Mechanical and Thermal Properties of Hybrid Non-Woven Kenaf Fibre Mat-Graphene Nanoplatelets reinforced Polypropylene Composites

2020 ◽  
Vol 1010 ◽  
pp. 124-129 ◽  
Author(s):  
Haziq Amri Mohd ◽  
Mohamad Bashree Abu Bakar ◽  
Mohamad Najmi Masri ◽  
Muhammad Azwadi Sulaiman ◽  
Mohd Hazim Mohamad Amini ◽  
...  

In this study, kenaf fibre mat (NWKFM)-graphene nanoplatelets (GNP) reinforced polypropylene (PP) composites were fabricated by using compression moulding. The hybridization was done to enhance the mechanical and thermal properties by adding different amount of graphene nanoplatelets as filler in the biocomposite samples. Pure PP and nanocomposite samples of PP+GNP were also fabricated. Maleic anhydride grafted polypropylene (MAPP) was used as a coupling agent to increase the interfacial adhesion of matrix and reinforcement of the biocomposites and hybrid composites samples. The chemical composition and constituent changes were studied by using Fourier transform infrared spectroscopy (FTIR) analysis. The mechanical properties in term of flexural and tensile were tested using a universal testing machine (UTM). Thermogravimetric analysis (TGA) was carried out to determine the thermal stability of the composite’s samples. Overall, the results show that the stiffness properties (young’s and tensile modulus) of pure PP and biocomposites enhanced with addition of GNP. The flexural strength also shows promising result with the inclusion of GNP. However, the tensile strength shows a reduction with the addition of GNP. The TGA results reveal that the addition of GNP increases the thermal stability of pure PP and the biocomposites based on the comparison of Tonset values.

2019 ◽  
Vol 972 ◽  
pp. 172-177
Author(s):  
Sirirat Wacharawichanant ◽  
Patteera Opasakornwong ◽  
Ratchadakorn Poohoi ◽  
Manop Phankokkruad

This work studied the effects of various types of cellulose fibers on the morphology, mechanical and thermal properties of poly(lactic acid) (PLA)/propylene-ethylene copolymer (PEC) (90/10 w/w) blends. The PLA/PEC blends before and after adding cellulose fibers were prepared by melt blending method in the internal mixer and molded by compression method. The morphological analysis observed that the presence of cellulose in PLA did not change the phase morphology of PLA, and PLA/cellulose composite surfaces were observed the cellulose fibers inserted in PLA matrix and fiber pull-out. The phase morphology of PLA/PEC blends was changed from brittle fracture to ductile fracture behavior and showed the phase separation between PLA and PEC phases. The presence of celluloses did not improve the compatibility between PLA and PEC phases. The tensile stress and strain curves found that the tensile stress of PLA was the highest value. The addition of all celluloses increased Young’s modulus of PLA. The PEC presence increased the tensile strain of PLA over two times when compared with neat PLA and PLA was toughened by PEC. The incorporation of cellulose fibers in PLA/PEC blends could improve Young’s modulus, tensile strength, and stress at break of the blends. The thermal stability showed that the degradation temperatures of all types of cellulose were less than the degradation temperatures of PLA. Thus, the incorporation of cellulose in PLA could not enhance the thermal stability of PLA composites and PLA/PEC composites. The degradation temperature of PEC was the highest value, but it could not improve the thermal stability of PLA. The incorporation of cellulose fibers had no effect on the melting temperature of the PLA blend and composites.


2013 ◽  
Vol 748 ◽  
pp. 201-205
Author(s):  
Abd Aziz Noor Zuhaira ◽  
Rahmah Mohamed

In this research, rice husk and kenaf fiber were compounded with calcium carbonate (CaCO3)/high density polyethylene (HDPE) composite.Different loadings of up to 30 parts of 50 mesh sizes of rice husk particulate and kenaf fiber were compounded using twin-screw extruder with fixed 30 parts of CaCO3 fillerto produce hybrid composites of rice husk/CaCO3/HDPE and kenaf/CaCO3/HDPE.Compounded hybrid composites were prepared and tested for thermal properties. The thermal stability of the components was examined by thermogravimetricanalysis (TGA) and differential scanning calorimetric (DSC). The DSC results showed a slightly changes in melting temperature (Tm), crystallization temperature (Tc) and the degree of crystallinity (Xc) with addition of natural fiber. TGA indicates thermal stability of hybrid composite filled with kenaf or rice husk is better than unfilledCaCO3/HDPE composite.


2020 ◽  
pp. 002199832097681
Author(s):  
DKK Cavalcanti ◽  
MD Banea ◽  
JSS Neto ◽  
RAA Lima

In this work, a comparative analysis of the mechanical and thermal properties of polyester and epoxy single and hybrid natural fibre-reinforced composites was performed. Pure jute, jute + curauá and jute + sisal composites with two distinct thermoset polymer resins (an epoxy and a polyester) were produced. Tensile, flexural and impact tests were carried out, in accordance to ASTM standards, to investigate and compare the mechanical properties of the composites as a function of matrix and hybridization. In addition, a thermogravimetric analysis (TGA) was used to complete the comparative analysis of the thermal properties. Finally, a scanning electron microscopy (SEM) was used to examine the fracture surface of the tested specimens. It was found that the hybridization process improved the mechanical properties of the non-hybrid jute fibre based composites for both matrices used. The resin used as matrix plays an important role on the mechanical properties of the composites. The epoxy matrix based composites presented higher tensile strength, while the polyester based composites presented higher tensile and flexural stiffness as well as higher impact energy, when compared to the epoxy-based composite. TGA analysis showed that the thermal stability of epoxy-based composites was higher compared to the polyester-based composites.


Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1557 ◽  
Author(s):  
Khaliq Majeed ◽  
Ashfaq Ahmed ◽  
Muhammad Saifullah Abu Bakar ◽  
Teuku Meurah Indra Mahlia ◽  
Naheed Saba ◽  
...  

In recent years, there has been considerable interest in the use of natural fibers as potential reinforcing fillers in polymer composites despite their hydrophilicity, which limits their widespread commercial application. The present study explored the fabrication of nanocomposites by melt mixing, using an internal mixer followed by a compression molding technique, and incorporating rice husk (RH) as a renewable natural filler, montmorillonite (MMT) nanoclay as water-resistant reinforcing nanoparticles, and polypropylene-grafted maleic anhydride (PP-g-MAH) as a compatibilizing agent. To correlate the effect of MMT delamination and MMT/RH dispersion in the composites, the mechanical and thermal properties of the composites were studied. XRD analysis revealed delamination of MMT platelets due to an increase in their interlayer spacing, and SEM micrographs indicated improved dispersion of the filler(s) from the use of compatibilizers. The mechanical properties were improved by the incorporation of MMT into the PP/RH system and the reinforcing effect was remarkable as a result of the use of compatibilizing agent. Prolonged water exposure of the prepared samples decreased their tensile and flexural properties. Interestingly, the maximum decrease was observed for PP/RH composites and the minimum was for MMT-reinforced and PP-g-MAH-compatibilized PP/RH composites. DSC results revealed an increase in crystallinity with the addition of filler(s), while the melting and crystallization temperatures remained unaltered. TGA revealed that MMT addition and its delamination in the composite systems improved the thermal stability of the developed nanocomposites. Overall, we conclude that MMT nanoclay is an effective water-resistant reinforcing nanoparticle that enhances the durability, mechanical properties, and thermal stability of composites.


2018 ◽  
Vol 280 ◽  
pp. 264-269
Author(s):  
Heng Chun Wei ◽  
Teh Pei Leng ◽  
Yeoh Chow Keat

This work reports on mechanical and thermal properties of a novel polymer blend. Blends were prepared by mixing silicone rubber with diphenyl – 4,4 – dissocyanate in different ratios. Graphene nanoplatelets was added as conductive filler to improve the electrical conductivity of the blends. The mechanical properties, including tensile and tear performances were measured by a material testing system. The thermal stability of the blends was measured by thermogravimetric analysis. Incorporation 20 vol.% of silicone rubber can help to improve the thermal stability of the blend, meanwhile optimum mechanical properties of the blends is achieved.


2009 ◽  
Vol 79-82 ◽  
pp. 2027-2030 ◽  
Author(s):  
Poonsub Threepopnatkul ◽  
Chanin Kulsetthanchalee ◽  
K. Bunmee ◽  
N. Kliaklom ◽  
W. Roddouyboon

This research was to study the related mechanical and thermal properties of recycled polypropylene from post consumer containers reinforced with coir fiber. Surface of coir fiber was treated with sodium hydroxide to remove lignin and hemicelluloses and likely to improve the interfacial adhesion in the composites. The composites of treated coir fiber and recycled polypropylene were prepared by varying the coir fiber contents at 5%, 10% and 20% by weight using a twin screw extruder. The thermal properties were investigated by thermal gravimetric analysis (TGA) and differential scanning calorimeter (DSC). The results from TGA showed that thermal stability of the composites was lower than that of recycled polypropylene resin and thermal stability decreased with increasing coir fiber content. From DSC results, it indicated that the crystallinity of treated coir fiber composites increased as a function of fiber content. The mechanical properties of injection-molded samples were studied by universal testing machine. The treated coir fiber composites produced enhanced mechanical properties. The tensile strength, tensile modulus and impact strength of modified coir fiber/recycled polypropylene composites increased as a function of coir fiber content.


2015 ◽  
Vol 37 ◽  
pp. 15 ◽  
Author(s):  
Azin Paydayesh ◽  
Ahmad Aref Azar ◽  
Azam Jalali Arani

In this work, Poly Lactic Acid/Poly methyl Methacrylate (PLA/PMMA) blends in various compositions prepared and morphology and properties of these blends was investigated. Moreover, the effect of adding different amounts of Graphene Nanoplatelets (GNP) on the morphology of the blends (by SEM), the interaction of nanopalates with polymer phases (by FTIR) and its effect on the mechanical properties and thermal stability of the samples were examined. The results of the study showed that in different amounts of graphene, these plates were preferentially located in the polymer phases dissimilarly and thus, caused the change of the blend morphology. In addition, measuring the mechanical properties by tensile test and results of thermal analysis by TGA indicated the improvement of thermal stability, modulus and mechanical strength and reduction of the elongation at break of graphene containing blends with increasing the loading of GNP. The changing behavior of the mechanical and thermal properties was proportional to the Graphene localization in blend phases.


2017 ◽  
Vol 31 (2) ◽  
pp. 246-264 ◽  
Author(s):  
JZ Liang ◽  
JZ Wang ◽  
Gary CP Tsui ◽  
CY Tang

The thermal properties and thermal stability of polypropylene (PP) composites separately filled with graphene nanoplatelets (GNPs) with three different sizes were measured using a differential scanning calorimetry and a thermal gravimetric analyser. The results showed that the values of the melting temperature of the composites were higher than that of the unfilled PP; the thermal stability increased with increasing the weight fraction and lateral dimension of GNPs in the case of low filler concentration, while the effect of the GNPs thickness on the thermal stability was insignificant; the onset decomposition temperature increased with increasing the GNPs lateral dimension, while the maximum thermal decomposition rate increased first and then decreased with increasing the GNPs weight fraction. The thermal stability improvement should be attributed to the sheet barrier function of the GNPs.


2019 ◽  
Vol 2019 ◽  
pp. 1-7 ◽  
Author(s):  
Zahra Dashtizadeh ◽  
K. Abdan ◽  
M. Jawaid ◽  
Masoud Dashtizadeh

In this paper, hybrid composites were fabricated by using kenaf and recycled carbon with a cashew nut shell liquid (CNSL) derivative known as cardanol as the matrix by a compression molding technique. In this work, we look for the effect of recycled carbon weight loading (15%, 25%, and 35%) on the thermal properties of kenaf/cardanol composites while maintaining the total fiber loading of 50 wt%. TGA, DSC, DMA, and flammability UL 90 HB properties of the specimens were studied. The results indicate that cardanol improved the thermal stability of kenaf and hybridization with recycled carbon also further improved the thermal stability of the specimens. The flammability UL 90 HB test determines the flame retardancy property of all specimens.


2019 ◽  
Vol 89 (11) ◽  
pp. 1680
Author(s):  
С.Ю. Зуев ◽  
А.Я. Лопатин ◽  
В.И. Лучин ◽  
Н.Н. Салащенко ◽  
Д.А. Татарский ◽  
...  

The optical, mechanical, and thermal properties of freestanding films based on nitrided molybdenum and zirconium disilicides were investigated. It has been shown that nitriding of silicides leads to a significant increase in the thermal stability of the films. So, if crystallization of initially amorphous freestanding MoSi2 or ZrSi2 films is observed at temperatures of 330-370°C, the introduction of nitrogen into the film makes it possible to increase the temperature up to 600-700°С at which MoSi2Nx and ZrSi2Ny (at least for x ≥ 0.25, y ≥ 1.3) films can be used for many hours when heated under vacuum. The study of mechanical tensile strength showed that the ultimate strength is weakly dependent on the nitrogen content in MoSi2Nx films (0 ≤ x ≤ 0.55). Comparison of the properties of MoSi2Nx and ZrSi2Ny films obtained by the magnetron method at the same nitrogen partial pressure demonstrated that at similar values of the transmittance at 13.5 nm, nitrated ZrSi2 films are more effective as protective coatings (less susceptible to oxidation and more resistant to degradation at high temperatures).


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