Effect of Annealing on Magnetic Properties and Domain Structures of FePt Thin Films by Rapid Thermal Annealing Technique

2009 ◽  
Vol 79-82 ◽  
pp. 911-914
Author(s):  
S.C. Chen ◽  
T.H. Sun ◽  
Po Cheng Kuo

Single-layered FePt films of 30 nm thick were annealed at temperature between 300 and 800 °C for 1–180 sec by a rapid thermal annealing (RTA) with a high heating rate of 100 °C/sec. It is found that both the grain size and magnetic domain size of the FePt film increase with increasing annealing temperature and annealing time. The FePt films exhibited soft magnetic properties and without domain images were observed by magnetic force microscope (MFM) when the films were post-annealed at below 500 °C for 180 sec. The in-plane coercivity (Hc//) and perpendicular coercivity (Hc⊥) of FePt film increases significantly to 7.5 and 6.5 kOe respectively as annealing temperature increases to 600 °C. When the annealing temperature is increased to 700 °C, they are increased to 11.1 and 9.5 kOe, respectively, and the domain structure inclines to isolated domain. However, further increasing the annealing temperature to 800 °C, the Hc// and Hc⊥ values decrease to 9.8 and 8.9 kOe respectively due to largely increase the grain size of FePt and change the domain structure from isolation to continuity. On the other hand, in order to transform the FePt film from disordered γ phase to the ordered L10 phase, the annealing time of over 3 seconds is necessary when the film was post-annealed at 700 °C with a high heating rate of 100 °C/sec by RTA technique.

2007 ◽  
Vol 14 (01) ◽  
pp. 141-145
Author(s):  
Q. Y. ZHANG ◽  
S. W. JIANG ◽  
Y. R. LI

The rapid thermal annealing (RTA) process was adapted to crystallize the amorphous ( Ba,Sr ) TiO 3 thin films prepared on Si (111) substrates by RF magnetic sputtering deposition. The effect of annealing temperature, heating rate and duration time on crystallization was studied through X-ray diffraction and atomic force microscopy. The result shows that the crystallinity and grain size were strongly dependent on the temperature, heating rate, and duration time. Higher heating rate leads to smaller grain size. In high heating rate, the grain size shows different dependence of temperature from that of low heating rate. For a heating rate of 50°C/s, the grain size decreased with temperature increasing below 700°C, while after that temperature, the grain size increased slightly with the temperature increasing. At a certain temperature, the crystallinity and surface roughness improved with increase in annealing time, while grain size changed little. The effect of rapid heating rate on the nucleation and grain growth has been discussed, which contributes to the limited grain size of the annealed ( Ba,Sr ) TiO 3 thin films.


2016 ◽  
Vol 879 ◽  
pp. 350-355
Author(s):  
Fatayalkadri Citrawati ◽  
Md Zakaria Quadir ◽  
Paul Munroe

In this study the effects of heating rate on the sharpness and size of Goss oriented ({110}<001>) grains during secondary recrystallization annealing at 900 °C was observed. The results show that, at the same annealing temperature, rapid heating of the samples to this temperature generates a higher drag force compared to a slower heating rate (5°C/min). The two groups of samples show different growth kinetics for Goss grains, in which at the longest annealing time, the rapid heating sample exhibits larger maximum Goss grain size compared to the slower heated samples.


Ceramics ◽  
2021 ◽  
Vol 4 (1) ◽  
pp. 56-69
Author(s):  
Lihong Liu ◽  
Koji Morita ◽  
Tohru S. Suzuki ◽  
Byung-Nam Kim

High strength transparent Y2O3 ceramics were fabricated from commercial powders using spark plasma sintering (SPS) technique by optimizing the heating rate. The heating rate significantly influenced the microstructures and the optical/mechanical properties of the Y2O3 ceramics. Grain growth was limited accordingly with increasing the heating rate. The ball milling process of the commercial Y2O3 powders is likely to further enhance the sinterability during the SPS processing. The dense Y2O3 ceramics, which were sintered by SPS with 100 °C/min, showed good transmittance range from visible to near infrared (IR). For a high heating rate of 100 °C/min, the in-line transmittance at a visible wavelength of 700 nm was 66%, whereas for a slow heating rate of 10 °C/min, it reduced to 46%. The hardness Hv tends to increase with increasing the heating rate and rigorously followed the Hall–Petch relationship; that is, it is enhanced with a reduction of the grain size. The toughness KIC, on the other hand, is less sensitive to both the heating rate and the grain size, and takes a similar value. This research highlighted that the high heating rate SPS processing can fabricate fully dense fine-grained Y2O3 ceramics with the excellent optical and mechanical properties.


2014 ◽  
Vol 616 ◽  
pp. 204-211
Author(s):  
Jiang Hao Liu ◽  
Zheng Yi Fu

The technique of combustion reaction and quick pressing was adopted to prepare dense nanocrystalline ceramics. The densification process of magnesia compact with a particle size of 100 nm was investigated, under the applied pressure of up to 170 MPa, and the temperature of 1740–2080 K with ultra-high heating rate of above 1700 K/min. As a result, pure magnesia ceramics with a relative density of 98.8% and an average grain size of 120 nm was obtained at 1740 K and 170 MPa, while the ones with decreased relative density and increased grain size were produced under the increasing temperature and the identical pressure conditions. The results indicated that grain growth of the nanocrystalline magnesia was effectively restrained by the combined effect of the ultra-high heating rate and the high pressure. Moreover, under the particular sintering conditions, there existed an appropriate temperature range for the preparation of dense nanocrystalline magnesia, and the excessive temperature would not only exaggerate grain growth but also impede densification.


CIRP Annals ◽  
1983 ◽  
Vol 32 (1) ◽  
pp. 47-51 ◽  
Author(s):  
H.J. Xu ◽  
X.C. Tong ◽  
X.S. Zhao ◽  
Y.Z. Zhang ◽  
J. Peklenik

2012 ◽  
Vol 43 ◽  
pp. 23-31 ◽  
Author(s):  
Francesco Carbone ◽  
Alberto C. Barone ◽  
Federico Beretta ◽  
Andrea D’Anna

Open Ceramics ◽  
2021 ◽  
Vol 8 ◽  
pp. 100182
Author(s):  
Mirele Horsth Paiva Teixeira ◽  
Vasyl Skorych ◽  
Rolf Janssen ◽  
Sergio Yesid Gómez González ◽  
Agenor De Noni Jr ◽  
...  

Author(s):  
T. Pikula ◽  
T. Szumiata ◽  
K. Siedliska ◽  
V. I. Mitsiuk ◽  
R. Panek ◽  
...  

AbstractIn this work, BiFeO3 powders were synthesized by a sol–gel method. The influence of annealing temperature on the structure and magnetic properties of the samples has been discussed. X-ray diffraction studies showed that the purest phase was formed in the temperature range of 400 °C to 550 °C and the samples annealed at a temperature below 550 °C were of nanocrystalline character. Mössbauer spectroscopy and magnetization measurements were used as complementary methods to investigate the magnetic state of the samples. In particular, the appearance of weak ferromagnetic properties, significant growth of magnetization, and spin-glass-like behavior were observed along with the drop of average grain size. Mössbauer spectra were fitted by the model assuming cycloidal modulation of spins arrangement and properties of the spin cycloid were determined and analyzed. Most importantly, it was proved that the spin cycloid does not disappear even in the case of the samples with a particle size well below the cycloid modulation period λ = 62 nm. Furthermore, the cycloid becomes more anharmonic as the grain size decreases. The possible origination of weak ferromagnetism of the nanocrystalline samples has also been discussed.


2017 ◽  
Vol 105 ◽  
pp. 642-647
Author(s):  
Tian Li ◽  
Yanqing Niu ◽  
Liang Wang ◽  
Terese Løvås

2020 ◽  
Vol 1 ◽  
Author(s):  
L. A. Villegas-Armenta ◽  
R. A. L. Drew ◽  
M. O. Pekguleryuz

AbstractEarlier work by the authors suggested that the formation of molten eutectic regions in Mg-Ca binary alloys caused a discrepancy in ignition temperature when different heating rates are used. This effect was observed for alloys where Ca content is greater than 1 wt%. In this work, the effect of two heating rates (25 °C/min and 45 °C/min) on the ignition resistance of Mg-3Ca is evaluated in terms of oxide growth using X-ray Photoelectron Spectroscopy. It is found that the molten eutectic regions develop a thin oxide scale of ~100 nm rich in Ca at either heating rate. The results prove that under the high heating rate, solid intermetallics are oxidized forming CaO nodules at the metal/oxide interface that eventually contribute to the formation of a thick and non-protective oxide scale in the liquid state.


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