Thermal Stability Of

In this paper, hybrid composites were fabricated by using kenaf and recycled carbon with a cashew nut shell liquid (CNSL) derivative known as cardanol as the matrix by a compression molding technique. In this work, we look for the effect of recycled carbon weight loading (15%, 25%, and 35%) on the thermal properties of kenaf/cardanol composites while maintaining the total fiber loading of 50 wt%. TGA, DSC, DMA, and flammability UL 90 HB properties of the specimens were studied. The results indicate that cardanol improved the thermal stability of kenaf and hybridization with recycled carbon also further improved the thermal stability of the specimens. The flammability UL 90 HB test determines the flame retardancy property of all specimens.

Mechanical and thermal characterization of grafted PP-NCC nanocomposites

2019 ◽  
pp. 089270571987822
Author(s):  
Saud Aldajah ◽  
Mohammad Y Al-Haik ◽  
Waseem Siddique ◽  
Mohammad M Kabir ◽  
Yousef Haik
Keyword(s):  
Thermal Properties ◽  
Interfacial Adhesion ◽  
Thermal Characterization ◽  
Mechanical And Thermal Properties ◽  
Screw Extruder ◽  
Scanning Calorimetry ◽  
Three Point Bending ◽  
Twin Screw ◽  
Thermal Stability Of

This study reveals the enhancement of mechanical and thermal properties of maleic anhydride-grafted polypropylene (PP- g-MA) with the addition of nanocrystalline cellulose (NCC). A nanocomposite was manufactured by blending various percentages of PP, MA, and NCC nanoparticles by means of a twin-screw extruder. The influence of varying the percentages of NCC on the mechanical and thermal behavior of the nanocomposite was studied by performing three-point bending, nanoindentation, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and Fourier-transform infrared (FTIR) spectroscopy tests. The novelty of this study stems on the NCC nanoparticles and their ability to enhance the mechanical and thermal properties of PP. Three-point bending and nanoindentation tests revealed improvement in the mechanical properties in terms of strength, modulus, and hardness of the PP- g-MA nanocomposites as the addition of NCC increased. SEM showed homogeneity between the mixtures which proved the presence of interfacial adhesion between the PP- g-MA incorporated with NCC nanoparticles that was confirmed by the FTIR results. DSC and TGA measurements showed that the thermal stability of the nanocomposites was not compromised due to the addition of the coupling agent and reinforced nanoparticles.

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