DEFROSTING OF ANIMAL COLOSTRUM IN A RING RESONATOR OF ULTRA-HIGH FREQUENCY INSTALLATION

The article is devoted to the development of a two-resonator ultra-high-frequency (UHF) installation for defrosting and warming up animal colostrum, which ensures electromagnetic safety during continuous operation. As well as the development and study of the parameters of a microwave installation, which allows defrosting and uniformly warming up colostrum of animals in the field of a standing wave in the electromagnetic field of a traveling wave. A microwave installation is described with working chambers arranged in tiers in the form of an annular and conical resonators, containing, respectively, dielectric containers and dielectric conical plates. The out-of-limit waveguide is calculated and the radiation of the electric field through the loading hole is considered in the absence of the out-of-limit waveguide at a distance from the ring resonator that is greater than the wavelength. For uniform defrosting of colostrum in plastic bottles, they should be moved in a ring resonator and the magnetrons should be positioned with a shift of 120 degrees around the perimeter. Then the resulting strength of the electric field consisting of several initial fields will be equal to the vector sum of their strengths. To achieve a high heating rate of raw materials in the region of positive temperatures, it is necessary to provide a condition for heating a thin layer of liquid with the help of coaxially located conical dielectric trays

The Role of the Activator Additives Introduction Method in the Cold Sintering Process of ZnO Ceramics: CSP/SPS Approach

The great prospects for introducing the cold sintering process (CSP) into industry determine the importance of finding approaches to reduce the processing time and mechanical pressure required to obtain dense ceramics using CSP. The introducing zinc acetate into the initial ZnO powder of methods, such as impregnation, thermovapor autoclave treatment (TVT), and direct injection of an aqueous solution into a die followed by cold sintering process using a spark plasma sintering unit, was studied. The effect of the introduction methods on the density and grain size of sintered ceramics was analyzed using SEM, dynamic light scattering, IR spectroscopy, and XRD. The impregnation method provides sintered samples with high relative density (over 0.90) and significant grain growth when sintered at 250 °C with a high heating rate of 100 °C/min, under a uniaxial pressure of 80 MPa in a vacuum, and a short isothermic dwell time (5 min). The TVT and aqueous solution direct injection methods showed lower relative densities (0.87 and 0.76, respectively) of CSP ZnO samples. Finally, the development of ideas about the processes occurring in an aqueous medium with CSP and TVT, which are subject to mechanical pressure, is presented.

Investigation of MXenes Oxidation Process during SPS Method Annealing

This paper discusses the effects of the environment and temperature of the Ti3C2 (MXene) oxidation process. The MXene powders were annealed at temperatures of 1000, 1200, 1400, 1600, and 1800 °C in argon and vacuum using a Spark Plasma Sintering (SPS) furnace. The purpose of the applied annealing method was to determine the influence of a high heating rate on the MXene degradation scheme. Additionally, to determine the thermal stability of MXene during the sintering of SiC matrix composites, SiC–C–B–Ti3C2 powder mixtures were also annealed. The process parameters were as follows: Temperatures of 1400 and 1600 °C, and pressure of 30 MPa in a vacuum. Observations of the microstructure showed that, due to annealing of the SiC–C–B–Ti3C2 powder mixtures, porous particles are formed consisting of TiC, Ti3C2sym, and amorphous carbon. The formation of porous particles is a transitional stage in the formation of disordered carbon structures.

Catalytic Fast Pyrolysis of Lignocellulosic Biomass to Benzene, Toluene, and Xylenes

Catalytic Fast Pyrolysis is a rapid method to depolymerize lignocellulose to its constituent components of hemicellulose, cellulose, and lignin. The pyrolysis reaction in absence of oxygen occurs at a very high heating rate to a targeted temperature of 400 to 600 °C for very short residence time. Vapors which are not condensed and are then contacted with a catalyst that is efficient to deoxygenate and aromatize the pyrolyzed biomass. One class of highly valuable material that is produced is a mixture of benzene, toluene, and xylenes. From this mixture, para-xylene is extracted for further upgrading to polyethylene terephthalate, a commodity polyester which has a demand in excess of 80 million tonnes/year. Addressed within this review is the catalytic fast pyrolysis, catalysts examined, process chemistry, challenges, and investigation of solutions.

Obtaining Zonal Isolation in Geothermal Wells

Cementing is one of the sequences in the drilling operations to isolate different geological zones and provide integrity for the life of the well. As compared with oil and gas wells, geothermal wells have unique challenges for cementing operations. Robust cementing design and appropriate best practices during the cementing operations are needed to achieve cementing objectives in geothermal wells. Primary cementing in geothermal wells generally relies on a few conventional methods: long string, liner-tieback, and two-stage methods. Each has challenges for primary cementing that will be analyzed, compared, and discussed in detail. Geothermal wells pose challenges of low fracture gradients and massive lost circulation due to numerous fractures, which often lead to a need for remedial cementing jobs such as squeeze cementing and lost circulation plugs. Special considerations for remedial cementing in geothermal wells are also discussed here. Primary cement design is critical to ensure long-term integrity of a geothermal well. The cement sheath must be able to withstand pressure and temperature cycles when steam is produced and resist corrosive reservoir fluids due to the presence of H2S and CO2. Any fluid trapped within the casing-casing annulus poses a risk of casing collapse due to expansion under high temperatures encountered during the production phase. With the high heating rate of the geothermal well, temperature prediction plays an important part in cement design. Free fluid sensitivity test and centralizer selection also play an important role in avoiding mud channeling as well as preventing the development of fluid pockets. Analysis and comparison of every method is described in detail to enable readers to choose the best approach. Massive lost circulation is very common in surface and intermediate sections of geothermal wells. On numerous occasions, treatment with conventional lost-circulation material (LCM) was unable to cure the losses, resulting in the placement of multiple cement plugs. An improved lost circulation plug design and execution method are introduced to control massive losses in a geothermal environment. In addition, the paper will present operational best practices and lessons learned from the authors’ experience with cementing in geothermal wells in Indonesia. Geothermal wells can be constructed in different ways by different operators. In light of this, an analysis of different cementing approaches has been conducted to ensure robust cement design and a fit-for-purpose cementing method. This paper will discuss the cementing design, equipment, recommendations, and best available practices for excellence in operational execution to achieve optimal long-life zonal isolation for a geothermal well.

Zirconium alloyed tungsten borides synthesized by spark plasma sintering

Tungsten borides (WBx; x = 2.5 or 4.5) with an increasing substitution of tungsten by zirconium from 0 to 24 at.% were synthesized by spark plasma sintering (SPS) for the first time. The influence of the holding time (2.5–30 min) on the densification behavior, microstructure evolution and development of the properties of W–Zr–B compounds were studied. The samples were characterized using scanning electron microscopy (SEM) for microstructure analysis, X-ray diffraction (XRD) for phase identification, Vickers micro-indentation for microhardness measurements, tribological tests to determine the coefficient of friction and specific wear rate, as well as measurements of electrical conductivity. The XRD results confirm the presence of the WB4 phase in the microstructure, despite the high sintering temperature (1800 °C) and small overstoichiometric excess of boron (4.5) addition in the sintered samples. This is caused by the high heating rate (400 °C/min), short holding time (2.5 min) and addition of zirconium. The Vickers hardness (HV) values measured at 1 N are 24.8 ± 2.0 and 26.6 ± 1.8 GPa for 24 at.% zirconium in WB2.5 and for 0 at.% zirconium in WB4.5, respectively. In addition, the hardest sample (W0.76Zr0.24B2.5) showed electrical conductivity up to 3.961·106 S/m, which is similar to WC–Co cemented carbides. The friction and wear test results reveal the formation of a boron-based film which seems to play the role of a solid lubricant.